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`Entered: November 22, 2014
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`Trials@uspto.gov
`571-272-7822
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`UNITED STATES PATENT AND TRADEMARK OFFICE
`____________
`
`BEFORE THE PATENT TRIAL AND APPEAL BOARD
`____________
`
`
`
`
`TAIWAN SEMICONDUCTOR MANUFACTURING COMPANY, LTD.
`and TSMC NORTH AMERICA CORPORATION,
`Petitioners,
`
`v.
`
`ZOND, LLC,
`Patent Owner.
`____________
`
`Case IPR2014-00917
`Patent 6,805,779 B2
`____________
`
`
`
`Before KEVIN F. TURNER, DEBRA K. STEPHENS, JONI Y. CHANG,
`SUSAN L. C. MITCHELL, and JENNIFER M. MEYER,
`Administrative Patent Judges.
`
`
`CHANG, Administrative Patent Judge.
`
`
`
`DECISION
`Institution of Inter Partes Review
`37 C.F.R. § 42.108
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`IPR2014-00917
`Patent 6,805,779 B2
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`I. INTRODUCTION
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`Taiwan Semiconductor Manufacturing Company, Ltd. and TSMC
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`North America Corporation (collectively, “TSMC”) filed a Petition
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`requesting inter partes review of claims 7, 9, 20, 21, 38, and 44 of U.S.
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`Patent No. 6,805,779 B2 (“the ’779 patent”). Paper 2 (“Pet.”). Zond, LLC
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`(“Zond”) filed a Preliminary Response. Paper 8 (“Prelim. Resp.”). We have
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`jurisdiction under 35 U.S.C. § 314.
`
`The standard for instituting an inter partes review is set forth in
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`35 U.S.C. § 314(a), which provides:
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`THRESHOLD.—The Director may not authorize an inter
`partes review to be instituted unless the Director determines
`that the information presented in the petition filed under section
`311 and any response filed under section 313 shows that there
`is a reasonable likelihood that the petitioner would prevail with
`respect to at least 1 of the claims challenged in the petition.
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`Upon consideration of TSMC’s Petition and Zond’s Preliminary
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`Response, we conclude that the information presented in the Petition
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`demonstrates that there is a reasonable likelihood that TSMC would prevail
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`in challenging claims 7, 9, 20, 21, 38, and 44 as unpatentable under
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`35 U.S.C. § 103(a). Pursuant to 35 U.S.C. § 314, we hereby authorize an
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`inter partes review to be instituted as to claims 7, 9, 20, 21, 38, and 44 of the
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`’779 patent.
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`A. Related Matters
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`
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`TSMC indicates that the ’779 patent was asserted in several related
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`district court proceedings, including Zond, LLC v. Fujitsu Corp., No. 1:13-
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`IPR2014-00917
`Patent 6,805,779 B2
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`cv-11634-WGY (D. Mass.). Pet. 1. TSMC also identifies other Petitions for
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`inter partes review that are related to the instant proceeding. Id.
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`
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`B. The ’779 patent
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`The ’779 patent relates to a method and a system for generating a
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`plasma with a multi-step ionization process. Ex. 1401, Abs. For instance,
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`Figure 2 of the ’779 patent, reproduced below, illustrates a cross-sectional
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`view of a plasma generating apparatus:
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`
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`In the embodiment shown in Figure 2, feed gas source 206 supplies
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`ground state atoms 208 (e.g., ground state argon atoms) to metastable atom
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`source 204 that generates metastable atoms 218 from ground state atoms
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`208. Id. at 4:26–42. Plasma 202 is generated from the metastable atoms 218
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`in process chamber 230. Id. at 5:25–34.
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`The metastable atom source may include a parallel plate discharge
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`chamber, an electron gun, or an inductively coupled discharge chamber that
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`IPR2014-00917
`Patent 6,805,779 B2
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`excites a portion of the volume of ground state atoms 208 to a metastable
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`state. Id. at 10:1–13. More specifically, ground state atoms 208 are excited
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`to a metastable state by using an energy source, such as a DC plasma source,
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`a radio frequency (RF) plasma source, an ultraviolet (UV) radiation source,
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`an X-ray radiation source, an electron beam radiation source, a microwave
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`plasma source, or a magnetron plasma discharge source. Id. at 19:1–10.
