throbber
UNITED STATES PATENT AND TRADEMARK OFFICE
`____________________________________________
`
`BEFORE THE PATENT TRIAL AND APPEAL BOARD
`____________________________________________
`
`TAIWAN SEMICONDUCTOR MANUFACTURING COMPANY LTD.
`Petitioner
`
`v.
`
`GODO KAISHA IP BRIDGE 1
`Patent Owner.
`
`Case IPR2017-018431
`
`REPLY DECLARATION OF STANLEY R. SHANFIELD, PH.D.
`
`1 Case IPR2017-01844 has been consolidated with this proceeding.
`
`TSMC 1232
`TSMC v. GODO KAISHA
`IPR2017-01843
`
`

`

`U.S. Patent 7,893,501
`IPR2017-01843
`Reply Declaration of Stanley R. Shanfield, Ph.D.
`
`
`
`
`I, Stanley R. Shanfield, Ph.D., declare as follows:
`
`1. My name is Stanley R. Shanfield. I have been retained by counsel for
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`Taiwan Semiconductor Manufacturing Company, Ltd. to serve as a technical
`
`expert in this inter partes review proceeding.
`
`2. My background is set forth in paragraphs 2-12 of my initial
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`Declaration in this proceeding (Ex. 12022). As I explained in paragraphs 2-12 and
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`34-36 of my initial Declaration, I would have been a person with at least ordinary
`
`skill in the art of U.S. Patent No. 7,893,501 (the “’501 patent”) as of the time of its
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`alleged invention.
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`3.
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`Since my prior declaration, I have reviewed Patent Owner’s
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`Preliminary Responses dated November 8, 2017, Patent Owner’s district court
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`infringement contentions (Ex. 1228), the Board’s Decision to Institute dated
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`February 6, 2018, the transcript of my deposition on March 27, 2018 and March
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`28, 2018 (Exs. 2009 and 2010), the Patent Owner’s Response dated April 20, 2018,
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`the Declaration of Dr. Alexander D. Glew (Ex. 2008), the transcript of Dr. Glew’s
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`deposition (Ex. 1231), and the exhibits submitted in connection with the forgoing.
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`2 Unless otherwise specified with the “-01844” prefix, references to exhibits and
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`papers herein are to those filed in Case IPR2017-01843.
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`U.S. Patent 7,893,501
`IPR2017-01843
`Reply Declaration of Stanley R. Shanfield, Ph.D.
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`I confirm that everything I included in my prior declaration, and all of the
`
`testimony given during my deposition on March 27, 2018 and March 28, 2018
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`remain true to the best of my knowledge. I have been asked to provide expert
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`testimony in this declaration in reply to issues raised by the Patent Owner’s
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`Response (“Response”) and the Declaration of Alexander D. Glew (Ex. 2208).
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`4.
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`Specifically, I understand that, with the exception of the “protruding
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`gate” limitation (“the gate electrode protrudes upward from a surface level of parts
`
`of the silicon nitride film located at both side surfaces of the gate electrode”),
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`Patent Owner does not dispute that the instituted grounds expressly disclose every
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`U.S. Patent 7,893,501
`IPR2017-01843
`Reply Declaration of Stanley R. Shanfield, Ph.D.
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`limitation recited by the challenged claims of the ’501 patent. Nor does Patent
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`Owner dispute that the references would have been obvious to combine.
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`5.
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`For example, there is no dispute that Misra’s gate 28b protrudes above
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`Misra’s silicon nitride film 20, just as gate 6a protrudes above silicon nitride film
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`8a in the ’501 patent.
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`
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`Ex. 1202, ¶¶112-114; Petition, 40-42. Instead, Patent Owner argues gate 28b must
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`also protrude above spacers 23 because in some embodiments spacers 23 are also
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`made of silicon nitride.
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`6.
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`As I will describe below, Patent Owner’s arguments incorrectly
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`assume that the spacers 23 are necessarily made of silicon nitride. Misra expressly
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`states with regard to spacers 23 that the “nitride spacers formed by deposition may
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`be replaced or composited with a sidewall thermal growth,” Ex. 1204, 6:54-58
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`(emphasis added), as I confirmed on cross-examination when questioned about this
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`U.S. Patent 7,893,501
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`Reply Declaration of Stanley R. Shanfield, Ph.D.
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`language. Ex. 2210, 262:6-24. It is therefore undisputed that Misra discloses the
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`“protruding gate” limitation in the embodiments where spacers 23 are replaced
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`with sidewall thermal growth.
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`7. Moreover, Patent Owner’s arguments do not rebut the showing that
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`Misra discloses the “protruding gate” limitation “regardless of whether spacers 23
