WILLARD W. PULKRABEK
`
`.
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`Page 1 of 65
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`r I
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`Engineering Fundamentals
`of the
`Internal Combustion Engine
`
`Willard W. Pulkrabek
`University of Wisconsin-Platteville
`
`Prentice Hall
`Upper Saddle River, New Jersey 07458
`
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`Library of Congress Cataloging·in·Pnblication D»ta
`
`Pulkrabek, Willard W.
`Engineering fundamentals of the internal combustion engine I by
`Willard W. Pulkrabek.
`p. em.
`Includes bibliographical references and index.
`ISBN 0-13-570854-0
`1. Internal combustion engines.
`TJ785.P78 1997
`621.43---"-<ic21
`
`I. Title.
`
`96-54259
`CIP
`
`Acquisitions editor: William Stenquist
`Production editor: Rose Kernan
`Editor-in-chief" Marcia Horton
`Copy editor: Sharyn Vitrano
`Cover designer: Bruce Kenselaar
`Cover photo: Cutaway view of General Motors L82 V6 engine.
`Copyright General Motors Corp.; used with permission.
`Director of production and manufacturing: David W. Riccardi
`Managing editor: Bayani Mendoza De Leon
`Manufacturing buyer: Julia Meehan
`Compositor: Prepare Inc. I Ernilcomp sri
`
`© 1997 by Prentice-Hall, Inc.
`Simon & Schuster I A Viacom Company
`Upper Saddle River, New Jersey 07458
`
`All rights reserved. No part of this book may be
`reproduced, in any form or by any means,
`without permission in writing from the publisher.
`
`The author and publisher of this book have used their best efforts in preparing this book. These efforts
`include the development, research, and testing of the theories and programs to determine their
`effectiveness. The author and publisher make no warranty of any kind, expressed or implied, with
`regard to these programs or the documentation contained in this book. The author and publisher shall
`not be liable in any event for incidental or consequential damages in connection with, or arising out of,
`the furnishing, performance, or use of these programs.
`
`Printed in the United States of America
`
`10 9 8 7 6
`
`ISBN 0-13-570854-0
`
`Prentice-Hall International (UK) Limited, London
`Prentice-Hall of Australia Pty. Limited, Sydney
`Prentice-Hall Canada Inc:; 1"oronto
`Prentice-Hall Hispanoamericana, S.A., Mexico
`Prentice-Hall of India Private Limited, New Delhi
`Prentice-Hall of Japan, Inc., Tokyo
`Simon & Schuster Asia Pte. Ltd., Singapore
`Editora Prentice-Hall do Brasil, Ltda., Rio de Janeiro
`
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`
`
`Contents
`
`PREFACE
`
`NOTATION
`
`1
`
`INTRODUCTION
`
`1—1
`Introduction, 1
`1-2 Early History, 5
`13
`Engine Classifications, 5
`1—4 Terminology and Abbreviations, 14
`1-5 Engine Components, 18
`1—6 Basic Engine Cycles, 24
`1—7
`Engine Emissions and Air Pollution, 30
`Problems, 33
`Design Problems, 34
`
`OPERATING CHARACTERISTICS
`
`Engine Parameters, 35
`2—1
`2—2 Work, 44
`
`xi
`
`XV
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`35
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`vi
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`Contents
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`2—3
`2—4
`
`2-6
`
`2—7
`
`2-9
`
`2-10
`
`2—11
`
`2—12
`
`Mean Effective Pressure, 49
`Torque and Power, 50
`Dynamometers, 53
`Air—Fuel Ratio and Fuel—Air Ratio, 55
`
`Specific Fuel Consumption, 56
`Engine Efficiencies, 59
`Volumetric Efficiency, 60
`Emissions, 62
`
`Noise Abatement, 62
`Conclusions——Working Equations, 63
`Problems, 65
`Design Problems, 67
`
`ENGINE CYCLES
`
`68
`
`3-1
`
`3—2
`
`3-3
`
`3-4
`
`3-5
`
`3—6
`
`3—7
`
`3-8
`
`3—9
`
`3-10
`
`3-11
`
`3-12
`
`3—13
`
`3—14
`
`Air—Standard Cycles, 68
`Otto Cycle, 72
`Real Air—Fuel Engine Cycles, 81
`SI Engine Cycle at Part Throttle, 83
`Exhaust Process, 86
`
`Diesel Cycle, 91
`Dual Cycle, 94
`Comparison of Otto, Diesel, and Dual Cycles, 97
`Miller Cycle, 103
`Comparison of Miller Cycle and Otto Cycle, 108
`Two—Stroke Cycles, 109