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`Electrons and ions are formed in metastable atom source 204 along
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`with metastable atoms 218. Id. at 8:20–23. In another embodiment, the ions
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`and electrons are separated from metastable atoms 218 and trapped in an
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`electron/ion absorber before metastable atoms 218 are injected into plasma
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`chamber 230. Id. at 8:23–26, 18:62–67, Fig. 10. Figure 12B of the ’779
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`patent illustrates the electron/ion absorber and is reproduced below:
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`As shown in Figure 12B, electron/ion absorber 750 ʹ includes magnets
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`776 and 778 that generate magnetic field 780, trapping electrons 772 and
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`ions 774 in chamber 760ʹ. Id. at 20:9–13. Metastable atoms 768 and ground
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`state atoms 770 then flow through output 754ʹ. Id. at 20:19–21.
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`IPR2014-00917
`Patent 6,805,779 B2
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`C. Illustrative Claims
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`Of the challenged claims, claim 44 is the sole independent claim.
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`Claims 7 and 9 depend directly from independent claim 1; claims 20 and 21
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`depend directly from claim 18; and claim 38 depends directly from
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`independent claim 30. TSMC is not challenging independent claims 1, 28,
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`and 30 in the instant proceeding.1
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`Claims 1 and 7 are illustrative:
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`1. A plasma generator that generates a plasma with a
`multi-step ionization process, the plasma generator comprising:
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`a feed gas source comprising ground state atoms;
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`an excited atom source that receives ground state atoms
`from the feed gas source, the excited atom source comprising a
`magnet that generates a magnetic field for substantially
`trapping electrons proximate to the ground state atoms, the
`excited atom source generating excited atoms from the ground
`state atoms;
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`a plasma chamber that is coupled to the excited atom
`source, the plasma chamber confining a volume of excited
`atoms generated by the excited atom source; and
`
`an energy source that is coupled to the volume of excited
`atoms confined by the plasma chamber, the energy source
`raising an energy of excited atoms in the volume of excited
`atoms so that at least a portion of the excited atoms in the
`volume of excited atoms is ionized, thereby generating a
`plasma with a multi-step ionization process.
`
`
`
`
`1 Independent claims 1 and 18 are being challenged in
`GLOBALFOUNDRIES U.S., Inc. v. Zond, LLC, Case IPR2014-01073
`(Paper 2), and independent claim 30 is being challenged in Taiwan
`Semiconductor Mfg. v. Zond, LLC, Case IPR2014-00828 (Paper 2).
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`7. The plasma generator of claim 1 wherein the excited
`atom source comprises an electron gun that directs an electron
`beam into the ground state atoms, the electron beam exciting
`the ground state atoms.
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`Id. at 21:9–29, 21:50–53 (emphases added).
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`
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`
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`D. Prior Art Relied Upon
`
`TSMC relies upon the following prior art references:
`
`
`Pinsley
`Angelbeck
`Iwamura
`
`Gruber
`Wells
`
`
`
`
`
`US 3,761,836
`US 3,514,714
`US 5,753,886
`
`Sept. 25, 1973
`May 26, 1970
`May 19, 1998
`
`(Ex. 1405)
`(Ex. 1406)
`(Ex. 1407)
`
`
`EP 0146509
`PCT WO 83/01349
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`Jun. 26, 1985
`Apr. 14, 1983
`
`(Ex. 1413)
`(Ex. 1414)
`
`D.V. Mozgrin, et al., High-Current Low-Pressure Quasi-Stationary
`Discharge in a Magnetic Field: Experimental Research, 21 PLASMA
`PHYSICS REPORTS, NO. 5, 400–409 (1995) (Ex. 1403, “Mozgrin”).
`
`
`A. A. Kudryavtsev and V.N. Skrebov, Ionization Relaxation in a
`Plasma Produced by a Pulsed Inert-Gas Discharge, 28(1) SOV. PHYS.
`TECH. PHYS. 30–35 (1983) (Ex. 1404, “Kudryavtsev”).
