`
`Trials@uspto.gov
`Entered: January 5, 2016
`
`571-272-7822
`UNITED STATES PATENT AND TRADEMARK OFFICE
`____________
`
`BEFORE THE PATENT TRIAL AND APPEAL BOARD
`____________
`
`GLOBALFOUNDRIES U.S., INC., GLOBALFOUNDRIES DRESDEN
`MODULE ONE LLC & CO. KG, GLOBALFOUNDRIES DRESDEN
`MODULE TWO LLC & CO. KG, and THE GILLETTE COMPANY,
`Petitioners,
`
`v.
`
`ZOND, LLC,
`Patent Owner.
`____________
`
`Case IPR2014-010891
`Patent 6,806,652 B1
`____________
`
`
`Before KEVIN F. TURNER, JONI Y. CHANG, SUSAN L.C. MITCHELL,
`and JENNIFER MEYER CHAGNON, Administrative Patent Judges.
`
`MITCHELL, Administrative Patent Judge.
`
`FINAL WRITTEN DECISION
`Inter Partes Review
`35 U.S.C. § 318(a) and 37 C.F.R. § 42.73
`
`
`1 Case IPR2014-01004 has been joined with the instant inter partes review.
`
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`Patent 6,806,652 B1
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`
`I. INTRODUCTION
`
`We have jurisdiction under 35 U.S.C. § 6(c). This Final Written
`Decision is entered pursuant to 35 U.S.C. § 318(a) and 37 C.F.R. § 42.73.
`For the reasons set forth below, we determine that Petitioners have shown,
`by a preponderance of the evidence, that claim 35 of U.S. Patent
`No. 6,806,652 B1 (Ex. 12012, “the ’652 patent”) is unpatentable under
`35 U.S.C. § 103(a).
`
`A. Procedural History
`GlobalFoundries U.S., Inc., GlobalFoundries Dresden Module One
`
`LLC & Co. KG, and GlobalFoundries Dresden Module Two LLC & Co. KG
`(collectively, “GlobalFoundries”) filed a revised Petition (Paper 4, “Pet.”)
`seeking inter partes review of claim 35 (“the challenged claim”) of the ’652
`patent. GlobalFoundries included a Declaration of Dr. Uwe Kortshagen (Ex.
`1202) to support its positions. Patent Owner Zond, LLC (“Zond”) filed a
`Preliminary Response (Paper 10, “Prelim. Resp.”). Pursuant to 35 U.S.C.
`§ 314(a), on January 6, 2015, we instituted an inter partes review of the
`challenged claim to determine if the claim is unpatentable under 35 U.S.C. §
`103 as obvious over various combinations of Mozgrin, Kudryavtsev, Fahey,
`and Iwamura. Paper 13 (“Dec.”).
`
`Subsequent to institution, we granted a revised Motion for Joinder
`filed by the Gillette Company, joining Case IPR2014-01004 with the instant
`
`
`2 Petitioners filed a revised version for each of Exhibits 1201–1214, on
`July 11, 2014. All citations are to the revised Exhibits, unless otherwise
`indicated.
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`trial (IPR2014-01004, Paper 14). Zond filed a Patent Owner Response
`(Paper 23, “PO Resp.”), along with a Declaration of Larry D. Hartsough,
`Ph.D. (Ex. 2002) to support its positions. GlobalFoundries filed a Reply
`(Paper 24, “Reply”) to the Patent Owner Response, along with a
`supplemental Declaration of Dr. Kortshagen (Ex. 1216). An oral hearing3
`was held on August 13, 2015. A transcript of the hearing is included in the
`record. Paper 35 (“Tr.”).
`
`B. Related Matters
`GlobalFoundries indicates that the ’652 patent was asserted in seven
`
`patent infringement actions in the District of Massachusetts, naming many of
`the Petitioners as defendants. Pet. 1; Paper 7, 1; Ex. 1214. GlobalFoundries
`also identifies Petitions for inter partes review that are related to this
`proceeding. Pet. 1; Paper 7, 2–3.