`Stirling Cycle, 111
`Lenoir Cycle, 113
`Summary, 115
`Problems, 116
`Design Problems, 120
`
`THERMOCHEMISTRY AND FUELS
`
`121
`
`4—1
`
`4—2
`
`4—3
`
`4—4
`
`4—5
`
`4-6
`
`4—7
`
`Thermochemistry, 121
`Hydrocarbon Fuels~Gasoline, 131
`Some Common Hydrocarbon Components, 134 ‘
`Self-Ignition and Octane Number, 139
`Diesel’Fuel, 148
`
`Alternate Fuels, 150
`Conclusions, 162
`
`Problems, 162
`Design Problems, 165
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`Contents
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`5
`
`AIR AND FUEL INDUCTION
`
`vii
`
`166
`
`5-1
`
`5-2
`
`5—3
`
`5—4
`
`5—5
`
`5—6
`
`5—7
`
`58
`
`5-9
`5-10
`
`Intake Manifold, 166
`Volumetric Efficiency of SI Engines, 168
`Intake Valves, 173
`Fuel Injectors, 178
`Carburetors, 181
`Supercharging and Turbocharging, 190
`Stratified Charge Engines
`and Dual Fuel Engines, 195
`Intake for TWO—Stroke Cycle Engines, 196
`Intake for CI Engines, 199
`Conclusions, 201
`Problems, 202
`Design Problems, 204
`
`6
`
`FLUID MOTION WITHIN COMBUSTION CHAMBER
`
`206
`
`6-1
`6-2
`
`6—3
`
`6—4
`
`6-5
`
`6-6
`
`6—7
`
`6-8
`
`Turbulence, 206
`Swirl, 208
`Squish and Tumble, 213
`Divided Combustion Chambers, 214
`Crevice Flow and Blowby, 215
`Mathematical Models and Computer
`Simulation, 219
`Internal Combustion Engine Simulation
`Program, 221
`Conclusions, 225
`Problems, 226
`Design Problems, 228 ‘7
`
`7
`
`COMBUSTION
`
`229
`
`7—1
`
`7—2
`
`7—3
`
`7—4
`
`7-5
`
`7—6
`
`Combustion in SI Engines, 229
`Combustion in Divided Chamber Engines
`and Stratified Charge Engines, 243
`Engine Operating Characteristics, 246
`Modern Fast Burn Combustion Chambers, 248
`Combustion in CI Engines, 251
`Summary, 259
`Problems, 260
`Design Problems, 261
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`viii
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`8
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`EXHAUST FLOW
`
`Contents
`
`262
`
`8-1 Blowdown, 262
`8—2 Exhaust Stroke, 265
`8-3 Exhaust Valves, 268
`8—4 Exhaust Temperature, 269
`8—5 Exhaust Manifold, 270
`
`8-6 Turbochargers, 272
`8—7 Exhaust Gas RecyclemEGR, 273
`8-8 Tailpipe and Muffler, 273
`8—9
`Two—Stroke Cycle Engines, 274
`8-10 Summary and Conclusions, 274
`Problems, 275
`Design Problems, 276
`
`9
`
`EMISSIONS AND AIR POLLUTION
`
`277
`
`9—1 Air Pollution, 277
`9—2 Hydrocarbons (HC), 278
`9-3 Carbon Monoxide (CO), 285
`9—4 Oxides of Nitrogen'(NOx), 285
`9—5
`Particulates, 287
`
`9—6 Other Emissions, 290
`
`9—7 Aftertreatment, 292
`9—8 Catalytic Converters, 293
`9-9 CI Engines, 301
`9—10 Chemical Methods to Reduce Emissions, 303
`9—11 Exhaust Gas Recycle—EGR, 304
`9-12 Non—Exhaust Emissions, 307
`
`Problems, 308
`Design Problems, 311
`
`10
`
`HEAT TRANSFER IN ENGINES
`
`312
`
`10~1 Energy Distribution, 313
`102 Engine Temperatures, 314
`10-3 Heat Transfer in Intake System, 317
`104 Heat Transfer in Combustion Chambers, 318
`
`10—5 Heat Transfer in Exhaust System, 324
`10—6 Effect of Engine Operating Variables
`on Heat Transfer, 327
`10-7 Air Cooled Engines, 334
`10—8 Liquid Cooled Engines, 335
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`10—9 Oil as a Coolant, 340
`10—10 Adiabatic Engines, 341
`10—11 Some Modern Trends in Engine Cooling, 342
`10-12 Thermal Storage, 343
`10—13 Summary, 345
`-
`Problems, 345
`Design Problems, 348
`
`11
`
`FRICTION AND LUBRICATION
`
`349
`
`11-1 Mechanical Friction and Lubrication, 349
`
`11—2 Engine Friction, 351
`11—3
`Forces on Piston, 360
`11—4 Engine Lubrication systems, 364
`11—5
`Two—Stroke Cycle Engines, 366
`11—6
`Lubricating Oil, 367
`11~7 Oil Filters, 373
`11—8
`Summary and Conclusions, 375
`Problems, 376
`
`Design Problems, 377
`
`APPENDIX
`
`A—l
`A—Z
`A—3
`A-4
`
`Thermodynamic Properties of Air, 379
`Properties of Fuels, 380
`Chemical Equilibrium Constants, 381
`Conversion Factors for Engine Parameters, 382
`
`REFERENCES
`
`ANSWERS T0 SELECTED REVIEW PROBLEMS
`
`INDEX
`
`378
`
`384
`
`392
`
`395
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`1