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`E. Asserted Grounds of Unpatentability
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`TSMC asserts the following grounds of unpatentability:
`
`Claims
`
`Basis
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`7, 20
`
`§ 103(a)
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`References
`Iwamura, Angelbeck, Pinsley,2 and Wells
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`9, 21, 44
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`§ 103(a)
`
`Iwamura, Angelbeck, Pinsley, and Gruber
`
`38
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`7, 20
`
`§ 103(a)
`
`Iwamura, Angelbeck, and Pinsley
`
`§ 103(a) Mozgrin, Kudryavtsev, Pinsley, and Wells
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`9, 21, 44
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`§ 103(a) Mozgrin, Kudryavtsev, Pinsley, and Gruber
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`38
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`
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`§ 103(a) Mozgrin, Kudryavtsev, Pinsley, and Iwamura
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`II. ANALYSIS
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`A. Claim Construction
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`In an inter partes review, claim terms in an unexpired patent are given
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`their broadest reasonable construction in light of the specification of the
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`patent in which they appear. 37 C.F.R. § 42.100(b). Claim terms are given
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`their ordinary and customary meaning as would be understood by one of
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`ordinary skill in the art in the context of the entire disclosure. In re
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`Translogic Tech., Inc., 504 F.3d 1249, 1257 (Fed. Cir. 2007). An inventor
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`may rebut that presumption by providing a definition of the term in the
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`2 Pinsley is omitted inadvertently from each statement of the asserted
`grounds of unpatentability based, in whole or in part, on the combination of
`Iwamura and Angelbeck, although included in the corresponding analysis.
`See, e.g., Pet. 38, 46. Therefore, we treat the statements as mere harmless
`error and presume that TSMC intended to include Pinsley in each of those
`asserted grounds of unpatentability.
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`specification with reasonable clarity, deliberateness, and precision. In re
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`Paulsen, 30 F.3d 1475, 1480 (Fed. Cir. 1994). In the absence of such a
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`definition, limitations are not to be read from the specification into the
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`claims. In re Van Geuns, 988 F.2d 1181, 1184 (Fed. Cir. 1993).
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`We construe the claim terms below in accordance with the above-
`
`stated principles.
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`
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`1. “excited atoms”
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`Claim 7 depends from claim 1, which recites “the excited atom source
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`generating excited atoms from the ground state atoms.” TSMC’s Declarant,
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`Dr. Uwe Kortshagen, testifies that “[i]f all of an atom’s electrons are at their
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`lowest possible energy state, the atom is said to be in the ‘ground state,’”
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`and that “if one or more of an atom’s electrons is in a state that is higher
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`than its lowest possible state, then the atom is said to be an ‘excited atom.’”
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`Ex. 1402 ¶¶ 23–24 (emphases added). In the context of the Specification of
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`the ’779 patent, we therefore construe the claim term “excited atoms”
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`broadly, but reasonably as “atoms that have one or more electrons in a state
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`that is higher than its lowest possible state.”
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`
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`2. “metastable atoms”
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`Claim 38 depends from claim 30, which recites “generating a volume
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`of metastable atoms from the volume of ground state atoms.” TSMC
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`submits that the claim term “metastable atoms” is defined in the
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`Specification of the ’779 patent as “excited atoms having energy levels from
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`which dipole radiation is theoretically forbidden.” Pet. 5 (emphasis added)
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`(citing Ex. 1401, 7:22–25). We agree the term is defined in the
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`Specification.
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`In that regard, Dr. Kortshagen further explains that a “metastable atom
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`is a type of excited atom that is relatively long-lived, because it cannot
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`transition into the ground state through dipole radiation, i.e., through the
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`emission of electromagnetic radiation.” Ex. 1402 ¶ 24 (citing Ex. 1401,
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`7:22–25). According to Dr. Kortshagen, generating excited argon atoms
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`means also generating metastable atoms because, when generating excited
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`argon atoms, multiple levels of excited states are formed, and some of the
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`lowest states are metastable. Id. (citing Exs. 1411–1412).3 The
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`Specification also provides that all noble gases, including argon, have
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`metastable states. Ex. 1401, 7:37–39.
