`
`
`
`POLVFLON Papers
`
`POLYFLON Paper is a new type of permeable
`sheet developed by Daikin. POLYFLON Paper
`is made of PTFE (tetrailuoroetylene resin),
`and contains no impurities such as binders.
`it
`Although it looks like ordinary filter paper,
`exhibits superior flexibility and elasticity, and
`shows no chemical or physical change at
`temperatures up to 260°C. POLYFLON Paper
`is theretore a permeable sheet having the
`superior thermal and chemical properties of
`POLYFLON PTFE.
`
`
`
`
`
`
`
`
`
`
`
`
`
`Feature
`‘
`POLYFLON Paper possesses the lotion
`
`
`
`superior prdperties by merit oi fluorin
`'
`,
`atomsrnrts ole larstructure:
`*
`
`
`Iehperature range
`OWIdeserv'
`(-IIIIt“C~2_eII_“€i
`,_
`*
`
`.Superrorchemicalresistance
`POLYFLON PaperIsnet harmed any‘o
`acids, alkais, "oxidizers or organic solvents
`
`with the exception at special chemical a
`
`fluorine. gas (elemental fluorine), chloriII
`
`.
`trilluoride,abd-tuSedalkalinemetals,
`
`_
`.Low surface‘tension
`
`Although POLYFLON Paper is wet with low
`surface tension liquids,
`it tends not to b
`wet with high surface tension liquids
`POLYFLON Paper can separate liquidse‘
`mixture tor example water and oil,carbon
`tetrachloride or perchloroethylene.
`
`
`
`Major Application
`
`
`
`‘
`
`
`
`
`OUntque properties
`POLYFLON Paper is ot great use to
`cushion sheet for the production process 0
`
`LCD utilizing the following excelten
`
`properties
`
`,
`,
`1.Contamination tree
`2.Excellentthermal and chemicalresistance
`
`3Cushioning (unilonn transmission or pressure)
`4.Unstuck on glass '(e‘esy removali
`,
`
`5.Emdure to repeated use,
`
`Table.BasicProperties ofPOLYFLON Papers
`
`PA-‘SLH.
`,
`averagedangerninwnax)
`.PMOLt-l
`wacelranoemimmeo
`
`,
`
`

`

`.
`
`.
`
`
`
`EGO-9b
`(Except for USA)
`
`
`
`Technical Information
`
`TM:DAiKiN INDUSTRIES trademark for its Fluoroplastics
`
`PA-5LHg PA-10LH
`POLYFL MM Papers
`
`
`DAIKIN INDUSTRI‘ES.LTD. Chemical Division.
`
`

`

`_ O
`»,
`POLYFLON Papers_
`
`
`O
`
`
`
`Relation between POLYFLON Paper's cutting direction and
`Shrinkage ratio.
`
`TD(Transversely direction)
`
`/ wMachine direction)
`
`
`
`
`a roll of paper
`
`Comparioson of paper's
`shrinkage ratio
`MD>>TD
`
`,
`WIdth
`
`
`
`~5%> >~3%(at 180°C)
`
`
`
`
`Relation between POLYFLON F'aper's thickness and trial cycles
`1cycle: (temp.25°C,tim:e 2h,pressure 0.04MPa)
`
`1000 l———-
`900
`800
`
`_‘_—“‘-’——'
`
`
`700
`
`500
`400
`
`300
`
`200
`
`E3
`
`.v
`U)
`(D
`a)
`
`cx.
`
`9.c
`l—
`
`100
`
`0
`
`
`
`—-— 5LH
`
`______.____.
`
`
`
`0
`
`20
`
`40
`
`60
`
`80
`
`1‘00
`
`120
`
`140
`
`160
`
`180
`
`200
`
`Cycle number(cycles)
`
`
`
`