`
`Introduction
`
`This chapter introduces and defines the internal combustion engine. It lists ways of
`classifying engines and terminology used in engine technology. Descriptions are
`given of many common engine components and of basic four-stroke and two-stroke
`cycles for both spark ignition and compression ignition engines.
`
`1-1 INTRODUCTION
`
`The internal combustion engine (IC) is a heat engine that converts chemical energy
`in a fuel into mechanical energy, usually made available on a rotating output shaft.
`Chemical energy of the fuel is first converted to thermal energy by means of com(cid:173)
`bustion or oxidation with air inside the engine. This thermal energy raises the
`temperature and pressure of the gases within the engine, and the high-pressure gas
`then expands against the mechanical mechanisms of the engine. This expansion is
`converted by the mechanical linkages of the engine to a rotating crankshaft, which is
`the output of the engine. The crankshaft, in turn, is connected to a transmission
`and/or power train to transmit the rotating mechanical energy to the desired final
`use. For engines this will often be the propulsion of a vehicle (i.e., automobile, truck,
`locomotive, marine vessel, or airplane). Other applications include stationary
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`2
`
`Introduction
`
`Chap. 1
`
`engines to drive generators or pumps, and portable engines for things like chain
`saws and lawn mowers.
`Most internal combustion engines are reciprocating engines having pistons
`that reciprocate back and forth in cylinders internally within the engine. This book
`concentrates on the thermodynamic study of this type of engine. Other types of IC
`engines also exist in much fewer numbers, one important one being the rotary
`engine [104]. These engines will be given brief coverage. Engine types not covered
`by this book include steam engines and gas turbine engines, which are better classi(cid:173)
`fied as external combustion engines (i.e., combustion takes place outside the
`mechanical engine system). Also not included in this book, but which could be clas(cid:173)
`sified as internal combustion engines, are rocket engines, jet engines, and firearms.
`Reciprocating engines can have one cylinder or many, up to 20 or more. The
`cylinders can be arranged in many different geometric configurations. Sizes range
`from small model airplane engines with power output on the order of 100 watts to
`large multicylinder stationary engines that produce thousands of kilowatts per
`cylinder.
`There are so many different engine manufacturers, past, present, and future,
`that produce and have produced engines which differ in size, geometry, style, and
`operating characteristics that no absolute limit can be stated for any range of engine
`characteristics (i.e., size, number of cylinders, strokes in a cycle, etc.). This book will
`work within normal characteristic ranges of engine geometries and operating para(cid:173)
`meters, but there can always be exceptions to these.
`Early development of modern internal combustion engines occurred in the lat(cid:173)
`ter half of the 1800s and coincided with the development of the automobile. History
`records earlier examples of crude internal combustion engines and self-propelled
`road vehicles dating back as far as the 1600s [29]. Most of these early vehicles were
`steam-driven prototypes which never became practical operating vehicles. Technol(cid:173)
`ogy, roads, materials, and fuels were not yet developed enough. Very early examples
`of heat engines, including both internal combustion and external combustion, used
`gun powder and other solid, liquid, and gaseous fuels. Major development of the
`modern steam engine and, consequently, the railroad locomotive occurred in the lat(cid:173)
`ter half of the 1700s and early 1800s. By the 1820s and 1830s, railroads were present
`in several countries around the world.
