NBS CIRCULAR 514
`AD-A278 956
`lltl
`11111111111111111
`IIIliii 11111
`1111
`Table of Dielectric Constants
`of Pure Liquids
`
`DTICELECTESAPR
`
`2 81994
`
`UNITED STATES DEPARTMENT OF COMMERCE
`NATIONAL BUREAU OF STANDARDS
`
`MYLAN INST. EXHIBIT 1129 PAGE 1
`
`MYLAN INST. EXHIBIT 1129 PAGE 1
`
`

`

`a7
`
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`MYLAN INST. EXHIBIT 1129 PAGE 2
`
`MYLAN INST. EXHIBIT 1129 PAGE 2
`
`

`

`UNITED) STA
`ES)IP.RI'NEN'r OF COMMERCE *Charles
`Sawyer, Srcretary
`NATIONAL. BUF ýAU OF STANDARD)S
`e E. U. Condon,, Dirtelo,
`
`Table of Dielectric Constants
`of Pure Liquids
`
`Arthur A. Maryott and Edgar R. Smith
`
`Accesion For
`NTIS CRAMi
`OTIC
`TAB
`Unannounced
`Justification
`
`By -...... .........
`Distr ibution I
`Availability Codes
`Avail and/ or
`-Special
`
`Dist
`
`National Bureau of Standards Circular 514
`Issued August 10, 1951
`94-12769
`
`For ale by the S
`
`n n
`
`fDcu
`
`a
`
`..
`
`o
`
`it
`
`a
`
`
`e t o
`ino2,
`
`V~~
`
`062
`
`MYLAN INST. EXHIBIT 1129 PAGE 3
`
`MYLAN INST. EXHIBIT 1129 PAGE 3
`
`

`

`Page
`
`Contents
`1. Introduction -------------
`--------------------------------
`2. Description of table ---.--------------------------------------
`2.1 List of svmhol
`........-------------------
`.
`-..
`2.2 Standard liquids ----------------------
`-----------
`2.3 Chemical formulas and the order of listing of substances
`_II
`2.4 Estimated accuracy of the values of fiielectric constant_-
`2.5 Variation of dielectric constant with temperature ----------
`2.6 Literature references in table --------------------------
`3. Table of dielectric constants ----------------------------
`A. Standard liquids- --.----------------------------------
`B. Inorganic liquids- -------------------
`C. Organic liquids ----------------
`-----------------------
`4. Bibliography ---------------------------------------------
`
`Iv
`Iv
`Iv
`7
`8
`15
`40
`
`I!
`
`MYLAN INST. EXHIBIT 1129 PAGE 4
`
`MYLAN INST. EXHIBIT 1129 PAGE 4
`
`

`

`Table of Dielectric Constants of Pure Liquids
`Arthur A. Maryott and Edgar R. Smith
`The "static" dielectric constants of more than 800 substances in the liquid state were
`critically examined and tabulated ini concise form. Tihe table consists of three sections: A,
`Standard Liquids; 13, Inorganic liquids; and (', Organic Liquids. An indication of the prob-
`able accuracy of the data is given. Wherever feasible, a simple analytical fuinction is em-
`ployed to express the variation of dielectric constant with temperature.
`1. Introduction
`quency is given in a footnote. Temperature is
`the only variable considered explicitly. Usually
`This tabulation of the dielectric constants of
`the pressure is atmospheric or insignificantly differ-
`pure liquids is part of a program for a critical ex-
`ent with respect to its effect on dielectric constant.
`amination of the data of physics and chemistry,
`However, where data are listed at temperatures
`sponsored by the National Bureau of Standards in
`above the normal boiling point, the pressure cor-
`cooperation with the Committee on Tables of
`responds to the vapor pressure of the liquid unless
`Constants and Numerical Data of the National
`indicated otherwise in a footnote.
`Research Council and the Commission on Tables
`of Constants of
`the International Union of
`2.1. List of Symbols
`Chemistry. The preparation of additional tables
`of the dielectric constants of gases, solids, aqueous
`C = I)
`I=dielectric constant. ('
`t1= temperature, Celsius (°C)
`and nonaqueous solutions and mixtures, and of
`T=temperature, absolute (0 K)
`dipole moments is in progress.
`a=-de/t
`The assemblage and evaluation of the data
`a=-dlogio e/dt
`have been made entirely at the National Bureau
`f=frequency of alternating current in cycles per
`Sbsecond
`of Standards with the assistance of 'I. Eden
`t1, t2=the limits of temperature between which a or
`during the preliminary stages. However, helpful
`a is considered applicable
`suggestions from M. E. Hobbs of Duke University,
`mp = melting point
`C. P. Smyth of Princeton University, and the
`bp=boiling point
`2.2. Standard Liquids
`Committees of the National Research Council
`and International Union of Chemistry are grate-
`fully acknowledged. The compilations of P.
`Section A contains values of the dielectric con-
`Debye and H. Sack (Tables de Constantes et
`stant at selected temperatures for 10 substances
`Donn6es Numdriques XI, Fasicule 2, 1931-34;
`that are recommended as reference liquids because
`XII, Fasicule :32, 1935-:36 and earlier volumes of
`of their chemical stability, availability, and the
`Tables Annuelles), International Critical Tables,
`reliability of the data. The probable 'accuracy is
`and Landolt-Bornstein Tabellen have been useful
`estimated to be about 0.2 percent for methanol
`in checking the tables for accuracy and complete-
`and nitrobenzene and about 0.1 percent
`in the
`ness. In several instances data have been obtained
`remaining cases. Values of a or a are included
`from the Tables of Dielectric Materials, volume
`for
`interpolating or for extrapolating over a
`III, prepared by the Laboratory of Insulation
`limited range of temperature without materially
`Research, Massachusetts Institute of Technology,
`altering the accuracy. Additional (lata for these
`Cambridge, Mass., 1948.
`substances are contained in sections B or C.
`2. Description of the Table
`2.3. Chemical Formulas and the Order of
`Listing Substances
`The table consists of three sections: A, Standard
`Liquids, B, Inorganic Liquids, C, Organic Liquids.
`Formulas for
`the
`inorganic substances are
`The (dielectric constants are intended to be the
`written in the usual manner. The order of listing
`limiting values at low frequencies, the so-called
`compounds in section B is alphabetical according
`"static" values. Data obtained at such high fre-
`to the symbols for the elements in these formulas
`quencies that anomalous dispersion was evident
`with consideration also given to the number of
`are not included.
`In questionable cases the fre-
`atoms of each kind.
`
`lII
`
`MYLAN INST. EXHIBIT 1129 PAGE 5
`
`MYLAN INST. EXHIBIT 1129 PAGE 5
`
`