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`Given the evidence before us, we construe the claim term “metastable
`
`atoms,” consistent with the Specification, as “excited atoms having energy
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`levels from which dipole radiation is theoretically forbidden,” and observe
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`that exciting noble gas atoms would generate metastable atoms.
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`
`
`
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`3 J. Vlček, A Collisional-Radiative Model Applicable to Argon Discharges
`Over a Wide Range of Conditions. I: Formulation and Basic Data, 22 J.
`PHYS. D: APPL. PHYS. 623–631 (1989) (Ex. 1411).
`
`J. Vlček, A Collisional-Radiative Model Applicable to Argon Discharges
`Over a Wide Range of Conditions. II: Application to Low-Pressure, Hollow-
`Cathode Arc and Low-Pressure Glow Discharges, 22 J. PHYS. D: APPL.
`PHYS. 632–643 (1989) (Ex. 1412).
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`3. “multi-step ionization process”
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`
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`Claim 44 recites “raising an energy of the metastable atoms so that at
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`least a portion of the volume of metastable atoms is ionized, thereby
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`generating a plasma with a multi-step ionization process.”
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`The parties indicate that the claim term “multi-step ionization
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`process” is defined in the Specification of the ’779 patent as “an ionization
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`process whereby ions are ionized in at least two distinct steps.” Prelim.
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`Resp. 19; Pet. 15–16 (citing Ex. 1401, 6:60–63, Figs. 2, 3) (emphasis added
`
`by TSMC). Indeed, the Specification expressly provides:
`
`The term “multi-step ionization process” is defined herein to
`mean an ionization process whereby ions are ionized in at least
`two distinct steps. However, the term “multi-step ionization
`process” as defined herein may or may not include exciting
`ground state atoms to a metastable state. For example, one
`multi-step ionization process according to the present invention
`includes a first step where atoms are excited from a ground
`state to a metastable state and a second step where atoms in the
`metastable state are ionized. Another multi-step ionization
`process according to the present invention includes a first step
`where atoms are excited from a ground state to an excited state
`and a second step where atoms in the excited state are ionized.
`The
`term “multi-step
`ionization process” also
`includes
`ionization processes with three or more steps.
`
`Ex. 1401, 6:60–7:9 (emphases added).
`
`We observe that the Specification sets forth a definition for the claim
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`term “multi-step ionization” with reasonable clarity, deliberateness, and
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`precision. See Paulsen, 30 F.3d at 1480. Further, that definition is
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`consistent with the ordinary and customary meaning of the term, as would be
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`understood by one with ordinary skill in the art. As such, in the context of
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`the claimed subject matter, we construe the claim term “multi-step
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`ionization” as “an ionization process having at least two distinct steps.”
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`
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`B. Principles of Law
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`A patent claim is unpatentable under 35 U.S.C. § 103(a) if the
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`differences between the claimed subject matter and the prior art are such that
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`the subject matter, as a whole, would have been obvious at the time the
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`invention was made to a person having ordinary skill in the art to which said
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`subject matter pertains. KSR Int’l Co. v. Teleflex Inc., 550 U.S. 398, 406
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`(2007). The question of obviousness is resolved on the basis of underlying
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`factual determinations including: (1) the scope and content of the prior art;
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`(2) any differences between the claimed subject matter and the prior art;
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`(3) the level of ordinary skill in the art; and (4) objective evidence of
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`nonobviousness. Graham v. John Deere Co., 383 U.S. 1, 17–18 (1966).
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`The level of ordinary skill in the art is reflected by the prior art of
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`record. See Okajima v. Bourdeau, 261 F.3d 1350, 1355 (Fed. Cir. 2001);
`
`In re GPAC Inc., 57 F.3d 1573, 1579 (Fed. Cir. 1995); In re Oelrich,
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`579 F.2d 86, 91 (CCPA 1978).
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`We analyze the asserted grounds of unpatentability in accordance with
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`the above-stated principles.
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`
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`C. Claims 7, 9, 20, 21, 38, and 44—Obviousness over Iwamura
`in Combination of Other Cited References
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`TSMC asserts that claims 7 and 20 are unpatentable under 35 U.S.C.