`
`HISTORIC-ATMOSPHERIC ENGINES
`
`Most of the very earliest internal combustion engines of the 17th
`and 18th centuries can be classified as atmospheric engines. These were
`large engines with a single piston and cylinder, the cylinder being open
`on the end. Combustion was initiated in the open cylinder using any of the
`various fuels which were available. Gunpowder was often used as the
`fuel. Immediately after combustion, the cylinder would be full of hot
`exhaust gas at atmospheric pressure. At this time, the cylinder end was
`closed and the trapped gas was allowed to cool. As the gas cooled, it ere-
`
`'I
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`I:
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`Sec. 1-1
`
`Introduction
`
`3
`
`Figure 1-1 The Charter Engine made in 1893 at the Beloit works of Fairbanks,
`Morse & Company was one of the first successful gasoline engine offered for sale in
`the United States. Printed with permission, Fairbanks Morse Engine Division,
`Coltec Industries.
`
`ated a vacuum within the cylinder. This caused a pressure differential
`across the piston, atmospheric pressure on one side and a vacuum on the
`other. As the piston moved because of this pressure differential, it would
`do work by being connected to an external system, such as raising a
`weight [29].
`Some early steam engines also were atmospheric engines. Instead
`of combustion, the open cylinder was filled with hot steam. The end was
`then closed and the steam was allowed to cool and condense. This cre(cid:173)
`ated the necessary vacuum.
`
`In addition to a great amount of experimentation and development in Europe
`and the United States during the middle and latter half of the 1800s, two other tech(cid:173)
`nological occurrences during this time stimulated the emergence of the internal
`combustion engine. In 1859, the discovery of crude oil in Pennsylvania finally made
`available the development of reliable fuels which could be used in these newly
`developed engines. Up to this time, the lack of good, consistent fuels was a major
`drawback in engine development. Fuels like whale oil, coal gas, mineral oils, coal,
`and gun powder which were available before this time were less than ideal for
`engine use and development. It still took many years before products of the petro(cid:173)
`leum industry evolved from the _first crude oil to gasoline, the automobile fuel of the
`20th century. However, improved hydrocarbon products began to appear as early
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`4
`
`Introduction
`
`Chap. 1
`
`1:
`
`•
`
`Figure 1-2 Ford Taurus SHO 3.4 liter (208 in. 3), spark ignition, four-stroke cycle
`engine. The engine is rated at 179 kW at 6500 RPM (240 hp) and develops 305 N-m
`of torque at 4800 RPM (225lbf-ft). It is a 60° V8 with ~20 em bore (3.23 in.), 7.95 em
`stroke (3.13 in.), and a compression ratio of 10:1. The engine has four chain driven
`camshafts mounted in aluminum heads with four valves per cylinder and coil-on(cid:173)
`plug ignition. Each spark plug has a separate high-voltage coil and is fired by Ford's
`Electronic Distributorless Ignition System (EDIS). Courtesy of Ford Motor
`Company.
`
`as the 1860s and gasoline, lubricating oils, and the internal combustion engine
`evolved together.
`The second technological invention that stimulated the development of the
`internal combustion engine was the pneumatic rubber tire, which was first marketed
`by John B. Dunlop in 1888 [141]. This invention made the automobile much more
`practical and desirable and thus generated a large market for propulsion systems,
`including the internal combustion engine.
`During the early years of the automobile, the internal combustion engine com(cid:173)
`peted with electricity and steam engines as the basic means of propulsion. Early in
`the 20th century1 electricity and steam faded from the automobile picture-electricity
`because of the limited range it provided, and steam because of the long start-up time
`needed. Thus, the 20t~ century is the period of the internal combustion engine and
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`Sec. 1-3
`
`Engine Classifications
`
`5
`
`the automobile powered by the internal combustion engine. Now, at the end of the
`century, the internal combustion engine is again being challenged by electricity and
`other forms of propulsion systems for automobiles and other applications. What
`goes around comes around.
`
`1-2 EARLY HISTORY
`
`During the second half of the 19th century, many different styles of internal com(cid:173)
`bustion engines were built and tested. Reference [29] is suggested as a good history
`of this period. These engines operated with variable success and dependability using
`many different mechanical systems and engine cycles.
