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`5,741,626
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`[11] Patent Number:
`Jain et al.
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`[45] Date of Patent: Apr. 21, 1998
`
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`
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`US005741626A
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`
`
`[54] METHOD FOR FORMING A DIELECTRIC
`
`
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`
`
`TANTALUM NITRIDE LAYER AS AN ANTI-
`
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`
`
`REFLECTIVE COATING (ARC)
`
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`[75]
`
`
`
`Inventors: Ajay Jain; Kevin Lucas, both of
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`
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`Austin, Tex.
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`[73] Assignee: Motorola, Inc., Schaumburg, Il.
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`[21] Appl. No.: 632,209
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`[22] Filed:
`Apr. 15, 1996
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`[5] Ent, C08 occcescssccssnneecee GO3F 7/00; HOIL 21/314
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`[52] US. Che cessssessccsesesecnssoneee 430/314; 430/311; 430/312;
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`430/316; 430/317; 438/626; 438/633; 438/634;
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`438/636; 438/692; 438/694; 438/703; 438/785;
`216/18
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`[58] Field of Search .......
`w+ 430/311, 312,
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`56/652.1, 661.11;
`430/314,
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`437/229, 195; 216/18: 438/598, 626, 634,
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`636, 637, 638, 618, 703, 692, 694, 126,
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`133. 355, 389, 785, 633
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`OTHER PUBLICATIONS
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`Dan C. Anderson et al., “The Great Static Protection
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`Debate”, Australian Electronics Engineering 17(10):52-5
`
`
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`Oct. 1984, 5 pgs.
`Yasushiro Fukudaet al., “Electrical Overstress/Electrostatic
`
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`Discharge”, VLSI ESD Phenomenon and Protection—-1988
`
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`EOS/ESD Symposium Proceedings, pp. 228-234.
`“Dual Damascene: A ULSI Wiring Technology,” Kaanta,et
`
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`
`
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`al.; VMIC Conference, Jun. 11, 1991.
`
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`“Chemical Vapor Deposition of Vanadium, Niobium, and
`Tantalum Nitride Thin Films,” Fix,et al.; Chem. Mater, vol.
`
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`
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`
`
`5, No. 5, 1993.
`
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`
`
`Primary Examiner—Bernard P. Codd
`
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`Attorney, Agent, or Firm—Keith E. Witek
`
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`ABSTRACT
`
`
`[57]
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`The present invention provides an anti-reflective TaN,
`coating which can be used in a dual damascenestructure and
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`for I line or G line lithographies. In addition, the Ta,N,
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`coating mayalso be used as an etch stop and.a barrier layer.
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`References Cited
`[56]
`
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`A dual damascene structure is formed by depositingafirst
`
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`dielectric layer (16). A dielectric tantalum nitride layer (18)
`U.S. PATENT DOCUMENTS
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`
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`is deposited on top of the first dielectric layer. A second
`3/1975 Kakihama et al. oo...ceseeeeeee
`3,884,698
`dielectric layer (20) is deposited on the tantalum nitride
`
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`2/1983 Kaneki et al.
`...
`4,374,912
`layer. A dual damascene opening (34) is etched into the
`
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`
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`
`
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`
`
`
`2/1989 Ohnoet al.
`.
`4,804,606
`dielectric layers by patterning a first opening portion (26)
`2/1992 Biomard .....
`5,091,244
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`and a second opening portion (32) using photolithography
`9/1995 Wooet al.
`..
`5,451,543
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`
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`operations. Dielectric tantalum nitride layer (18) serves as an
`5,635,423
`6/1997 Huanget al.
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`ARClayer during these operations to reduce the amount of
`FOREIGN PATENT DOCUMENTS
`reflectance from conductive region (14) to reduce distortion
`
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`
`
`of the photoresist pattern. The use of a dielectric tantalum
`
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`0661736Al
`7/1995 European Pat. Off. .
`
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`nitride layer as an ARC is particularly suitable for I line and
`
`60-32980=2/1985 Japan cescssessecsseessanesernecaneee FO3G 7/06
`
`
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`
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`G linelithography.