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`are constructed out of silicon nitride.” Ex. 1202, ¶115; Petition, 42. Patent Owner
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`raises the same principal arguments it raised in the POPR. Each argument was
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`already rejected by the Board. First, Patent Owner again incorrectly argues that the
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`“silicon nitride film” includes both the “contiguous” plasma enhanced layer 20 and
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`silicon nitride spacers 23. See e.g., Response, 45. Then, Patent Owner again
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`incorrectly argues that Misra’s gate does not protrude above the parts of the silicon
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`nitride film closest to the gate, which it argues are the silicon nitride spacers 23.
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`See e.g., Response, 71.
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`8.
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`I provide further explanation below regarding these issues, with which
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`I disagree with the Patent Owner and Dr. Glew.
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`
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`I.
`
`Patent Owner Does Not Dispute Misra’s Thermally Grown Sidewall
`Embodiments Discloses the Claimed Protruding Gate
`9. My initial declaration demonstrated that Misra discloses the
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`“protruding gate” limitation because gate 28b protrudes above silicon nitride film
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`U.S. Patent 7,893,501
`IPR2017-01843
`Reply Declaration of Stanley R. Shanfield, Ph.D.
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`20. Ex. 1201, ¶¶112-115; Petition, 40-42. My initial declaration also showed that
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`Misra discloses the “protruding gate” limitation “regardless of whether spacers 23
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`are constructed out of silicon nitride.” Ex. 1201, ¶115; Petition, 42. As discussed
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`in the sections that follow, Patent Owner fails to rebut Petitioner’s additional
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`showing for the embodiments where the spacers 23 are made of silicon nitride.
`
`PO’s arguments also fail for the simple reason that they are based on the incorrect
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`premise that spacers 23 are necessarily made of silicon nitride – they are not.
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`Patent Owner offers no response for Misra’s embodiments where spacers 23 are
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`made of other materials such as silicon oxide.
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`10. Misra expressly states that the spacers 23 may be replaced with other
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`materials formed through a thermal growth: “While nitride spacers formed by
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`deposition may be replaced or composited with a sidewall thermal growth, some
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`silicides do not oxidize effectively and may at least some deposition process to
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`obtain adequate source/drain to gate isolation.” Ex. 1204, 6:54-58 (emphasis
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`added). This disclosure refers to a silicon oxide formed on top of the silicide layer
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`in an oxidizing environment at an elevated temperature. The silicon oxide is
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`grown as thermally-driven diffusion of excess silicon in the silicide is oxidized
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`U.S. Patent 7,893,501
`IPR2017-01843
`Reply Declaration of Stanley R. Shanfield, Ph.D.
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`(e.g. in an oxidizing environment of nitrous oxide or ozone). In this scenario, the
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`gate spacers 23 are silicon dioxide, not silicon nitride.
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`11. Well aware of this disclosure in Misra, Patent Owner specifically
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`questioned me on this language during cross-examination. Ex. 2210, 262:6-24. In
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`response to Patent Owner’s questioning, I confirmed that the silicon nitride may be
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`“replac[ed] with sidewalk thermal growth.” Ex. 2210, 262:6-24. Patent Owner
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`next asked whether this disclosure in Misra was at least “describing that it is
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`preferred to have some deposition portion, at least some silicon nitride 23.” I then
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`confirmed that it was not stating a preference for making spacers 23 out of silicon
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`nitride: “No, it’s explaining that you can form spacers, or you can replace the
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`nitride spacers with sidewall thermal growth, but this [some silicides not oxidizing
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`effectively] is something to watch out for.” (Ex. 2210, 263:6-14.)
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`12. Patent Owner ignores this disclosure and testimony, offering no
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`response for Misra’s embodiments where the spacers 23 are made of other
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`materials than silicon nitride. Patent Owner’s arguments are each based on the
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`incorrect premise that the spacers 23 are necessarily made of silicon nitride. The
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`express disclosure of Misra confirms the silicon nitride may be replaced with other
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`materials formed through thermal growth. Thus, the showing that Misra discloses
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`U.S. Patent 7,893,501
