(12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT)
`
`(19) World Intellectual Property Organization
`International Bureau
`
`
`
`(43) International Publication Date
`26 July 2007 (26.07.2007)
`
`International Patent Classification:
`
`(51)
`
`(21)
`
`C07D 213/69 (2006.01)
`
`C07C 15/04 (2006.01)
`
`International Application Number:
`PCT/GB2007/000095
`
`(22)
`
`International Filing Date: 15 January 2007 (15.01.2007)
`
`(25)
`
`Filing Language:
`
`(26)
`
`Publication Language:
`
`English
`
`English
`
`(30)
`
`(71)
`
`(72)
`(75)
`
`Priority Data:
`06009146
`
`17 January 2006 (17.01.2006)
`
`GB
`
`Applicants (for all designated States except US): SYN-
`GENTA LIMITED [GB/GB]; European Regional Centre,
`Priestley Road, Surrey Research Park, Guildford, Surrey
`GU2 7YH (GB). SYNGENTA PARTICIPATIONS AG
`[CH/CH]; Sehwarzwaldallee 215, CH—4058 Basel (CH).
`
`Inventors; and
`Inventors/Applicants (for US only): BEAUDEGNlES,
`Renaud [BF/CH]; Syngenta Crop Protection AG, Werk
`Rosental, Sehwarzwaldallee 215, CII—4058 Basel (CII).
`CASSAYRE, Jéréme [FR/CH]; Syngenta Crop Protection
`AG, Werk Rosental, Schwarzwaldallee 215, CH—4058
`Basel (CII). GOTT, Brian, David [GB/GB]; Syngenta,
`Huddersfield Manufacturing Centre, Huddersfield, West
`Yorkshire, HD2 1FF (GB). JACKSON, David, Anthony
`[GB/GB]; Syngenta, Huddersfield Manufacturing Centre,
`Huddersfield, West Yorkshire, HD2 1FF (GB). LUTHY,
`Christoph [CH/CH]; Mittelweg 1, CH—4142 Munchen—
`stein (CII). QUARANTA, Laura [IT/CH]; Syngenta Crop
`Protection AG, Werk Rosental, Schwarzwaldallee 215,
`CH-4058 Basel (CH). VETTIGER, Thomas [CH/CH];
`Syngenta Crop Protection Muenchwilen AG, Breiten—
`loh 5, CH74333 Muenchwilen (CH). WENGER, Jean
`
`(54) Title: PROCESS
`
`(10) International Publication Number
`
`WO 2007/083090 A2
`
`[CH/CH]; Syngenta Crop Protection AG, Werk Rosental,
`Schwarzwaldallee 215, CH—4058 Basel (CH). ZELLER,
`Martin [CH/CH]; Syngenta Crop Protection Muenchwilen
`AG, Breitenloh 5, CH—4333 Muenchwilen (CH).
`
`Agents: LEE, 1Vfichael, David et al.; Intellectual Property
`Department, Syngenta Limited, PO. Box 3538, Jealott’s
`Hill lnternational Research Centre, Bracknell, Berks RG42
`6YA (GB).
`
`Designated States (unless otherwise indicated, for ever
`kind of national protection available): AE, AG, AL, AM,
`AT, AU, AZ, BA, BB, BG, BR, BW, BY, BZ, CA, CH, CN,
`CO, CR, CU, CZ, DE, DK, DM, DZ, EC, EE, EG, ES, FI,
`GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IS,
`JP, KE, KG, KM, KN, KP, KR, KZ, LA, LC, LK, LR, LS,
`LT, LU, LV, LY, MA, MD, MG, MK, MN, MW, MX, MY,
`MZ, NA, NG, NI, NO, NZ, OM, PG, PH, PL, PT, RO, RS,
`RU, SC, SD, SE, SG, SK, SL, SM, SV, SY, TJ, TM, TN,
`TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW.
`
`Designated States (unless otherwise indicated, for ever
`kind of regional protection available): ARIPO (BW, G1 I,
`GM, KE, LS, MW, MZ, NA, SD, SL, SZ, TZ, UG, ZM,
`ZW), Eurasian (AM, AZ, BY, KG, KZ, MD, RU, TJ, TM),
`European (AT, BE, BG, CI I, CY, CZ, DE, DK, EE, ES, FI,
`FR, GB, GR, HU, 1E, 18, [1, LT, LU, LV, MC, NL, PL, PT,
`RO, SE, SI, SK, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA,
`GN, GQ, GW, ML, MR, NE, SN, TD, TG).
`
`(74)
`
`(81)
`
`(84)
`
`Published:
`
`without international search report and to be republished
`upon receipt of that report
`
`For two-letter codes and other abbreviations, refer to the "Guid-
`ance Notes on Codes and Abbreviations ” appearing at the begin—
`ning of each regular issue of the PCT Gazette.
`
`9
`
`.
`
`If
`I/
`i
`1
`\Y \ORE
`R~-\U/N\‘r//O
`'\U/N\ («PT/0
`0X1/
`\{AXZ
`
`(I)
`
`/\
`
`f 7”
`\TAOR3
`0
`‘
`.
`
`II
`
`(
`
`)
`
`OCN\‘/A\
`X1Av//
`
`1
`
`RKI/NHRZ
`/o\
`\Ho
`
`(III)
`
`(57) Abstract: A process of making a compound of formula (I), the process comprising reacting a compound of formula (H), with
`a compound of formula (HI)111 which R1 is C1 to C3 alkyl or C1 to C3 haloalkyl, R2 is C1 to C3 alkyl, X and X2 are halogen R3
`is a C 1— 6 alkanoic acid 1—6 alkyl ester residue R415 C 1— 6 straight or branched—chain alkyl, such as methyl, ethyl, propyl or butyl,
`preferably ethyl.
`
`
`
`W02007/083090A2|||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
`
`
