`(10) Patent N0.:
`US 6,383,906 B1
`
`Wieczorek et al.
`(:45) Date of Patent:
`May 7, 2002
`
`USOO6383906B1
`
`(54) METHOD OF FORMING
`JUNCTION-LEAKAGE FREE METAL
`SALICIDE IN A SEMICONDUCTOR WAFER
`WITH ULTRA-LOW SILICON
`CONSUMPTION
`
`6,072,222 A *
`
`6/2000 Nistler
`
`..................... .. 438/659
`
`FOREIGN pATENT DOCUMENTS
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`EP
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`0651076 B1 *
`
`8/1999
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`....... .. H01L/21/285
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`(75)
`
`I
`Inventors: Karsten Wieczorek,
`Reichenberg-Boxdorf (DE); Nicholas
`Kepler, Saratoga, CA (US); Paul R.
`Bess”? A1159“, TX (Us); Larry Y-
`Wang san Jose> CA (US)
`
`(73) Assignee: Advanced Micro Devices, Inc.,
`Sunnyvale, CA (US)
`Subject to any disclaimer the term of this
`atem is extended or adiusted under 35
`{3 S C 154(b) by 0 days]
`
`( * ) Notice.
`'
`
`(21) Appl. No; 09/641,436
`.
`.
`(22) Flled'
`
`(60)
`
`Aug' 18’ 2000
`Related u_s_ Application Data
`Provisional application No. 60/149,470, filed on Aug. 19,
`1999
`Int. Cl.7 .......................................... .. H01L 21/4763
`(51)
`(52) U.S. Cl.
`..................... .. 438/592; 438/305; 438/683;
`438/663
`(58) Field of Search ............................... .. 438/305, 592,
`438/656, 664, 683, 685, 655, 659, 661,
`663
`
`(56)
`
`References Cited
`U.S. PATENT DOCUMENTS
`
`* cited by examiner
`
`Primary Examiner%harles Bowers
`Assistant Examiner—Yennhu B. Huynh
`
`(57)
`
`ABSTRACT
`
`A method for forming ultra shallow junctions in a semicon-
`ductor wafer uses disposable spacers and a Silicon cap layer
`to achieve ultra-low low silicon consumption during a
`salicide formation process. A refractory metal layer, such as
`
`a cobalt layer, is deposited over the gate and source/drain
`junctions of a semiconductor device. Silicon nitride dispos-
`able spacers are formed over the metal layer in the region of
`the sidewall spacers previously formed on the sidewalls of
`the gate. Asilicon cap layer is deposited over the metal layer
`and the disposable spacers. Rapid thermal annealing is
`performed to form the high-ohmic phase of the salicide, with
`the disposable spacers preventing interaction and between
`the cobalt and the silicon in the area between the gate and the
`source/drain junctions along the sidewall spacers. The sili-
`con cap layer provides a source of silicon for consumption
`during the first phase of salicide formation, reducing the
`amount of silicon of the source/drain junctions that
`is
`consumed.
`
`5,899,720 A *
`
`5/1999 Nikagi
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`..................... .. 438/303
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`11 Claims, 5 Drawing Sheets
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`US 6,383,906 B1
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`1
`METHOD OF FORMING
`JUNCTION-LEAKAGE FREE METAL
`SALICIDE IN A SEMICONDUCTOR WAFER
`WITH ULTRA-LOW SILICON
`CONSUMPTION
`
`RELATED APPLICATIONS
`
`This application claims priority from Provisional Appli-
`cation Ser. No. 60/149,470 filed on Aug. 19, 1999 entitled:
`“METHOD OF FORMING JUNCTION-LEAKAGE FREE
`METAL SALICIDE IN A SEMICONDUCTOR WAFER
`WITH ULTRA-LOW SILICON CONSUMPTION”,
`the
`entire disclosure of which is hereby incorporated by refer-
`ence therein.
`
`FIELD OF THE INVENTION
`
`The present invention relates to the field of semiconductor
`device manufacturing, and more particularly, to the forma-
`tion of low resistivity self-aligned silicide (“salicide”)
`regions on the gate and source/drain junctions with an
`ultra-low silicon consumption.