`IPR2017-01843
`Reply Declaration of Stanley R. Shanfield, Ph.D.
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`the “protruding gate” limitation stands unrebutted. Ex. 1201, ¶¶112-115; Petition,
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`40-42.
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`13.
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`In my opinion, Patent Owner’s attempt to rebut Petitioner’s additional
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`showing that Misra discloses the “protruding gate” limitation even for
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`embodiments where “spacers 23 are constructed out of silicon nitride,” (Petition,
`
`42) is also incorrect for the reason discussed below.
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`II.
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`Patent Owner’s Construction of “Silicon Nitride Film” Applies an
`Unreasonable Interpretation of “Layer”
`14. Patent Owner argues that Misra’s silicon nitride film 20 and its
`
`sidewall spacers 23 are somehow multiple layers of a single film. This is the same
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`argument Patent Owner advanced in the POPR through an unduly narrow
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`construction of the term “the gate electrode protrudes upward from a surface level
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`of parts of the silicon nitride film located at both side surfaces of the gate
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`electrode.” The POPR proposed the following construction: “the gate electrode
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`protrudes upward from a surface level of parts of the silicon nitride film (which
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`can be formed of one or more layers) located closest to both side surfaces of the
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`gate electrode.” POPR, 58. The Board properly rejected this argument in the
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`Institution Decision (“DI”), explaining: “Patent Owner, however, mischaracterizes
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`Petitioner’s argument. Nowhere does Petitioner argue that the claims exclude a
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`U.S. Patent 7,893,501
`IPR2017-01843
`Reply Declaration of Stanley R. Shanfield, Ph.D.
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`silicon nitride film having multiple layers. Petitioner simply argues that a silicon
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`nitride film need not include every silicon nitride structure in a prior art device.”
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`DI, 8; see also, id., 8-9 (“[W]e disagree that the claim requires that the silicon
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`nitride film must encompass all silicon nitride structures in a prior art device.”).
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`15. Now in its Response, Patent Owner has merely restructured its prior
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`construction and still attempts to interpret the claim in the same way already
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`rejected by the Board (compare “the gate electrode protrudes upward from a
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`surface level of parts of the silicon nitride film located at both side surfaces of the
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`gate electrode” as “the gate electrode protrudes upward from a surface level of
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`parts of the silicon nitride film (which can be formed of one or more layers)
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`located closest to both side surfaces of the gate electrode,” POPR, 58, with “silicon
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`nitride film” as “thin coating of one or more layers of silicon nitride.” Response,
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`28.)
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`16. Patent Owner then applies an unreasonable interpretation of “layer” to
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`this construction to repeat the same arguments that were rejected in the POPR.
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`That is, Patent Owner argues that two adjacent structures made of silicon nitride
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`U.S. Patent 7,893,501
`IPR2017-01843
`Reply Declaration of Stanley R. Shanfield, Ph.D.
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`are somehow layers of the same film, even when they are separate structures,
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`formed through separate processes, different functions. See e.g., Response, 31.
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`17. This interpretation of “layer” is plainly contradicted by the
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`specification of the ’501 patent. Specifically, the ’501 patent depicts two adjacent
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`silicon nitride films 8a and 8b in Fig. 1:
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`
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`Ex. 1201, Fig. 1. Although films 8a and 8b are both made of silicon nitride and are
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`both stress films, the ’501 patent refers to them as separate films, namely, “a first-
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`type internal stress film 8 a” and a “a second-type internal stress film 8 b formed.”
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`Nowhere does the patent refer to films 8a and 8b as somehow being different
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`“layers” of a single film.
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`U.S. Patent 7,893,501
`IPR2017-01843
`Reply Declaration of Stanley R. Shanfield, Ph.D.
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`18.
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`In the case of Misra, even a cursory visual inspection of Fig. 5 shows
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`that silicon nitride film 20 and spacers 23 are two separate structures, not different
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`layers of a single film.
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`
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`
