throbber
U.S. Patent 6,805,779, Claims 7, 9, 20, 21, 38, and 44
`Petition for Inter Partes Review
`
`
`DOCKET NO.: 0107131-00269 US5
`Filed on behalf of Intel Corporation
`By: Michael A. Diener, Reg. No. 37,122
`Yung-Hoon Ha, Reg. No. 56,368
`Wilmer Cutler Pickering Hale and Dorr LLP
`60 State Street, Boston, MA 02109
`Tel: (617) 526-6000
`Email: Michael.Diener@wilmerhale.com
` Yung-Hoon.Ha@wilmerhale.com
`
`
`
`
`
`
`
`
`
`
`UNITED STATES PATENT AND TRADEMARK OFFICE
`____________________________________________
`
`
`BEFORE THE PATENT TRIAL AND APPEAL BOARD
`____________________________________________
`
`
`INTEL CORPORATION
`Petitioner
`
`v.
`
`ZOND INC.
`Patent Owner
`
`Case No. IPR2014-00913
`
`
`PETITION FOR INTER PARTES REVIEW OF
`U.S. PATENT NO. 6,805,779
`CHALLENGING CLAIMS 7, 9, 20, 21, 38, AND 44
`UNDER 35 U.S.C. § 312 AND 37 C.F.R. § 42.104
`
`
`
`

`

`
`
`
`TABLE OF CONTENTS
`
`
`
`
`I. 
`
`Mandatory Notices ...................................................................................... - 1 - 
`A. 
`Real Party-in-Interest ....................................................................... - 1 - 
`B. 
`Related Matters ................................................................................. - 1 - 
`C. 
`Counsel ............................................................................................. - 1 - 
`D. 
`Service Information .......................................................................... - 1 - 
`Certification of Grounds for Standing ........................................................ - 2 - 
`II. 
`III.  Overview of Challenge and Relief Requested ............................................ - 2 - 
`A. 
`Prior Art Patents and Printed Publications ....................................... - 2 - 
`B. 
`Grounds for Challenge ..................................................................... - 3 - 
`IV.  Brief Description of Technology ................................................................ - 3 - 
`A. 
`Plasma............................................................................................... - 3 - 
`B. 
`Ions, excited atoms, and metastable atoms ...................................... - 3 - 
`V.  Overview of the ‘779 Patent ....................................................................... - 5 - 
`A. 
`Summary of Alleged Invention of the ‘779 Patent .......................... - 5 - 
`B. 
`Prosecution History .......................................................................... - 9 - 
`VI.  Overview of the Primary Prior Art References ........................................ - 10 - 
`A. 
`Summary of the Prior Art ............................................................... - 10 - 
`B. 
`Overview of Mozgrin ..................................................................... - 11 - 
`C. 
`Overview of Kudryavtsev .............................................................. - 12 - 
`D.  Overview of Iwamura ..................................................................... - 12 - 
`E. 
`Overview of Pinsley and Angelbeck .............................................. - 13 - 
`VII.  Claim Construction ................................................................................... - 14 - 
`A. 
`“multi-step ionization” ................................................................... - 15 - 
`VIII.  Specific Grounds for Petition ................................................................... - 15 - 
`A.  Ground I: Claims 9, 21 and 44 would have been obvious in view
`of Mozgrin, Kudryavtsev, Pinsley and Gruber .............................. - 16 - 
`1. 
`Independent claim 1 ............................................................. - 16 - 
`2. 
`Independent claim 18 ........................................................... - 29 - 
`
`i
`
`

`

`B. 
`
`C. 
`
`
`
`Dependent claims 9 and 21 .................................................. - 32 - 
`3. 
`Independent claim 44 ........................................................... - 34 - 
`4. 
`Ground II: Claims 7 and 20 would have been obvious in view of
`Mozgrin, Kudryavtsev, Pinsley, and Wells .................................... - 36 - 
`Ground III: Claim 9, 21 and 44 would have been obvious over
`Iwamura, Angelbeck and Gruber ................................................... - 38 - 
`1. 
`Independent claim 1 ............................................................. - 38 - 
`2. 
`Independent claim 18 ........................................................... - 50 - 
`3. 
`Dependent claims 9 and 21 .................................................. - 52 - 
`4. 
`Independent claim 44 ........................................................... - 54 - 
`D.  Ground IV: Claims 7 and 20 would have been obvious in view
`of the combination of Iwamura, Angelbeck, and Wells ................ - 55 - 
`Ground V: Claim 38 would have been obvious in view of
`Mozgrin, Kudryavtsev, Pinsley, and Iwamura ............................... - 57 - 
`Ground VI: Claim 38 would have been obvious in view of the
`Iwamura and Angelbeck ................................................................. - 59 - 
`IX.  Conclusion ................................................................................................ - 60 - 
`
`
`E. 
`
`F. 
`
`
`
`
`
`ii
`
`

