Philip Morris Products, S.A.
`Exhibit 1033
`Page 001
`
`

`

`Copyright Elsevier 2020
`This book belongs to Maria Jamass
`
`Copyright Elsevier 2020 This book belongs to Maria Jamass
`
`Philip Morris Products, S.A.
`Exhibit 1033
`Page 002
`
`

`

`Handbok of
`Polymers
`
`2nd Edtion
`
`
`Toronto 2016
`
`Copyright Elsevier 2020 This book belongs to Maria Jamass
`
`Philip Morris Products, S.A.
`Exhibit 1033
`Page 003
`
`

`

`Published by ChemTec Publishing
`38 Earswick Drive, Toronto, Ontario M1E 1C6, Canada
`
`© ChemTec Publishing, 2012, 2016
`ISBN 978-1-895198-92-8 (bound)
`ISBN 978-1-927885-11-6 (E-PUB)
`Cover design: Anita Wypych
`
`All rights reserved. No part of this publication may be reproduced, stored
`or transmitted in any form or by any means without written permission
`of copyright owner. No responsibility is assumed by the Author and the
`Publisher for any injury or/and damage to persons or properties as a
`matter of products liability, negligence, use, or operation of any methods,
`product ideas, or instructions published or suggested in this book.
`
`Library and Archives Canada Cataloguing in Publication
`
`Wypych, George, author
` Handbook of polymers / George Wypych. -- Second
`edition
`
`Includes bibliographical references and index.
`Issued in print and electronic formats.
`ISBN 978-1-895198-92-8 (bound)
`ISBN 978-1-927885-11-6 (E-PUB)
`
`1. Polymers--Handbooks, manuals, etc. I. Title.
`
`TA455.P58W96 2016 668.9 C2015-907777-X
`C2015-907778-8
`
`Printed in United States, United Kingdom, and Australia
`
`Copyright Elsevier 2020 This book belongs to Maria Jamass
`
`Philip Morris Products, S.A.
`Exhibit 1033
`Page 004
`
`

`

`
`
`
`ABA
`
`ABS
`
`AK
`
`ASA
`
`BIIR
`
`BMI
`
`BZ
`
`C
`
`CA
`
`CAB
`
`CAP
`
`CAPh
`
`CAR
`
`CB
`
`CEC
`
`CHI
`
`CIIR
`
`CMC
`
`CN
`
`COC
`
`CPE
`CPVC
`CR
`
`CSP
`
`CTA
`
`CY
`
`DAP
`
`E-RLPO
`EAA
`
`EAMM
`EBAC
`
`EBCO
`EC
`
`ECTFE
`EEAC
`
`EMA
`
`EMA-AA
`ENBA
`
`EP
`
`EPDM
`EPR
`
`ETFE
`
`EVAC
`
`EVOH
`FEP
`
`FR
`
`GEL
`
`GT
`
`HCP
`
`HDPE
`HEC
`
`HPMC
`HPMM
`
`
`
`Introduction
`acrylonitrile-butadiene-acrylate copolymer
`poly(acrylonitrile-co-butadiene-co-styrene)
`alkyd resin
`poly(acrylonitrile-co-styrene-co-acrylate)
`bromobutyl rubber
`polybismaleimide
`polybenzoxazine
`cellulose
`cellulose acetate
`cellulose acetate butyrate
`cellulose acetate propionate
`cellulose acetate phthalate
`carrageenan
`cellulose butyrate
`carboxylated ethylene copolymer
`chitosan
`chlorobutyl rubber
`carboxymethyl cellulose
`cellulose nitrate
`cyclic olefi n copolymer
`polyethylene, chlorinated
`poly(vinyl chloride), chlorinated
`polychloroprene
`polyethylene, chlorosulfonated
`cellulose triacetate
`cyanoacrylate
`poly(diallyl phthalate)
`poly(ethyl acrylate-co-methyl methacrylate-co-triammonioethyl methacrylate chloride)
`poly(ethylene-co-acrylic acid)
`poly(ethyl acrylate-co-methyl methacrylate)
`poly(ethylene-co-butyl acrylate)
`ethylene-n-butyl acrylate-carbon monoxide terpolymer
`ethyl cellulose
`poly(ethylene-co-chlorotrifl uoroethylene)
`poly(ethylene-co-ethyl acrylate)
`poly(ethylene-co-methyl acrylate)
`poly(ethylene-co-methyl acrylate-co-acrylic acid)
`poly(ethylene-co-n-butyl acrylate)
`epoxy resin
`ethylene-propylene diene terpolymer
`ethylene propylene rubber
`poly(ethylene-co-tetrafl uoroethylene)
`ethylene-vinyl acetate copolymer
`ethylene-vinyl alcohol copolymer
`fl uorinated ethylene-propylene copolymer
`furan resin
`gelatin
`gum tragacanth
`hydroxypropyl cellulose
`high density polyethylene
`hydroxyethyl cellulose
`hydroxypropyl methylcellulose
`poly(methacrylic acid-co-methyl methacrylate)
`
`Table of Contents
`1
`3
`5
`12
`15
`20
`22
`25
`28
`33
`39
`43
`46
`48
`50
`52
`54
`57
`60
`63
`67
`71
`74
`77
`81
`84
`87
`90
`92
`93
`96
`98
`100
`102
`105
`109
`111
`113
`115
`117
`122
`126
`129
`133
`138
`142
`146
`149
`151
`153
`156
`164
`166
`168
`
`HANDBOOK OF POLYMERS / Copyrights 2016; ChemTec Publishing
`
`iii
`
`Copyright Elsevier 2020 This book belongs to Maria Jamass
`
`Philip Morris Products, S.A.
`Exhibit 1033
`Page 005
`
`