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`19. Moreover, no person of ordinary skill in the art would have
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`considered silicon nitride film 20 and spacers 23 to be two layers of a single film
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`because they are separate structures, they are formed through separate process
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`steps, and they perform different functions, as demonstrated in my initial
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`declaration and discussed further below. Ex. 1201, ¶¶114-118; Petition, 42-43.
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`20. The ’501 patent simply states that “each of the internal stress films 8a
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`and 8b does not have to be a single layer but may include multiple layers, as long
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`as each of the internal stress films 8a and 8b can apply a stress to the substrate as a
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`whole.” Ex. 1201, 5:60-63 (emphasis added). This description merely recognizes
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`U.S. Patent 7,893,501
`IPR2017-01843
`Reply Declaration of Stanley R. Shanfield, Ph.D.
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`that a film can have multiple layers deposited on top of each other. Nowhere does
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`the ’501 patent state that two adjacent films, such as films 8a and 8b, would be
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`considered “layers” of a single film, much less than any two adjacent structures
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`made of the same material are somehow “layers” of a single film. In my opinion,
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`such an interpretation is plainly not the reasonable. The ’501 patent itself merely
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`recognizes that the film 8a could be deposited with a single layer or it could be
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`deposited in multiple layers (and the same for goes for the separate, adjacent film
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`8b). This does not mean that other, partially adjacent, or even fully adjacent,
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`structures necessarily become part of the same film simply as a result of being
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`adjacent.
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`21. Finally, as discussed in more detail below, Patent Owner also repeats
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`its rejected argument that the silicon nitride film must be “located closest to both
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`side surfaces of the gate electrode,” this time without expressly including this
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`requirement in its claim construction. See e.g., Response, 11, 20, 58. In my
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`opinion, this argument again is incorrect.
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`III. No POSITA Would Have Thought the Layer 20 and the Spacer 23 Were
`the Same Film
`A.
`The Petition is Confirmed by the Prosecution History
`22. Patent Owner argues that the Petition’s interpretation of Misra is
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`inconsistent with the prosecution history, in that the claims “would not distinguish
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`U.S. Patent 7,893,501
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`Reply Declaration of Stanley R. Shanfield, Ph.D.
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`over Xiang or Matsuda, and would read on those references in the same manner the
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`Petitions seek to read the claims onto Misra.” Response, 63-66. I disagree with
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`Patent Owner.
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`23.
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`In Xiang, both “etch stop layers” 80 and 82 (208 and 210 in Fig. 10)
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`perform the same function (“etch stop”) and are deposited in the same
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`manufacturing step. Ex. 2202, 4:9-14, 6:35-36 (“As illustrated in FIG. 10, etch
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`stop layers 208 and 210 are deposited in step 212.”) Likewise, in Matsuda,
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`“protective insulating film 9a” is deposited together with “sidewall insulating film
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`10” and “underlying insulting film 8” during a single manufacturing step, forming
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`“sidewalls 11.” Ex. 2203, 8:11-14 (“[I]n a process step shown in FIG. 3B, the
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`sidewall insulating film 10, the protective insulating film 9 and the underlying
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`insulating film 8 are etched in this order by anisotropic dry etching, thereby
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`forming sidewalls 11 each having a multilayer structure including an underlying
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`insulating film 8 a, a protective insulating film 9 a and a sidewall insulating film 10
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`a.”) Accordingly, in both Xiang and Matsuda, the layers cited during prosecution
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`are each: deposited in a single step; perform a single function; and comprise a
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`singular structure.
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`24.
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`In contrast, Misra’s layer 20 and spacer 23 are formed through
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`different process steps, serve different functions, and are part of separate
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`U.S. Patent 7,893,501
`IPR2017-01843
`Reply Declaration of Stanley R. Shanfield, Ph.D.
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`structures. As Misra describes for layer 20: “FIG. 2 illustrates that a thin plasma-