`3/1985
`60-55657
`Japan .....
`HOIL 27/04
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`
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`63-76325
`«» HOLL 21/30
`4/1988
`Japan .....
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`4-124869—4/1992 Japan .carsssssessecsesersenreeree HOIL 27/04
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`27 Claims, 6 Drawing Sheets
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`117/217
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`yo
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`ee,
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`KW
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`Page 1 of 12
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`TSMC Exhibit 1007
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`TSMC Exhibit 1007
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`Page 1 of 12
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`U.S. Patent
`
`Apr. 21, 1998
`
`Sheet 1 of 6
`
`5,741,626
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`RSS
`16
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`
` rn
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`RXR
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`18
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`16
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`18
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`Page 2 of 12
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`Page 2 of 12
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`16
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`U.S. Patent
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`Apr. 21, 1998
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`Sheet 2 of 6
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`5,741,626
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`18
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`Lok
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`|
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`18
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`REFLECTIVITY,
`
`
`ze
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`0.0
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`0.8000
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`Page 3 of 12
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`0.8750
`0.8500
`0.8250
`
`OXIDE THICKNESS (jm)
`
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`
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`0.9000
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`Page 3 of 12
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`US. Patent
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`Apr. 21, 1998
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`Sheet 3 of 6
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`5,741,626
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`100.0
`
`75.0
`
`REFLECTIVITY,
`7
`
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`
`
`50.0
`
`29.0
`
`
`
`0.0
`0.0000
`
`
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`0.0500
`
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`0.1000
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`
`0.2000
`
`
`
`
`
`TASNS THICKNESS (um)
`
`0.1500
`
`
`
`FTG.7
`
`REFLECTIVITY,
`
`
`
`
`100.0
`
`75.0
`
`50.0
`
`29.0
`
`
`
`
`
`
`0.0
`
`
`0.0000
`
`
`
`
`
`
`
`
`
`0.0500
`
`
`
`
`
`
`
`
`
`
`
`
`0.1000
`
`
`
`
`
`TA3N5 THICKNESS (jm)
`
`
`
`
`
`
`0.1500
`
`
`
`
`
`
`
`
`
`0.2000
`
`
`
`
`
`
`
`
`LIG.S
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`Page 4 of 12
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`Page 4 of 12
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`U.S. Patent
`
`Apr. 21,1998 Sheet 4 of 6
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`5,741,626
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`
`
`RRR
`
`
`re
`
` WDE
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`
`
`O—+>—'iCWIIIALI
`
`Le
`
`LT
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`Page 5 of 12
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`Page 5 of 12
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`Sheet 5 of 6
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`5,741,626
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`US. Patent
`Apr. 21, 1998
`FIG.12
`
`yo”
`
`QW
`LW
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`Page6 of 12
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`Page 6 of 12
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`US. Patent
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`Apr. 21, 1998
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`Sheet 6 of 6
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`5,741,626
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` |es®|
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`NSE
`Le
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`FIGLTS
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`Page 7 of 12
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`5,741,626
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`
`1
`METHOD FOR FORMINGA DIELECTRIC
`
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`TANTALUM NITRIDE LAYER AS AN ANTL
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`REFLECTIVE COATING (ARC)
`FIELD OF THE INVENTION
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`The present invention relates to semiconductor devices in
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`general, and more particularly to semiconductor devices
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`having anti-reflective coatings to aid in photolithography
`steps, such as those used to form in a dual damascene
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`interconnect structure.
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`2
`of a dual damascene structure in accordance with an alter-
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`native embodimentof the present invention.
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`FIGS. 13-15 illustrate in cross-section an alternative
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`process which may be used to form a dual damascene
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`structure having an ARC layer in accordance with the
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`present invention.
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`10
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`25
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`BACKGROUND OF THE INVENTION
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`The semiconductor industry’s continuing drive toward
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`integrated circuits with ever decreasing geometries, coupled
`. with its pervasive use of highly reflective materials, such as
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`polysilicon, aluminum, and :metal silicides, has lead to
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`increased photolithographic patterning problems. Unwanted
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`reflections from these underlying reflective materials during
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`the photoresist patterning process often cause the resulting
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`photoresist patterns to be distorted.
