`
`I, Yoshiko Ishikawa, a translator fluent in Japanese and English languages, on behalf of Phoenix
`Translations, do declare that attached as Exhibit A is a documentwritten in the Japanese language
`(353-45352) and attached as Exhibit B is a true andcorrect translation of the document included
`as Exhibit A to the best of my knowledge andbelief. The translation attached as Exhibit B reflects
`the form that best reflects the intention and meaningofthe original Japanesetext.
`
`I hereby declare under penalty of perjury that the foregoingis true andcorrect.
`
`Executed on:|May 30, 2023
`
`
`Date
`
`Signature =
`YOSHIKO ISHIKAWA
`
`1
`
`APPLE 1005
`
`1
`
`APPLE 1005
`
`
`
`EXHIBIT A
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`// DOLF DOI1F=9/1279/127
`
`
`
`13
`
`13
`
`
`
`EXHIBIT B
`
`14
`
`
`
`(19) Japan Patent Office (JP)
`
`(12) KOKAI LAID-OPEN
`(11) Patent Application Publication No.
`PATENT PUBLICATION (A) “8“iesOr1998].1ae
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`(43) Publication date: July 21, 1998
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`FI
`(51) Int.cL.®
`Z
`10/40
`HOIM
`HOIM 10/40
`101Z
`31/04
`CO1IB
`101
`CO1B 31/04
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`HOIM§4/02 HO1M 4/02 Cc
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`D
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`Identification Code
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`4/58
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`4/58
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`Examination Request: Not requested Number ofClaims: 7 OL (total of 11 pages)
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`(21) Application No.
`H8[1996]-343403
`(71) Applicant
`000226242
`Nikkiso Co., Ltd.
`3-43-2 Ebisu, Shibuya-ku, Tokyo
`(22) Application Date
`Hiroshi Abe
`498-1 Shizutani, Haibara-cho,
`Haibara-gun, Shizuoka Prefecture
`Shizuoka Plant, Nikkiso Co., Ltd.
`Takeshi Murai
`498-1 Shizutani, Haibara-cho,
`Haibara-gun, Shizuoka Prefecture
`ShizuokaPlant, Nikkiso Co., Ltd.
`Takashi Osaki
`498-1 Shizutani, Haibara-cho,
`Haibara-gun, Shizuoka Prefecture
`Shizuoka Plant, Nikkiso Co., Ltd.
`Patent Attomey Naoki Fukumura
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`(74) Representative
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`December24, 1996
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`(72) Inventor
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`(72) Inventor
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`(72) Inventor
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`(54)[Title of Invention]
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`NON-AQUEOUS ELECTROLYTE-BASED SECONDARY BATTERY
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`(57) {Abstract]
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`[Problem] non-aqueous_electrolyte-basedProvide
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`secondary batteries with no risk of rupture and ignition,
`excellent cycle characteristics, and good stability against
`‘higher loads.
`{Solution] A non-aqueous electrolytic secondary battery
`comprising a negative electrode having a pressurized
`molding with a specific filling density, a positive electrode
`having a lithium-containing composite oxide, and an
`electrolyte obtained by dissolving a lithium salt
`in a
`carbonate mixture solvent formed by pressurized molding a
`graphitized vapor-phase-grown carbon fiber having a
`specific surface area ofat most 5 m?/g and an averageaspect
`ratio of 2 to 30;
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`15
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`(2)
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`Patent Application No. H10[1998]-189052
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`[SCOPE OF THE PATENT CLAIMS]
`[Claim 1] A non-aqueouselectrolyte-based secondary battery comprising a negative electrode having a
`pressurized molding so as to obtain a graphitized vapor-phase-grown carbonfiber having a specific surface
`area of at most 5 m’/g and an averageaspectratio of 2 to 30, and having a pressurized moldingso that the
`filling density is 1.22.0 g/cm*, a cathode havinga lithium-containing composite oxide, andan electrolyte
`obtained by dissolvinga lithium salt in a mixed solvent of a cyclic carbonate and a chain carbonate.
`[Claim 2] The non-aqueous electrolyte secondary battery according to Claim 1, wherein the lithium-
`containing composite oxide is a composite oxide having lithium and at least one metal selected from the
`group consisting of a Group 3B metal, a Group 6A metal, a Group 7A metal, and a Group 8 metal.
`[Claim 3] The non-aqueous electrolyte secondary battery of Claim 1, wherein the lithium-containing
`complex oxide is at least one selected from the group consisting of lithium-complex oxide and LiMmOs
`represented by the following general formula (1).
`LiNtiu Mr OQ:
`© «+ (1)
`(However, in the above formula, M indicates aluminum, manganese, chromium, cobalt, and iron, and X
`indicates any number between0, 1, and 0 to I.)