`
`C. The ’652 Patent
`
`The ’652 patent notes several problems with known magnetron
`sputtering systems, such as poor target utilization resulting from a relatively
`high concentration of positively charged ions in the region that results in a
`non-uniform plasma. Ex. 1201, 4:23–28. The ’652 patent states that while
`increasing the power applied to the plasma may increase the uniformity and
`density of the plasma, doing so may significantly increase the probability of
`establishing an electrical breakdown condition of arcing. Id. at 4:31–37.
`The invention set forth in the ’652 patent involves a plasma generation
`
`3 The oral arguments for the instant review and IPR2014-00861 and
`IPR2014-01088 were consolidated.
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`3
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`method that provides independent control of two or more co-existing
`plasmas in a system. Id. at 4:62–64.
`One embodiment of the ’652 patent is shown in Figure 2A set forth
`below.
`
`
`Figure 2A, reproduced above, shows a cross-sectional view of plasma
`generating apparatus 200 with segmented cathode 202. Id. at 5:43–45. Such
`segmented cathode has inner cathode section 202a and outer cathode section
`202b. Id. at 5:45–47. Outer cathode 202b is coupled to first output 204 of
`first power supply 206, which can operate in a constant power mode or a
`constant voltage mode. Id. at 5:56–67. Second output 208 of first power
`supply 206 is coupled to first anode 210 that has insulator 211 to isolate it
`from outer cathode section 202b. Id. at 6:5–7.
`Gap 212 is formed between first anode 210 and outer cathode section
`202b that is sufficient to allow current to flow through region 214 within
`gap 212. Id. at 6:34–38. Gap 212 can be a plasma generator where plasma
`is ignited in gap 212 from feed gas 234, such as argon, fed from gas
`line 230. Id. at 6:59–61, 8:1–3, 10–11. Such an ignition condition and
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`plasma development in the gap can be optimized by crossed electric and
`magnetic fields in gap 212 that trap electrons and ions improving the
`efficiency of the ionization process. Id. at 6:61–67. Gap 212 can be
`configured to generate excited atoms, which can increase the density of
`plasma, from ground state atoms. Id. at 6:44–46. “Since excited atoms
`generally require less energy to ionize than ground state gas atoms, a volume
`of excited atoms can generate higher density plasma than a similar volume
`of ground state feed gas atoms for the same input energy.” Id. at 6:46–50.
`Gap 212 facilitates high input power by having additional feed gas
`supplied to gap 212 that displaces some of the already developing plasma
`and absorbs any excess power applied to the plasma. Id. at 7:1–6. Such
`absorption prevents the plasma from contracting and terminating. Id. at 7:6–
`9. Feed gases 234, 236 are introduced into the chamber from more than one
`feed source, such as feed sources 238, 240, through gas lines 230, 232 that
`may include in-line gas valves 242, 244 to control gas flow to the chamber.
`Id. at 8:1–5. Pulsing the feed gas can help generate excited atoms, including
`metastable atoms, by increasing the instantaneous pressure in gap 212, while
`the average pressure in the chamber is unchanged. Id. at 8:23–28.
`Second power supply 222 applies high power pulses between inner
`cathode section 202a and second anode 226 after an appropriate volume of
`initial plasma is present in region 252. Id. at 12:1–5. “The high-power
`pulses create an electric field 254 between the inner cathode section 202b
`and the second anode 226 that strongly-ionizes the initial plasma thereby
`creating a high-density plasma in the region 252.” Id. at 12:5–9. These high
`power pulses from second power supply 222, which add additional power to
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`an already strongly-ionized plasma, super-ionizes the high-density plasma in
`region 252. Id. at 11:54–57. The ’652 patent defines “super-ionized” to
`mean that “at least 75% of the neutral atoms in the plasma are converted to
`ions.” Id. at 5:8–10.
`Figure 2B, reproduced below, shows a more detailed cross-sectional
`view of the segmented cathode of Figure 2A.