`

`
`IIR
`
`LCP
`
`LDPE
`LLDPE
`MABS
`MBS
`
`MC
`
`MF
`
`MP
`
`NBR
`
`PA-3
`
`PA-4,6
`PA-4,10
`PA-6
`
`PA-6,6
`PA-6,10
`PA-6,12
`PA-6,66
`PA-6I/6T
`PA-11
`
`PA-12
`
`PAA
`
`PAAm
`
`PAC
`
`PAEK
`
`PAH
`
`PAI
`
`Palg
`
`PAN
`
`PANI
`
`PAR
`
`PARA
`
`PB
`
`PBA
`
`PBAA
`
`PBD,cis
`PBD,trans
`PBI
`
`PBMA
`PBN
`
`PBT
`
`PC
`
`PCL
`
`PCS
`
`PCT
`
`PCTFE
`PCTG
`PDCPD
`PDL
`
`PDMS
`PDPD
`PDS
`
`PE
`
`PEA
`
`PEC
`
`PEDOT
`
`iv
`
`
`
`
`
`
`
`
`
`isobutylene-isoprene rubber
`liquid crystalline polymers
`low density polyethylene
`linear low density polyethylene
`poly(methyl methacrylate-co-acrylonitrile-co-butadiene-co-styrene)
`poly(styrene-co-butadiene-co-methyl methacrylate)
`methylcellulose
`melamine-formaldehyde resin
`melamine-phenolic resin
`acrylonitrile-butadiene elastomer
`polyamide-3
`polyamide-4,6
`polyamide-4,10
`polyamide-6
`polyamide-6,6
`polyamide-6,10
`polyamide-6,12
`polyamide-6,66
`polyamide-6I/6T
`polyamide-11
`polyamide-12
`poly(acrylic acid)
`polyacrylamide
`polyacetylene
`acrylonitrile-butadiene-acrylate copolymer
`polyanhydride
`poly(amide imide)
`alginic acid
`polyacrylonitrile
`polyaniline
`polyarylate
`polyamide MXD6
`1,2-polybutylene
`poly(p-benzamide)
`poly(butadiene-co-acrylonitrile-co-acrylic acid)
`cis-1,4-polybutadiene
`trans-1,4-polybutadiene
`polybenzimidazole
`polybutylmethacrylate
`poly(butylene 2,6-naphthalate)
`poly(butylene terephthalate)
`polycarbonate
`poly(-caprolactone)
`polycarbodihydridosilane
`poly(cyclohexylene terephthalate)
`polychlorotrifl uoroethylene
`poly(ethylene-co-1,4-cyclohexylenedimethylene terephthalate)
`polydicyclopentadiene
`polylysine
`polydimethylsiloxane
`poly(dicyclopentadiene-co-p-cresol)
`polydioxanone
`polyethylene
`poly(ethyl acrylate)
`poly(ester carbonate)
`poly(3,4-ethylenedioxythiophene)
`
`
`
`
`
`
`
`
`
` 171
`174
`178
`185
`190
`193
`196
`199
`202
`204
`207
`209
`213
`215
`221
`227
`231
`235
`238
`241
`246
`251
`254
`257
`260
`262
`265
`269
`271
`276
`280
`283
`286
`290
`292
`294
`296
`301
`305
`307
`310
`316
`323
`326
`327
`330
`334
`337
`339
`340
`345
`346
`349
`355
`358
`362
`
`HANDBOOK OF POLYMERS / Copyrights 2016; ChemTec Publishing
`
`Copyright Elsevier 2020 This book belongs to Maria Jamass
`
`Philip Morris Products, S.A.
`Exhibit 1033
`Page 006
`
`

`

`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`PEEK
`
`PEF
`
`PEI
`
`PEK
`
`PEKK
`
`PEM
`
`PEN
`
`PEO
`
`PES
`
`PET
`
`PEX
`
`PF
`
`PFA
`
`PFI
`
`PFPE
`
`PGA
`
`PHB
`
`PHBV
`PHEMA
`PHSQ
`PHT
`
`PI
`
`PIB
`
`PIP,cis
`PIP,trans
`PK
`
`PLA
`
`PLGA
`
`PLS
`
`PLT
`
`PMA
`
`PMAA
`PMAN
`PMFS
`PMMA
`PMP
`
`PMPS
`PMS
`
`PMSQ
`PN
`
`PNR
`
`POE
`
`POM
`
`PP
`
`PP,iso
`
`PP,syndio
`PPA
`
`PPG
`
`PPMA
`PPO
`
`PPP
`
`PPS
`
`PPSE
`
`PPSQ
`PPSU
`
`PPT
`
`
`
`
`
`
`
`
`
`
`polyetheretherketone
`poly(ethylene furanoate)
`
`poly(ether imide)
`
`
`polyetherketone
`
`
`polyetherketoneketone
`poly(ethylene-co-methacrylic acid)
`poly(ethylene 2,6-naphthalate)
`poly(ethylene oxide)
`poly(ether sulfone)
`poly(ethylene terephthalate)
`silane-crosslinkable polyethylene
`phenol-formaldehyde resin
`perfl uoroalkoxy resin
`perfl uorinated ionomer
`perfl uoropolyether
`poly(glycolic acid)
`poly(3-hydroxybutyrate)
`poly(3-hydroxybutyrate-co-3-hydroxyvalerate)
`poly(2-hydroxyethyl methacrylate)
`polyhydridosilsesquioxane
`polyhexahydrotriazine
`polyimide
`polyisobutylene
`cis-polyisoprene
`trans-polyisoprene
`polyketone
`poly(lactic acid)
`poly(DL-lactide-co-glycolide)
`poly(L-serine)
`poly(l-tyrosine)
`poly(methyl acrylate)
`poly(methacrylic acid)
`polymethacrylonitrile
`polymethyltrifl uoropropylsiloxane
`polymethylmethacrylate
`polymethylpentene
`polymethylphenylsilylene
`poly(p-methylstyrene)
`polymethylsilsesquioxane
`polynorbornene
`phthalonitrile resin
`very highly branched polyethylene
`polyoxymethylene
`polypropylene
`polypropylene, isotactic
`polypropylene, syndiotactic
`polyphthalamide
`polypropylene glycol
`polypropylene, maleic anhydride modifi ed
`poly(phenylene oxide)
`poly(1,4-phenylene)
`poly(p-phenylene sulfi de)
`poly(trimethylsilyl phosphate)
`polyphenylsilsesquioxane
`poly(phenylene sulfone)
`poly(propylene terephthalate)
`
`HANDBOOK OF POLYMERS / Copyrights 2016; ChemTec Publishing
`
`366
`371
`372
`377
`380
`383
`385
`390
`394
`398
`404
`407
`410
`413
`416
`419
`422
`425
`427
`429
`430
`431
`437
`440
`443
`446
`450
`455
`456
`457
`458
`460
`463
`465
`467
`472
`475
`477
`480
`482
`485
`486
`490
`497
`505
`510
`514
`517
`520
`522
`526
`529
`534
`535
`537
`540
`
`v
`
`Copyright Elsevier 2020 This book belongs to Maria Jamass
`
`Philip Morris Products, S.A.
`Exhibit 1033
`Page 007
`
`