`The first fairly practical engine was invented by J.J.E. Lenoir (1822-1900) and
`appeared on the scene about 1860 (Fig. 3-19). During the next decade, several hun(cid:173)
`dred of these engines were built with power up to about 4.5 kW (6 hp) and
`mechanical efficiency up to 5%. The Lenoir engine cycle is described in Section
`3-13. In 1867 the Otto-Langen engine, with efficiency improved to about 11%, was
`first introduced, and several thousand of these were produced during the next
`decade. This was a type of atmospheric engine with the power stroke propelled by
`atmospheric pressure acting against a vacuum. Nicolaus A. Otto (1832-1891) and
`Eugen Langen (1833-1895) were two of many engine inventors of this period.
`During this time, engines operating on the same basic four-stroke cycle as the
`modern automobile engine began to evolve as the best design. Although many peo(cid:173)
`ple were working on four-stroke cycle design, Otto was given credit when his
`prototype engine was built in 1876.
`In the 1880s the internal combustion engine first appeared in automobiles [ 45].
`Also in this decade the two-stroke cycle engine became practical and was manufac(cid:173)
`tured in large numbers.
`By 1892, Rudolf Diesel (1858-1913) had perfected his compression ignition
`engine into basically the same diesel engine known today. This was after years of
`development work which included the use of solid fuel in his early experimental
`engines. Early compression ignition engines were noisy, large, slow, single-cylinder
`engines. They were, however, generally more efficient than spark ignition engines. It
`wasn't until the 1920s that multicylinder compression ignition engines were made
`small enough to be used with automobiles and trucks.
`
`1-3 ENGINE CLASSIFICATIONS
`
`Internal combustion engines can be classified in a number of different ways:
`
`1. Types of Ignition
`(a) Spark Ignition (SI). An SI engine starts the combustion process in each
`cycle by use of a spark plug. The spark plug gives a high-voltage electrical
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`6
`
`Introduction
`
`Chap. 1
`
`Figure 1-3 1955 Chevrolet "small block" V8 engine with 265 in. 3 ( 4.34 L) displace(cid:173)
`ment. The four-stroke cycle, spark ignition engine was equipped with a carburetor
`and overhead valves. Copyright General Motors Corp., used with permission.
`
`discharge between two electrodes which ignites the air-fuel mixture in the
`combustion chamber surrounding the plug. In early engine development,
`before the invention of the electric spark plug, many forms of torch holes
`were used to initiate combustion from an external flame.
`(b) Compression Ignition (CI). The combustion process in a CI engine starts
`when the air-fuel mixture self-ignites due to high temperature in the com(cid:173)
`bustion chamber caused by high compression.
`2. Engine Cycle
`(a) Four-Stroke Cycle. A four-stroke cycle experiences four piston move(cid:173)
`ments over two engine_revolutions for each cycle.
`(b) Two-Stroke Cycle. A two-stroke cycle has two piston movements over one
`revolution for each cycle.
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`.. -··o.
`' r ~
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`24
`
`Introduction
`
`Chap.1
`
`HISTORIC-STARTERS
`
`Early automobile engines were started with hand cranks that
`connected with the crankshaft of the engine. This was a difficult and dan(cid:173)
`gerous process, sometimes resulting in broken fingers and arms when the
`engine would fire and snaj)'back the hand crank. The first electric starters
`appeared on the 1912 Cadillac automobiles, invented by C. Kettering, who
`was motivated when his friend was killed in the process of hand starting
`an automobile [45].
`
`Supercharger Mechanical compressor powered off of the crankshaft, used to com(cid:173)
`press incoming air of the engine.
`
`Throttle Butterfly valve mounted at the upstream end of the intake system, used
`to control the amount of air flow into an SI engine. Some small engines and
`stationary constant-speed engines have no throttle.
`
`Turbocharger Turbine-compressor used to compress incoming air into the engine.
`The turbine is powered by the exhaust flow of the engine and thus takes very
`little useful work from the engine.
`
`Valves Used to allow flow into and out of the cylinder at the proper t:hne in the
`cycle. Most engines use poppet valves, which are '!;pring loaded closed and
`pushed open by camshaft action (Fig. 1-12). Valves are mostly made of forged
`steel. Surfaces against which valves close are called valve seats and are made of
`hardened steel or ceramic. Rotary valves and sleeve valves are sometimes used,
`but are much less common. Many two-stroke cycle engines have ports (slots) in
`the side of the cylinder walls instead of mechanical valves.
