`
`I,
`
`of
`
`VERIFICATION OF TRANSLATION
`
`Rumiko Whitehead
`
`1950 Roland Clarke Place
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`Reston, VA 20191
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`declare that I am well acquainted with both the Japanese and English languages, and that
`the attachecl is an accurate translation, to the best of my knowledge and ability, of
`Japanese Unexamined Patent Application Publication No. H08-214098, published
`
`October 18, 1996.
`
`I further declare that all statements made herein of my own knowledge are true and that
`all statements made on information and belief are believed to be true; and further that
`these statements were made wìth the knowledge that willful false statements and the like
`so made are punishable by fine or irnprisonment, or both, under Section 1001 of Title 18
`of the United States Cocle and that such willful false statements may jeopardize the
`validity of the above-captioned application or any patent issuecl thereon.
`
`Signature
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`2
`Rumiko Whitehead
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`Date
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`à
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`7.ol
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`{J70ee0s 030 l 4284.Doc}
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`Page 1 of 8
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`IP Bridge Exhibit 2019
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`IPR2016-01264
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`(19) Japan Patent Office (JP)
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`(12) Unexamined Patent Application
`Publication (A)
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`(11) Patent Application Publication
`No.
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`H08-274098
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`(43) Publication Date October 18, 1996
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`(51) Int.Cl6
`H01L 21/3205
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`21/768
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`Identification
`Symbol
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`Patent Office
`Ref. No.
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`H01L 21/88
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`21/90
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`B
`R
`A
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`Display of
`Technology
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`Request for Examination Not requested Number of claims 4 OL (4 pages total)
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`(21) Application No.
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`(22) Application Date
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`H07-76699
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`March 31, 1995
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`(71) Applicant
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`
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`(72) Inventor
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`(74) Agent
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`000002369
`Seiko Epson Corporation
`2-4-1, Nishi-shinjuku, Shinjuku-ku,
`Tokyo
`Takako Inoue
`Seiko Epson Corporation
`3-3-5, Owa, Suwa-shi, Nagano
`Patent Agent Kisaburo Suzuki (and
`one other)
`
`(54) [Title of Invention] Semiconductor Device and Manufacture Method of Semiconductor Device
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`(57) [Abstract]
`[Structure] A wiring structure of a multi-layered
`wiring semiconductor device characterized by the
`entire upper portion, lower portion, and side walls of
`a metal wiring being covered by a barrier metal. A
`semiconductor device characterized by a first metal
`wiring layer formed on a first insulating film formed
`on a semiconductor substrate, in which the first metal
`wiring layer is formed such that the side walls, lower
`portion and upper portion thereof are covered by a
`second metal wiring layer, and in which the second
`and subsequent wiring layers of a semiconductor
`device having a multi-layered wiring structure are
`similarly formed, and a manufacturing method
`thereof.
`[Purpose] To dramatically improve the reliability,
`and in particular the electromigration resistance, of
`metal wiring layers. Even when a high current is
`applied, metal, such as aluminum and the like from
`wiring materials, is prevented from moving and
`flowing out from side walls that are not in contact
`with TiN and causing disconnection failure. In
`addition to aluminum, the first metal wiring layer
`may be primarily composed of copper, gold, silver,
`zinc, platinum or iron; a second metal wiring layer
`may be primarily composed of titanium, tungsten,
`molybdenum, titanium nitride, tungsten nitride or
`molybdenum nitride.
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`[Scope of Claims]
`[Claim 1] A semiconductor device characterized by a first metal wiring layer formed on a first insulating
`film formed on a semiconductor substrate, in which the first metal wiring layer is formed so that side
`walls and a lower portion and an upper portion thereof are covered by a second metal wiring layer, and in
`which the second and subsequent wiring layers of a semiconductor device having a multi-layered wiring
`structure are similarly formed.
`
`[Claim 2] In the semiconductor device according to the aforementioned Claim 1, a first primary
`component metal is at least aluminum, copper, gold, silver, zinc, platinum, or iron, and a second primary
`component metal is at least titanium, tungsten, molybdenum, titanium nitride, tungsten nitride, or
`molybdenum nitride.
`
`[Claim 3] With respect to a manufacturing method of a semiconductor device, a manufacturing method of
`a semiconductor device characterized by including at least a process of forming a first insulating film, a
`process of forming TiN, a process of forming aluminum, a process of patterning the aforementioned
`aluminum, a process of again forming TiN, and a process of forming the aforementioned TiN to be larger
`than the aluminum.
`
`[Claim 4] With respect to a manufacturing method of a semiconductor device, a manufacturing method of
`a semiconductor device characterized by including at least a process of forming a first insulating film, a
`process of forming TiN, a process of forming aluminum, a process of patterning the aforementioned
`aluminum, a process of again forming TiN to be thick, and a process of subjecting the aforementioned
`TiN to anisotropic etching.