`
`§ 103(a) as obvious over the combination of Iwamura, Angelbeck, Pinsley,
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`and Wells. Pet. 38–51, 55–57. TSMC also asserts that claims 9, 21, and 44
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`are unpatentable over the combination of Iwamura, Angelbeck, Pinsley, and
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`Gruber (id. at 38–55), and claim 38 is unpatentable over the combination of
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`Iwamura, Angelbeck, and Pinsley (id. at 59–60). In support of those
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`asserted grounds of unpatentability, TSMC provides detailed explanations as
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`to how each claim limitation is met by the aforementioned combinations of
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`the references and rationales for combining the references. Id. at 38–60.
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`TSMC also proffers the Declaration of Dr. Kortshagen (Ex. 1402) to support
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`its contentions. Id.
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`In its Preliminary Response, Zond responds that those combinations
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`of cited prior art references do not disclose every claim limitation. Prelim.
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`Resp. 50–53. Zond also argues that TSMC has not articulated a sufficient
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`rationale to combine the references. Id. at 39–41.
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`We have reviewed the parties’ contentions and supporting evidence.
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`Given the evidence on this record, we determine that TSMC has
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`demonstrated a reasonable likelihood of prevailing on its assertion that
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`claims 7, 9, 20, 21, 38, and 44 are unpatentable over Iwamura in
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`combination with the other cited references. Our discussion focuses on the
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`deficiencies alleged by Zond as to the claims.
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`Iwamura
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`
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`Iwamura discloses a plasma treatment apparatus for generating a
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`stable plasma with a multi-step ionization process to treat a semiconductor
`
`wafer. Ex. 1407, Abs., 6:67–7:8. Figure 1 of Iwamura, reproduced below
`
`(with our annotations added), illustrates a plasma treatment apparatus.
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`Pre-excitation unit
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`First plasma generation unit
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`Second plasma generation unit
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`
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`As shown in Figure 1 of Iwamura, plasma treatment chamber 10 is
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`coupled to the gas supply pipe (shown as items 20a and 20b). Gas supply 20
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`supplies a gas capable of plasma discharge (e.g., argon) through a
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`pre-excitation unit that includes ultraviolet lamp 24 and a first plasma
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`generation unit that includes electrodes 26. Ex. 1407, 6:67–7:17, 49.
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`Ultraviolet lamp 24 causes photoionization, raising the excitation level of the
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`gas—in other words, generating excited atoms from ground state atoms. Id.
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`at 7:55–60.
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`The first plasma generation unit, positioned along the flow path of the
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`gas supply, pre-activates the gas to generate a plasma. Id. at 2:56–58. At
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`this stage, the gas is not yet fully ionized, but its excitation level is high due
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`to the plasma pre-activation. Id. at 2:37–38. The gas maintains the ionized
`
`or near-ionized state, reaching a second plasma generation unit positioned
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`downstream from the first plasma generation unit. The second plasma
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`generation unit, which includes electrodes 30, activates the gas to generate a
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`plasma. Id. at 2:59–61, 8:4–9, 8:32–46.
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`According to Iwamura, because the excitation level of the gas is raised
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`first, a uniform and stable plasma can be generated. Id. at 2:39–41 (“[T]he
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`generation of a plasma and formulation of activated gas species in the
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`downstream region is made easier and more uniform and stable.”), 8:32–37.
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`Consequently, the uniformity of the plasma density as well as the yield of
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`the treatment of semiconductor wafer can be improved. Id. at 2:46–50,
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`8:41–46.
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`
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`Generating excited or metastable atoms
`
`Claim 7 depends from claim 1, which recites an “excited atom source
`
`generating excited atoms from the ground state atoms.” Claim 44 recites a
`
`similar limitation. Claim 20 depends from claim 18, which recites a
`
`“metastable atom source generating metastable atoms from the ground state
`
`atoms.” Claim 38 depends from claim 30, which also recites a similar
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`“metastable atoms” limitation.
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`In its Petition, TSMC asserts that Iwamura’s pre-excitation unit, the
`
`first plasma generation unit, or the combination of the pre-excitation unit
`
`and first plasma generation unit, describes an excited or metastable atom
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`source for generating excited or metastable atoms from ground state argon
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`atoms. Pet. 38–42, 44, 50–51 (citing Ex. 1402 ¶¶ 106–113, 114–115, 117,
`
`132–133). At this stage of the proceeding, Zond does not challenge that
`
`assertion. See Prelim. Resp. 50–53.