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`enhanced nitride (PEN or like material) layer 20 is deposited overlying the trench
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`isolation regions 14 and the silicide layer 18. Preferably, the plasma enhanced
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`nitride layer is deposited to a thickness of roughly 500 angstroms. Plasma
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`enhanced nitride layer 20 is provided for use as an etch stop layer when
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`subsequently forming contact openings to source and drain electrodes of the MOS
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`transistors.” Ex. 1204, 5:20-27 (emphasis added).
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`25. Misra then describes a separate process to form spacer 23: “After
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`formation of the sacrificial oxide 25, silicon nitride is deposited and reactive ion
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`etched to form silicon nitride spacers 23 on top of the sacrificial oxide 25. The etch
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`used to form silicon nitride spacers 23 is selective to the sacrificial oxide 25….
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`Notice that the spacers 23 provides a necessary offset not only to compensate for
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`lateral diffusion of the source and drain regions 26 and 28, but to electrically
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`isolate subsequent gate electrode formations from the silicide regions 18 whereby
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`Miller effects may be reduced.” Ex. 1204, 6:37-54.
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`26. As shown in the figures below, the steps to form silicon nitride film
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`20 in Fig. 2 and spacers 23 in Fig. 5 are not only separate steps that form
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`completely different structures, they are also separated by multiple intervening
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`steps shown in Figs. 3-4.
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`U.S. Patent 7,893,501
`IPR2017-01843
`Reply Declaration of Stanley R. Shanfield, Ph.D.
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`Ex-1204, Figs. 2-5.
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`27.
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`I note that Dr. Glew confirmed this understanding during his
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`deposition, agreeing that Misra describes forming silicon nitride layer 20 during
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`the process shown in Figure 2 (above), and that Figures 3 and 4 show intervening
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`process steps that occur before the spacers 23 are formed in Figure 5:
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`Q. If we look first at Figure 2 in Misra.
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`U.S. Patent 7,893,501
`IPR2017-01843
`Reply Declaration of Stanley R. Shanfield, Ph.D.
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`A. I have Figure 2 before me.
`Q. So Figure 2 shows an embodiment of Misra at an
`intermediate stage in the manufacturing process, correct?
`A. Yes, Figure 2 is part of a sequence of -- the sequence
`represented methods in Figures 1 through 7.
`Q. In Figure 2, the silicon nitride film 20 has already been
`deposited, right?
`A. Layer 20 is shown being deposited in Figure 2. It's
`described in Column 5, Line 20 as Figure 2 illustrates that
`a thin plasma enhanced nitride pen or like material layer
`20 is deposited overlying the trench isolation region 14
`and the silicide layer 18. I see layer 20.
`Q. In Figure 2, spacers 23 have not yet been formed,
`correct?
`A. Column 6, Lines 34 through 56 describe that spacers
`23 are formed in Figure 5, and that's where it's shown,
`and it's not yet present.
`Q. Figure 5 shows a later stage in the manufacturing
`process that includes both 20 and 23, correct?
`A. Yes, Figure 5 is later in the process, and shows both 20
`and 23.
`Q. Figures 3 and 4 show additional intermediate stages in
`the manufacturing process in between the steps shown in
`Figure 2 and what's depicted in Figure 5, correct?
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`U.S. Patent 7,893,501
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`Reply Declaration of Stanley R. Shanfield, Ph.D.
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`A. Yes, Figure 3 are intermediate in between Figures 2
`and 5 in the manufacturing process.
`Ex. 1231, 130:2-131:12 (emphasis added).
`28. The disclosure in Misra for the silicon nitride layer 20 and the spacers
`
`23 is just like the description in the ’501 patent, where the silicon nitride film 8a
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`and the spacers 7 are formed through separate steps shown in Figs. 2A-2C.
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`Ex. 1201, Figs. 2A-2C.
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`29. By contrast, in Xiang and Matsuda, the film is deposited in a single
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`step. As shown below, “etch stop layers” 208 and 210 in Xiang are formed during
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`a single manufacturing step (namely, step 212, “Deposit Etch Stop Layer”).
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`
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`Consistent with the disclosure in Xiang, a POSITA would have understood that
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`etch stop layer 208 on the left side of the gate and etch stop layer 210 on the right
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`side of the gate are formed by depositing a single silicon nitride film on each side
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`of the gate and that the activities associated with this deposition process would be
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`IPR2017-01843
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`considered a single manufacturing step. Ex. 2202, 4:9-14, 6:35-36 (“As illustrated
`
`in FIG. 10, etch stop layers 208 and 210 are deposited in step 212.”), Figs. 2, 9, 10.
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`30. Likewise, in Matsuda, “protective insulating film 9a” is deposited