`

`IV
`INTRODUCTION
`Formulas for the organic compounds are written
`2.5. Variation of Dielectric Constant With
`with carbon first and hydrogen, if present, second.
`Temperature
`Symbols for all remaining elements then follow ill
`the variation of dielectric
`feasible,
`Where
`alphabetical sequence The arrangement of these
`compounds in section C is determined first by the
`constant with temperature is represented by one
`of the following equations:
`number of carbon atoms, secondliv b% tile nulnber
`of hydrogen atoms, and finally by thle symbols for
`the remaining helements in alphal)etical order.'
`2.4. Estimated Accuracy of the Values
`of Dielectric Constant
`Values of dielectric constant recorded in sections
`B and C have an estimated accuracy indicated by
`tie number of figures retained.
`(a) Values listed to four figures are considered
`probably accurate to 0.5 percent or better,
`(b) Values listed
`to three figures are con-
`sidered probably accurate to 2 percent or better.
`(c) Values listed to two figures are considered
`probal)ly less accurate than 2 percent.
`lack of detailed
`However, where
`information
`makes any assignment of accuracy difficult or
`where excessive rounding off is undesirable, an
`additional figure is often retained which is not to
`be counted in determining the probable range of
`accuracy. Such
`figures are printed
`in smaller
`type as subscripts. They are also retained when
`significant with respect to variations of dielectric
`constant with
`temperature or
`to differences
`between isomeric or other closely related com-
`pounds in a series of measurements.
`These estimates of accuracv were assigned
`arbitrarily after considerations of the
`investi-
`gators' apparatus and methods, precision, prob-
`able purity of materials, and comparisons, where
`possible, with the results of others,
`Exception is made for certain series of polymers (e. g., polysiloxanes)
`which may he represented by the general formula (X). or .4(X).H. where
`n = 1, 2. 3. etc. The location of all compounds of such a series is determined
`hy the formuia corresponding to n-l.
`
`g10 et-Log,0 f,-a(t'-t
`(2)
`where •,, 1, and a (or a if the value is followed
`immediately by a in parentheses) are specified in
`the table. Occasionally other equations are in-
`dicated in footnotes.
`The range of temperature over which the equa-
`tion is considered satisfactory appears under the
`heading t,, t2. This range was chosen such that
`the deviations between the calculated and reported
`values of e are not greater than one-fourth of the
`accuracy assigned to E. Thus if E is listed to four
`figures (discounting figures in smaller type), the
`equation fits the reported data to 0.13 percent or
`better over the specified range of temperature;
`and,
`if e is listed to three figures (discounting
`figures in smaller type), the equation fits the data
`to 0.5 percent or better. Values of e falling out-
`side of this range of temperature are listed at
`selected temperatures.
`2.6. Literature Reference in Table
`All tabulated data are based on the references
`indicated by numbers not enclosed in brackets.
`The numbers refer to the bibliography following
`the table. Some additional references not em-
`ployed for one reason or another are enclosed in
`brackets. These latter references are not
`in-
`tended to be complete with regard to data pub-
`lished for each substance but have been selected
`on the basis that they probably merit considera-
`tion in any revision of the tabulated data.
`
`MYLAN INST. EXHIBIT 1129 PAGE 6
`
`MYLAN INST. EXHIBIT 1129 PAGE 6
`
`

`

`Table of Dielectric Constants
`of Pure Liquids
`
`MYLAN INST. EXHIBIT 1129 PAGE 7
`
`MYLAN INST. EXHIBIT 1129 PAGE 7
`
`