`[Claim 4] A non-aqueouselectrolytic secondary battery comprising a negative electrode formed by a
`graphitized vapor-phase-grown carbonfiber having a specific surfacearea ofat least 5 m’/g and an average
`aspectratio of 2 to 30, a positive electrode havingalithium-containing composite oxide, and an electrolyte
`solution obtained by dissolving a lithium salt in a mixed solvent of cyclic carbonate and chain carbonate,
`wherein the design capacity of the negative electrode is greater than the design capacity of the positive
`electrode.
`[Claim 5] The non-aqueouselectrolyte-based secondary battery of Claim 4, wherein the design capacity of
`the negative electrode relative to the design capacity of the positive electrodeis greater than | andless than
`or equalto 1.6.
`[Claim 6] The non-aqueous electrolyte secondary battery of Claim 4, wherein the lithium-containing
`composite oxide is a composite oxide having lithium and at least one metal selected from the group
`consisting of a Group 3B metal, a Group 6A metal, a Group 7A metal, and a Group 8 metal.
`[Claim 7] The non-aqueous electrolyte secondary battery according to Claim 4, wherein the lithium-
`containing complex oxideis at least one selected from the group consisting oflithium-complex oxide and
`LiMn.O,represented by the following general formula(1).
`LiNdi Mi O2 +++ €1)
`
`(However, in the above formula, M indicates aluminum, manganese, chromium,cobalt, and iron, and X
`indicates any numberbetween 0, |, and 0 to 1.)
`[DETAILED DESCRIPTION OF THE INVENTION]
`{0001}
`[Field of the Invention] The present inventionrelates to non-aqueouselectrolyte system secondary batteries,
`and moreparticularly to non-aqueouselectrolyte system secondary batteries with improvedsafety and load
`characteristics.
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`16
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`16
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`(3)
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`Patent Application No. H10[1998]-189052
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`[0002]
`[Conventional Technology] Vapor-phase-grown carbonfibers can be produced by thermally decomposing
`carbon compoundsby heatingultrafine particulate metals such as tron andnickel to 800 to 1,300°C as a
`catalyst. This vapor-phase-grown carbon fiber has the characteristic of being easily convertedto a graphite
`structure by heat treatment. For example, graphitized vapor-phase-growncarbonfibers heated at or above
`2,800°C have fewercrystal defects, and the mesh surface of the carbon hexagonallattice develops in a
`tubular shape around the fiber shaft, and the outer surface of the carbon hexagonal lattice develops
`concentrically, like rings ona tree, with similar mesh layers. Therefore, this graphitized vapor-phase-grown
`carbonfiber has high strength and elasticity, and also has high thermal andelectrical conductivity.
`[0003] Examples of applications that utilize the properties of this graphitized vapor-phase-grown carbon
`fiber include a non-aqueouselectrolyte-based secondary battery using the graphitized vapor-phase-grown
`carbonfiber as an electrode active material.
`[0004] Typically, the non-aqueous electrolyte-based secondary battery will have a negative electrode, a
`separator, a positive electrode, and anelectrolyte solution.
`[0005] Materials used in negative electrodes can include carbonaceous materials such as natural graphite,
`artificial graphite, refractory carbon,also called hard carbon, MesoCarbon MicroBeads, pitch-based carbon
`fibers, vapor-phase-grown carbonfibers, etc.
`[0006] Substances usedin the positive electrode can includelithium-containing composite oxides, such as
`lithium cobaltate (LiCoO2), lithium manganate (LiMn2O,, LiMnO:>),lithium nickelate (LiNiO2), etc.
`[0007] Examples of the substance used in the electrolyte include a non-aqueouselectrolyte solution
`obtained by mixing a lithium salt and an organic solvent. The lithium salts can include LiClO;, LiPFs,
`LiBF4, LiAsFs, LiCF3SOs3, etc. Examples of the organic solvent include ethylene carbonate (hereinafter
`sometimes referred to as EC), propylene carbonate (hereinafter sometimes referred to as PC), dimethyl
`carbonate (hereinafter sometimes referred to as DMC), diethyl carbonate (hereinafter sometimesreferred
`to as DEC), and methyl ethyl carbonate (hereinafter sometimes referred to as MEC).
`[0008]
`[Problems to be Solved bythe Invention] In recent years, non-aqueouselectrolyte-based secondary batteries
`with high energy density and excellent cycle characteristics have attracted attention as large-scale batteries,
`such as batteries for electric vehicles and household powerstorage systems.
`[0009] Incidentally, in general, in the case of overcharging lithium-ion s