`
`
`
`Figure 2B shows that electric fields 250, 254, which enhance the
`formation of ions in the plasma, can facilitate a multi-step ionization process
`of feed gases 234, 236, respectively, that substantially increases the rate at
`which the high-density plasma is formed. Id. at 12:50–56.
`Figure 12, set forth below with GlobalFoundries’s annotations, Pet. 8,
`shows another embodiment of the ’652 patent.
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`Excited atom source 732b generates an initial plasma and excited
`atoms, which include metastable atoms, from ground state atoms from feed
`gas 234. Ex. 1201, 25:35–38. Nozzle chamber 738 traps a large fraction of
`ions and electrons, while excited atoms and ground state atoms flow through
`aperture 737 of skimmer 736. Id. at 27:18–21. The ’652 patent further
`provides:
`After a sufficient volume of excited atoms including
`
`metastable atoms is present proximate to the inner cathode
`section 732a of the cathode assembly 732, the second power
`supply 222 generates an electric field (not shown) proximate to
`the volume of excited atoms between the inner cathode section
`732a and the second anode 706. The electric field
`super-ionizes the initial plasma by raising the energy of the
`initial plasma including the volume of excited atoms which
`causes collisions between neutral atoms, electrons, and excited
`atoms including metastable atoms in the initial plasma. The
`high-density collisions generate the high-density plasma
`proximate to the inner cathode section 732a. The high-density
`plasma includes ions, excited atoms and additional metastable
`atoms. The efficiency of this multi-step ionization process
`increases as the density of excited atoms and metastable atoms
`increases.
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`Id. at 27:22–37.
`
`D. Challenged Claim
`The single challenged claim 35 is an independent claim. Claim 35 is
`reproduced below.
`35. A high-density plasma source comprising:
`a) means for generating an initial plasma and excited atoms
`from a volume of feed gas;
`b) means for transporting the initial plasma and excited atoms
`proximate to a cathode assembly; and
`c) means for super-ionizing the initial plasma proximate to the
`cathode assembly, thereby generating a high-density plasma.
`Ex. 1201, 36:15–22.
`
`E. Prior Art Relied Upon
`GlobalFoundries relies upon the following prior art references:
`Iwamura et al.
`US 5,753,886
`May 19, 1998
`(Ex. 1208)
`
`D.V. Mozgrin, et al., High-Current Low-Pressure Quasi-Stationary
`
`Discharge in a Magnetic Field: Experimental Research, 21 PLASMA
`PHYSICS REPORTS 400–409 (1995) (Ex. 1203) (“Mozgrin”).
`
`
`A. A. Kudryavtsev and V. N. Skrebov, Ionization Relaxation in a
`Plasma Produced by a Pulsed Inert-Gas Discharge, 28(1) SOV. PHYS. TECH.
`PHYS. 30–35 (Jan. 1983) (Ex. 1206) (“Kudryavtsev”).
`
`
`
`D. W. Fahey, W. F. Parks, and L. D. Schearer, High Flux Beam
`Source of Thermal Rare-Gas Metastable Atoms, 13 J. PHYS. E: SCI.
`INSTRUM. 381–383 (1980) (Ex. 1205) (“Fahey”).
`
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`F. Asserted Grounds of Unpatentability
`We instituted the instant trial based on the following grounds of
`unpatentability (Dec. 30–31):
`
`Claim
`35
`35
`
`References
`Basis
`§ 103(a) Mozgrin, Kudryavtsev, Fahey, and Iwamura
`§ 103(a) Mozgrin, Iwamura, and Fahey
`
`
`
`II. ANALYSIS
`A. Claim Construction
`In an inter partes review, claim terms in an unexpired patent are given
`their broadest reasonable construction in light of the specification of the
`patent in which they appear. 37 C.F.R. § 42.100(b). Claim terms are given
`their ordinary and customary meaning as would be understood by one of
`ordinary skill in the art in the context of the entire disclosure. In re
`Translogic Tech., Inc., 504 F.3d 1249, 1257 (Fed. Cir. 2007). An inventor
`may rebut that presumption by providing a definition of the term in the
`specification with reasonable clarity, deliberateness, and precision. In re
`Paulsen, 30 F.3d 1475, 1480 (Fed. Cir. 1994). In the absence of such a
`definition, limitations are not to be read from the specification into the
`claims. In re Van Geuns, 988 F.2d 1181, 1184 (Fed. Cir. 1993).