`

`Technical
`
`information
`
`
`Relation between POLYFLON F’aper's shrinkage and trial cycles
`1cycle:room temperature,time 2h,
`(pressure 0.04MPa)
`
`1
`
`,5
`2E
`8
`x
`6‘_l
`
`a
`
`110
`
`105
`
`100
`
`95
`
`90
`
`
`
`. 5LH/TD(%)
`o 5LH/MD(%)
`
`
`.10LH/TD(%)
`
`
`A1OLH/MD(%)
`
`3
`
`O
`
`20
`
`4O
`
`60
`
`80
`
`100 120 140 160 180 200
`
`Cycle number(cycles)
`
`
`
`
`
`Relation between POLYFLON F'aper's thickness and trial cycles
`1cycle: (temp.180°C,heatinag time 7h,pressure 0.06MPa)
`
`1 000
`
`900
`
`800
`
`700
`600
`
`500
`400
`
`300
`
`200
`
`100
`
`0
`
`Thickness(pm)
`
`
`
`"
`
`—-— PA-5LH
`
`—-— PA-1OLH
`
`0
`
`1O
`
`2O
`
`30
`
`40
`
`50
`
`60
`
`Cycle number(cycles)
`
`
`
`
`
`
`

`

`,
`
`_ 0
`
`I
`
`POLYFLON Papers_
`
`
`Relation between POLYFLON F’aper's shrinkage and trial cycles
`1cycle:temperature 180°C,heating time 7h,
`No.1 (pressure 0MPa), No.2 (pressure 0.06MPa)
`
`
`
`
`
`
`
`I No.1:fl'D(%)
`El No.1:/MD(%)
`. No.2:/TD(%) -
`o No.2:/MD(°/o)
`
`
`
`
`104
`
`1 03
`
`102
`
`101
`
`1 00
`
`99
`
`98
`
`97
`
`96
`
`95
`
`94
`
` (L/L0)><100(%)
`
`0
`
`10
`
`20
`
`30
`
`4O
`
`50
`
`60
`
`7O
`
`Cycle number(cycles)
`
`
`
`Evaluation of POLYFLON Paper's Compression propeties
`(Kato Tech., KES G5 Hancly type compression tester)
`Piston
`
`s
`
`compression directior
`
`—-> P(Pa)
`pressure
`
`Fig.Compression curve of paper
`Compression working amounts(Pa)=a+b
`Restoration working amounts(Pa)=b
`
`
`
`

`

`
`
`Technical
`
`information
`
` —1
`
`Relation between POLYFLON Paper's thickness and Compression
`restoration ratio at 25°C
`(Kato Tech., KES G5 Handy type compression tester)
`
`
`
`
`
`Compressionrestoration
`
`30
`
`20
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`200
`
`300
`
`400
`
`500
`
`600
`
`700
`
`800
`
`900
`
`1000
`
`1100
`
`Sheet Th ickness( p m)
`
`