`

`A. STANDARD LIQUIDS
`
`CGH12
`CC14
`CoNs
`
`Cyclohexane ............................................
`Carbon tetrachloride ...................................
`Benzene ................................................
`
`Cam0 Ce
`
`Chlorobenzene ..........................................
`
`1,2-Dichloroethane .....................................
`Methanol ...............................................
`
`C2H4Ca 2
`CN4O
`CGNHN02 Nitrobenzene ...........................................
`" 20
`Water ..................................................
`H 2
`
`Hydrogen ...............................................
`
`02
`
`Oxygen ................................................
`
`E DO c
`
`E 2o 0
`
`a (or a)
`
`2.023
`2.238
`
`2.284
`
`5.708
`
`10.65
`
`33.62
`
`35.74
`
`80.37
`
`2.015
`2.228
`2.274
`
`5.621
`
`10.36
`
`32.63
`
`34.82
`
`78.54
`
`0.0016
`.0020
`.0020
`
`.00133
`
`(a)
`
`.00240 (a)
`
`.00260 (a)
`
`.00225 (q)
`
`.00200 (a)
`
`1.228 at 20.14 K
`
`1.507 at 80.O°K
`
`.00314
`
`.0024
`
`*The values of a or a given in this table are derived from data in the vicinity of room temperature and
`are not necessarily identical with the values listed in Parts 8 and C. They may be used to calculate values
`of dielectric constant between 150 and 300 C without introducing significant error.
`
`(1)
`
`MYLAN INST. EXHIBIT 1129 PAGE 8
`
`MYLAN INST. EXHIBIT 1129 PAGE 8
`
`

`

`INORGANIC LIQUIDS
`a (or a) Range
`x10 2
`t2.tr
`
`toc
`
`E
`
`References
`
`0.34
`0.33
`....................
`....................
`0.43
`....................
`0.28
`0.7
`....................
`0.31
`0.32
`
`-191,-184
`100,240
`
`-116,-72
`
`-70,80
`0,50
`
`-65,-33
`-22,114
`
`93
`226
`17,20
`14,17,20
`183 [30]
`20
`265
`64,87,226
`39 [10,313
`193
`5,10,19
`
`1.53o
`3.38
`9.0a
`12.e'
`2.50
`7..0 b
`2.58
`3.09
`1.60c
`2.101
`1.91
`1.7,
`1.54
`2.6'
`1.277
`78.25
`1.54
`2.430
`7.00
`3.8b
`6.35
`12.
`4.6
`17,.
`134.
`Ill.
`84.
`3.39
`2.9b
`1.228
`78.54
`
`-191
`100
`35
`20
`-100
`150
`0
`20
`20
`-50
`111
`77
`142
`20
`20 0K
`25
`-202
`25
`-85
`25
`-15
`-113
`28
`-73
`-142
`-27
`
`0
`-50
`22
`20.4 0K
`25
`
`B.
`
`Substance
`
`Argon ........................
`Aluminum bromide .............
`Arsenic tribromide ...........
`Arsenic trichloride ..........
`Arsine .......................
`Arsenic triiodide ............
`Boron bromide ................
`Bromine ......................
`Carbon dioxide ...............
`Chlorine ......................
`
`A
`AIBr3
`AsBr 3
`AsC1 3
`ASH3
`Asl 3
`BBr3
`Br2
`C02
`C12
`
`Cr0 2CI 2
`D,
`
`D20
`
`F,
`GeC1 4
`HBr
`
`Chromyl chloride .............
`Deuterium ....................
`Deuterium oxide ..............
`Fluorine .....................
`Germanium tetrachloride ......
`Hydrogen bromide .............
`
`MCI
`
`Hydrogen chloride ............
`
`HF
`
`HI
`
`H2
`H 20
`
`Hydrogen fluoride ............
`
`Hydrogen iodide ..............
`
`Hydrogen .....................
`Water ........................
`
`.
`
`..................
`0.4
`
`(d)
`0.19
`0.240
`0.26(a)
`....................
`0.288(a)
`....................
`....................
`....................
`
`0.8
`....................
`0.34
`(')
`
`17
`18.8,21.2-K 249
`210 [135]
`0.4,98
`193
`-216,-i9O
`0,55
`147
`137 [296]
`-85,-70
`25
`173
`101,137,193
`25
`75
`
`-85,-15
`
`-51,-37
`
`137
`25
`14,21-K 47,58,220,229,249
`89,99,210,218 [50a,
`0,100
`105,112,118,264]
`284
`291 [119]
`
`1) 900,370
`-30,20
`
`H20 2
`
`Hydrogen peroxide ............
`
`34.5,
`84.2
`
`200
`0
`
`(
`(?)
`
`a f= 4x 10 cycles/sec.
`b 1=3.6 X10" cycles/sec.
`SAt presure of 50 atmospheres.
`4 E =78.25 [1 - 4.617(10-3)(t- 25) +1.22(10-5)(t- 25)2
`-2.7(10-8)(t-25)3]; av. dev. ±0.0O4%.
`(2)
`
`[I - 4.579(l0- 3)(t- 25) +1.19(10-5)
`E =78.54
`(t-25f- 2.8 (10-)(t - 25)3]; av. dev. +0.03%.
`YE =5321/T+233.76- 0.9297T+0. 001417T
`-0-0000008292T 3.
`"E84.2- 0.62t+O.0032t 2 .
`
`MYLAN INST. EXHIBIT 1129 PAGE 9
`
`MYLAN INST. EXHIBIT 1129 PAGE 9
`
`