`In the instant proceeding, GlobalFoundries proposed constructions for
`the following claim elements from challenged claim 35 that GobalFoundries
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`construed as means-plus-function elements, invoking 35 U.S.C. 112, ¶ 6:4
`(1) “means for generating an initial plasma and excited atoms from a volume
`of feed gas”; (2) “means for transporting the initial plasma and excited
`atoms proximate to a cathode assembly”; and (3) “means for super-ionizing
`the initial plasma proximate to the cathode assembly.” Pet. 12–17.
`The first step in construing a means-plus-function claim element is to
`identify the recited function in the claim element. Med. Instrumentation &
`Diagnostics Corp. v. Elekta AB, 344 F.3d 1205, 1210 (Fed. Cir. 2003). The
`second step is to look to the specification and identify the corresponding
`structure for that recited function. Id. A structure disclosed in the
`specification qualifies as “corresponding” structure only if the specification
`or prosecution history clearly links or associates that structure to the function
`recited in the claim. B. Braun Med., Inc. v. Abbott Labs., 124 F.3d 1419,
`1424 (Fed. Cir. 1997). “While corresponding structure need not include all
`things necessary to enable the claimed invention to work, it must include all
`structure that actually performs the recited function.” Default Proof Credit
`Card Sys. Inc. v. Home Depot U.S.A., Inc., 412 F.3d 1291, 1298 (Fed. Cir.
`2005).
`We agreed that the three claim elements identified by
`GlobalFoundries were written in means-plus-function form and fall under
`35 U.S.C. § 112, ¶ 6. Dec. 9–10. Upon review of the parties’ contentions
`
`
`4 Section 4(c) of the Leahy-Smith America Invents Act (AIA) re-designated
`35 U.S.C. § 112, ¶ 6, as 35 U.S.C. § 112(f). Pub. L. No. 112-29, 125 Stat.
`284, 296 (2011). Because the ’652 patent has a filing date before September
`16, 2012 (effective date), we will refer to the pre-AIA version of § 112.
`10
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`and the Specification, we set forth our claim constructions in the Decision on
`Institution for the means-plus-function elements identified by the parties.
`Dec. 11–19. For convenience, our claim constructions are reproduced in the
`table below:
`
`11
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`Means-Plus-
`Function Claim
`Elements
`
`“means for
`generating an
`initial plasma and
`excited atoms
`from a volume of
`feed gas”
`
`“means for
`transporting the
`initial plasma and
`excited atoms
`proximate to a
`cathode
`assembly”
`
`Corresponding Structures
`
`A chamber or gap structure containing the feed gas
`and a power source that applies a voltage to the feed
`gas. See Ex. 1201, 6:34–7:9 (describing Fig. 2 that
`includes gap 212 or region 214 defined by an outer
`cathode section and an anode spaced apart from the
`cathode sufficient to allow current to flow through
`region 214, and first power supply 206, which is
`separate from a second power supply used to super-
`ionize the plasma); Id. at 25:30–26:15 (describing
`Fig. 12 that includes an excited atom source 732b
`(cathode assembly) that has tube 733, which is
`surrounded by enclosure 735, that defines electrode
`chamber 739, in which is positioned electrode 741
`connected to first power supply 731); id. 25:60–
`26:15 (describing excited atom source 732b); Dec.
`11–13.