`BACKGROUND OF THE INVENTION
`
`In the manufacture of integrated circuits, a commonly
`used practice is to form silicide on source/drain regions and
`on polysilicon gates. This practice has become increasingly
`important for very high density devices where the feature
`size is reduced to a fraction of a micrometer. Silicide
`provides good ohmic contact, reduces the sheet resistivity of
`source/drain regions and polysilicon gates,
`increases the
`eifective contact area, and provides an etch stop.
`A common technique employed in the semiconductor
`manufacturing industry is self-aligned silicide (“salicide”)
`processing. Salicide processing involves the deposition of a
`metal that forms intermetallic with silicon (Si), but does not
`react with silicon oxide or silicon nitride. Common metals
`
`employed in salicide processing are titanium (Ti), cobalt
`(Co), and nickel (Ni). These common metals form low
`resistivity phases with silicon, such as TiSiz, CoSi2 and NiSi.
`The metal is deposited with a uniform thickness across the
`entire semiconductor wafer. This is accomplished using, for
`example, physical vapor deposition (PVD) from an ultra-
`pure sputtering target and a commercially available ultra-
`high vacuum (UHV), multi-chamber, DC magnetron sput-
`tering system. Deposition is performed after both gate etch
`and source/drain junction formation. After deposition, the
`metal blankets the polysilicon gate electrode,
`the oxide
`spacers,
`the oxide isolation, and the exposed source and
`drain electrodes. A cross-section of an exemplary semicon-
`ductor wafer during one stage of a salicide formation
`process in accordance with the prior art
`techniques is
`depicted in FIG. 1.
`As shown in FIG. 1, a silicon substrate 10 has been
`provided with the source/drain junctions 12, 14 and a
`polysilicon gate 16. Oxide spacers 18 have been formed on
`the sides of the polysilicon gate 16. The refractory metal
`layer 20, comprising cobalt, for example, has been blanket
`deposited over the source/drain junctions 12, 14, the poly-
`silicon gate 16 and the spacers 18. The metal layer 20 also
`blankets oxide isolation regions 22 that isolate the devices
`from one another.
`
`Afirst rapid thermal anneal (RTA) step is then performed
`at a temperature of between about 450°—700° C. for a short
`period of time in a nitrogen atmosphere. The nitrogen reacts
`with the metal to form a metal nitride at the surface of the
`metal, while the metal reacts with silicon and forms silicide
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`in those regions where it comes in direct contact with the
`silicon. Hence, the reaction of the metal with the silicon
`forms a silicide 24 on the gate 16 and source/drain regions
`12, 14, as depicted in FIG. 2.
`After the first rapid thermal anneal step, any metal that is
`unreacted is stripped away using a wet etch process that is
`selective to the silicide. A second, higher temperature rapid
`thermal anneal step, for example above 700° C, is applied
`to form a lower rcsistancc silicidc phase of the metal suicide.
`The resultant structure is depicted in FIG. 3 in which the
`higher resistivity metal silicide 24 has been transformed to
`the lowest resistivity phase metal silicide 26. For example,
`when the metal is cobalt, the higher resistivity phase is CoSi
`and the lowest resistivity phase is CoSiz. When the poly-
`silicon and diffusion patterns are both exposed to the metal,
`the silicide forms simultaneously over both regions so that
`this method is described as “salicide” since the silicides
`formed over the polysilicon and single-crystal silicon are
`self-aligned to each other.
`Titanium is currently the most prevalent metal used in the
`integrated circuit
`industry,
`largely because titanium is
`already employed in other areas of 0.5 micron CMOS logic
`technologies.
`In the first rapid thermal anneal step,
`the
`so-callcd “C49” crystallographic titanium phase is formed,
`and the lower resistance “C54” phase forms during the
`second rapid thermal anneal step. However,
`the titanium
`silicide sheet resistance rises dramatically due to narrow—line
`effects. This is described in European Publication No.
`0651076. Cobalt silicide (CoSiz) has been introduced by
`several integrated circuit manufacturers as the replacement
`for titanium suicide. Since cobalt silicide forms by a diffu-
`sion reaction,
`it does not display the narrow-line effects
`observed with titanium silicide that forms by nucleation-
`and-growth. Some of the other advantages of cobalt over
`alternative materials such as titanium, platinum, or palla-
`dium are that cobalt silicide provides low resistivity, allows
`lower-temperature processing, and has a reduced tendency
`for forming diode-like interfaces.