`

`B.
`
`INORGANIC LIQUIDS-Continued
`
`a (or a)
`tReferOence
`2
`
`Range
`
`References
`
`Substance
`
`Hydrogen sulfide .............
`
`Helium .......................
`
`Iodine .......................
`
`Ammonia ......................
`
`Nitrosyl bromide .............
`Nitrosyl chloride ............
`Nitrogen ......................
`Hydrazine ....................
`Dinitrogen oxide .............
`
`Dinitrogen tetroxide .........
`Oxygen .......................
`Phosphorus ...................
`
`Phosphorus tribromide ........
`Phosphorus trichloride .......
`Phosphorus pentachloride.....
`Phosphine ....................
`
`HS
`
`He
`
`12
`
`NH3
`
`NOBr
`NOCl
`N2
`N2H4
`N20
`
`N204
`02
`P
`
`PBr 3
`PCi 3
`PCl5
`PH3
`
`Phosphorus triiodide .........
`Phosphoryl chloride ..........
`Thiophosphoryl chloride ......
`Lead tetrachloride...........
`
`9.26
`9.05
`1.0555
`1.0559
`1.0553
`1.0539
`1.051e
`1.048
`11.1
`II.?
`13.o
`25.
`22.4
`18.9
`17.8
`16.9
`16.3
`13.4
`18.2
`1.454
`52.9
`1.97
`1.61
`2.5seb
`1.507
`4.10
`4.06
`3.86
`3.9b
`3.43
`2.85
`2.5,b
`2.7,b
`4.1b
`13.3
`5.8
`2.78
`
`955049 0
`
`- 51 - 2
`
`-85.5
`-78.5
`2.060 K .
`2.30O
`2.63
`3.09
`3.58
`4.19
`118
`IIto
`168
`-77.7
`-33. 4.
`5
`15
`25
`35
`15
`12
`-203
`20
`-90
`0
`15
`-193
`34
`46
`85
`20
`25
`160
`-60
`-25
`65
`22
`22
`20
`
`.
`
`.
`
`.
`
`.
`
`..................
`...................
`..................
`
`152
`165
`46,72,73 [290]
`
`........
`
`..........
`
`..........
`
`........
`...................
`....................
`
`117
`
`152
`144
`175
`
`....................
`....................
`0.29
`0.21(a)
`....................
`0.6
`....................
`0.214
`..................
`
`-210,-195
`0,25
`
`-6,14
`
`-218,-183
`
`252
`252
`54,205,229 L93J
`123
`11,93
`5
`20
`59,193,224
`126 E20]
`
`....................
`20
`120 L14,20,26]
`1',60
`0.84
`.........
`120 1108]
`.........
`................... 28
`
`....................
`....................
`....................
`..........
`
`.........
`
`20
`14,26
`26
`65
`
`P13
`POC1 3
`PSCI 3
`PbCl 4
`b f =3.6 X 10" cycles/sec.
`rLiquid transition and discontinuity in variation of dielectric constant with temperaturb at 2.2950 K.
`Values reported in reference 290 agree closely with those listed.
`
`MYLAN INST. EXHIBIT 1129 PAGE 10
`
`MYLAN INST. EXHIBIT 1129 PAGE 10
`
`

`

`B.
`
`Substanco
`
`Sulf I ......................
`
`Thionyl bromide ..............
`Thionyl chloride .............
`Sulfur dioxide ...............
`
`Sulfur trioxide ..............
`Sulfur monochloride ..........
`Sulfuryl chloride ............
`Antimony tribromide ..........
`Antimony trichloride .........
`Antimony pentachloride .......
`; .........
`Stibine ............
`
`Antimony triiodide ...........
`Selenium .....................
`Silicon tetrachloride ........
`Tin tetrachloride ............
`Titanium tetrachloride .......
`Vanadium tetrachloride .......
`Vanadium oxybromide ..........
`
`Vanadium oxychloride .........
`
`INORGANIC LIQUIDS-Continued
`a (or
`'•)
`a2C
`
`E
`
`t
`
`Range
`
`References
`
`3.52
`3.48
`9.06
`9.25
`17.6
`15.08
`14.1
`2.1o
`3.11
`4.79
`I0.o
`2 0 .9b
`33.b
`3.22
`2.9 3 b
`2 . 58 b
`1 3 ,b
`5.40
`2.4o
`2.87
`2.80
`3.05b
`.4 b
`3. 6 b
`3..4 b
`
`fig
`231
`20
`20
`-20
`0
`20
`154h
`is
`Is
`22
`100
`75
`20
`-80
`-50
`175
`250
`16
`20
`20
`25
`-70
`25
`25
`
`.
`
`(9)
`
`.........
`
`125 [95J
`
`at 20
`at 20
`-65,-15
`
`14,1•10
`
`..........
`-41,15
`
`.........
`2,47
`
`237,301
`
`-30,20
`-20,20
`
`3.0
`3.9
`0.287(a)
`....................
`7.7
`
`.........
`0.1 6(c)
`....................
`....................
`..........
`0.46
`....................
`
`....................
`0.25
`....................
`0.30
`0.20
`....................
`....................
`
`....................
`
`203
`203 [l14
`299
`294
`5,10,15 [l4-j
`
`197 f1q1j
`92 L114,26]
`26 [14.171
`20
`14
`108 [lit]
`28
`
`20
`209
`20
`65,124 L14,22,26]
`65,124 [22]
`33
`33
`
`33
`
`S
`
`SOrta
`SOcla
`SO,
`
`s0o
`SaCla
`SOaC1 2
`Sb8r3
`SbC13
`SbCl5
`SbH3
`
`Sb1 3
`Se
`SiCl 4
`SnCl 4
`TiC14
`VC14
`VOBr 3
`
`VOCl 3
`
`b f =3.6 xlO1 cycles/sec.
`'Graphical data in the range 118 0 -350 0 C show a minimum near 1600 and a broad maximum near 2000.
`hCritical temperature.
`
`MYLAN INST. EXHIBIT 1129 PAGE 11
`
`MYLAN INST. EXHIBIT 1129 PAGE 11
`
`