`
`Water jacket System of liquid flow passages surrounding the cylinders, usually
`constructed as part of the engine block and head. Engine coolant flows
`through the water jacket and keeps the cylinder walls from overheating. The
`coolant is usually a water-ethylene glycol mixture.
`
`Water pump Pump used to circulate engine coolant through the engine and radia(cid:173)
`tor. It is usually mechanically run off of the engine.
`
`Wrist pin Pin fastening the connecting rod to the piston (also called the piston pin).
`
`1-6 BASIC ENGINE CYCLES
`
`Most internal combustion engines, both spark ignition and compression ignition,
`operate on either a four-stroke cycle or a two-stroke cycle. These basic cycles are
`fairly standard for all engines, with only slight variations found in individual designs.
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`'I
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`Sec. 1-6
`
`Basic Engine Cycles
`
`25
`
`Four-Stroke Sl Engine Cycle {Fig. 1-16)
`
`1. First Stroke: Intake Stroke or Induction The piston travels from TDC to
`BDC with the intake valve open and exhaust valve closed. This creates an increasing
`volume in the combustion chamber, which in turn creates a vacuum. The resulting
`pressure differential through the intake system from atmospheric pressure on the
`outside to the vacuum on the inside causes air to be pushed into the cylinder. As the
`air passes through the intake system, fuel is added to it in the desired amount by
`means of fuel injectors or a carburetor.
`2. Second Stroke: Compression Stroke When the piston reaches BDC, the
`intake valve closes and the piston travels back to TDC with all valves closed. This
`compresses the air-fuel mixture, raising both the pressure and temperature in the
`cylinder. The finite time required to close the intake valve means that actual com(cid:173)
`pression doesn't start until sometime aBDC. Near the end of the compression
`stroke, the spark plug is fired and combustion is initiated.
`3. Combustion Combustion of the air-fuel mixture occurs in a very short but
`finite length of time with the piston near TDC (i.e., nearly constant-volume com(cid:173)
`bustion). It starts near the end of the compression stroke slightly bTDC and lasts
`into the power stroke slightly aTDC. Combustion changes the composition of the
`gas mixture to that of exhaust products and increases the temperature in the cylin(cid:173)
`der to a very high peak value. This, in turn, raises the pressure in the cylinder to a
`very high peak value.
`4. Third Stroke: Expansion Stroke or Power Stroke With all valves closed,
`the high pressure created by the combustion process pushes the piston away from
`TDC. This is the stroke which produces the work output of the engine cycle. As the
`piston travels from TDC to BDC, cylinder volume is increased, causing pressure and
`temperature to drop.
`5. Exhaust Blowdown Late in the power stroke, the exhaust valve is opened
`and exhaust blowdown occurs. Pressure and temperature in the cylinder are still
`high relative to the surroundings at this point, and a pressure differential is created
`through the exhaust system which is open to atmospheric pressure. This pressure
`differential causes much of the hot exhaust gas to be pushed out of the cylinder and
`through the exhaust system when the piston is near BDC. This exhaust gas carries
`away a high amount of enthalpy, which lowers the cycle thermal efficiency. Opening
`the exhaust valve before BDC reduces the work obtained during the power stroke
`but is required because of the finite time needed for exhaust blowdown.
`6. Fourth Stroke: Exhaust Stroke By the time the piston reaches BDC,
`exhaust blowdown is complete, but the cylinder is still full of exhaust gases at
`approximately atmospheric pressure. With the exhaust valve remaining open, the
`piston now travels from BDC to IDC in the exhaust stroke. This pushes most of the
`remaining exhaust gases out of the cylinder into the exhaust system at about atmos(cid:173)
`pheric pressure, leaving only that trapped in the clearance volume-when the piston
`reaches TDC. Near the end of the exhaust stroke bTDC, the intake valve starts to
`
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`

`

`26
`
`Introduction
`
`Chap. 1
`
`0
`
`(a)
`
`(b)
`
`(c)
`
`0
`
`(d)
`
`(e)
`
`(f)
`
`Figure 1-16 Four-stroke SI engine operating cycle. (a) Intake stroke. Ingress of air(cid:173)
`fuel as piston moves from TDC to BDC. (b) Compression stroke. Piston moves from
`BDC to TDC. Spark ignition occurs near end of compression stroke. (c) Combus(cid:173)
`tion at almost constant volume near TDC. (d) Power or expansion stroke. High
`cylinder pressure pushes piston from TDC towards BDC. (e) Exhaust blowdown
`when exhaust valve opens near end of expansion stroke. (f) Exhaust stroke.