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`Anti-reflective coatings (ARCs) have been developed to
`minimize the adverse impact dueto reflectance from these
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`reflective materials. In many instances, these ARCs are
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`conductive materials which are deposited as a blanket layer
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`on top of metal and simultaneously patterned with the metal
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`to form interconnects. A problem with these ARCsis that
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`manyof these materials cannot be used in applications such
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`as dual damascene, wherein the metal layer is not patterned.
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`In a dual damascene application, openings are formedin the
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`interlayer dielectric, and the metal is blanketly deposited in
`those openings and subsequently polished back to form a
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`planar inlaid plug. In such application, the metal layer is
`never etched and therefore, any conductive ARC on top of
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`the inlaid metal would cause the metal plugs to be electri-
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`cally short circuited together through the conductive ARC.
`Somedielectric ARCs are also known,such as. silicon rich
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`silicon nitride or aluminum nitride, but a disadvantage with
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`these ARCsis that they are most suitable for deep ultraviolet
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`(DUV)radiation, whereas a vast majority of photolithogra-
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`phy steps occur at higher wave lengths such as Lline or
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`G-line where these ARCs are not optimal.
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`Accordingly, there is a need for an improved semicon-
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`ductor manufacturing operation which utilizes an anti-
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`reflective coating that is applicable to the more prevalent
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`Lline or G-line lithographies and which can be used in
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`applications, such as dual damascene, which require ARCs
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`that are nonconductive and potentially used as a damascene
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`etch stop layer.
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`DETAILED DESCRIPTION OF A PREFERRED
`
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`EMBODIMENT
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`Generally, the present invention involves using a dielec-
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`tric phase of tantalum nitride (Ta,;N.)in conjunction with
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`damascene or dual
`inlaid metalization processing.
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`Specifically, a conductive region is provided. overlying the
`surface of a semiconductor wafer. A damascene-type contact
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`is etched to expose the conductive region. The damascene
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`processtypically involves deposition of two dielectric layers
`with a silicon nitride (PEN) in the middle as an etch stop
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`material. In one form, an opening with a small width (via)
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`is formed using the PEN as an etch stop, followed by a
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`formation of a larger opening (interconnect trench). The
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`photolithographic processing used to form this damascene
`contact would be benefited by the use of an antireflective
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`coating (ARC) layer. In order to reduce reflected light,
`reduce destructive and constructive interference from reflec-
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`tive light, and reduce adverse effects of light reflection
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`during photoresist processing, a tantalum nitride dielectric
`layer (Ta;N;)is formed overlying the patterned inlaid con-
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`ductive region to function as an anti-reflective coating
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`(ARC).
`The use of this dielectric phase tantalum nitride ARC
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`layer provides several advantages. First, the tantalum nitride
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`ARC layer made of Ta;Nshas superior light absorption
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`qualities beyond other known ARClayers whenI line photo
`processing is used. In addition,
`the dielectric phase of
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`tantalum nitride (Ta;N,)is non-conductive and will therefore
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`not produce electrical short circuits of the inlaid damascene
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`structure. In addition, the Ta,N,, dielectricARC layer may be
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`deposited between the two dielectric layers (or oxide layers)
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`to replace the PEN layer so that the tantalum nitride ARC
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`layer can serve the dual purpose of being an anti-reflective
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`coating and being an etch stop layer used to form the
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`damascene contact. In addition, the Ta,N,, coating may be
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`deposited directly on top of the underlying conductive
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`region as a barrier layer which prevents atoms of copper or
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`like atoms from diffusing into adjacent dielectric regions.
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`The use of a dielectric tantalum nitride layer as an ARC
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`coating/etch stop layer/barrier material can be better under-
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`stood with reference to FIGS. 1-12.