`

`PPTA
`PPTI
`PPV
`PPX
`PPy
`PR
`PS
`PS,iso
`PS,trans
`PSM
`PSMS
`PSR
`PSU
`PTFE
`PTFE-AF
`PTMG
`PTT
`PU
`PVAc
`PVAl
`PVB
`PVC
`PVCA
`PVDC
`PVDF
`PVDF-HFP
`PVF
`PVK
`PVME
`PVP
`PZ
`SAN
`SBC
`SBR
`SBS
`SEBS
`SIS
`SMA
`SMAA
`ST
`TPU
`UF
`UHMWPE
`ULDPE
`UP
`VE
`XG
`
`poly(p-phenylene terephthalamide)
`poly(m-phenylene isophthalamide)
`poly(1,4-phenylene vinylene)
`poly(p-xylylene)
`polypyrrole
`proteins
`polystyrene
`polystyrene, isotactic
`polystyrene, syndiotactic
`polysilylenemethylene
`poly(styrene-co--methylstyrene)
`polysulfi de
`polysulfone
`polytetrafl uoroethylene
`poly(tetrafl uoroethylene-co-2,2-bis(trifl uoromethyl)-4,5-difl uoro-1,3-dioxole)
`poly(tetramethylene glycol)
`poly(trimethylene terephthalate)
`polyurethane
`poly(vinyl acetate)
`poly(vinyl alcohol)
`poly(vinyl butyrate)
`poly(vinyl chloride)
`poly(vinyl chloride-co-vinyl acetate)
`poly(vinylidene chloride)
`poly(vinylidene fl uoride)
`poly(vinylidene fl uoride-co-hexafl uoropropylene)
`poly(vinyl fl uoride)
`poly(N-vinyl carbazole)
`poly(vinyl methyl ether)
`poly(N-vinyl pyrrolidone)
`polyphosphazene
`poly(styrene-co-acrylonitrile)
`styrene-butadiene block copolymer
`poly(styrene-co-butadiene)
`styrene-butadiene-styrene triblock copolymer
`styrene-ethylene-butylene-styrene triblock copolymer
`styrene-isoprene-styrene block copolymer
`poly(styrene-co-maleic anhydride)
`poly(styrene-co-methylmethacrylate)
`starch
`thermoplastic polyurethane
`urea-formaldehyde resin
`ultrahigh molecular weight polyethylene
`ultralow density polyethylene
`unsaturated polyester
`vinyl ester resin
`xanthan gum
`
`vi
`
`HANDBOOK OF POLYMERS / Copyrights 2016; ChemTec Publishing
`
`542
`546
`549
`551
`554
`557
`560
`567
`570
`574
`575
`577
`580
`586
`591
`593
`595
`599
`606
`610
`615
`618
`625
`627
`630
`635
`639
`643
`646
`649
`652
`654
`658
`662
`666
`670
`673
`675
`679
`682
`686
`690
`693
`698
`700
`702
`704
`
`Copyright Elsevier 2020 This book belongs to Maria Jamass
`
`Philip Morris Products, S.A.
`Exhibit 1033
`Page 008
`
`

`

`Introduction
`Polymers selected for this edition of the Handbook of Polymers include all ma-
`jor polymeric materials used by the plastics and other branches of the chemi-
`cal industry as well as specialty polymers used in the electronics, pharmaceuti-
`cal, medical, and space fi elds. Extensive information is provided on biopolymers.
`
`The data included in the Handbook of Polymers come from open literature
`
`(published articles, conference papers, and books), literature available from manu-
`facturers of various grades of polymers, plastics, and fi nished products, and patent
`literature. The above sources were searched, including the most recent literature.
`It can be seen from the references that a large portion of the data comes from in-
`formation published in 2011-2016. This underscores one of the major goals of this
`undertaking, which is to provide readers with the most up-to-date information.
`
`Frequently, data from diff erent sources vary in a broad range and they have to
`
`be reconciled. In such cases, values closest to their average and values based on test-
`ing of the most current grades of materials are selected to provide readers with infor-
`mation which is characteristic of currently available products, focusing on the potential
`use of data in solving practical problems. In this process of verifi cation many older
`data were rejected unless they have been confi rmed by recently conducted studies.
`
`Presentation of data for all polymers is based on a consistent pattern of
`
`data arrangement, although, depending on data availability, only data fi elds which
`contain actual values are included for each individual polymer. The entire scope
`of the data is divided into sections to make data comparison and search easy.
`
`The following sections of data are included:
`• General
`• History
`• Synthesis
`• Structure
`• Commercial polymers
`• Physical properties
`• Mechanical properties
`• Chemical resistance
`• Flammability
`• Weather stability
`• Biodegradation
`• Toxicity
`• Environmental impact
`• Processing
`• Blends
`• Analysis
`
`HANDBOOK OF POLYMERS / Copyrights 2016; ChemTec Publishing
`
`1
`
`Copyright Elsevier 2020 This book belongs to Maria Jamass
`
`Philip Morris Products, S.A.
`Exhibit 1033
`Page 009
`
`