`A gas source with controlled flow in a contained area
`to achieve the transportation of the initial plasma and
`excited atoms. Dec. 15–16 (describing structure for
`transporting function as gas exchange system 238,
`242 that flows gas through the outer cathode sections
`202b/656b/702b/722b/732b (shown, e.g., in Figures
`2, 3, 5, 6, and 12), through gap 214, toward inner
`cathode assembly 202a/732a); see, e.g., Ex. 1201,
`8:1–5 (stating in relation to Figure 2A of the ’652
`patent, that feed gases 234, 236 are introduced into
`the chamber from more than one feed source, such as
`feed source 238, 240, through gas lines 230, 232 that
`may include in-line gas valves 242, 244 to control
`gas flow to the chamber); 8:36–52 (describing feed
`gas 234 is supplied into gap 212 between outer
`cathode section 202b and first anode 210, which
`defines region 214, by controlling gas valve 242).
`
`12
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`Corresponding Structures
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`Means-Plus-
`Function Claim
`Elements
`“means for super-
`ionizing the initial
`plasma proximate
`to the cathode
`assembly, thereby
`generating a high-
`density plasma”
`
`Although Zond applied these constructions that we adopted in the
`Decision on Institution in its Patent Owner Response, PO Resp. 10, it noted
`some areas of disagreement with how we construed the functions associated
`with the means elements set forth above that we will address here.5
`
`A second power supply 222 that generates an electric
`field across inner cathode 202a (e.g., Fig. 2A, 2B, 3,
`5, and 6) or inner cathode 732a (Fig. 12); and inner
`anode 226 or 658 (e.g., Fig. 2A, 2B, 3, 5 and 6) or
`inner anode 703 (Fig. 12). Dec. 18.
`
`1. “means for generating an initial plasma and excited ions
`from a volume of feed gas”
`Claim 35 recites “means for generating an initial plasma and excited
`ions from a volume of feed gas.” Ex. 1201, 34:45–36:14. In its Preliminary
`Response, Zond proposes that the function of this claim element should be
`construed as “generation of both an initial plasma and excited atoms from
`the same volume of feed gas, wherein a feed gas is a gas that is a flowing
`gas.” Prelim. Resp. 11. In its Patent Owner Response, Zond reiterates this
`
`
`5 Zond asserts that although it uses the constructions adopted in the Decision
`on Institution, it is “not waiving its right to challenge these interpretations on
`Appeal or in other forums.” PO Resp. 10. Zond had the opportunity in its
`Patent Owner Response to address our tentative claim constructions set forth
`in the Decision on Institution, but chose not to do so, except to challenge our
`construction of “volume of a feed gas.”
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`construction stating that it disagrees with our construction of “from a volume
`of feed gas” because our construction reads out the word “feed,” and states
`that “the patent’s pulsed gas pressure embodiment changes nothing since it
`too causes the gas to flow.” PO Resp. 10, n.20.
`Zond asserts in its Preliminary Response that the recitation of a
`“volume of feed gas” requires that both ionization and excitation occur in the
`same volume of feed gas, and that “feed gas” implies a flow of gas. Prelim.
`Resp. 9. In its Patent Owner Response, Zond reiterates this understanding of
`the meaning of “generating an initial plasma and excited ions from a volume
`of feed gas,” by asserting as follows regarding Kudryavtsev.
`
`Kudryavtsev says that the “studied effects” are
`characteristic of a system in which a field is applied to a pre-
`existing weak plasma, i.e. an initial plasma has already been
`created when the electric field is applied. In the claims at issue,
`excited atoms are formed from a volume of feed gas at the same
`time as an initial plasma is being formed from the same volume
`of feed gas. Kudryavtsev does not consider this situation. The
`analysis deals only with the reaction of an existing plasma
`when an electric field is suddenly applied.
`
`PO Resp. 17–18 (citations omitted) (emphasis added); see also PO Resp. 16
`(“Kudryavtsev deals with the reaction of an existing plasma when an
`electric field is suddenly applied, and the formation of ions and excited
`atoms as a result of that pulse.”).
`As we stated in our Decision on Institution, see Dec. 9–10, the
`recitation of “feed gas” in claim 35 does not imply necessarily the flow of
`gas. Dec. 11.