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`FIGS. 1-5illustrate a method for forming a semiconduc-
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`tor structure 10 using a dielectric phase tantalum nitride
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`(Ta;Ns) anti-reflective coating (ARC) layer. In FIG. 1, a
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`semiconductor substrate 12 is provided. Typically, the anti-
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`reflective layer processing taught herein is performed
`between conductive layers of an integrated circuit which
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`may comprise one or morelayers of polysilicon, amorphous
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`silicon,silicides, salicides, metal regions, refractory metals,
`and the like. Therefore, semiconductor substrate 12 not only
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`includes a semiconductor wafer portion, but may also
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`include a plurality of dielectric and conductivelayers as are
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`necessaryto form active devices on a semiconductor sub-
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`strate. A conductive region 14 is formed overlying the
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`semiconductor substrate 12 which contains the active cir-
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`cuitry (not specifically illustrated in FIG. 1). The conductive
`region 14 is usedto electrically connect one active element
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`in the substrate 12 to one or moreother active element in the
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`substrate 12 as is known in the art. Conductive region 14 is
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`BRIEF DESCRIPTION OF THE DRAWINGS
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`FIGS. 1-5illustrate in cross-section a portion of a semi-
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`conductor device having a dual damascenestructure utiliz-
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`ing an anti-reflective coating in accordance with one
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`embodimentof the present invention.
`FIG.6 is an x-y graphillustrating the reflectivity of a dual
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`damascenestructure without having an ARC layer present.
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`FIG. 7 is an x-y graph illustrating the reflectivity of the
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`same dual damascene structure having a dielectric tantalum
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`nitride layer used as an ARC between thefirst and second
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`dielectric layers of the dual damascenestructure.
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`FIG. 8 is an x-y graphillustrating thereflectivity in the
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`dual damascene structure wherein a dielectric tantalum
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`nitride ARC is located between thefirst dielectric layer and
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`the metal layer of the dual damascenestructure.
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`FIGS. 9-12 illustrate in cross-section a portion of a
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`semiconductor device in which an ARCisusedat the bottom
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`Page 8 of 12
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`Page 8 of 12
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`5,741,626
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`4
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`tantalum nitride layer is preferably etched via a plasma
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`preferably made of 99% aluminum with a remainder of the
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`fluorine chemistry (CF,).
`material comprising copper. In another form,the conductive
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`FIG.3 illustrates that photoresist 28 is deposited overly-
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`region 14 may be copper, polysilicon, gold, or any like
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`ing the seconddielectric layer 20 and the dielectric tantalum.
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`conductive layer which has a surfacethatis reflective to light
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`nitride layer 18. A second masking and photolithographic
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`during photolithography processing. The layer 14 may be
`process is used to expose the photoresist 28 to light wherein
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`formed by a damascene process or may be patterned and
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`the anti-reflective dielectric tantalum nitride layer 18 is once
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`etched using conventional photolithography and. etch tech-
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`again used to reduce the adverse effects of light reflection
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`nology.
`from the surface of conductive region 14 to improve the
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`A first dielectric layer 16 is deposited over the conductive
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`critical dimension control of openings formed through pho-
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`region 14. In a preferred form, dielectric layer 16 is a
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`toresist layer 28. FIG. 3 illustrates that the opening 30
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`tetraethelorthosilicate (TEOS) layer. A dielectric tantalum
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`formed through photoresist layer 28 has a width which is
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`nitride layer Ta,N;is deposited overlying thefirst dielectric
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`less than a width of the opening formed through photoresist
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`layer 16. In a preferred form, the layer 18 is deposited
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`layer 22 and second dielectric layer 20. This two-tier etch
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`having a thickness of 100 angstroms to 1000 angstroms,
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`processing is typical when forming damascene contacts
`however, any thickness oflayer 18 will provide at least some
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`since the opening formed throughlayer 20 is used to provide
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`anti-reflective properties. A seconddielectric layer 20 is then
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`an electrical interconnect portion of conductive material
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`deposited over the dielectric tantalum nitride layer 18. Ina
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`between two contact openings and the opening formed using
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`preferred form, the second dielectric layer 20 is a TEOS
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`opening 30 as used to form a one contact portion of the
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`dielectric layer.
`damascene electrical interconnect.