`

`It can be anticipated from the above breakdown of information that the Handbook
`of Polymers contains information on all essential data used in practical applications,
`research, and legislation, providing such data are available for a particular material. In
`total, over 230 diff erent types of data were searched for each individual polymer. The
`last number does not include special fi elds that might be added to characterize the
`performance of specialty polymers in their applications.
`
`In most cases, the information provided is self-explanatory, considering that each
`data fi eld is composed of parameter (or measured property), unit, value, and (in many
`cases) reference. In some cases, diff erent values or a range of values are given. This
`is to indicate the fact that there is a disagreement in the published data which cannot
`be reconciled, or that the data falls into a broader range because various grades diff er
`in properties. Utmost care is taken that the specifi ed range contains grades known from
`published data. If there are specifi c grades diff ering in properties, a set of separate
`ranges is given in some cases.
`
`After some data, information is given in parenthesis to indicate additional
`characteristics of tested samples. The usual convention is that the fi rst value given is
`for pure or typical material, followed by its diff erent modifi cations (e.g., reinforcements
`with diff erent fi bers or diff erent levels of crystallinity, structure, or diff erent conditions of
`sample preparation as to its temperature, state, etc.).
`
`The range of molecular weights and related data (e.g., polymerization degree)
`requires additional explanation. In some cases, the number average molecular weight
`data do not correspond to mass average molecular data (as could be expected from a
`given range of polydispersities). This is because these data are given based on values
`found in literature without any attempts to reconcile them by means of calculation,
`which seems to be the correct approach because the data strictly refl ect values found
`in the literature, not the results of any approximations which will artifi cially compare
`sets of data for materials coming from diff erent experimental or production conditions.
`This is in agreement with one essential goal of this collection – authenticity of the data
`selected.
`
`We hope that the results of our thorough search will be useful and that the
`data will be skillfully applied by users of this book for the benefi t of their research and
`applications.
`
`2
`
`HANDBOOK OF POLYMERS / Copyrights 2016; ChemTec Publishing
`
`Copyright Elsevier 2020 This book belongs to Maria Jamass
`
`Philip Morris Products, S.A.
`Exhibit 1033
`Page 010
`
`

`

`ABA acrylonitrile-butadiene-acrylate copolymer
`
`PARAMETER
`
`UNIT
`
`VALUE
`
`REFERENCES
`
`GENERAL
`Common name
`Acronym
`COMMERCIAL POLYMERS
`Some manufacturers
`Trade names
`
`-
`-
`
`-
`-
`
`PHYSICAL PROPERTIES
`Density at 20oC
`Melting temperature, DSC
`Thermal expansion coeffi cient,
`23-80oC
`Glass transition temperature
`
`Heat defl ection temperature at
`1.8 MPa
`Volume resistivity
`Electric strength K20/P50,
`d=0.60.8 mm
`
`g cm-3
`oC
`oC-1
`
`oC
`
`oC
`
`ohm-m
`kV mm-1
`
`acrylonitrile-butadiene-acrylate copolymer
`ABA
`
`Solvay
`AvaSpire
`
`1.29-1.32
`340; 340-345 (30-40% glass fi ber); 340 (30% carbon fi ber)
`0.45-0.47E-4; 0.16-0.17E-4 (30-40% glass fi ber)
`
`150-158; 150-158 (30-40% glass fi ber); 150 (30% carbon
`fi ber)
`161-252; 213-286 (30-40% glass fi ber); 267-276 (30% carbon
`fi ber)
`2E16 (30-40% glass fi ber)
`16 (30-40% glass fi ber)
`
`Tensile modulus
`
`Elongation
`Tensile yield strain
`Flexural strength
`
`Flexural modulus
`
`Compressive strength
`Izod impact strength, unnotched,
`23oC
`Izod impact strength, notched,
`23oC
`Shear strength
`Shrinkage
`
`Melt viscosity, shear rate=1000
`s-1
`Melt index, 400oC/2.16 kg
`
`CHEMICAL RESISTANCE
`Aromatic hydrocarbons
`Esters
`Halogenated hydrocarbons
`Ketones
`
`MECHANICAL & RHEOLOGICAL PROPERTIES
`Tensile strength
`MPa
`84-93.8; 156-191 (30-40% glass fi ber); 176-201 (30% carbon
`fi ber)
`2,900-3,720; 9,900-15,200 (30-40% glass fi ber); 18,800-
`22,100 (30% carbon fi ber)
`26-76; 1.8-2.9 (30-40% glass fi ber); 1.5-2.0 (30% carbon fi ber)
`5.0-6.7
`122-141; 234-253 (30-40% glass fi ber); 259-317 (30% carbon
`fi ber)
`3,100-3,720; 9,400-14,800 (30-40% glass fi ber); 16,500-
`19,300 (30% carbon fi ber)
`228 (30-40% glass fi ber)
`no break; 590-960 (30-40% glass fi ber); 530 (30% carbon
`fi ber)
`75-100; 53-110 (30-40% glass fi ber)
`
`MPa
`
`%
`%
`MPa
`
`MPa
`
`MPa
`J m-1
`
`J m-1
`
`MPa
`%
`
`79 (30-40% glass fi ber)
`0.8-1.3; 0.3-1.3 (30-40% glass fi ber); 0.1-0.5 (30% carbon
`fi ber)
`410-450; 410-450 (30-40% glass fi ber); 470 (30% carbon
`fi ber)
`g/10 min 1-5; 7-9 (30-40% glass fi ber)
`
`Pa s
`
`-
`-
`-
`-
`
`excellent
`excellent
`excellent
`excellent
`
`HANDBOOK OF POLYMERS / Copyrights 2016; ChemTec Publishing
`
`3
`
`Copyright Elsevier 2020 This book belongs to Maria Jamass
`
`Philip Morris Products, S.A.
`Exhibit 1033
`Page 011
`
`