`

`TABLE OF AUTHORITIES
`
`FEDERAL STATUTES
`
`
`
`
`Pages
`
`35 U.S.C. § 312………………………………………………………....Cover Page
`
`REGULATIONS
`
`37 C.F.R. § 42.22……………………………………………………….…………2
`
`37 C.F.R. § 42.100…………………………………………………………...14, 15
`
`37 C.F.R. § 42.104…………………………………….……........Cover page, 2, 16
`
`CASE LAW
`
`In re ICON Health & Fitness, Inc., 496 F.3d 1374, 1379 (Fed. Cir. 2007)……...15
`
`
`
`
`
`iii
`
`

`

`
`
`I. MANDATORY NOTICES
`A. Real Party-in-Interest
`Intel Corporation (“Petitioner”) is the real party-in-interest.
`
`B. Related Matters
`Zond has asserted U.S. Patent No. 6,805,779 (“‘779 Patent”) (Ex. 1401)
`
`against parties in the District of Massachusetts, 1:13-cv-11570-RGS (Zond v.
`
`Intel); 1:13-cv-11577-DPW (Zond v. AMD, Inc., et al); 1:13-cv-11581-DJC (Zond
`
`v. Toshiba Am. Elec. Comp. Inc.); 1:13-cv-11591-RGS (Zond v. SK Hynix, Inc.);
`
`1:13-cv-11625-NMG (Zond v. Renesas Elec. Corp.) ; 1:13-cv-11634-WGY (Zond
`
`v. Fujitsu, et al.); and 1:13-cv-11567-DJC (Zond v. Gillette, Co.). Petitioner has
`
`filed Petition Nos. IPR2014-00598, IPR2014-00686, IPR2014-00765, IPR2014-
`
`00820 for claims 1-6, 8, 10-19, 22-37, 39-43, 45 and 46 of the ‘779 patent.
`
`C. Counsel
`Lead Counsel: Michael A. Diener (Registration No. 37,122)
`
`Backup Counsel: Yung-Hoon Ha (Registration No. 56,368)
`
`Service Information
`
`D.
`E-mail: Michael.Diener@wilmerhale.com
`
`Yung-Hoon.Ha@wilmerhale.com
`
`Post and hand delivery: Wilmer, Cutler, Pickering, Hale and Dorr, LLP
`
`
`
`
`
`
`
`
`
`60 State Street, Boston, MA 02109
`
`Telephone: 617-526-6000
`
`
`
`Fax: 617-526-5000
`
`
`
`
`
`

`

`
`
`
`II. CERTIFICATION OF GROUNDS FOR STANDING
`Petitioner certifies pursuant to Rule 42.104(a) that the patent for which
`
`review is sought is available for inter partes review and that Petitioner is not
`
`barred or estopped from requesting an inter partes review challenging the patent
`
`claims on the grounds identified in this Petition.
`
`III. OVERVIEW OF CHALLENGE AND RELIEF REQUESTED
`Pursuant to Rules 42.22(a)(1) and 42.104(b)(1)-(2), Petitioner challenges
`
`Claims 7, 9, 20, 21, 38, and 44 of the ‘779 Patent.
`
`Prior Art Patents and Printed Publications
`
`A.
`The following references, and others listed in the Table of Exhibits, are
`
`pertinent to the grounds of unpatentability explained below, and are each prior art
`
`under (pre-AIA) 102(b):
`
`1.
`
`D.V. Mozgrin, et al, High-Current Low-Pressure Quasi-Stationary
`
`Discharge in a Magnetic Field: Experimental Research, Plasma Physics Reports,
`
`Vol. 21, No. 5, pp. 400-409, 1995 (“Mozgrin” (Ex. 1403)).
`
`2.
`
`A. A. Kudryavtsev, et al, Ionization relaxation in a plasma produced by a
`
`pulsed inert-gas discharge, Sov. Phys. Tech. Phys. 28(1), January 1983
`
`(“Kudryavtsev” (Ex. 1404)).
`
`3. U.S. Patent No. 3,761,836 (“Pinsley” (Ex. 1405)).
`
`4.
`
`5.
`
`U.S. Patent No. 3,514,714 (“Angelbeck” (Ex. 1406)).
`
`U.S. Patent No. 5,753,886 (“Iwamura” (Ex. 1407)).
`
`- 2 -
`
`