`We previously noted that the Specification of the ’652 patent
`describes the use of in-line gas valves 242, 244 that can control the flow of
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`gas to the chamber (Ex. 1201, 8:3–5), and also describes pulsing feed gases
`234, 236 to help generate excited atoms, including metastable atoms, in
`gap 212 (Ex. 1201, 8:3–5, 8:23–25). See Dec. 10–11. Therefore, we
`concluded that such control of the feed gas supports the notion that “feed
`gas” does not necessitate a “gas that is a flowing gas.” Id. Although we
`agree with Zond that this pulsed gas pressure embodiment can cause the gas
`to flow, it does not necessitate that the gas flow.
`We also previously stated that the Specification of the ’652 patent
`further states that feed gases may be introduced from multiple locations into
`the chamber. Id. (citing Ex. 1201, 8:1–3). We also stated that having
`multiple sources for feed gases does not support a construction that “a
`volume of feed gas” requires that the initial plasma and excited ions are
`generated from the same volume of feed gas, assuming that a particular
`volume of feed gas may be identified in such a process. Id. We discern no
`reason to modify our conclusions that the claim limitation does not imply
`necessarily the flow of gas nor does it require that the initial plasma and
`excited ions are generated from the same volume of feed gas.
`
`2. “means for transporting the initial plasma and excited atoms
`proximate to a cathode assembly”
`GlobalFoundries asserts that a plain reading of this function means
`
`that “the initial plasma with excited atoms is generated in one location ( . . .
`in a gap or with an ‘excited atom source’), and moved to another location
`near a cathode assembly where the plasma is super-ionized.” Pet. 15.
`Because the structure for the previous element, “means for generating,”
`includes a cathode, GlobalFoundries asserts that the cathode assembly which
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`is recited in this element must be a different cathode. Id. at 16.
`GlobalFoundries notes that all embodiments shown in the figures of the ’652
`patent have an “outer” and an “inner” cathode to which initial plasma is
`transported. Id.
`In its Preliminary Response, Zond proposes that the function means to
`“transport the initial plasma and excited atoms to a region that is proximate
`to a cathode assembly.” Prelim. Resp. 16. Zond asserts that the claim
`language does not require that the cathode assembly in this element be
`distinct from the cathode structure that corresponds to the “means for
`generating” element. Id. at 17. Zond did not reiterate these arguments in its
`Patent Owner Response.
`In our Decision on Institution, we noted that if the cathode assembly
`in this element is not distinct, however, the “means for transporting” element
`would appear superfluous; there would be no need to transport the initial
`plasma and excited atoms if the cathode assembly were the same. Dec. 14.
`In fact, the ’652 patent describes a plasma generation method that provides
`independent control of two or more co-existing plasmas in a system. Id. at
`14–15 (citing Ex. 1201, 4:62–64). Without the two cathode assemblies, we
`found there would be no such independent control. Id. at 15. As
`GlobalFoundries indicates, all figures show segmented cathode assemblies
`with an inner and outer cathode. See Ex. 1201, Figures 2–12. We agreed in
`our Decision on Institution that the cathode assembly in the “means for
`transporting” element is distinct from the cathode assembly corresponding
`structure for the “means for generating” element. See Dec. 15. Neither
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`party subsequently challenged this construction, and we see no reason to
`change our construction based on review of the entire record now before us.
`
`3. “means for super-ionizing the initial plasma proximate to the cathode
`assembly, thereby generating a high-density plasma”
`
`GlobalFoundries notes that the Specification of the ’652 patent
`defines super-ionizing to mean that “at least 75% of the neutral atoms in the
`plasma are converted to ions.” Pet. 16 (citing Ex. 1201, 5:8–10; Ex. 1202
`¶ 47). From this definition, GlobalFoundries concludes that the function
`should be construed as “converting at least 75% of the neutral atoms in the
`initial plasma into ions near the cathode assembly.” Id. (emphasis added).
`Zond asserts that the function should be construed to mean “ionizing the
`plasma that is proximate to the cathode so that at least 75% of the neutrals in
`the original feed gas have been converted to ions.” Prelim. Resp. 19.