`

`ABA acrylonitrile-butadiene-acrylate copolymer
`
`PARAMETER
`
`
`
`FLAMMABILITY
`UL 94 rating
`
`TOXICITY
`Carcinogenic eff ect
`PROCESSING
`Typical processing methods
`
`Preprocess drying: temperature/
`time/residual moisture
`Processing temperature
`Applications
`
`Outstanding properties
`
`UNIT
`
`VALUE
`
`REFERENCES
`
`-
`
`-
`
`-
`
`oC/h/%
`
`oC
`-
`
`-
`
`V-0; V-0 or V-1 (30-40% glass fi ber)
`
`
`not listed by ACGIH, NIOSH, NTP
`
`extrusion blow molding, fi ber spinning, fi lm extrusion, injection
`blow molding, injection molding, machining, profi le extrusion,
`thermoforming, wire and cable extrusion
`150/4/-; 149-175/2.5-4/- (30-40% glass fi ber)
`
`354-382; 366-404 (30-40% glass fi ber)
`aircraft, automotive, bearings, bushings, connectors, electrical/
`electronics, fi lm, fuel lines, gears, medical, oil/gas, semicon-
`ductors, seals
`ductile, high heat resistance, fl ame retardant
`
`4
`
`HANDBOOK OF POLYMERS / Copyrights 2016; ChemTec Publishing
`
`Copyright Elsevier 2020 This book belongs to Maria Jamass
`
`Philip Morris Products, S.A.
`Exhibit 1033
`Page 012
`
`

`

`ABS poly(acrylonitrile-co-butadiene-co-styrene)
`
`UNIT
`
`VALUE
`
`REFERENCES
`
`poly(acrylonitrile-co-butadiene-co-styrene)
`buta-1,3-diene; prop-2-enenitrile; styrene
`2-propenenitrile, polymer with 1,3-butadiene and ethenyl-
`benzene
`ABS
`9003-56-9
`AT6970000
`[CH2CH(CN)]x(CH2CH=CHCH2)y[CH2CH(C6H5)]z
`
`ABS was patented in 1948 and introduced to commercial
`markets by the Borg-Warner Corporation in 1954
`
`H2C CHC N
`
`H2C CHCH CH2
`
`107-13-1 (acrylonitrile); 106-99-0 (butadiene); 100-42-5
`(styrene)
`53.06; 54.09; 104.15
`
`variable
`acrylonitrile: 15-50%; butadiene: 5-30%; styrene: 40-60%
`90-40/10-60
`H2O (solvent) 17,070, emulsifi er 3558, polybutadiene latex
`6384, tertdodecyl mercaptan 70, FeSO4 1610, styrene 8565,
`acrylonitrile 4236, cumene hydroperoxide 53
`the most frequently used are emulsion, mass, and suspension
`polymerizations; styrene and acrylonitrile are being grafted
`onto rubber by chemical grafting, chemical grafting blending,
`or physical mixing; chemical grafting blending is the most fre-
`quently used method and specifi cally emulsion grafting-bulk
`SAN blending is a method of choice
`62-75
`styrene: 647; acrylonitrile: 2290; ABS: 890
`30,000-200,000
`
`81,000-308,000
`
`2.72-2.88
`
`Hu, K-H; Kao, C-S; Duh, Y-S, J.
`Hazardous Matrer., 159, 25-34,
`2008.
`
`Huang, P; Tan, D; Luo, Y, J. Env.
`Sci., Technol., 3, 3, 148-58, 2010.
`
`<1,000 (emulsion polymerization); 500-5,000 (mass polymer-
`ization)
`
`32.3-97.0 (polybutadiene); 1.5-51.6 (trans in polybutadiene)
`
`Lucarini, M; Pedulli, G F; Motyakin,
`M V; Schlick, S, Prog. Polym. Sci.,
`28, 331–340, 2003.
`Yu, Z; Li, Y; Zhao, Z; Wang, C;
`Yang, J; Zhang, C; Li, Z; Wang,
`Y, Polym. Eng. Sci., 49, 2249-56,
`2009.
`
`PARAMETER
`
`GENERAL
`Common name
`IUPAC name
`CAS name
`
`Acronym
`CAS number
`RTECS number
`Linear formula
`
`HISTORY
`Details
`
`SYNTHESIS
`Monomer(s) structure
`
`Monomer(s) CAS number(s)
`
`-
`-
`-
`
`-
`-
`-
`
`-
`
`-
`
`-
`
`Monomer(s) molecular weight(s)
`
`dalton,
`g/mol,
`amu
`Monomer(s) expected purity(ies) %
`Monomer ratio
`-
`SAN/BP
`Formulation example
`
`-
`
`Method of synthesis
`
`-
`
`Temperature of polymerization
`Heat of polymerization
`Number average molecular
`weight, Mn
`
`Mass average molecular weight,
`Mw
`
`Polydispersity, Mw/Mn
`
`STRUCTURE
`Domain size of rubber
`
`Cis content
`
`oC
`J g-1
`dalton,
`g/mol,
`amu
`dalton,
`g/mol,
`amu
`-
`
`nm
`
`%
`
`HANDBOOK OF POLYMERS / Copyrights 2016; ChemTec Publishing
`
`5
`
`Copyright Elsevier 2020 This book belongs to Maria Jamass
`
`Philip Morris Products, S.A.
`Exhibit 1033
`Page 013
`
`