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`together with “sidewall insulating film 10” and “underlying insulting film 8”
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`during a single manufacturing step to form “sidewalls 11.” Ex. 2203, 8:11-14.
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`31. Additionally, and contrary to Dr. Glew’s assertions (Ex. 2208, ¶¶146-
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`147), a POSITA would have understood that the references to “etch stop layers 80
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`and 82” in Xiang’s Fig. 1 refer to the etch stop layer 80 on the left side of the gate
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`and etch stop layer 82 on the right side of the gate, not to vertical and horizontal
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`portions of each etch stop layer. This is confirmed by the consistent usage of pairs
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`of identifiers for the left and right structures (e.g., left spacer 70 and right spacer
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`72, left filler layer 84 and right filler layer 86, left silicide region 26 and right
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`silicide region 28, etc.).
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`32. Dr. Glew’s testimony is also contrary to Figs. 10-12 in Xiang, where
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`the labels 208 and 210 both point to the same respective portions of the left and
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`right etch stops, confirming that the numerals identify a left etch stop and a right
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`etch stop, not upper and lower portions of each etch stop. This is also confirmed
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`by the shading in the figures in Xiang, where etch stop layer 80 and etch stop layer
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`82 (as well as etch stop layers 208 and 210) are each shaded in a single pattern of
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`vertical lines. There is no distinction or separation within either etch stop layer 80
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`or etch stop layer 82 to suggest that either etch stop somehow comprises multiple
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`separate structures. Likewise, in Matsuda, layer 9a is shaded in a consistent
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`pattern of diagonal lines, with no distinction or separation made to denote two
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`separate structures.
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`33. Therefore, simply positioning Misra’s silicon nitride film 20 and
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`spacer 23 next to each other cannot make them a single structure when they have
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`each been formed using a different technique and, in my opinion, will undisputedly
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`have significant differences in their individual properties and functions.
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`
`
`B.
`
`Patent Owner Cannot Overcome the Evidence with its Narrow
`Interpretation of “Silicon Nitride Film”
`34. As described above, Patent Owner again argues that the plasma
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`enhanced layer 20 and silicon nitride spacers 23 of Misra are both part of a single
`
`“silicon nitride film” because a film can have multiple layers under its proposed
`
`interpretation. As noted previously, ’501 patent merely recognizes that a film may
`
`have multiple layers in the context of a film formed by stacking additional layers
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`on top of previous layers: “Furthermore, each of the internal stress films 8a and 8b
`
`does not have to be a single layer but may include multiple layers, as long as each
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`of the internal stress films 8a and 8b can apply a stress to the substrate as a whole.”
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`Ex. 1201, 5:60-63. The ’501 patent provides no support for the notion that two
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`adjacent structures would be considered multiple layers of a single film.
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`35. Dr. Glew’s own testimony confirms that the term “layer” simply
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`refers to different layers of a film formed on top of each other. E.g., Ex. 2208, ¶71
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`(“It is somewhat akin to spray painting where each spray of paint (even if from the
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`same spray paint can) is a different process that produces a layer.”). That is, a film
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`can be applied in a single layer or multiple layers, but that does not mean that
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`adjacent structures are somehow part of the same film.
`
`36. The processes of applying multiple layers of paint on top of each other
`
`or depositing a film in a semiconductor device with multiple layers stacked on top
`
`of each other is completely distinct from Misra. As described above, layer 20 and
`
`spacer 23 are two different structures, formed through different process steps, and
`
`performing different functions. That they happened to be adjacent does not make
`
`them into a single film.
`
`37. There is a distinction between multiple stacked layers (as
`
`contemplated and described by the ’501 patent and confirmed by Dr. Glew) and
`
`multiple separate structures that are adjacent to each other. For example, looking
`
`at the diagram of stacked layers provided in the Response (Response, 33), the
`
`stress field adds and compressive stress is approximately double on the bottom. As
`
`the ’501 patent describes, “Furthermore, each of the internal stress films 8a and 8b
`
`does not have to be a single layer but may include multiple layers, as long as each
`
`of the internal stress films 8a and 8b can apply a stress to the substrate as a whole.”
`
`Ex. 1201, 5:60-63. That is, the film applies a stress based on the sum of the
`
`stresses of the stacked layers. By contrast, for separate structures that are adjacent
`
`- 24 -
`
`