`One of the concerns associated with cobalt silicide tech-
`
`nologies is that of junction leakage, which occurs when
`cobalt silicide is formed such that it extends to the bottom
`and beyond of the source and drain junctions. An example
`of this occurrence is depicted in FIG. 3. One source of this
`problem is the high silicon consumption during the salicide
`formation process. One way to account for the high con-
`sumption of silicon during salicide processing is to make the
`junctions deeper. Making the junctions deeper, however, is
`counter to the desire for extremely shallow source and drain
`junctions that support device scaling, and negatively impacts
`device performance.
`SUMMARY OF THE INVENTION
`
`There is a need for a method of producing ultra-shallow
`junctions and forming salicidc in a manner that reduces the
`amount of silicon consumed in the junctions.
`This and other needs are met by embodiments of the
`present invention which provide a method of forming ultra-
`shallow junctions in a semiconductor wafer with low silicon
`consumption during a salicide formation process. In this
`method,
`the gate and the source/drain junctions are first
`formed by doping a semiconductor material. Sidewall spac-
`ers are formed on the sidewalls of the gate. A metal layer,
`such as cobalt, is deposited over the gate and source/drain
`junctions. Disposable spacers, made of silicon nitride, for
`example, are formed over the metal layer where the metal
`layer covers the sidewall spacers. A silicon cap layer is
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`US 6,383,906 B1
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`deposited over the metal layer and the disposable spacers.
`Annealing is then performed to form high resistivity metal
`silicide regions on the gate and source/drain junctions.
`Unreacted portions of the silicon cap layer, the disposable
`spacers, and the unreacted portions of the metal layer are
`removed. Another annealing step converts the high resistiv-
`ity metal silicide regions into low resistivity metal silicide
`regions.
`The silicon cap layer provides a source of consumable
`silicon for the salicidation process,
`thereby reducing the
`amount of silicon consumed in the source/drain junctions.
`This maintains the advantages of ultra-shallow junctions. At
`the same time, salicide formation between the gate and the
`source/drain junctions along the sidewall spacers is pre-
`vented by the interposition of the disposable spacers
`between the metal layer and the silicon cap layer. The
`disposable spacers prevent the interaction of the metal and
`the silicon in this region during the annealing that forms the
`salicide. The reduced amount of silicon consumption per-
`mits the junctions to be made ultra-shallow and avoids
`creating excess junction leakage.
`The earlier stated needs are also met by another embodi-
`ment of the present invention which provides a method of
`forming a salicide. Semiconductor material is doped to form
`a gate and source/drain junctions. Amorphous regions are
`formed within the gate and source/drain junctions. A metal
`layer, such as a cobalt layer, is deposited over the gate and
`source/drain junctions. A consumable silicon layer is depos-
`ited over the metal layer. The metal silicide regions are
`formed on the gate and source/drain junctions by annealing.
`Formation of metal silicide regions between the gate and the
`source/drain junctions is prevented. In certain embodiments,
`the prevention involves the interposing spacers between the
`metal layer and the consumable silicon layer to prevent
`interaction of the metal layer and the consumable silicon
`layer in that region.
`Additional features and advantages of the present inven-
`tion will become readily apparent to those skilled in the art
`from the following detailed description, when embodiments
`of the invention are described, simply by way of illustration
`of the best mode contemplated for carrying out the inven-
`tion. As will be realized, the invention is capable of other
`and different embodiments and its several details are capable
`of modifications and various obvious respects, all without
`departing from the invention. Accordingly, the drawings and
`description are to be regarded as illustrative in nature, and
`not as restrictive.
`
`BRIEF DESCRIPTION OF THE DRAWINGS
`
`FIG. 1 is a cross-section of a portion of a semiconductor
`wafer processed in accordance with the prior art during one
`step of a salicide process.
`FIG. 2 depicts the cross-section of FIG. 1 after a first rapid
`thermal anneal step to form a high resistivity metal silicide
`region in accordance with the prior art.
`FIG. 3 is a cross—section of the semiconductor wafer of
`
`FIG. 2 following a second rapid thermal annealing step to
`form lower resistivity metal silicide regions in accordance
`with the prior art, depicting the high consumption of silicon
`in the substrate.
`
`FIG. 4 is a cross-section of a portion of a semiconductor
`wafer prior to a salicidation process in accordance with
`certain embodiments of the present
`invention, after the
`deposition of a refractory metal layer.
`FIG. 5 is a depiction of the semiconductor device of FIG.