`

`C. ORGANIC LIQUIDS
`a (or ci) Range
`xO
`tt
`
`tC
`
`References
`
`Substac
`CI
`Phosgene .....................
`
`Carbon tetrachloride .........
`
`Tetranitrooethane ............
`Carbon dioxide ...............
`Carbon disulfide .............
`
`CCI•O
`
`CC14
`
`CNO,
`CO
`CS,
`
`CNBr 3
`CHC1,
`
`Bromoform ....................
`Chloroform ...................
`
`CNN
`
`Hydrocyanic acid .............
`
`CH2 Br2
`
`CHICI 2
`CH21
`CH20 2
`CH38r
`CHC]
`Cthi
`CHANO
`CHSK0 2
`CHNOs
`CH,
`ChN0
`
`Dibromooethane ...............
`
`Dichloromethane ..............
`Diiodomethane ................
`Formic acid ..................
`Bromomethane .................
`Chloromethane ................
`lodomethane ..................
`Formamide ....................
`Nitromethane .................
`Methyl nitrate ...............
`Methane ......................
`Methanol .....................
`
`. 4 .7 2 b
`4.3 4 b
`2.238
`
`0
`22
`20
`
`2.52,
`1.60,'
`2.641
`3.001
`2.19
`4.39
`4.806
`6.76
`6.12
`5.61
`3.71
`3.3,
`2.9,
`158.1
`I I.q
`7.77
`6.68
`9.08
`5.32
`58.5a
`9.82
`12.6
`7.00
`109.
`35.87
`23.,b
`1.70
`32.63
`64.
`54.
`40.
`
`25
`0
`20
`-110
`180
`20
`20
`-60 .
`-40
`-20
`100
`140
`ISO
`0
`20
`10
`40
`20
`25
`16
`0
`-20
`20
`20
`30
`18
`-173
`25
`-113
`-80
`-20
`
`.........
`
`.........
`
`52
`
`0.200
`
`-10,60
`
`.
`
`...................
`....................
`0.268
`
`-90,130
`
`146,169,233,240a,
`245,292
`225 [26]
`139 [10,31]
`16,146,188,196,204,
`240a,292
`[80,200,20o7
`97,156,160
`10,70
`0.105(a)
`85,146,169
`0,50
`0.160(a)
`................... 70,94,187 E36,801
`
`.......... ..........
`
`16
`
`-13,18
`(1)
`18,26
`0.63(,)
`.................... 97
`
`255 r39,761
`
`(J)
`....................
`..................
`
`.
`
`(k)
`(1)
`
`(i)
`
`72.
`0.189(a)
`...................
`0.2
`0.264(a)
`..........
`
`-80,25
`
`-80,0
`-70,-20
`-70,40
`18,25
`12.92
`
`-181,-159
`5,55
`.........
`
`94,285
`97 [12"
`7 E4,27-I
`94 [2821
`94,123
`94 E12,41,1601
`270,280
`78,295 [411
`14
`93
`218,264 [7t,112,207]
`9
`
`"f = , x log cycles/sec.
`b f= 3.6 X 109 cycles/sec.
`cAt pressure of 50 atomspheres.
`Log o c = 2.199 - 0.0079t +0.00005t2
`
`J 6 = (3320/T) - 2.24
`k 6 = (3320/T) - 2.34
`' e= 12.6-0.061 (t+20) f0.0005 (t +20)2
`ffiE=(2160/ T) - 0.39
`
`(•)
`
`MYLAN INST. EXHIBIT 1129 PAGE 12
`
`MYLAN INST. EXHIBIT 1129 PAGE 12
`
`