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`Upon review of the evidence before us, we agree with TSMC. As
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`discussed previously, we adopted the definition set forth in the Specification
`
`of the ’779 patent as the broadest reasonable interpretation for the claim
`
`term “metastable atoms”—namely, “excited atoms having energy levels
`
`from which dipole radiation is theoretically forbidden.” Ex. 1401, 7:22–24
`
`(emphasis added). According to the Specification, all noble gases have
`
`metastable states. Ex. 1401, 7:37.
`
`As noted by TSMC, Iwamura’s gas supply 20 introduces a gas, such
`
`as helium or argon, into the pre-excitation unit and the first plasma
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`generation unit. Pet. 50–51 (citing Ex. 1407, 7:48–50). Iwamura discloses
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`that the pre-excitation unit raises the excitation level of the ground state
`
`atoms to generate excited atoms, using either an ultraviolet lamp or a
`
`magnetron which radiates microwaves along the direction of the gas flow.
`
`Ex. 1407, 7:55–60, 9:38–53.
`
`Dr. Kortshagen explains that when atoms are excited, there is a
`
`distribution of multiple excited states. Ex. 1402 ¶ 133. Dr. Kortshagen
`
`testifies that metastable atoms are among the lower energy states that have a
`
`long lifetime, and excited atoms tend to accumulate in metastable states,
`
`because “it cannot transition into the ground state through dipole radiation,
`
`i.e., through the emission of electromagnetic radiation.” Id. ¶ 24 (citing
`
`Ex. 1401, 7:22–25), ¶ 133. Indeed, the Specification notes that
`
`“[m]etastable atoms have relatively long lifetimes compared with other
`
`excited atoms,” and “in practice, there is a finite probability that the
`
`metastable atoms relax to the ground state and emit dipole radiation.” Ex.
`
`1401, 7:24–32.
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`Dr. Kortshagen further explains that both helium and argon are noble
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`gases. Ex. 1402 ¶ 133. According to Dr. Kortshagen, generating excited
`
`argon atoms means also generating metastable atoms. Ex. 1402 ¶ 24 (citing
`
`Exs. 1311–1312). Dr. Kortshagen testifies that it has been shown that the
`
`four lowest excited states of excited argon atoms have at least 100 times
`
`higher density than the next higher excited states. Id. On this record, we are
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`persuaded that one of ordinary skill in the art at the time of the invention
`
`would have recognized that exciting ground state argon atoms would
`
`generate excited argon atoms, including metastable atoms—excited argon
`
`atoms having two of the four lowest excited levels (levels with n=2 and n=4)
`
`from which dipole radiation is theoretically forbidden.
`
`Given the evidence before us, we determine that TSMC has
`
`established adequately that Iwamura describes an excited or metastable atom
`
`source for generating excited or metastable atoms from ground state atoms.
`
`
`
`Ionizing excited/metastable atoms and generating a plasma with a multi-step
`ionization process
`
`Claim 7 depends from claim 1, which recites an “energy source
`
`raising an energy of excited atoms in the volume of excited atoms so that at
`
`least a portion of the excited atoms in the volume of excited atoms is
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`ionized, thereby generating a plasma with a multi-step ionization process.”
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`Emphases added. Claim 20 depends from claim 18, which likewise recites a
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`“power supply generating a power that raises an energy of metastable atoms
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`in the volume of metastable atoms so that at least a portion of the metastable
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`atoms in the volume of metastable atoms is ionized, thereby generating a
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`plasma with a multi-step ionization process.” Emphases added.
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`Claim 44 recites a similar limitation, and claim 38 depends from claim 30,
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`which also recites a similar limitation.
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`TSMC maintains that Iwamura’s second plasma generation unit,
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`which includes electrodes coupled to a high-frequency power supply,
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`provides energy to the excited/metastable atoms and generates a plasma
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`within the chamber. Pet. 49, 59. According to TSMC, Iwamura discloses a
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`plasma device that utilizes a multi-step ionization process in which a pre-
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`excitation unit is used to excite the ground state gas into an
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`excited/metastable state, and a second plasma generation unit is used to
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`ionize the excited/metastable atoms, in two distinct steps. Id. at 38–44, 49,
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`59 (citing Ex. 1402 ¶¶ 106–112, 114–115).