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`In FIG. 1, a photoresist material 22 is formed overlying
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`FIG. 4 illustrates that the opening 30 through the photo-
`the seconddielectric layer 20. A portion of the photoresist 22
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`resist layer 28 is extended through the anti-reflective coating
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`is exposed to light or some radiation while other portions of
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`dielectric tantalum nitride layer 18 and thefirst dielectric
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`the photoresist 22 are shielded or masked from exposure to
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`layer 16 to expose a top surface of the conductive region 14.
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`the light. Typical wavelengths of light used for this exposure
`Therefore, the processing illustrated in FIGS. 2-4 result in
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`process is a wavelength selected from the range of 200
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`a two tier contact having a first portion 26 and a second
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`nanometers to 440 nanometers. Whenthis light is selectively
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`portion 32 wherein a width of the portion 26 is greater than
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`exposed to photoresist layer 22, the light passes through
`a width of the portion 32 asillustrated in FIG. 4. In FIG. 4.
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`layer 22, through layer 20, and will encounter the anti-
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`the photoresist layer 28 is removed from a surface of a
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`reflective coating dielectric tantalum nitride layer 18. The
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`semiconductive structure 10.
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`dielectric tantalum nitride layer 18 will attenuate (via
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`FIG. 5 illustrates that a conformal conductive layer is
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`absorption of energy) someofthe light passing through layer
`deposited overlying the semiconductor structure 10 and that
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`18 and will also phase shift someof the light through layer
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`this layer is chemically mechanically polished (CMP) or
`18 so that reflection off a surface of layer 14 will not
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`processed via resist etch back (REB) technology to form a
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`adversely impact the light exposure and subsequent devel-
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`planarized conductive plug 36 within the first portion 26 and
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`opmentof portions of the photoresist 22. Due to the presence
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`secondportion 32 of the opening formed via the processing
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`of layer 18, the dimensions of various openings through the
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`illustrated in FIG. 4. It is important to note that since the
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`photoresist 22 are rendered more controllable and an open-
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`layer 18 is a dielectric tantalum nitride layer, the layer 18
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`ing 24 can be developedthrough photoresist 22 in a manner
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`does not need to be isolated from any one of layer 14 or
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`that is much more manufacturable than openings which are
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`conductive plug 36 by dielectric spacers or additional depo-
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`manufactured using no anti-reflective coating layer.
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`sition steps. Therefore, by using a dielectric tantalum nitride
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`Therefore, FIG.1 illustrates an opening 24 which is superior
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`layer 18: (1) reflection from layer 14 is reduced to improve
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`to other openings formedin the prior art due to the presence
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`photoresist and photolithographic processing;(2) layer 18 is
`of the ARC dielectric tantalum nitride layer 18.
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`used as an etch stop to properly form damascene contacts;
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`It is importantto note that the attenuation properties of the
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`and (3) no additional processing steps are needed to deposit
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`Ta,N, dielectric tantalum nitride layer 18 is maximized at a
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`materials which isolate the conductive plug 36 from the
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`wavelength of roughly 300 nanometers. Optimal attenuation
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`layer 18 since the tantalum nitride layer 18 is nonconductive.
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`of reflection is also achieved when the thickness of the
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`Therefore, in summary, FIGS. 1-5 illustrate a method for
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`dielectric tantalum nitride layer 18 is between 100 ang-
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`forming an inter-metal damascene contact using a dielectric
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`stroms and 1000 angstroms. An optimal thickness being
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`tantalum nitride layer 18 which is superior to that taught in
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`roughly 500 angstroms in most circumstances. Therefore,
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`the prior art.
`the dielectric tantalum nitride layer 18 is a superior anti-
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`FIG. 6 illustrates, in an x-y plot, the percentage reflec-
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`reflective coating layer when used for I line processing and
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`tivity of photolithographic light versus the thickness of the
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`other photolithographic processing involving light exposure
`dielectric layer 16. FIG.6 illustrates the reflectivity for light
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`in the vicinity of 300 nanometers.