`

`ABS poly(acrylonitrile-co-butadiene-co-styrene)
`
`PARAMETER
`COMMERCIAL POLYMERS
`Some manufacturers
`Trade names
`
`UNIT
`
`VALUE
`
`REFERENCES
`
`-
`-
`
`BASF; Daicel; Denka; Formosa; Sabic
`Lustran, Terluran; Cevian; Novodur; Tairilac; Cycolac
`
`PHYSICAL PROPERTIES
`Density at 20oC
`g cm-3
`Bulk density at 20oC
`g cm-3
`-
`Refractive index, 20oC
`Transmittance
`%
`Haze
`%
`Gloss, 60o, Gardner (ASTM D523) %
`
`1.03-1.09; 0.93 (melt)
`0.6
`1.540
`80-90
`0.4-5
`85-95 (glossy); 1.8-6.6 (matt)
`
`Melting temperature, DSC
`
`Softening point
`Heat defl ection temperature
`
`Onset temperature of thermal
`degradation
`
`Thermal expansion coeffi cient,
`23-80oC
`Thermal conductivity, melt
`
`Glass transition temperature
`
`oC
`
`oC
`oC
`
`oC
`
`220-260
`
`>90
`76.5-79.2
`
`385-407
`
`oC-1
`
`0.6-1.1E-4
`
`W m-1
`K-1
`oC
`
`0.16
`
`102-107 (acrylonitrile-styrene mesophase) and -58 (butadiene
`component); 103 (DSC) and 121 (DMA); 112-115 (DMA)
`
`Specifi c heat capacity
`Maximum service temperature
`Heat defl ection temperature at
`0.45 MPa
`Heat defl ection temperature at
`1.8 MPa
`Vicat temperature VST/A/50
`Vicat temperature VST/B/50
`Melting enthalpy peak
`
`J K-1 kg-1
`oC
`oC
`
`1,780-2,030 (88oC); 2,300-2,400 (melt)
`80
`89-113
`
`oC
`
`oC
`oC
`J g-1
`
`67-109
`
`90-112
`95-100
`9.6
`
`Relative permittivity at 100 Hz
`Relative permittivity at 1 MHz
`Dissipation factor at 100 Hz
`Dissipation factor at 1 MHz
`Volume resistivity
`
`-
`-
`E-4
`E-4
`ohm-m
`
`2.9
`2.8
`48-160
`79-140
`1E+13; 1E+1 (with 0.18 vol fraction of Ni coated mica)
`
`6
`
`HANDBOOK OF POLYMERS / Copyrights 2016; ChemTec Publishing
`
`Terluran, BASF; Cevian, Daicel
`
`Cevian, Daicel
`
`Arino, I; Kleist, U; Rigdahl, M,
`Polym. Eng. Sci., 45, 733-44, 2005.
`Terluran, BASF; Karahaliou, E K;
`Tarantili, P A, Polym. Eng. Sci., 49,
`2269-75, 2009.
`Terluran, BASF
`
`Basurto, F C; Garcia-Lopez, D;
`Villarreal-Bastardo, N; Merino, J C;
`Pastor, J M, Composites: Part B, 47,
`42-7, 2013.
`Li, Y; Zheng, Y; Liu, J; Shang, H,
`J. Appl. Polym. Sci., 115, 957-62,
`2010.
`Terluran, BASF; Cevian, Daicel
`
`Terluran, BASF
`
`Terluran, BASF; Xue, M-L; Yu,
`Y-L; Rhee, J M; Kim, N H; Lee, J
`H, Eur. Polym. J., 43, 9, 3826-37,
`2007; Santos, R M; Botelho, G
`L; Machado, A V, J. Appl. Polym.
`Sci., 2005-14, 2010; Karahaliou, E
`K; Tarantili, P A, Polym. Eng. Sci.,
`49, 2269-75, 2009; Torrado, A R;
`Shemelya, C M; English, J D; Lin, Y;
`Wicker, R B; Roberson, D A, Addit.
`Manufac., 6, 16-29, 2015.
`Terluran, BASF
`
`Terluran, BASF
`
`Terluran, BASF
`
`Terluran, BASF; Cevian, Daicel
`
`Terluran, BASF
`
`Terluran, BASF
`
`Karahaliou, E K; Tarantili, P A,
`Polym. Eng. Sci., 49, 2269-75,
`2009.
`Terluran, BASF
`Terluran, BASF
`Terluran, BASF
`Terluran, BASF
`Terluran, BASF; Kandasubramani-
`an, B; Gilbert, M, Macromol. Symp.,
`211, 185-95, 2005.
`
`Copyright Elsevier 2020 This book belongs to Maria Jamass
`
`Philip Morris Products, S.A.
`Exhibit 1033
`Page 014
`
`

`

`ABS poly(acrylonitrile-co-butadiene-co-styrene)
`
`PARAMETER
`
`UNIT
`
`VALUE
`
`Surface resistivity
`Electric strength K20/P50,
`d=0.60.8 mm
`Comparative tracking index, CTI,
`test liquid A
`Comparative tracking index,
`CTIM, test liquid B
`Shielding eff ectiveness
`
`Coeffi cient of friction
`
`Contact angle of water, 20oC
`
`ohm
`kV mm-1
`
`1E+13 to 1E+15
`37-41
`
`-
`
`(-)-
`
`dB
`
`ASTM
`D1894
`degree
`
`600
`
`225
`
`16-16.5
`
`0.21-0.28 (chrome steel); 0.40 (aluminum)
`
`80.9; 89.7
`
`Surface free energy
`
`mJ m-2
`
`35-42
`
`Speed of sound
`
`m s-1
`
`36.2-37.5
`
`Acoustic impedance
`
`2.31-2.36
`
`Attenuation
`
`dB cm-1,
`5 MHz
`
`10.9-11.3
`
`MECHANICAL & RHEOLOGICAL PROPERTIES
`Tensile strength
`MPa
`25-65
`
`Tensile modulus
`Tensile stress at yield
`Tensile creep modulus, 1000 h,
`elongation 0.5 max
`Elongation
`
`Tensile yield strain
`Flexural strength
`
`Flexural modulus
`Elastic modulus
`
`MPa
`MPa
`MPa
`
`%
`
`%
`MPa
`
`MPa
`MPa
`
`1900-2700
`35-58
`1250
`
`8-20
`
`2.4-4
`55-125
`
`2150-2300
`1208-1939
`
`Young modulus
`
`MPa
`
`1810-2390
`
`REFERENCES
`
`Terluran, BASF
`Terluran, BASF
`
`Terluran, BASF
`
`Terluran, BASF
`
`Kandasubramanian, B; Gilbert, M,
`Macromol. Symp., 211, 185-95,
`2005.
`Maldonado, J E, Antec, 3431-35,
`1998.
`
`Accu Dyne Test, Diversifi ed
`Enterprizes; K. Fukuzawa, in
`Adhesion Science and Technology,
`H. Mizumachi, ed., International
`Adhesion Symposium, Yokohama,
`Japan, 1994.
`D.A. Markgraf, in Film Extrusion
`Manual, 2nd Ed., T.I. Butler, ed.,
`TAPPI Press, Norcross, GA, 2005,
`p. 299.
`Alan R. Selfridge, IEEE Trans. Son-
`ics Ultrasonics, SU-32, 3, 381-394,
`1985.
`Alan R. Selfridge, IEEE Trans. Son-
`ics Ultrasonics, SU-32, 3, 381-394,
`1985.
`Alan R. Selfridge, IEEE Trans. Son-
`ics Ultrasonics, SU-32, 3, 381-394,
`1985.
`
`Li, J; Cai, C L, Current Appl. Phys.,
`11, 50, 2011; Lee, J-W; Lee, J-C;
`Pandey, J; Ahn, S-H; Kang, Y J, J.
`Compos. Mater., 44, 1701-16, 2010.
`Terluran, BASF
`Terluran, BASF
`Terluran, BASF
`
`Terluran, BASF; Karahaliou, E K;
`Tarantili, P A, Polym. Eng. Sci., 49,
`2269-75, 2009.
`Terluran, BASF
`Jin, F-L; Lu, S-L, Song, Z-B; Pang,
`J-X; Zhang, L; Sun, J-D; Cai, X-P,
`Mater. Sci. Eng., A527, 3438-41,
`2010; Terluran, BASF; Cevian,
`Daicel
`Vitands, E, Antec, 2986-2991, 1996.
`Lee, J-W; Lee, J-C; Pandey, J; Ahn,
`S-H; Kang, Y J, J. Compos. Mater.,
`44, 1701-16, 2010; Karahaliou, E K;
`Tarantili, P A, Polym. Eng. Sci., 49,
`2269-75, 2009.
`Basurto, F C; Garcia-Lopez, D;
`Villarreal-Bastardo, N; Merino, J C;
`Pastor, J M, Composites: Part B, 47,
`42-7, 2013.
`
`Compressive strength
`
`MPa
`
`65-86; 120 (30% glass fi ber)
`
`HANDBOOK OF POLYMERS / Copyrights 2016; ChemTec Publishing
`
`7
`
`Copyright Elsevier 2020 This book belongs to Maria Jamass
`
`Philip Morris Products, S.A.
`Exhibit 1033
`Page 015
`
`