`

`Caution
`
`The following points should be followed to ensure safety when handling POLYFLON PAPER
`°WARNING:VAPORS HARMFUL IF INHALED.
`
`The work area should be adequately ventilated at all times, because HF. COFZ begin to be produced at approximately higher
`then 260°C and the volume increases at approximately 380”C. IF PTFE is incinerated, the acidic gases must be removed by
`alkaline scrubbing techniques.
`
`'Personnel should be cautioned against inhaling the fumes liberated during processing and provided with suitable protective
`equipment.
`
`~Smoking should be prohibited in work areas. since smoking fluoropolymer contaminated tobacco may result in inhalation of
`decomposed gas.
`Do not bring tobacco in the work area.
`~Avoid breathing dust and contact with eyes.
`'Wash hands and face after handling.
`«Waste generated during processing should be treated by waste treatment specialists and/or licensed waste contractor
`disposed of in accordance with federal, state and local waste disposal regulations.
`
`Read the "Material Safety Data Sheet" before use.
`
`IMPORTANT NOTlCE
`
`The information contained herein is based on technical data and tests we believe to be reliable and is intended for use by persons having
`technical knowledge and skill, solely at their own discretion and risk. Since conditions of use are outside of our control. we assume no
`responsibility for results obtained or damages incurred through application of the data given: and the publication of the information herein
`shall not be understood as permission or recommendation for the use of our fluorocarbon compounds in violation of any patent or enter-
`wise. We only warrant that the product conforms to description and specification, and our only obligation shall be to replace goods shown
`to be defective or refund the original purchase price thereof.
`
` HMEleCAL use .
`This product is not specifically designed or manufactured for use in implantable medical and/or dental devices. We have not tested it for
`such application and will only sell it for such use pursuant to contract containing specific terms and conditions required by us.
`
`
`DAIKIN INDUSTRIES,LTD., DAIKIN AMERICA,INC.and DAllKIN CHEMICAL NETHERLANDS B.V. have obtained the ISO
`
`
`14001('1) certification for the environmental management system, and the ISO 900102) certification for the quality
`
`
`management system in our fluorochemical plants.
`
`*1. 180 14001 is a standard established by the ISO (International Organization for Standardization) which applies to environmental
`preservation activities. Activities. products and services of our company have been certified as being environmentally sound by an
`internationally recognized certification body.
`*2. ISO 9001 is a standard established by the iso and applied to quality management system.
`DAIKIN INDUSTRIES. LTD. Chemical Division,DAlKlN AMEFiliCA,INC.and DAIKIN CHEMlCAL EUROPE GmbH have been certified
`by an internationally recognized certification organization for our ability to consistently provide products, which satisfy customer's
`demand and applicable regulatory requirements.
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`(Agency)
`DAIKIN CHEMICAL SALES, LTD.
`Toshin-Kanda Bldg. 14,
`Kanda Matsushita-Cho,
`Chiyodaku, Tokyo 101 -0042. Japan.
`Phone:
`+81 -3-5256-0164
`URL:www.daikin-dcs.co.jp
`
`(Manufacturer)
`DAIKIN INDU$TRIES. LTD.
`Chemical Division
`URL:www.daikin.co.jlp/chm
`
`
`
`$692004 EGG-9b Al
`
`

`

`
`
`‘\
`
`ECG-15a
`
`Easy to use and extremely versatile
`
`Ultra-weatherp of, dirt resistant fluorocarbon-based varnish.
`
`
`
`

`

`C
`
`.
`
`”Easy-to-use ”and ”Tough ”
`
`Both of these great performances
`
`are superbly coordinated. .
`
`
`
`
`
`
`
`What is ZEFFLE?
`
`ZEFFLE is an easy—muse, ultra—weatherproof and highly dirt resistant fluorocarbo
`f
`A
`has been developed by Daikin Industries. It protects surfaces against even u d
`environmental conditions and maintains an attractive outward appearance for‘flgongd m
`expanding the number of applications for a wide range of coatings such as to
`industrial equipments and bridges.
`
`
`
`ZEFFLE protects surfaces and maintains attractive outward
`appearance for long periods of time.
`
`semi-permanent
`ZEFFLE offers
`protection for substrates even
`.
`.
`.
`.
`(1
`h
`2:121:11;
`acxd
`ra1n
`an
`hug
`
`ZEFFLE is highly resistant to
`dirty, and is easy to clean even
`if it should become dirty.
`
`

`

`
`
`Curing Type
`
`
`Lacquer Type
`basic
`its
`as
`tetrafluoro-ethylene
`Besides its excellent weather resistance and
`With
`
`‘ mdirt resistant,
`this novel new fluorocarboh-
`component, This type has the high fluorine
`: :basedr varnish comes in a Lacquer Type WhiC‘h
`content is, and no chlorine, as is the only
`‘dries at normal
`temperature, making 1“
`weather-resistant fluorocarbon coating material
`
`
`on the market. It's the reasons for greater
`“strength and higher durability of the series.
`
` are available to suit
`
`
`.applicati
`
`eeds
`
`'
`
`
`
`
`and
`free
`from the
`surface
`
`ated problems
`such as
`tensron
`
`Low
`
`
`
`oreover. over-coating, touching-
`‘ up and recoats can made freely.
`
` Strong
`oWeather
`bonding
`resistance
`
`
`
`
`OChemical
`resnstance
`—> oDirt resistance
`
`—> oLow wettability
`
`energy
`
`2.58M“)?G .
`
`(C-CE tbOfl‘)
`
`