`We noted in our Decision on Institution that the recited function for
`the claim element at issue requires “super-ionizing the initial plasma,”
`Dec. 17 (citing Ex. 1201, 36:20) (emphasis added), and that Zond’s
`construction does not reflect this claim language. Id. We also noted that
`Zond’s construction introduces a term “original feed gas” that does not
`appear to be used or defined in the Specification of the ’652 patent;
`therefore, Zond’s construction introduces an unnecessary ambiguity into the
`construction. Id. We also stated that GlobalFoundries’s proposed
`construction reflects the explicit definition of “super-ionized” provided in
`the ’652 patent Specification, and therefore, construed the recited function as
`“converting at least 75% of the neutral atoms in the initial plasma into ions
`near the cathode assembly.” Id. Neither party challenges our construction,
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`and we discern no reason to modify our construction based on the complete
`record now before us. Therefore, we construe the recited function “super-
`ionizing the initial plasma proximate to the cathode assembly” as
`“converting at least 75% of the neutral atoms in the initial plasma into ions
`near the cathode assembly.”
`
`B. Principles of Law
`A patent claim is unpatentable under 35 U.S.C. § 103(a) if the
`differences between the claimed subject matter and the prior art are such that
`the subject matter, as a whole, would have been obvious at the time the
`invention was made to a person having ordinary skill in the art to which said
`subject matter pertains. KSR Int’l Co. v. Teleflex Inc., 550 U.S. 398, 406
`(2007). The question of obviousness is resolved on the basis of underlying
`factual determinations including: (1) the scope and content of the prior art;
`(2) any differences between the claimed subject matter and the prior art;
`(3) the level of ordinary skill in the art; and (4) objective evidence of
`nonobviousness. Graham v. John Deere Co., 383 U.S. 1, 17–18 (1966).
`In that regard, an obviousness analysis “need not seek out precise
`teachings directed to the specific subject matter of the challenged claim, for
`a court can take account of the inferences and creative steps that a person of
`ordinary skill in the art would employ.” KSR, 550 U.S. at 418; see
`Translogic, 504 F.3d at 1259. A prima facie case of obviousness is
`established when the prior art itself would appear to have suggested the
`claimed subject matter to a person of ordinary skill in the art. In re Rinehart,
`531 F.2d 1048, 1051 (CCPA 1976). Notwithstanding that Dr. Hartsough
`provides a definition of “a person of ordinary skill in the art” in the context
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`of the ’652 patent,6 we are mindful that the level of ordinary skill in the art
`also is reflected by the prior art of record. See Okajima v. Bourdeau,
`261 F.3d 1350, 1355 (Fed. Cir. 2001); In re GPAC Inc., 57 F.3d 1573, 1579
`(Fed. Cir. 1995); In re Oelrich, 579 F.2d 86, 91 (CCPA 1978).
`We analyze the asserted grounds of unpatentability in accordance with
`the above-stated principles.
`
`C. Obviousness over, in Whole or in Part, the Combination of Mozgrin,
`Kudryavtsev, Fahey, and Iwamura
`GlobalFoundries asserts that claim 35 is unpatentable under 35 U.S.C.
`
`§ 103(a) as obvious over the combination of Mozgrin, Kudryavtsev, Fahey,
`and Iwamura, Pet. 38–42, and as obvious over the combination of Mozgrin,
`Fahey, and Iwamura, Pet. 50–52.
`As support, GlobalFoundries provides detailed explanations as to how
`each claim limitation is met by the references and rationales for combining
`the references, as well as an initial declaration and a supplemental
`declaration of Dr. Kortshagen to support GlobalFoundries’s Petition and
`Reply, respectively. Pet. 38–42; Ex. 1202; Reply 17-25; Ex. 1216. Zond
`responds that these combinations do not disclose every claim element.
`PO Resp. 29–41.
`We have reviewed the entire record before us, including the parties’
`explanations and supporting evidence presented during this trial. We begin
`
`6 “[A] person of ordinary skill in the art at the time of filing of the ’652
`patent [is] someone who holds at least a bachelor of science degree in
`physics, material science, or electrical/computer engineering with at least
`two years of work experience or equivalent in the field of development of
`plasma-based processing equipment.” Ex. 2002 ¶ 17.