`

`ABS poly(acrylonitrile-co-butadiene-co-styrene)
`
`PARAMETER
`Charpy impact strength,
`unnotched, 23oC
`Charpy impact strength,
`unnotched, -30oC
`Charpy impact strength, notched,
`23oC
`Charpy impact strength, notched,
`-30oC
`Izod impact strength, notched,
`23oC
`
`UNIT
`
`kJ m-2
`
`VALUE
`
`120-190 to NB
`
`kJ m-2
`
`80-140
`
`kJ m-2
`
`kJ m-2
`
`5-40
`
`2-25
`
`J m-1
`
`30-450
`
`Izod impact strength, notched,
`-40oC
`Shear modulus
`Rockwell hardness
`
`J m-1
`
`MPa
`-
`
`8-280
`
`700-1,50
`101; 102-124
`
`Ball indention hardness at 358
`N/30 S (ISO 2039-1)
`Shrinkage
`
`MPa
`
`97
`
`%
`
`0.4-0.7; 0.72 (across the fl ow), 1.11 (along the fl ow)
`
`Melt viscosity, shear rate=1000 s-1 Pa s
`
`140-250
`
`Melt volume fl ow rate (ISO 1133,
`procedure B), 220oC/10 kg
`Pressure coeffi cient of melt
`viscosity, b
`Melt index, 230oC/3.8 kg
`
`cm3/10
`min
`G Pa-1
`
`2-34
`
`33.7
`
`g/10 min 1.5; 2.5-7.0; 18-34
`
`Water absorption, equilibrium in
`water at 23oC
`Moisture absorption, equilibrium
`23oC/50% RH
`
`%
`
`%
`
`0.7-1.03
`
`0.21-0.35
`
`CHEMICAL RESISTANCE
`Acid dilute/concentrated
`Alcohols
`Alkalis
`Aliphatic hydrocarbons
`Aromatic hydrocarbons
`Esters
`Greases & oils
`Halogenated hydrocarbons
`Ketones
`Other
`
`-
`-
`-
`-
`-
`-
`-
`-
`-
`-
`
`no resistance to concentrated; good resistance to dilute
`limited resistance; insoluble
`good resistance to dilute
`limited resistance; insoluble
`no resistance
`no resistance
`limited resistance; insoluble: mineral oil
`no resistance; soluble: dichloromethane
`no resistance; soluble: acetone, methyl-ethyl ketone
`resistant: water, salt solutions; soluble: dimethylformamide,
`tetrahydrofuran, toluene
`
`8
`
`HANDBOOK OF POLYMERS / Copyrights 2016; ChemTec Publishing
`
`REFERENCES
`
`Terluran, BASF; Cevian, Daicel
`
`Terluran, BASF; Cevian, Daicel
`
`Terluran, BASF; Cevian, Daicel
`
`Terluran, BASF; Cevian, Daicel
`
`Jin, F-L; Lu, S-L, Song, Z-B; Pang,
`J-X; Zhang, L; Sun, J-D; Cai, X-P,
`Mater. Sci. Eng., A527, 3438-41,
`2010; Terluran, BASF; Cevian,
`Daicel
`Terluran, BASF; Cevian, Daicel
`
`(-); Jin, F-L; Lu, S-L, Song, Z-B;
`Pang, J-X; Zhang, L; Sun, J-D; Cai,
`X-P, Mater. Sci. Eng., A527, 3438-
`41, 2010.
`
`Terluran, BASF; Chang, T; Faison,
`E, Polym. Eng. Sci., 41, 5, 703-10,
`2001.
`Xue, M-L; Yu, Y-L; Rhee, J M; Kim,
`N H; Lee, J H, Eur. Polym. J., 43, 9,
`3826-37, 2007.
`Terluran, BASF
`
`Aho, J; Syrjala, S, J. Appl. Polym.
`Sci., 117, 1076–84, 2010.
`
`Karahaliou, E K; Tarantili, P A,
`Polym. Eng. Sci., 49, 2269-75,
`2009; (-); Jin, F-L; Lu, S-L, Song,
`Z-B; Pang, J-X; Zhang, L; Sun, J-D;
`Cai, X-P, Mater. Sci. Eng., A527,
`3438-41, 2010,
`Terluran, BASF
`
`Terluran, BASF
`
`Terluran, BASF
`Terluran, BASF
`Terluran, BASF
`Terluran, BASF
`Terluran, BASF
`Terluran, BASF
`Terluran, BASF
`Terluran, BASF
`Terluran, BASF
`Terluran, BASF
`
`Copyright Elsevier 2020 This book belongs to Maria Jamass
`
`Philip Morris Products, S.A.
`Exhibit 1033
`Page 016
`
`