`Remaining exhaust pushed from cylinder as piston moves from BDC tt/TDC.
`
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`

`Sec. 1-6
`
`Basic Engine Cyc~s
`
`27
`
`open, so that it is fully open by TDC when the new intake stroke s~ the next
`cycle. Near TDC the exhaust valve starts to close and finally is fully closed sometime
`aTDC. This period when both the intake valve and exhaust valve are open is called
`valve overlap.
`·
`
`Four-Stroke Cl Engine Cycle
`
`1. First Stroke: Intake Stroke The same as the intake stroke in an SI engine
`with one major difference: no fuel is added to the incoming air.
`2. Second Stroke: Compression Stroke The same as in an SI engine except
`that only air is compressed and compression is to higher pressures and temperature.
`Late in the compression stroke fuel is injected directly into the combustion chamber,
`where it mixes with the very hot air. This causes the fuel to evaporate and self-ignite,
`causing combustion to start.
`3. Combustion Combustion is fully developed by TDC and continues at
`about constant pressure until fuel injection is complete and the piston has started
`towards BDC.
`4. Third Stroke: Power Stroke The power stroke continues as combustion
`ends and the piston travels towards BDC.
`5. Exhaust Blowdown Same as with anSI engine.
`6. Fourth Stroke: Exhaust Stroke Same as with an Sl engine.
`
`Two-Stroke Sl Engine Cycle (fig. 1-17)
`
`1. Combustion With the piston at TDC combustion occurs very quickly, rais(cid:173)
`ing the temperature and pressure to peak values, almost at constant volume.
`2. First Stroke: Expansion Stroke or Power Stroke Very high pressure cre(cid:173)
`ated by the combustion process forces the piston down in the power stroke. The
`expanding volume of the combustion chamber causes pressure and temperature to
`decrease as the piston travels towards BDC.
`3. Exhaust Blowdown At about 75° bBDC, the exhaust valve opens and
`blowdown occurs. The exhaust valve may be a poppet valve in the cylinder head, or
`it may be a slot in the side of the cylinder which is uncovered as the piston
`approaches BDC. After blowdown the cylinder remains filled with exhaust gas at
`lower pressure.
`4. Intake and Scavenging When blowdown is nearly complete, at about 50°
`bBDC, the intake slot on the side of the cylinder is uncovered and intake air-fuel
`enters under pressure. Fuel is added to the air with either a carburetor or fuel injec(cid:173)
`tion. This incoming mixture pushes much of the remaining exhaust gases out the
`open exhaust valve and fills the cylinder with a combustible air-fuel mixture, a
`process called scavenging. The piston passes BDC and very quickly covers the
`intake port and then the exhaust port (or the exhanst valve closes). The higher pres-
`
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`

`4 V
`
` Thermochemistry
`
`'
`
`and Fuels
`
`This chapter reviews basic thermoChemistry principles as applied to IC engines. It
`studies ignition characteristics and combustion in engines, the octane number of SI
`fuels, and the cetane number of CI fuels. Gasoline and other possible alternate fuels
`are examined.
`
`4-1 THERMOCHEMISTRY
`
`Combustion Reactions
`
`Most IC engines obtain their energy from the combustion of a hydrocarbon fuel
`with air, which converts chemical energy of the fuel to internal energy in the gases
`Within the engine. There are many thousands of different hydrocarbon fuel compo-
`nents, which consist mainly of hydrogen and carbon but may also contain oxygen
`(alcohols), nitrogen, and/or sulfur, etc. The maximum amount of chemical energy
`that can be released (heat) from the fuel is when it reacts (combusts) with a stoi-
`chiometric amount of oxygen. Stoichiometric oxygen (sometimes called theoretical
`oxygen) is just enough to convert all carbon in the fuel to C02 and all hydrogen to
`
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`

`122
`
`Thermochemistry and Fuels
`
`Chap. 4
`
`H2 0, with no oxygen left over. The balanced chemical equation of the simplest
`hydrocarbon fuel, methane CH4 , burning with stoichiometric oxygen is:
`
`CH4 +202—9C02+2H20
`
`It takes two moles of oxygen to react with one mole of fuel, and this gives one
`mole of carbon dioxide and two moles of water vapor. If isooctane is the fuel com—
`ponent, the balanced stoichiometric combustion with oxygen would be:
`‘
`
`Cngg + 12.5 02 —> 8 C02 + 9 H20
`
`Molecules react with molecules, so in balancing a chemical equation, molar
`quantities (fixed number of molecules) are used and not mass quantities. One
`kgmole of a substance has a mass in kilograms equal in number to the molecular
`weight (molar mass),of that substance. In English units the lbmmole is used.