`

`6
`
`Substanc
`
`C. ORGANIC LIOUIDS-Continued
`a (or a)
`X102
`
`toC
`
`E
`
`Range
`ti~ta
`
`References
`
`CHN
`
`Methylamine ....................
`
`C2
`Oxalyl chloride ..............
`Tetrachloroethylene ..........
`Cyanogen .....................
`Bromal .......................
`Trichtoroethylene ............
`Chloral ......................
`
`C2C12 02
`C2C04
`CIN2
`C2 HBr 3O
`C2HC1S
`C 2HC 30
`
`C2HC1 302 Trichioroacetic acid .........
`C2HCi 5
`Pentachloroethane ............
`C2HF,0 2
`Trifluoroacetic acid .........
`
`C2HaBrCl
`
`C2H2Br2
`
`cis-I-Bromo-2-chloroethylene...
`trans-I-Bromo-2-
`chloroethylene
`cis-l,2-Dibromoethylene ......
`
`trans-I,2-Dibromoethylene ....
`
`C2H2 Br 20
`C2H2 8r 4
`
`Bromoacetyl bromide ..........
`l,I,2,2-Tetrabromoethane .....
`
`C2 HIC1 2
`
`1,1-Dichloroethylene .........
`cis-1v2-Dichloroethylene .....
`trans-I,2-Dichloroethylene...
`C2112C10202 Dichloroacetic acid ..........
`
`C2H2C04
`C2H212
`
`C•2 •8r0
`
`1,1,2,2-Tetrachioroethane ....
`cis-i,2-Diiodoethylene .......
`trans-l,2-Diiodoethylene .....
`Acetyl bromide ...............
`
`.
`
`* f = 4 x 108 cycles/sec.
`" f = 5 x 10 cycles/sec.
`
`i.1A
`9.14
`
`10
`25
`
`0.26(Q)
`..........
`
`-30,-10
`..........
`
`123
`268
`
`3.47
`2.30
`2.5,
`7.6"
`3.142
`4.94
`7.6
`4.2
`4.6
`3.73
`39.5
`26.2
`7.3,
`2.5o
`
`7.72
`7.0,
`2.97
`2.8R
`122.4
`8.6
`7.0
`4.67
`9.20
`2.14
`8.2
`7.8
`8.20
`1.110
`3.1,
`16.s'
`
`21
`25
`23
`20
`ca 16
`20
`-I0
`62
`60
`20
`20
`-II
`17
`17
`
`0
`25
`0
`25
`20
`3
`22
`16
`25
`25
`22
`61
`20
`83
`83
`20 ..
`
`.
`.
`
`....................
`0.20
`..................
`..................
`...................
`0.17(Q)
`
`.....................
`....................
`-50.
`
`....................
`....................
`
`...................
`
`....................
`
`...................
`...................
`
`....................
`....................
`..................
`....................
`
`...................
`....................
`....................
`...................
`
`25,90
`
`107
`100,196,279 [741
`14
`27
`45
`
`15,45
`
`E4 [1,71
`
`0,28
`
`26
`45,57,156
`297
`
`49
`49
`
`148 [It9
`18 [1491
`
`17
`26
`
`149
`227 [45,18,09,148]
`196,227[05,4S,-49,18]
`26 [271
`
`53 [45,571
`48
`48
`17
`
`MYLAN INST. EXHIBIT 1129 PAGE 13
`
`MYLAN INST. EXHIBIT 1129 PAGE 13
`
`

`

`C. ORGANIC LIQUIDS-Continued
`la -(or a)
`a (
`xlO0
`
`toC
`
`E
`
`Substance
`
`7
`
`Range
`t)
`tt~t
`
`References
`
`CHClO
`
`Acetyl chloride ..............
`
`C2H 3CI0 2 Chloroacetic acid ............
`1,1,1-Trichloroethane ........
`C2H3Cl3
`
`C2H 3 N
`
`C2H3NO
`C2NsNS
`
`C2H4BrCl
`
`Acetonitrile .................
`
`Glycolonitrile ...............
`Methyl thiocyanate ...........
`Methyl
`isothiocyanate ........
`I-Bromo-2-chloroethane .......
`
`C2H4 Br2
`
`1,2-Dibromoethane ............
`
`C2 H4C12
`
`5,I-Dichloroethane ...........
`1,2-Dichloroethane ...........
`
`C2H4N20
`C2H40
`
`Ethylene nitrate .............
`Ethylene oxide ...............
`Acetaldehyde ..................
`
`C2H403
`
`C211402
`
`Ethanethiolic acid ...........
`(Thioacetic acid)
`Acetic acid ..................
`
`Methyl formate ...............
`Bromoethane ..................
`
`C2H5Br
`
`CHC1
`
`Chloroethane .................
`
`C21sClO
`
`2-Chloroethanol ..............
`(Ethylene chlorohydrin)
`
`16.9
`15."
`12.3
`7.1o
`7.52
`37.5
`26.,
`68.'
`35.a
`19.3a
`7.14
`7.98
`.78
`4.09
`.0.0
`10.65
`10.36
`10.3 6
`12.7
`28.,
`13.,
`21.,-
`21.1a
`13.a
`
`.
`
`2
`22
`60
`0
`20
`20
`82
`20
`16
`38
`20
`-10
`25
`131
`18
`20
`25
`25
`-10
`20
`-1
`10
`21
`20
`
`...................
`
`2.
`3.6
`..........
`16.
`
`..........
`...................
`...................
`0.O140(a)
`
`0.60
`.........
`.........
`...................
`0.235(a)
`
`..................
`.........
`.........
`
`...................
`
`60,80
`-33,2
`.........
`15,25
`
`.........
`
`10,90
`
`10,55
`.........
`.........
`
`10,55
`
`.........
`.........
`
`26 [7,171
`
`123 [1811
`234
`156
`13,26,41,123
`
`17
`17,18,22
`17,18,22
`I10
`
`12,144,156,199,272
`41
`1,27
`138,170,263
`123,133,254,272
`
`244
`26
`7 [41
`
`17 E[87
`
`20
`6.15
`6.29
`40
`70
`6.62
`8.5
`20
`9.39
`20
`16.1
`-90
`13.6
`-60
`170
`6.29
`179
`6.0,
`183
`5.13
`4..6, 18 5 .5 h
`25
`25.,
`132
`13.2
`
`.........
`
`.........
`
`96,207 E7,1811
`
`5.
`0.196(a)
`
`0,20
`-30,30
`
`7,26
`34,70,94 127,272
`[207,2281
`
`.........
`
`.........
`
`..................
`
`15
`
`41
`
`Sf=4X JOs cycles/sec.
`h Critical temperature.
`"Value chosen to conform with the remainder of the tabulated data for this substance.
`
`MYLAN INST. EXHIBIT 1129 PAGE 14
`
`MYLAN INST. EXHIBIT 1129 PAGE 14
`
`