`

`U.S. Patent 7,893,501
`IPR2017-01843
`Reply Declaration of Stanley R. Shanfield, Ph.D.
`
`
`to each other, the tensile stress profile of each structure dips on the edge of each
`
`structure because there is nothing for it to act on.
`
`38. To illustrate this distinction, as would be understood by a POSITA, I
`
`refer to the following diagrams. The first diagram illustrates a single thin film (in
`
`gray) with intrinsic tensile stress that is deposited on a silicon substrate (blue).
`
`This single thin film applies a compressive stress (indicated by the arrows)
`
`downward into the substrate. The compressive stress has a magnitude and depth as
`
`shown by the compressive stress field profile (peach). The region of maximum
`
`substrate stress is measured at the approximate center of the substrate in this
`
`arrangement, where the compressive stress profile (peach) is at its maximum depth.
`
`The stress level induced in the underlying substrate drops to approximately zero at
`
`each edge of the thin film.
`
`Single thin film applying compressive stress into substrate
`
`
`
`- 25 -
`
`

`

`U.S. Patent 7,893,501
`IPR2017-01843
`Reply Declaration of Stanley R. Shanfield, Ph.D.
`
`39. The next diagram illustrates two films (one gray, one yellow), stacked
`
`one on top of the other as multiple layers that can apply a stress to the substrate
`
`(blue) as a whole, as is consistent with the disclosure of the ’501 patent (Ex. 1201,
`
`5:60-63: “Furthermore, each of the internal stress films 8a and 8b does not have to
`
`be a single layer but may include multiple layers, as long as each of the internal
`
`stress films 8a and 8b can apply a stress to the substrate as a whole.”) In this
`
`example, the two films apply a compressive stress field that is the sum of the two
`
`stacked layers, resulting in a greater compressive stress field (orange) in the
`
`substrate – approximately twice the magnitude of compressive stress as in the first
`
`example. Once again, the region of maximum substrate stress is measured at the
`
`approximate center of the substrate in this arrangement, where the compressive
`
`stress profile (orange) is at its maximum depth. The stress level induced in the
`
`underlying substrate drops to approximately zero at each edge of the thin film.
`
`
`
`- 26 -
`
`