`
`m = NM
`
`(4—1)
`
`where: m = mass
`
`N = number of moles
`
`M = molecular weight
`
`In SI units:
`
`In English units:
`
`1 kgmole of CH4 = 16.04 kg
`
`1 kgmole of 02 = 32.00 kg
`
`1 kgmole = 6.02 X 1026 molecules
`
`1 lbmmole of CH4 = 16.041bm
`
`1 lbmmole of 02 = 32.001bm
`
`1 lbmmole = 2.73 X 1026 molecules
`
`The components on the left side of a chemical reaction equation which are pre-
`sent before the reaction are called reactants, while the components on the right side of
`the equation which are present after the reaction are called products or exhaust.
`Very small powerful engines could be built if fuel were burned with pure oxy-
`gen. However, the cost of using pure oxygen would be prohibitive, and thus is not
`done. Air is used as the source of oxygen to react with fuel. Atmospheric air is made
`
`up of about:
`
`78% nitrogen by mole
`
`21% oxygen
`
`1% argon
`
`traces of C02, Ne, CH4, He, H20, etc.
`
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`Sec. 4—1
`
`Thermochemistry
`
`$23
`
`Nitrogen and argon are essentially chemically neutral and do not react in the
`combustion process. Their presence, however, does affect the temperature and pres-
`sure in the combustion chamber. To simplify calculations without causing any large
`error, the neutral argon in air is assumed to be combined with the neutral nitrogen,
`and atmospheric air then can be modeled as being made up of 21 % oxygen and 79%
`nitrogen. For every 0.21 moles of oxygen there is also 0.79 moles of nitrogen, or for
`one mole of oxygen there are 0.79/0.21 moles of nitrogen. For every mole of oxygen
`needed for combustion, 4.76 moles of air must be supplied: one mole of oxygen plus
`3.76 moles of nitrogen.
`'
`Stoichiometric combustion of methane with air is then:
`
`CH4 + 2 02 + 2(3.76) N2 —> C02 + 2 H2O + 2(3.76) N2
`
`and of isooctane with air is:
`
`Cngg + 12.5 02 + 12.5(3.76) N2 —> 8 C02 + 9 H20 + 12.5(3.76) N2
`
`It is convenient to balance combustion reaction equations for one kgmole of
`fuel. The energy released by the reaction will thus have units of energy per kgmole
`Of fuel, which is easily transformed to total energy when the flow rate of fuel is
`known. This convention will be followed in this textbook. Molecular weights can be
`found in Table 4—1 and Table A-2 in the Appendix. The molecular weight of 29 will
`be used for air. Combustion can occur, within limits, when more than stoichiometric
`air is present (lean) or when less than stoichiometric air is present (rich) for a given
`amount of fuel. If methane is burned with 150% stoichiometric air, the excess oxy—
`gen ends up in the products:
`CH4 + 302 + 3(3.76) N2 —> CO2 + 2 H2O + 3(3.76) N2 + 02
`
`If isooctane is burned with 80% stoichiometric air, there is not enough oxygen to
`convert all the carbon to C02, and carbon monoxide CO is found in the products:
`
`Cngg + 10 02 + 10(3.76) N2 ——> 3 C02 + 9 H20 “1‘ 5 C0 + 10(3.76) N2
`
`TABLE 4-1 MOLECULAR WEIGHTS
`
`SUBSTANCE
`
`MOLECULAR WEIGHT
`
`(kg/kgmole) or (lbm/lbmmole)
`
`Air
`Argon
`Carbon
`Carbon Monoxide
`Carbon Dioxide
`Hydrogen
`Water Vapor
`Helium
`Nitrogen
`
`Ar
`C
`CO
`co2
`H2
`H2 0
`He
`. N2
`
`.
`
`-
`
`28.97
`39.95
`12.01
`28.01
`44.01
`2.02
`18.02
`4.00
`28.01
`
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`124
`
`Thermochemistry and Fuels
`
`Chap. 4
`
`Carbon monoxide is a colorless, 'omrless,