`having a wavelength of 365 nanometers.It should be noted,
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`FIG. 2 illustrates that the opening 24 in the photoresist
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`however, that the reflectivity of nearly any wavelength of
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`layer 22 is extended through the second dielectric layer 20
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`light and nearly any thickness of TEOS is going to be
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`to formafirst portion 26 of a contact opening. The chemistry
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`substantial in a manner similar to that illustrated in FIG. 6.
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`used to etch the opening 26 in seconddielectric layer 22 is
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`FIG. 6 illustrates that when no ARC layer(like layer 18
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`selective to the layer 18. Therefore, the dielectric tantalum
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`taught herein) is placed onto a semiconductor substrate as
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`nitride layer 18 functions as an etch stop for the etching
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`illustrated in FIGS. 1-5, the reflectivity of light from the
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`process used to form the opening 26. In FIG. 2, the photo-
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`surface of conductive region 14 is roughly 90%. This
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`resist 22 is illustrated as being removed from the semicon-
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`reflected light may cause constructive or destructive inter-
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`ductor structure 1¢ after formation of the opening 26. While
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`ference during photolithographic processing which will ren-
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`this photoresist removal is performed in FIG. 2 ina preferred
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`der the critical dimensions (e.g. width) of contact openings
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`method, in another form, photoresist 22 may remain on the
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`to vary significantly. In addition, the reflected light may
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`surface of the semiconductor structure 10 and be removed
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`result in photoresists not being properly exposedtolight and
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`subsequently with photoresist 28 of FIG. 3. The dielectric
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`40
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`Page 9 of 12
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`Page 9 of 12
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`5,741,626
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`5
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`6
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`not being properly developed. When photoresist is not
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`opening 50 of FIG. 10. It is important to note that the
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`properly exposed to light, the yield of the semiconductor
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`opening 50 through the photoresist layer 48 has a width
`device may be decreased. Therefore, FIG. 6 illustrates the
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`whichis greater than a width of the opening 44 as illustrated
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`in FIG. 10.
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`need for reducinglight reflectivity from the layer 14 so that
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`photoresist processing can be improved.
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`FIG, 11 illustrates that the polish stop layer 46 and the
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`second dielectric layer 20 are etched by exposing the layers
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`FIG. 7 illustrates the reflectivity percentage from the
`46 and 20 to an etch chemistry. The etch chemistry used to
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`surface of the conductive region 14 once the ARCdielectric
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`etch the dielectric layer 20 is selective to the layer 42.
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`tantalum nitride layer 18 is in place as illustrated in FIGS.
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`Therefore, layer 42 will providea self-alignment mechanism
`1-5. FIG.7 clearly indicates that a dielectric tantalum nitride
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`whereby the etch chemistry used to etch layers 20 and 16
`layer 18 when formed to a thickness of between 100
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`will automatically, in a self-aligning manner, allow for the
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`angstroms and roughly 800 angstroms can significantly
`formation ofa first opening portion 52 and a second opening
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`reducethe reflectivity percentage of light from the surface of
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`portion 54. The first opening portion 52 has a width which
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`conductive layer 14. This significant reduction of reflected
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`is greater than the second opening portion 54 due to the
`light results in a more controlled critical dimension process
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`smaller radius opening 44 of FIG. 10. Therefore, the final
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`and a higher yield photoresist process than that previously
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`structure resulting in FIG. 11 is nearly identical
`to the
`available via the reflection illustrated in FIG, 6.
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`structure illustrated in FIG. 4 with the exception of the
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`FIG. 8 illustrates that the tantalum nitride layer 18 of
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`additional layers 46 and 42 illustrated in FIG. 11.
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`FIGS. 1-5 may be positioned at the interface of layers 14
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`FIG. 12 illustrates that a conductive layer 58 is deposited
`and 16 instead of between layers 16 and 20 as in FIG. 1
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`and is chemical mechanically polished (CMPed) to form a
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`while still obtaining significant reflection reduction. In
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`conductive plug 58. Conductive plug 58 forms an electrical
`addition, the dielectric tantalum nitride layer also provides a
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`interconnectportion and anelectrical contact portion which
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`diffusion barrier for metals such as copper which is known
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`allows for electrical signals to be provided between conduc-
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`to diffuse easily through dielectric materials (TEOS and
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`tive region 14 and other conductive portionsof the substrate
`polyimide). Therefore, in an alternate embodiment, the layer
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`12.