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`Zond counters that Iwamura does not describe the “ionization” and
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`“multi-step ionization process” claim features. Prelim. Resp. 50–53.
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`Specifically, Zond alleges that those claim features require more than
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`pre-exciting the gas and activating the gas, and “Iwamura makes no mention
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`of ionization.” Id. at 51, 53.
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`However, obviousness is not an ipsissimis verbis test. Rather, a prima
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`facie case of obviousness is established when the prior art, itself, would
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`appear to have suggested the claimed subject matter to a person of ordinary
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`skill in the art. In re Rinehart, 531 F.2d 1048, 1051 (CCPA 1976). In that
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`regard, an obviousness analysis “need not seek out precise teachings directed
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`to the specific subject matter of the challenged claim, for a court can take
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`account of the inferences and creative steps that a person of ordinary skill in
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`the art would employ.” KSR, 550 U.S. at 418. “A person of ordinary skill is
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`also a person of ordinary creativity, not an automaton.” Id. at 421.
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`The Specification of the ’779 patent indicates that “plasma is a
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`collection of charged particles that move in random directions.” Ex. 1401,
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`1:7–9 (emphases added). As discussed above, the Specification of the ’779
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`patent defines the claim term “multi-step ionization process” as “an
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`ionization process whereby ions are ionized in at least two distinct steps.”
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`Id. at 6:60–7:9 (emphases added). The Specification also provides that a
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`multi-step ionization process includes: (1) a first step where atoms are
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`excited from a ground state to an excited state; and (2) a second step where
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`atoms in the excited state are ionized, generating ions from the excited
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`atoms. Id. The term “ionization” ordinarily is understood as a “process by
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`which an atom or molecule receives enough energy (by collision with
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`electrons, photons, etc.) to split it into one or more free electrons and a
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`positive ion” (emphasis added).4
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`As TSMC indicates in its Petition, Iwamura discloses a plasma
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`treatment apparatus that generates a plasma with a multi-step ionization
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`process. Pet. 38–44. For the first step, Iwamura’s pre-excitation unit or first
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`plasma generation unit raises the excitation level of the argon gas—
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`i.e., generating excited/metastable atoms from ground state argon atoms—
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`
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`4 See THE AUTHORITATIVE DICTIONARY OF IEEE STANDARDS TERMS 589
`(7th ed.) (2000) (Ex. 3001) (defining “ionization” as “(B) The process by
`which an atom or molecule receives enough energy (by collision with
`electrons, photons, etc.) to split it into one or more free electrons and a
`positive ion. Ionization is a special case of charging.”).
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`using microwaves or ultraviolet radiation that causes photoionization.
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`Ex. 1407, 7:55–60, 9:46–48, Figs. 1, 2. For the second step, Iwamura’s
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`second plasma generation unit generates a plasma, which includes a
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`collection of ions and free electrons, by using a pair of electrodes coupled to
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`a high-frequency power supply. Id. at 7:61–63, 8:32–46, Figs. 1, 2.
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`Therefore, we are persuaded that one of ordinary skill in the art would have
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`recognized that the electrodes and power supply generate the ions and free
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`electrons by ionizing the excited/metastable atoms.
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`Given the evidence in this record, we determine that TSMC has
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`demonstrated sufficiently that Iwamura teaches or suggests the “ionization”
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`and “multi-step ionization process” claim features—raising an energy of the
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`excited/metastable atoms so that at least a portion of the volume of
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`excited/metastable atoms is ionized, thereby generating a plasma with a
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`multi-step ionization process.
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`Generating a magnetic field for trapping electrons
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`Claim 7 depends from claim 1, which recites “the excited atom source
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`comprising a magnet that generates a magnetic field for substantially
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`trapping electrons proximate to the ground state atoms.” Claim 20 depends
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`from claim 18, and claim 38 depends from claim 30. Claims 18 and 30 each
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`recite a similar limitation.