`4, following the deposition of a disposable spacer layer, in
`accordance with certain embodiments of the present inven-
`tion.
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`FIG. 6 depicts the semiconductor device of FIG. 5 fol-
`lowing the etching of the disposable spacer layer to form
`disposable spacers, in accordance with embodiments of the
`present invention.
`FIG. 7 depicts the semiconductor device of FIG. 6 fol-
`lowing the formation of a cap layer in accordance with
`embodiments of the present invention.
`FIG. 8 is a depiction of the semiconductor device of FIG.
`7 after a mask layer has been formed over the semiconductor
`device,
`in accordance with certain embodiments of the
`present invention.
`FIG. 9 is a depiction of the semiconductor device of FIG.
`8 after etching is performed in accordance with the mask and
`the subsequent removal of the mask,
`in accordance with
`certain embodiments of the present invention.
`FIG. 10 is a depiction of the semiconductor device of FIG.
`9 after a first annealing to form an initial, high-ohmic phase
`of the salicide, in accordance with certain embodiments of
`the invention.
`
`FIG. 11 is a depiction of the semiconductor device of FIG.
`10 following the removal of cap layer material in accordance
`with certain embodiments of the present invention.
`FIG. 12 is a depiction of the semiconductor device of FIG.
`11 after the disposable spacers have been removed,
`in
`accordance with certain embodiments of the present inven-
`tion.
`
`FIG. 13 is a depiction of the semiconductor device of FIG.
`12 after unreacted refractory metal has been removed.
`FIG. 14 is a depiction of the semiconductor device of FIG.
`12 after a second thermal annealing is performed to form
`lower resistivity metal silicide regions, in accordance with
`certain embodiments of the present invention.
`DETAILED DESCRIPTION OF THE
`INVENTION
`
`The present invention allows ultra-shallow junction for-
`mation simultaneously with low sheet—resistance salicide
`processing by reducing the amount of silicon consumed in
`the junctions during the formation of the salicide. This is
`accomplished in the present invention through the provision
`of a disposable spacer and formation of a silicon cap layer
`which provides silicon to be consumed during the salicide
`formation. The processing sequence of the present invention
`enables formation of a low-ohmic salicide layer while
`maintaining gate-to-source/drain self-alignment and ultra-
`shallow junction integrity, thereby supporting further device
`scaling. This allows junctions to be made shallower and
`improve device performance.
`FIG. 4 is a cross—section of a semiconductor device on a
`
`semiconductor wafer on which low resistivity metal silicide
`regions will be formed in accordance with embodiments of
`the present invention. As with conventional semiconductor
`devices, a source junction 32 and a drain junction 34 are
`formed within a silicon substrate 30. A gate etch has
`produced a gate 36. Oxide (or nitride) spacers 38 are
`provided on the sides of the polysilicon gate electrode 36.
`Oxide isolation (such as LOCOS) regions 42 isolate indi-
`vidual semiconductor devices from each other. After the
`
`source and drain junctions 32, 34 have been formed, a
`refractory metal layer 40 is deposited uniformly across the
`entire wafer, preferably using physical vapor deposition
`from an ultra-pure sputtering target and a commercially
`available ultra-high-vacuum, multi-chamber, DC magnetron
`sputtering system. The thickness of the layer 40 is between
`about 50 to about 200 A in certain preferred embodiments.
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`The metal comprising the refractory metal layer in certain
`preferred embodiments is cobalt (Co). Cobalt has a number
`of advantages over other types of metals. For example, in
`comparison to cobalt silicide, titanium silicide sheet resis-
`tance rises dramatically due to narrow-line effects. Since the
`low resistivity phase of cobalt silicide forms by a diffusion
`reaction rather than nucleation-and-growth as in the low
`resistivity phase of titanium silicide, cobalt silicide has been
`introduced by several integrated circuit manufacturers as the
`replacement for titanium. However, the use of cobalt in layer
`40 as a refractory metal is exemplary only. Another example
`of a metal that is the diffusing species in the first phase of a
`silicidation process is nickel (Ni).