`
`[Detailed Description of Invention]
`[0001]
`[Field of Industrial Application] The present invention relates to a structure of, and a manufacturing
`method of, a semiconductor device having a multi-layered wiring structure.
`
`[002]
`[Prior Art] Conventionally, as shown in Fig. 3, a barrier metal, the aforementioned first metal wiring layer,
`and a barrier metal are formed in this order on a first insulating film formed on the aforementioned
`semiconductor substrate, and then formed into a desired pattern through photolithography and etching
`processes. Thereafter, a first interlayer insulating film is formed. In this structure, only the lower and
`upper portions of the metal wiring are in contact with the barrier metal and the barrier metal is not formed
`on a side wall portion.
`
`[0003]
`[Problem to Be Solved by the Invention] However, as wiring structures have become increasingly multi-
`layered and finer in size, it is becoming difficult to sufficiently ensure reliability of metal wiring with
`conventional technology. When a high current is applied to metal wiring according to the conventional
`technology in order to test the reliability thereof, there is an issue in which a portion of the metal wiring
`moves and takes on a form as if it melted out from the side wall portion of the metal wiring that is not in
`contact with the barrier metal made of Ti or TiN, causing disconnection failures.
`
`[0004] The present invention solves this issue and the purpose thereof is to enable improvement of the
`reliability of metal wiring by covering the entire surface of metal wiring with a barrier metal.
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`[0005]
`[Means of Solving the Problem] A semiconductor device according to the present invention is
`characterized by a barrier metal covering the side walls and upper and lower sides of the aforementioned
`metal wiring formed on the aforementioned first insulating film formed on the aforementioned
`semiconductor substrate.
`
`[0006]
`[Embodiments] Fig. 3 is a cross-sectional view of a conventional semiconductor device. Fig. 2 is a cross-
`sectional view of a semiconductor device according to one embodiment of the present invention. Figs.
`1(a) through (d) are main cross-sectional views of each manufacturing process of a manufacturing method
`according to another embodiment (Claim 2) of the present invention. Figs. 4(a) through (d) are main
`cross-sectional views of each manufacturing process of a manufacturing method according to another
`embodiment (Claim 3) of the present invention. In all of the figures of the embodiments, parts having the
`same function are indicated by identical reference numerals, and redundant explanations thereof are
`omitted. Below, the manufacturing method (Claim 2) will be explained step by step with reference to
`Figs. 1(a) through (d).
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`[0007] (Embodiment 1) A first embodiment is described with reference to Fig. 1. First, as shown in Fig.
`1(a), using a chemical vapor deposition (CVD) method, an insulating film 102 composed of silicon
`dioxide film is formed [in a thickness of] approximately 500 nm on a semiconductor substrate 101. Next,
`as shown in Fig. (b), using a sputtering method, a second metal wiring layer 103 having a thickness of
`about 40 nm and a metal wiring layer (composed of aluminum, copper and the like) having a thickness of
`500 nm are formed. Next, as shown in Fig. (c), by applying photolithography, in which photoresist is
`used as a masking material, and an etching process, a first wiring layer 104 having a width of
`approximately 1.2 µm is formed. Thereafter, again using the sputtering method, a second metal wiring
`layer 105 is formed on the entire surface in a thickness of about 40 nm. Next, as shown in Fig. (d), by
`applying the photolithography and etching methods, the aforementioned second wiring layer is formed to
`have a width of approximately 1.6 µm, so as to have a width wider than the width of the aforementioned
`first metal wiring layer (approximately 1.2 µm).
`
`[0008] Up to the second wiring layer is formed as described above; third and subsequent wiring layers are
`similarly formed.
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`[0009] Fig. 2 shows a cross-sectional view of a semiconductor device in which up to the third wiring
`layer is formed.
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`[0010] First, using a chemical vapor deposition (CVD) method, an insulating film 202 composed of
`silicon dioxide film is formed [in a thickness of] approximately 500 nm on a semiconductor substrate 201.