`

`ABS poly(acrylonitrile-co-butadiene-co-styrene)
`
`UNIT
`
`VALUE
`
`REFERENCES
`
`PARAMETER
`
`Good solvent
`
`Non-solvent
`
`Chemicals causing
`environmental stress cracking
`
`Eff ect of EtOH sterilization
`(tensile strength retention)
`
`FLAMMABILITY
`Autoignition temperature
`Limiting oxygen index
`
`-
`
`-
`
`acetophenone, aniline, benzene, chlorobenzene, chloroform,
`dimethylformamide, dioxane, ethyl benzene
`cyclohexane, diethanolamine, diethylene glycol, dipropylene
`glycol, petroleum ether
`nonionic surfactants
`
`%
`
`105-110 (high gloss); 82-95 (low gloss)
`
`oC
`% O2
`
`>400
`18.1-20.5; 23-35 (with fl ame retardants)
`
`Kawaguchi, T; Nishimura, H; Kasa-
`hara, K; Kuriyama, T; Narisawa, I,
`Polym. Eng. Sci., 43, 2, 419-30,
`2003.
`Navarrete, L; Hermanson, N, Antec,
`2807-18, 1996.
`
`Terluran, BASF, MSDS
`
`Yan, l; Zheng, Y; Liu, J; Shang, H,
`J. Appl. Polym. Sci., 115, 957-62,
`2010; Hourston, D J, Shreir’s Corro-
`sion, Elsevier, 2010, Chapter 3.31,
`2369-2386; Li, Y; Zheng, Y; Liu, J;
`Shang, H, J. Appl. Polym. Sci., 115,
`957-62, 2010; Ren, Y-y; Chen, L;
`Zhang, Z-y; Wang, X-l; Yang, X-s;
`Kong, X-j; Yang, L, Polym. Deg.
`Stab., 109, 285-92, 2014.
`Du, X; Yu, H; Wang, Z; Tang, T,
`Polym. Deg. Stab., 95, 587-92,
`2010; Yu, B; Liu, M; Lu, L; Dong, X;
`Gao, W; Tang, K, Fire Mater., 34,
`251-61, 2010.
`Padey, D; Walling, J; Wood A, Poly-
`mers in Defence and Aerospace
`2007, Rapra, 2007, paper 15.
`Yang, S; Castilleja, J R; Barrera, E
`V; Lozano, K, Polym. Deg. Stab.,
`83, 3, 383-88, 2004; Du, X; Yu,
`H; Wang, Z; Tang, T, Polym. Deg.
`Stab., 95, 587-92, 2010; Karahaliou,
`E K; Tarantili, P A, Polym. Eng. Sci.,
`49, 2269-75, 2009; Lyon, R E; Wal-
`ters, R N, J. Anal. Appl. Pyrolysis,
`71, 27-46, 2004.
`Walters, R N; Hacket, S M; Lyon, R
`E, Fire Mater., 24, 5, 245-52, 2000.
`
`Yang, S; Castilleja, J R; Barrera, E
`V; Lozano, K, Polym. Deg. Stab.,
`83, 3, 383-88, 2004; Polli, H; Pon-
`tes, L A M; Araujo, A S; Barros, J M
`F; Fernandes, V J, J. Therm. Anal.
`Calorimetry, 95, 1, 131-34, 2009.
`Yang, S; Castilleja, J R; Barrera, E
`V; Lozano, K, Polym. Deg. Stab.,
`83, 3, 383-88, 2004.
`Yang, S; Castilleja, J R; Barrera, E
`V; Lozano, K, Polym. Deg. Stab.,
`83, 3, 383-88, 2004; Karahaliou, E
`K; Tarantili, P A, Polym. Eng. Sci.,
`49, 2269-75, 2009.
`Yang, S; Castilleja, J R; Barrera, E
`V; Lozano, K, Polym. Deg. Stab.,
`83, 3, 383-88, 2004.
`
`Heat release
`
`kW m-2
`
`1037; 602-796 (with organoclays); 243-268 (with fl ame
`retardant
`
`NBS smoke chamber
`
`Char, 554oC
`
`Ds
`
`%
`
`800
`
`0-0.6; 9.4; 0.43-2.89
`
`Heat of combustion
`
`J g-1
`
`39,840
`
`CO yield
`UL 94 rating
`
`%
`-
`
`13
`HB
`
`THERMAL STABILITY
`Activation energy under nitrogen
`
`kJ mol-1
`
`134.5-242.4
`
`Activation energy under air
`
`kJ mol-1
`
`156.3
`
`Temperature of maximum
`degradation (air)
`
`Weight loss
`
`oC
`
`%
`
`428-445 (1st step); 554 (2nd step)
`
`85.6 (1st step); 13.8 (2nd step)
`
`HANDBOOK OF POLYMERS / Copyrights 2016; ChemTec Publishing
`
`9
`
`Copyright Elsevier 2020 This book belongs to Maria Jamass
`
`Philip Morris Products, S.A.
`Exhibit 1033
`Page 017
`
`

`

`REFERENCES
`
`Duh, Y-S; Ho, T-C; Chen, J-R; Kao,
`C-S, Polymer, 51, 2, 171-84, 2010.
`
`Jouan, X; Gardette, J L, J. Polym.
`Sci., Polym. Chem., 29, 685, 1991;
`Bokria, J G; Schlick, S, Polymer, 43,
`3239-46, 2002.
`Santos, R M; Botelho, G L;
`Machado, A V, J. Appl. Polym. Sci.,
`2005-14, 2010.
`
`ABS poly(acrylonitrile-co-butadiene-co-styrene)
`
`PARAMETER
`
`UNIT
`
`VALUE
`
`Onset temperature of oxidation
`
`Heat of oxidation
`
`WEATHER STABILITY
`Activation wavelengths
`Depth of UV penetration
`
`Prod