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`18 may be placed between the layer 14 andthe layer 16 and
`FIGS. 13-15 illustrate an alternative embodiment for
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`not in between the layer 16 and the layer 20 as illustrated in
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`forming a dual damascene opening 34 in accordance with
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`FIG. 1. In yet another embodiment, the anti-reflective layer
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`another embodiment of the present
`invention.
`In this
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`18 may be placed between the seconddielectric layer 20 and
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`embodiment, rather than forming the larger portion of the
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`the photoresist layer 22. Experimentation has shown that
`dual damascene opening first as in FIGS. 1-5, the smaller
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`this upper placement of the dielectric tantalum nitride layer
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`portion of the opening is formedfirst. More specifically, in
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`18 still results in significant reduction in light reflectivity
`reference to FIG. 13, photoresist mask 60 is formed over-
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`similar to that indicated in FIGS. 7 and 8.
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`lying substrate 12, conductive region 14,first dielectric layer
`Given thatthe tantalum nitride dielectric layer 18 may be
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`16, dielectric tantalum nitride layer 18, and seconddielectric
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`positioned at different places within the interlevel dielectric
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`layer 20. An opening 62 is formed in photoresist mask 60,
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`composite, FIGS. 9-12illustrate and alternate embodiment.
`and the device is etched to formafirst portion 64 of an
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`FIG.9 illustrates a substrate 12 which is analogous to the
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`opening through second dielectric layer 20 and dielectric
`substrate illustrated in FIG. 1. A conductive region 14 is
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`tantalum nitride layer 18, as illustrated in FIG. 13. First
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`deposited where conductive region 14 is analogous to the
`portion 64 of the opening is used to define the smaller hole
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`conductive region 14 of FIG. 1. The dielectric tantalum
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`opening portion of the dual damascene structure. After
`nitride layer 18 is deposited on top of the conductive region
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`forming first portion 64, another photoresist mask 66 is
`14 as illustrated in FIG. 9. A dielectric layer 16 which is
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`formed on the device and is patterned to include an opening
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`analogous to the dielectric layer 16 of FIG. 1 is then
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`68, as illustrated in FIG. 14. Opening 68 will be used to
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`deposited overlying the dielectric tantalum nitride layer 18.
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`define the larger portion of the damascene opening while
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`A second etch stop layer or anti-reflective coating layer 42
`also etching a smaller opening in the dielectric layer 16. An
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`is then deposited overlying thefirst dielectric layer 16. Layer
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`etch operation is used while photoresist mask 66 is in place
`42 may be madeofdielectric tantalum nitride (Ta,N,)or may
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`to etch exposed portionsof the second dielectric layer 20 and
`be made of other dielectric anti-reflective coatings such as
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`the dielectric tantalum nitride layer within opening 68.
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`silicon rich silicon nitride. An opening 44 is etched through
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`Further, the etch will expose portionsoffirst dielectric layer
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`layer 42 using conventional photolithographic and etch
`16 within first portion 64 of an opening to the same etch
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`processing.
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`chemistry. Accordingly, the second etch step will simulta-
`After formation of the opening 44 asillustrated in FIG.9,
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`neously be etching the first and second dielectric layers to
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`a second dielectric layer 20 is deposited overlying the
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`ultimately form damascene opening 34 which whenfinished
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`opening 44 andthe layer 42. Dielectric layer 20 in FIG. 9 is
`is the same asthat formed in reference to FIG. 14. Therefore,
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`analogousto the dielectric layer 20 of FIG. 1. A polish stop
`FIGS..13-15 illustrate that there are a variety of processing
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`layer 46 is then deposited overlying a top portion of the
`sequences which may be used to form a damascenestructure
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`dielectric layer 20. The polish stop layer 46 may be formed
`in accordance with the present invention, and that the choice