`FIG. 5 depicts the semiconductor device of FIG. 4, after
`the deposition of a disposable spacer layer 44. As an
`exemplary material, silicon nitride may be used in the
`disposable spacer layer 44. However, other types of material
`may be used, provided that it can later be removed with a
`process that exhibits a high selectivity to the salicide that
`will be formed. Exemplary thicknesses of the disposable '
`spacer layer 44 are between about 100 to about 300
`The disposable spacer layer 44 is then etched in a con-
`ventional manner to form disposable spacers 46 over the
`refractory metal layer 40 located over the spacers 38 on the
`sides of the gate 36. The disposable spacers 46 will prevent
`interaction between a subsequently formed cap layer and a
`salicide layer. The resulting structure is depicted in FIG. 6.
`After the formation of the disposable spacers 46, a cap
`layer 48 is formed over the metal layer 40 and the disposable
`spacers 46. The cap layer 48 may comprise amorphous
`silicon, for example, deposited with a thickness of between
`about 50 to about 200
`The cap layer 48 provides
`consumable silicon for the salicide process. The resulting
`structure after the deposition of the cap layer 48 is shown in
`FIG. 7.
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`6
`polysilicon gate 36. However, the amount of silicon con-
`sumed from these regions 32, 34, 36 is greatly reduced as the
`amorphous silicon in the cap layer 48 is also consumed
`during the rapid thermal anneal step. This is also indicated
`in FIG. 10. By providing a second, consumable source of
`silicon through the use of the cap layer 48, excessive
`consumption of the silicon in the junctions 32, 34 is avoided.
`This prevents excess junction leakage from occurring.
`During the rapid thermal annealing to produce the high
`resistivity metal silicide regions 52, the disposable spacers
`46 located between the silicon cap layer 48 and the cobalt
`metal layer 40 prevents interaction between the cap layer 48
`and the metal layer 40. The high resistivity metal silicide
`regions 52 will therefore not form in this area, so that the
`disposable spacers 46 serve to maintain the gate to source/
`drain self-alignment.
`Any unreacted silicon in the cap layer 48 is removed, as
`depicted in FIG. 11. The silicon may be removed by expo-
`sure to a KOH solution at 50—70° C., for example, followed
`by subsequent RCA-cleaning to remove any residual K. This
`process is very selective to the underlying materials.
`Additionally, any remaining silicon on top of the disposable
`spacers 46 may be removed by lift-off during subsequent
`removal of the spacers 46 by hot H3PO4. These processes are
`exemplary only, however, as other processes may be used to
`remove the unreacted silicon without departing from the
`invention.
`
`FIG. 12 depicts the semiconductor device of FIG. 11 after
`the removal of the disposable spacers 36. As stated earlier,
`the disposable spacers 36 are made of silicon nitride (SiN)
`in certain preferred embodiments. Accordingly, the spacers
`36 may be removed by the use of phosphoric acid, which
`ensures high selectivity to the CoSi of the high resistivity
`metal silicide regions 52.
`With the disposable spacers 36 now removed, the unre-
`acted cobalt or other metal of the metal layer 40 is removed.
`The unreacted metal that is removed is located over the field
`
`FIG. 8 depicts the semiconductor device of FIG. 7, after
`a photoresist mask 50 has been positioned over the device,
`leaving the areas over the field oxide regions 42 exposed.
`The silicon in the cap layer 48 in the exposed regions is then
`removed by conventional
`reactive ion etching (RIE)
`employing, for example, CF4/02. The etch stops on the
`cobalt of the metal layer 40, as depicted in FIG. 8. The cobalt
`will not react during subsequent rapid thermal annealing
`steps, and will be removed later during selective cobalt
`stripping.
`Following the etching of the silicon in the cap layer 48
`over the exposed areas above the field oxide regions 42, the
`photoresist mask 50 is removed by 02 plasma ashing
`without wet-chemical treatment. The resulting structure is
`depicted in FIG. 9. The semiconductor device is now pre-
`pared for the first rapid thermal annealing step.
`FIG. 10 depicts the structure of FIG. 9 after the formation
`of high resistivity (“high-ohmic”) metal silicide regions 52.
`In certain preferred embodiments, the high resistivity metal
`silicide regions 52 are created by a rapid thermal anneal step.