`

`U.S. Patent 7,893,501
`IPR2017-01843
`Reply Declaration of Stanley R. Shanfield, Ph.D.
`
`
`Multiple stacked film layers applying compressive stress into substrate
`
`40. The final diagram illustrates two films (gray and yellow) deposited
`
`side-by-side onto the substrate (blue). In this example, and in contrast with the
`
`stacked arrangement shown above, each film applies its own compressive stress
`
`into the substrate, resulting in two independent compressive stress fields (peach).
`
`Here, there is a region of near zero compressive stress at the boundary between the
`
`two side-by-side films, as identified by the large arrow. In other words, placing
`
`two separately deposited (and, in this case, identical) thin films side-by-side does
`
`not provide a higher magnitude stress field and, in contrast, results in each film
`
`generating its own separate stress film, with the condition of zero stress in the
`
`underlying substrate at the point between the two separate films.
`
`Two films deposited side-by-side, each applying its own compressive stress
`
`41. Dr. Glew provides similar examples of stacked layers and side-by-side
`
`films deposited on substrates in his declaration, but omits the stress fields
`
`
`
`- 27 -
`
`

`

`U.S. Patent 7,893,501
`IPR2017-01843
`Reply Declaration of Stanley R. Shanfield, Ph.D.
`
`
`illustrating how two side-by-side films differ from a single film (whether formed
`
`with a single layer or multiple stacked layers). Ex. 2208, ¶70, Figure 1. For
`
`consistency, I have annotated those examples in the same way as above to
`
`illustrate: (i) the single added compressive stress field (orange) of the stacked
`
`layers (purple); and (ii) the two separate compressive stress fields (peach) of each
`
`of the separate side-by-side films (green).
`
`
`
`Figure 1 of Dr. Glew’s declaration (Ex. 2208) as annotated
`
`42. Accordingly, each structure applies different stresses because they are
`
`separate structures and there is a discontinuity in the stress profile at the boundary
`
`between the two structures, even when they are adjacent. In fact, that “non-
`
`uniform stresses exist near the edges of thin films as a result of satisfying the
`
`boundary conditions” has been a well-known mechanical property of thin films for
`
`decades. Ex. 1233.
`
`43. Because layer 20 and spacer 23 are separate structures, there will be a
`
`discontinuity at the boundary of 20 and 23 not present in Xiang or Matsuda. This
`
`is consistent with the position articulated in the my initial declaration (see e.g., Ex.
`
`- 28 -
`
`

`

`U.S. Patent 7,893,501
`IPR2017-01843
`Reply Declaration of Stanley R. Shanfield, Ph.D.
`
`
`1202, ¶¶138-142). Thus, a silicon nitride film can have one or more layers applied
`
`on top of each other, but two wholly different structures—namely, a silicon nitride
`
`film and a sidewall structure—cannot be considered layers of the same film, even
`
`if the edge of the silicon nitride film is adjacent to the sidewall.
`
`IV. Misra’s gate protrudes above the parts of the silicon nitride film
`44. Patent Owner’s argument that “Misra fails to satisfy the challenged
`
`claims even if silicon nitride layers 20, 23 are considered to be separate films” still
`
`implicitly requires that the plasma enhanced layer 20 and silicon nitride spacers 23
`
`both be part of the “silicon nitride film” in order for the silicon nitride spacers 23
`
`to be the closest part of the film, rather than a separate structure. Response, 71-76.
`
`45. Additionally, neither the plain language of the claims, the
`
`specification, nor the file history, prohibit there being a silicon nitride spacer
`
`between the gate electrode and the silicon nitride film. The claim language simply
`
`requires that “the gate electrode protrudes upward from a surface level of parts of
`
`the silicon nitride film located at both side surfaces of the gate electrode.” The
`
`claims in fact expressly recognize that the silicon nitride film “located at both side
`
`surfaces of the gate electrode” need not be located closest to the side surfaces of
`
`the gate, but instead may be separated from the side surfaces of the gate by spacers.
`
`For example, claim 7, which depends from claim 1, recites that “the silicon nitride
`
`- 29 -
`
`

`

`U.S. Patent 7,893,501

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