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`In its Petition, TSMC acknowledges that, although Iwamura discloses
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`multiple ways to generate excited atoms, Iwamura’s excited atom source—
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`the pre-excitation unit—does not use a magnet for generating a magnetic
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`field. Pet. 44–45. Nevertheless, TSMC maintains that it was well known in
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`the art at the time of the invention to use a magnet for generating a magnetic
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`field in a plasma apparatus for trapping electrons, as evidenced by
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`Angelbeck and Pinsley. Id. at 45–46 (citing Ex. 1406, 2:50–51, Fig. 1;
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`Ex. 1405, 2:43–60; Ex. 1402 ¶ 122). TSMC maintains that it would have
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`been obvious to combine Angelbeck’s transverse magnetic field with
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`Iwamura’s first plasma generation unit or the combination of the pre-
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`excitation unit with the first plasma generation unit, to trap electrons in order
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`to increase the efficiency of excitation. Id. at 46–47 (citing Ex. 1406, 1:36–
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`41; Ex. 1402 ¶ 123).
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`In its Preliminary Response, Zond counters that the combination of
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`the cited prior art references does not teach or suggest the “magnetic field”
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`claim limitations. Prelim. Resp. 51–52. In particular, Zond argues that
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`Iwamura does not have a magnet, and Angelbeck does not trap electrons
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`near the ground state atoms. Id.
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`Zond’s arguments, however, do not address what is taught or
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`suggested by the combination of cited prior art references. Nonobviousness
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`cannot be established by attacking references individually where, as here,
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`the ground of unpatentability is based upon the teachings of a combination
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`of references. In re Keller, 642 F.2d 413, 426 (CCPA 1981). Rather, the
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`test for obviousness is whether the combination of references, taken as a
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`whole, would have suggested the patentee’s invention to a person having
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`ordinary skill in the art. In re Merck & Co., Inc., 800 F.2d 1091, 1097
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`(Fed. Cir. 1986). As discussed above, TSMC relies upon the combination of
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`Iwamura, Angelbeck, and Pinsley to disclose or suggest the “magnetic field”
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`claim limitations. Pet. 44–47. As such, we are not persuaded by Zond’s
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`arguments.
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`In addition, Zond does not dispute that it was well known in the art at
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`the time of the invention to use a magnet in a plasma apparatus for trapping
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`electrons. Indeed, the admitted prior art, Figure 1 of the ’779 patent,
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`describes magnet 130 that generates magnetic field 132 to trap electrons.
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`Ex. 1401, 3:13–15. As TSMC points out, Pinsley and Angelbeck confirm
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`that one of ordinary skill in the art would have recognized that applying a
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`transverse magnetic field in a plasma apparatus would trap electrons.
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`Pet. 45–46 (citing Ex. 1405, 2:43–60; Ex. 1406, 2:50–51, Fig. 1).
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`Notably, Pinsley discloses a plasma generating apparatus having a
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`magnetic field for trapping electrons. Ex. 1405, 1:51–54, 2:43–47.
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`Pinsley’s sole Figure, reproduced below, illustrates a plasma generating
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`apparatus with magnets:
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`As shown in Pinsley’s sole Figure, conduit 10 includes anode 18 and
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`cathode 19, for establishing an electric discharge plasma, as well as magnets
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`24 and 26, for generating a magnetic field. Id. at 2:27–42. According to
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`Pinsley, “the interaction between the current and the magnetic field will
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`result in an upstream force as indicated by the force vector 32.” Id. at 2:43–
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`45. “This force is exerted upon the electrons, and tends to maintain the
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`electrons in an area between the anode and cathode,” trapping the electrons.
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`Id. at 2:45–47 (emphasis added).
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`More importantly, Angelbeck discloses applying a transverse
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`magnetic field in a plasma generating apparatus for creating a high density
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`of excited atoms. Ex. 1406, 1:36–41, 2:18–20, 2:29–33. Figure 1 of
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`Angelbeck, reproduced below, illustrates a plasma generating apparatus with
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`a magnet:
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`As shown in Figure 1 of Angelbeck, the current-excited discharge
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`passed through the gas within tube 10 creates a plasma in which the atoms
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`are ionized and electrons are freed. Id. at 2:55–57. Transverse magnetic
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`field B