`

`8
`
`C. ORGANIC LIQUIDS-Continued
`
`Substancft
`
`Is
`
`t
`
`a (or a)
`I X102
`
`Range
`t 'ts
`
`References
`
`CaH l
`
`lodoethane ...................
`
`C218NO
`
`Acetamide ....................
`Acetaldehyde oxime ...........
`C2 N1102 Nitroethane ..................
`Ethyl nitrate ................
`CY 5N110
`C2H.N2O
`N-Nitrosodimethylamine .......
`Ethanol ......................
`C2H6 0
`
`Methyl ether .................
`
`(C 2H6OS')n
`n = 4 OctamethylcycIotetrasiloxane..
`n =
`Doecanethylcyclopentasiloxane
`n =6
`Dodecamethylcyclohexasiloxane
`n =7
`Tetradecamethylcyclo-
`heptasiloxane
`Nexadecamethylcyclo-
`octasiloxane
`l.(,
`......
`Methyl sulfate ...............
`
`CA2 N502
`C2H6 04 S
`
`n =8
`
`C2NAS
`
`C2OIN
`
`Ethanethiol ..................
`Methyl sulfide ...............
`Ethylamine ....................
`Dimethylamine ................
`
`C211N2
`
`1,2-Ethanediauine ............
`
`7.82
`12.3
`10.2
`59.4
`3.0
`28.0,
`19.4
`53.4
`24.30
`24.3z
`41.0'
`5.02
`2.97
`2.64
`2.37
`2.26
`1.90
`
`2.39
`2.50
`2.59
`2.68
`
`2.74
`
`37.7
`60.,
`48.3
`42.s
`6.91
`6.2'
`6.94
`6.32
`5.26
`14.2
`
`20
`-90
`-50
`83
`23
`30
`20
`20
`25
`25
`-60
`25
`110
`120
`125
`126.1
`127.6P
`
`20
`20
`20
`20
`
`20
`
`25
`- 30
`0
`20
`15
`20
`10
`0
`25
`20
`
`0.150(a)
`
`-20,70
`
`81,207 [7,12,1601
`
`.........
`...................
`II.4
`9.
`....................
`..................
`0.270(a)
`0.297(a)
`2.38
`
`.
`
`.........
`
`30,35
`0,50
`
`-5,70
`-110,-20
`25,100
`
`17
`26 [17,271
`295 Lilt]
`7,17,26 [4,141•
`17
`111,174
`111,112,207
`81 [971
`161
`
`....................
`...................
`....................
`...................
`
`....................
`
`0.224(a)
`...................
`
`266
`266
`266
`266
`
`266
`
`20,100
`
`112 [26,131, 142,2361
`122 L17,26,1431
`
`...................
`..........
`(0)
`..........
`
`.........
`-20,10
`.........
`
`236
`17
`123 [l11
`268
`
`10.
`
`10,27
`
`199
`
`a f=1,xlO cycles/sec.
`o E -6. 94-0.O036( t- 10) +O.O0004(t-
`temperature = 126.9 0 C.
`'Critical
`'Value chosen to conform with the remainder of the tabulated data for this substance.
`
`1O)2
`
`MYLAN INST. EXHIBIT 1129 PAGE 15
`
`MYLAN INST. EXHIBIT 1129 PAGE 15
`
`