`The high resistivity metal suicide regions 52 may be made
`of cobalt silicide (CoSi), for example. The first rapid thermal
`annealing step may be performed by exposing the semicon-
`ductor wafer to a temperature between about 450° C. and
`about 600° C., and most preferably 500° C. The semicon-
`ductor wafer will be exposed for a relatively short time, for
`example, between about 5 and 90 seconds. As is apparent
`from FIG. 10, some of the silicon in the source and drain
`junctions 32, 34 is consumed during the first rapid thermal
`annealing step to become part of the high resistivity metal
`silicide regions 52. This is true also for the silicon in the
`
`oxide regions 42 and the spacers 38, in the region previously
`covered by the disposable spacers 36. The unreacted metal
`may by removed by a selective etch. Typical etchants
`employed to remove unreacted cobalt is 3HCle202, and
`another is H28042H202. Removal of the unreacted metal by
`the peroxide solution leaves the high resistivity metal sili-
`cide regions 52 intact. The resultant structure is depicted in
`FIG. 13.
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`A second rapid thermal anneal step is now performed to
`produce lower resistivity (“low-ohmic”) metal silicide
`regions 54, such as CoSiz, as depicted in FIG. 14. The
`second rapid thermal anneal step exposes the semiconductor
`wafer to a higher temperature than employed in the first
`rapid thermal anneal step. For example, the temperature in
`this second rapid thermal anneal step is between about 600°
`C. and about 850° C. The semiconductor wafer is exposed
`to the high temperature for between about 5 and about 90
`seconds. During this second rapid thermal anneal step, the
`higher resistivity monosilicide (e.g. CoSi) is converted to
`lower resistivity disilicide (e.g. CoSiz).
`The embodiments of the present invention allow ultra-
`shallow junctions to be formed and employed in a semicon-
`ductor device with low resistivity salicide, such as cobalt
`(CoSiz), without compromising the advantages of either
`ultra-shallow junctions or low resistivity salicide. An exem-
`plary embodiment has been described in which cobalt is
`employed as the refractory metal in forming the salicide.
`However, the present invention finds utility in other appli-
`cations employing other materials that react with silicon to
`form a salicide, such as Ti, Zr, Mo, W, or Ni.
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`Only certain preferred embodiments of the present inven-
`tion and but a few examples of its versatility are shown and
`described in the present disclosure. It is to be understood that
`the present
`invention is capable of using various other
`combinations and environments is capable of changes and
`modifications within the scope of the invention concept has
`expressed herein.
`What is claimed is:
`1. Amethod of forming a silicide, comprising the steps of:
`doping semiconductor material to form a gate and source/
`drain junctions;
`depositing a metal layer over the gate and source/drain
`junctions;
`forming spacers on the metal layer, the spacers extending
`between the gate and the source/drain junctions;
`depositing a consumable silicon layer over the spacers
`and the metal layer; and
`annealing to form metal silicide regions on the gate and
`source/drain junctions, the spacers on the metal layer '
`preventing interaction of the metal layer and the con-
`sumable silicon layer between the gate and the source/
`drain junctions to thereby prevent formation of metal
`silicide regions between the gate and source/drain
`junctions.
`2. The method of claim 1, wherein the spacers comprise
`silicon nitride.
`3. The method of claim 2, further comprising removing
`unreacted silicon from the consumable silicon layer after the
`step of annealing.
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`4. The method of claim 3, wherein the steps of removing
`unreacted silicon includes exposing the unreacted silicon to
`KOH solution and removing residual K with RCA—cleaning.
`5. The method of claim 3, further comprising removing
`the spacers following the step of removing the unreacted
`silicon.
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`5
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`6. The method of claim 5, wherein the step of removing
`the spacers includes exposing the spacers to phosphoric
`acid.
`
`7. The method of claim 6, wherein the step of forming the
`disposable spacers includes depositing a silicon nitride layer
`over the metal layer and etching the silicon nitride layer until
`the disposable spacers are formed.
`8. The method of claim 7, wherein the metal layer is
`between about 50 to about 200 A thick, the silicon nitride
`layer is between about 100 to about 300 A thick, and the
`silicon cap layer is between about 50 and about 200 A thick.
`9. The method of claim 1, wherein the metal
`layer
`comprises cobalt.
`10. The method of claim 1, wherein the step of forming
`the spacers includes depositing a silicon nitride layer over
`the metal layer and etching the silicon nitride layer until the
`disposable spacers are formed.
`11. The method of claim 10, wherein the metal layer is
`between about 50 to about 200 A thick, the silicon nitride
`layer is between about 100 to about 300 A thick, and the
`consumable silicon layer is between about 50 and about 200
`A thick.
`
`