`

`O
`
`IApplications
`ZEFFLE‘s high level of performance is shown by
`its many applications.
`
`
`
`
`
`
`

`

`m
`
`t
`5,
`
`mg.
`
`m‘
`
`

`

`I Coating properties
`
`
`, Curing type
`_§La"‘cique'r type «
`‘
`
`--; 533;; my Acrylic -'
`\
`1%,
`
`;
`the market ‘ Silicone a: _
`
`
`
`Mitsubishi UNI
`H
`
`
`
`
`1 00/1 00
`1 00/1 00
`Nichiban
`’ Cross cut adhesiéri
`1 00/1 00
`
`Dupohfiimpacuci‘ri)
`1 0
`5009.1 /2inch
`
`
`>1
`.1
`
`
`erma‘nent
`marker
`
`esistance
`VTest piete system
`
`
`
`
`
`
`
`
`x
`x
`
`I
`
`‘VO‘Substrate : Bn#T44steel(ZnP04treatment)
`
`OPrimer : Epoxy
`
`OTop coat: White
`
`
`
`IACcelerated weathering test
`
`(D Gloss Retention (white film)
`
`(Testing with; super ~UV tester for 1,000 hours is estimated to be correspond to 20 years of ac 3i user)
`
`
`
`
`GlossRetention(%)
`
` ~ -0— A LC-930
`
`-——-O—— GK57O
`on the market
`_ Cl _ Fluoro Varnish I
`- - A — - Acrylic urethane
`- - (>- - Acrylic lacquer
`
` - - - * - - - Acrylic silicone
`
`
`
`Time (hr)
`
`ITop coat : White
`
`ITest machine : Super UV tester type W-1 3
`(IWASAKI electoric. co. Ltd.)
`
`iICondition : Cycle mam >
`{3:53:13}I
`Black panel temp,
`70%
`63°C
`
`1 00%
`30°C
`85%
`63°C
`
`Showerz‘l Oseconds/hr
`
`Test piece System
`OSubstrate : Bn#144steel(ZnPOatreatment)
`IPrimer : Epoxy
`
`spotrnormal
`temperature,
`Leave for 2 weeks
`
`_,Acryiic“
`~lacquer
`70~75
`
`._
`
`_
`
`,
`
`-
`
`3x
`
`x
`
`
`
`
`x
`
`V
`
`
`
`linkedwith SAKURA MARKER
`,‘
`:
`magamc solimoii].
`'
`
`gggifhours, w‘ped w'th
`
`
`
`
`
`
`
`

`

`
`
`® Coating surface after SUV test
`Scanning electron microscope photographs taken
`after 1,000 hours of exposure to a super UV tester
`IWhite coating (base/primer/white coatings from
`different companies)
`OMagnification2500
`
`Scanning electron microscope photographs taken
`after 1,000 hours of exposure to a super UV tester
`'Clear coating (base/primer/white coatings from
`other companies)
`0Magnification:50
`
`
`
`
` (According to Japan Highway
`
`INeutralization
`p r e V e n t i O n t e S t
`
`Public Corporation standards)
`When the blocks immersed into carbon dioxide gas, the non—
`coated sections (photo n'ght)were neutralized (white area),
`whereas the alkalinity of the coated sections (photo left,
`green area) was maintained (red area).After becoming
`neutralized, steel corrosion is accelerated and cracks and
`chipping Stan appearing in the concrete.
`
`—1 month after test (concrete cross-section) —
`
`LC-930 coated section
`
`Non coated section(both Sides)
`
`i‘—-l
`*— Non Neutralization —> Neutralimnon
`0mm
`1 5mm
`
`l-—~i
`Neutralization
`17mm
`
`