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`our discussion with a brief summary of Mozgrin, Kudryavtsev, Fahey, and
`Iwamura.
`
`Mozgrin
`Mozgrin discloses experimental research conducted on high-current,
`low-pressure, quasi-stationary discharge in a magnetic field. Ex. 1203, 400,
`Title. In Mozgrin, pulse or quasi-stationary regimes are discussed in light of
`the need for greater discharge power and plasma density. Id. Mozgrin
`discloses a planar magnetron plasma system having cathode 1, anode 2
`adjacent and parallel to cathode 1, and magnetic system 3, as shown in
`Figure 1(a). Id. at 400–01. Mozgrin also discloses a power supply unit that
`includes a pulsed discharge supply unit and a system for pre-ionization. Id.
`at 401–02, Fig. 2. For pre-ionization, an initial plasma density is generated
`when the square voltage pulse is applied to the gas. Id.
`Figure 3(b) of Mozgrin is reproduced below.
`
`
`Figure 3(b) of Mozgrin illustrates an oscillogram of voltage of the
`quasi-stationary discharge. Id. at 402. In Figure 3(b), Part 1 represents the
`voltage of the stationary discharge (pre-ionization stage); Part 2 displays the
`square voltage pulse application to the gap (Part 2a), where the plasma
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`density grows and reaches its quasi-stationary value (Part 2b); and Part 3
`displays the voltage as the discharge current grows and both the voltage and
`discharge current attain their quasi-stationary value. Id. More specifically,
`the power supply generates a square voltage with rise times of 5–60 µs and
`durations of as much as 1.5 ms. Id. at 401.
`Mozgrin further discloses the current-voltage characteristic of the
`quasi-stationary plasma discharge that has four different stable forms or
`regimes: (1) pre-ionization stage, id. at 401–02; (2) high-current magnetron
`discharge regime, in which the plasma density exceeds 2 x 1013 cm-3,
`appropriate for sputtering, id. at 402–04, 409; (3) high-current diffuse
`discharge regime, in which the plasma density produces large-volume
`uniform dense plasmas η1 ≈ 1.5 x 1015 cm-3, appropriate for etching, id.; and
`(4) arc discharge regime, id. at 402–04. Id. at 402–409, Figs. 3–7.
`
`Kudryavtsev
`Kudryavtsev discloses a multi-step ionization plasma process,
`comprising the steps of exciting the ground state atoms to generate excited
`atoms, and then ionizing the excited atoms. Ex. 1206, Abs., Figs. 1, 6.
`Figure 1 of Kudryavtsev illustrates the atomic energy levels during the
`slow and fast stages of ionization. Figure 1 of Kudryavtsev is reproduced
`below (with annotations added by GlobalFoundries, Pet. 17).
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`As shown in Figure 1 of Kudryavtsev, ionization occurs with a “slow
`stage” (Fig. 1a) followed by a “fast stage” (Fig. 1b). During the initial slow
`stage, direct ionization provides a significant contribution to the generation
`of plasma ions (arrow Γ1e showing ionization (top line labeled “e”) from the
`ground state (bottom line labeled “1”)). Dr. Kortshagen explains that
`Kudryavtsev shows the rapid increase in ionization once multi-step
`ionization becomes the dominant process. Ex. 1202 ¶ 60; Pet. 21–22.
`Indeed, Kudryavtsev discloses:
`For nearly stationary n2 [excited atom density] values . . . there
`is an explosive increase in ne [plasma density]. The subsequent
`increase in ne then reaches its maximum value, equal to the rate
`of excitation . . . which is several orders of magnitude greater
`than the ionization rate during the initial stage.
`
`Ex. 1206, 31, right col., ¶ 6 (emphasis added). Kudryavtsev also recognizes
`that “in a pulsed inert-gas discharge plasma at moderate pressures . . . [i]t is
`shown that the electron density increases explosively in time due to
`accumulation of atoms i