`

`C. ORGANIC LIQUIDS-Continued
`
`•u
`
`lO=
`a (or a)
`
`Range
`i•t
`
`References
`
`46.b
`I14.,"
`7.4
`7.0
`.lI.o.
`6.45
`8.7
`8.2
`17.5
`
`30.n
`25 .,
`22.,
`II.o.
`12. "
`13.3
`
`7.5n
`6.1n
`31.0
`27.2
`214.3
`38.4
`34.5
`29.3
`23.4
`19."
`19.3
`
`36
`20
`I
`19
`21
`20
`I
`20
`20
`
`19
`1
`22
`20
`21
`20
`
`20
`19
`0
`20
`50
`20
`3
`21
`2
`21
`20
`
`....................
`...................
`...................
`
`....................
`...................
`...................
`
`...................
`
`...................
`..................
`
`....................
`...................
`...................
`
`...................
`..........
`.........
`
`.........
`....................
`
`....................
`
`...................
`
`.........
`.........
`
`.........
`
`1.87,
`1.79
`1.69o
`1.53o
`I.1411
`1.33,
`4.3"
`
`20
`145
`65
`85
`90
`91.9h
`20
`
`.........
`
`.........
`
`...................
`
`is
`27
`26
`
`27
`244
`26 [271
`
`244
`
`27
`26 [271
`
`17 [27]
`27
`2414
`
`27
`27
`13,17,26
`
`17
`26 [17,18,22]
`
`26 [17,18,221
`
`244
`
`161
`
`27
`
`Sustnc
`
`Substanco
`C3
`Malononitrile ................
`I,I-Dichloro-2-propanone .....
`3-Iromo-l-propene ............
`
`2N2N
`C3
`C 314 C020
`C 3H 5Br
`
`CM,6rO, a-Bromopropionic acid ........
`1,2,3-Tribromopropane ........
`CH 5 Br3
`3-Chloro-l-propene ...........
`C3 N5 Cl
`
`COHIClO
`
`C3H5C10 2
`
`C 31 5C1N,0 6 3-Chloro-l,2-propanediol
`dinitrate
`I-Chloro-2-propanone .........
`3-Chloro-l,2-epoxypropane ....
`(Epichlorohydrin)
`Ethyl chloroformate ..........
`Methyl chloroacetate .........
`C315C0 2N10 1,3-Dichloro-2-propanol
`nitrate
`1,2,3-Trichloropropane .......
`3-1odo-l-propene .............
`Propionitrile ................
`
`COHICl 3
`C3"11
`CimN
`
`C3 H5NO
`C3HINS
`
`Lactonitrile .................
`Ethyl thiocyanate .............
`
`Ethyl
`
`isothiocyanate .........
`
`C015N309
`
`C
`
`1,2,3-Propanetriol trinitrate
`(Nitroglycerin)
`Propene ......................
`
`C3 NHBr2
`
`1,2-Dibromopropane ...........
`
`£ f=14x I0s cycles/sec.
`b = 3.6 X 10 cycles/sec.
`hCritical temperature.
`" f= 5 x 108 cycles/sec.
`
`MYLAN INST. EXHIBIT 1129 PAGE 16
`
`MYLAN INST. EXHIBIT 1129 PAGE 16
`
`

`

`10
`
`Substance
`
`C. ORGANIC LIQUIDS-Continued
`Range
`a (or a)
`x|O 10sReeene
`
`E
`
`t
`
`References
`
`8.93
`.10.1,
`26.,
`19.0
`21.,
`20.7,
`
`17.7
`18.59
`3.30
`3.41
`7.1,
`6.68
`22.
`8.09
`9.46
`16.1
`7.7"
`37.
`31.
`7.00
`8.19
`23.24
`25.5,
`14.2
`12. b
`13.,b
`1.61
`20.1
`38.
`29.
`18.3
`
`26
`20
`20
`20
`15
`25
`
`56
`17
`10
`140
`25
`25
`17
`25
`25
`-85
`20
`3
`19
`20
`20
`30
`30
`50
`19
`18
`0
`25
`-80
`-311
`25
`
`.........
`-33,20
`
`.........
`0.247(a)
`....................
`.........
`..........
`.......... .........
`0.205(a)
`-60,40
`
`.........
`.........
`.........
`.........
`.......... .........
`
`107
`234
`21414
`244
`..
`
`27J
`p5,240,271
`,2071
`
`7 E41
`149 [5,7,271
`
`.........
`25,40
`
`1,55
`1,55
`
`30,35
`30,35
`50,70
`.........
`
`-90,15
`20,90
`
`.........
`2.2
`....................
`3.35
`4.40
`....................
`....................
`...................
`
`...................
`....................
`10.1
`10.9
`5.2
`.........
`....................
`0.20
`0.293(a)
`....................
`
`160 [1,77
`63,260
`4,8 [7]
`272
`272
`211
`27
`26
`
`242
`242
`295
`295
`123 [141
`14
`
`14
`172
`112,222,279
`[DI,,51,157, 1771
`9
`
`0.310(a)
`
`20,70
`
`112,222 [1571
`
`C35.C12
`
`1,2-Dichloropropane ..........
`2,2-Dichioropropane ..........
`C3H1N6142 1,2-Propanediol dinitrate ....
`1,3-Propanediol dinitrate ....
`2-Propen-l-ol (Allyl alcohol)
`Acetone ......................
`
`C3NO
`
`Propionaldehyde ..............
`Propionic acid ...............
`
`C3 A02
`
`Ethyl formate ................
`Methyl acetate ...............
`di-Lactic acid ...............
`I-Bromopropane ...............
`2-Bromopropane ...............
`
`C3H6 03
`C3H7 Br
`
`I-Chloropropane ..............
`CHCI
`C041C102 3-Ch