`

`Cautions on handling and storing - - - - - ‘ ' ' ' 1| Store in a cool, dark place with adequate ventilation.
`W Wash hands well after handling. Be particularly
`careful to wash hands before eatingor smoking.
`0 Do not inhale the vapors, spray mist or the fumes
`which are given out during application. Be sure to
`provide adequate ventilation (such as
`installing
`localized air circulation equipment) when using.
`'I The solvent used in this product may irritate the
`skin and membranes, particularly eyes, so avoid
`touching it directly. If it should happen to get onto
`skin, wash it off immediately with plenty of water.
`4' This product is flamable liquid, so be extremely
`careful in keeping it away from fire.
`0 Keep container closed when not in use.
`II If disposing of this product, please ask a qualified
`industrial waste disposal agent.
`
` package unit .................................
`
`5
`
`Safe Handling information
`
`contain
`(MSDS)
`a Material Safety Data Sheets
`pertinent information that you may need to protect
`your employees and customers against any known
`health or safety hazards associated our products.
`
`
`
`
`.DAIKIN INDUSTRIES, LTD. and DAIKIN AMERICA. INC. have obtained the ISO 14001(*1)certification which is an intemational
`
`Standard concerning the environmental management system. DAIKIN INDUSTRIES, LTD has obtained the ISO 9001(*2) and DAIKIN
`
`AMERICA. INC. has obtained the ISO 9002(*3)
`
`
`*1. ISO 1 4001 is a standard established by the ISO (International Organization for Standardization) which applies to environmental
`
`
`preservation activities.Activities. products and services of our fluorocrhemicals plant have been certified as being environmentally sound by
`an internationally recognized certification body.
` *2. ISO 9001-2000 is a certification system for quality control established by the ISO which certifies our quality control system
`
`
`concerning our products.
` *3. ISO 9002-1994 is a plant certification system for quality control established by the ISO which certifies our quality control system
`
`concerning manufacture and inspection of the products manufactured at our plant (division)
`
`
`IMPORTANT NOTICE: The information contained herein is besed on technical data and tests we believe to be reliable and is intended
`for use by persons having technical knowledge and sklll, solely at their own discretion and risk. since conditions of use are outside of our
`control. we assume no responsibility for results obtained or damages incurred through application of the data givin; and the publication of
`the information herein shall not be understood as permission or recommendation for the use of our fluorocarbon compounds in violation of
`any patent or otherwise. We only warrant that the product conforms to description and specification, and our only obligation shall he to
`replace goods shown to be defective or refund the original purchase prince there of.
`
`
`
`DAIKIN INDUSTRIES,LTD.
`CHEMICAL DIVISION
`Umeda center Bldg.,
`4-1 2-2-chome, Nakazaki-nishi
`Kite-ku OSAKA, 530-8323 JAPAN
`Phone:+81-6-6373-7237
`F A X:+B1-6-6373-4390
`URL:www.daikin.co.jp/chm
`
`DAIKIN CHEMICAL
`(HONG KONG) LTD.
`Room 21 08-9, on 2151 Floor
`New York Life Tower, Windsor
`House. 31 1 Gloucester Road,
`Causeway Bay, Hongkong
`Phone:+852-2979-5320
`F A x:+asz—2979-5aoe
`
`DAIKIN CHEMICAL
`INTERNATIONAL TRADING
`(SHANGHAI) CO, LTD.
`2201 Bund Center,222 Yan
`An Road (East). shanghai
`China Zip Code : 200002
`Phone:+BS-(O)21-6335-oo1 1
`F A X:+66-(O)21-6335~O7OO
`
`DAIKIN INDUSTRIES, LTD.
`Beijing Representative Office
`chemical DIV.
`_
`Room 51 1 - Full “n" PI?“ Bldg.
`”0-18 Chagyangmenwak
`Area”:- BEIJING, P - R- C Ina
`.3'1‘: 0:81503220658 1830~32
`F A X:+86-(0)10-6588-301 5
`one-
`-(
`) 0-
`8-
`
`May 2003 ace-15a(oo1)ex
`
`

`

`
`
`“It It
`- ‘ II IV-I -
`4‘-’ CI 1-." _
`
`o-"a-b —
`
`