`Next, using a sputtering method, a second metal wiring layer 203 having a thickness of about 40 nm and a
`metal wiring layer (the material thereof being aluminum, copper and the like) having a thickness of 500
`nm are formed, and then, by applying photolithography, in which photoresist is used as a masking
`material, and an etching process, a first wiring layer 204 having a width of approximately 1.2 µm is
`formed. Thereafter, again using the sputtering method, the second metal wiring layer is formed on the
`entire surface in a thickness of about 40 nm. By applying the photolithography and etching methods, the
`aforementioned second wiring layer is formed to have a width of approximately 1.6 µm, so as to have a
`width wider than the width of the aforementioned first metal wiring layer (approximately 1.2 µm). Next,
`using the CVD method, an interlayer insulating film 205 composed of silicon dioxide film is formed in a
`thickness of approximately 800 nm. After forming the aforementioned first interlayer insulating film, a
`hole of about 0.7 µm is formed by applying the photolithography and etching processes. Thereafter,
`using the sputtering method, the second metal wiring layer having a thickness of about 40 nm and a metal
`wiring layer having a thickness of 500 nm are formed on the entire surface, and then a third wiring layer
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`207 is formed by applying photolithography, in which photoresist is used as the masking material, and the
`etching process. Thereafter, again using the sputtering method, the second metal wiring layer is formed
`on the entire surface in a thickness of about 40 nm. Using the photolithography and etching methods, the
`aforementioned barrier metal is formed so as to have a width that is slightly wider (by about 0.4 µm) than
`the width of the aforementioned second wiring layer.
`
`[0011] (Embodiment 2) Next, a second embodiment is described with reference to Fig. 4. First, as shown
`in Fig. 4(a), using a chemical vapor deposition (CVD) method, an insulating film 402 composed of silicon
`dioxide film is formed [in a thickness of] approximately 500 nm on a semiconductor substrate 401. Next,
`as shown in Fig. (b), using a sputtering method, a second metal wiring layer 403 having a thickness of
`about 40 nm and a first metal wiring layer (the material thereof being aluminum, copper and the like) 404
`having a thickness of 500 nm are formed, and then a second metal wiring layer 405 is again formed in a
`thickness of 40 nm. By applying photolithography, in which photoresist is used as a masking material,
`and the etching process, the first metal wiring layer 404 having a width of approximately 1.2 µm is
`formed. Thereafter, again using the sputtering method, the second metal wiring layer is formed on the
`entire surface in a thickness of about 500 nm. The aforementioned barrier metal is subjected to
`anisotropic etching by an etch-back method.
`
`[0012] The foregoing describes a manufacturing method characterized by covering the entire surface,
`such as the side walls, upper portion and lower portion, of the aforementioned first metal wiring layer 404,
`with the aforementioned second metal wiring layer.
`
`[0013] The invention created by the present inventor is described in detail above based on the
`aforementioned embodiments; however, the present invention is not limited to the aforementioned
`embodiments, and modifications are of course possible to the extent that they do not depart from the
`scope of the present invention. For example, the multi-layered wiring can be three layers or more. Also,
`in addition to aluminum, similar effects are obtained even when the first metal wiring layer is primarily
`composed of copper, gold, silver, zinc, platinum, or iron. Further, similar effects are obtained when the
`second metal wiring layer is primarily composed of titanium, tungsten, molybdenum, titanium nitride,
`tungsten nitride, or molybdenum nitride.
`
`[0014]
`[Effects of the Invention] As stated above, according to the present invention, since the side walls, the
`lower portion and the upper portion of the first metal wiring layer are covered by the second metal wiring
`layer, even when a high current is applied to the metal wiring layers, aluminum and the like which are
`used in the first metal wiring layer will not move and flow out from the side walls that are not in contact
`with the second metal wiring layer. Thus, the reliability, and in particular the electromigration resistance,
`of metal wiring layers is improved dramatically, which makes it possible to accommodate, in particular,
`the increasing miniaturization and multi-layering of metal wiring.
`
`[Brief Description of Drawings]
`[Fig. 1] are main cross-sectional views to describe, step by step, an example of a manufacturing method
`of a semiconductor device according to the present invention.
`[Fig. 2] is a main cross-sectional view of an embodiment of a semiconductor device according to the
`present invention.
`[Fig. 3] is a main cross-sectional view of a conventional semiconductor device.
`[Fig. 4] are main cross-sectional views to describe, step by step, another example of a manufacturing
`method of a semiconductor device according to the present invention.
`
`[Description of Reference Numerals]
`101 ...semiconductor substrate
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`H08-274098
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`102 ...first insulating film
`103 ...second metal wiring layer
`104 ...first metal wiring layer
`105 ...second metal wiring layer
`201 ...semiconductor substrate
`202 ...first insulating film
`203 ...barrier metal
`204 ...first metal wiring layer
`205 ...first interlayer insulating film
`206 ...second metal wiring layer
`207 ...third metal wiring layer
`301 ...semiconductor substrate
`302 ...first insulating film
`303 ...second metal wiring layer
`304 ...first metal wiring layer
`305 ...first interlayer insulating film
`306 ...second metal wiring layer
`307 ...third metal wiring layer
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`[Fig. 1]
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`H08-274098
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`[Fig. 2]
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`[Fig. 3]
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`[Fig. 4]
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