`

`
`
`
`6.
`
`7.
`
`
`
`EPO Patent Publication No. EP 0 146 509 (“Gruber” (Ex. 1413)).
`
`PCT Patent Publication No. WO 83/01349 (“Wells” (Ex. 1414)).
`
`Of these, only Mozgrin was of record during prosecution.
`
`B. Grounds for Challenge
`Petitioner requests cancellation of claims 7, 9, 20, 21, 38, and 44 (hereinafter
`
`“challenged claims”) of the ‘779 Patent as unpatentable under 35 U.S.C. §103.
`
`This Petition, supported by the declaration of Uwe Kortshagen, Ph.D.
`
`(“Kortshagen Decl.” (Ex. 1402)) herewith, demonstrates that there is a reasonable
`
`likelihood that Petitioner will prevail with respect to at least one challenged claim
`
`and that each challenged claim is not patentable. See 35 U.S.C. § 314(a).
`
`IV. BRIEF DESCRIPTION OF TECHNOLOGY
`A.
`Plasma
`A plasma is a collection of ions, free electrons, and neutral atoms. Dr.
`
`Kortshagen Decl. provides some general background on plasma and their use in
`
`sputtering at Kortshagen Decl. ¶ 21-22 (Ex. 1402). The “density” of a plasma
`
`refers to the number of ions or electrons that are present in a unit volume. Id. (Ex.
`
`1402).
`
`Ions, excited atoms, and metastable atoms
`
`B.
`Atoms have equal numbers of protons and electrons. Kortshagen Decl. ¶ 23
`
`(Ex. 1402). Each electron has an associated energy state. Id. (Ex. 1402). If all of
`
`an atom’s electrons are at their lowest possible energy state, the atom is said to be
`
`- 3 -
`
`

`

`
`
`
`in the “ground state.” Id. (Ex. 1402).
`
`On the other hand, if one or more of an atom’s electrons is in a state that is
`
`higher than its lowest possible state, then the atom is said to be an “excited atom.”
`
`Id. at ¶ 24 (Ex. 1402). A metastable atom is a type of excited atom that is
`
`relatively long-lived, because it cannot transition into the ground state through
`
`dipole radiation, i.e., through the emission of electromagnetic radiation. Id. (Ex.
`
`1402). See also ‘779 Patent at 7:22-25 (“The term ‘metastable atoms’ is defined
`
`herein to mean excited atoms having energy levels from which dipole radiation is
`
`theoretically forbidden. Metastable atoms have relatively long lifetimes compared
`
`with other excited atoms.”) (Ex. 1401). “All noble gases have metastable states.”
`
`‘779 Patent at 7:37 (Ex. 1401). When generating excited atoms, multiple levels of
`
`excited states are formed. Of these, some of the lowest states are metastable, and
`
`would typically be more common than the higher states. Id. (Ex. 1402), where Dr.
`
`Kortshagen provides additional support with reference to Exs. 1411 and 1412.
`
`Excited and metastable atoms are electrically neutral – they have equal
`
`numbers of electrons and protons. Kortshagen Decl. ¶ 25 (Ex. 1402). A collision
`
`with a low energy free electron (e-) can convert a ground state atom to an excited
`
`or metastable atom. Id. (Ex. 1402). For example, the ‘779 Patent uses the
`
`following equation to describe production of an excited argon atom, Ar*, from a
`
`ground state argon atom, Ar. See ‘779 Patent at 8:7 (Ex. 1401).
`
`- 4 -
`
`

`

`
`
`
`Ar + e-  Ar* + e-
`
`An ion is an atom that has become disassociated from one or more of its
`
`electrons. Kortshagen Decl. ¶ 26 (Ex. 1402). A collision between a free, high
`
`energy electron and a ground state, excited, or metastable atom can create an ion.
`
`Id. (Ex. 1402). For example, the ‘779 Patent uses the following equations to
`
`describe production of an argon ion, Ar+, from a ground state argon atom, Ar, or an
`
`excited argon atom, Ar*. See ‘779 Patent at 3:40 and 8:9 (Ex. 1401).
`
`Ar + e-  Ar+ + 2e-
`
`Ar* + e-  Ar+ + 2e-
`
`The production of excited atoms, metastable atoms, and ions was well
`
`understood long before the ‘779 Patent was filed. Kortshagen Decl. ¶ 27 (Ex.
`
`1402).
`
`V. OVERVIEW OF THE ‘779 PATENT
`A.
`Summary of Alleged Invention of the ‘779 Patent
`The ‘779 Patent relates to generating a plasma using a multi-step ionization
`
`process with an excited/metastable atom/molecule source that generates excited
`
`atoms, or metastable atoms or molecules, and then provides the excited/metastable
`
`atoms or molecules to a plasma chamber where the plasma is formed, thereby
`
`generating a plasma with a “multi-step ionization” process. Kortshagen Decl. ¶ 28
`
`(Ex. 1402). For convenience, this section will just use the term “excited atom
`
`source.” In any event, there appears to be no substantial difference between
`
`- 5 -
`
`

`

`
`
`
`excited and metastable sources. Id. (Ex. 1402). The ‘779 Patent does not indicate
`
`any particular difference in the operation of an excited atom source when it is a
`
`metastable atom source. Id. (Ex. 1402). The specification repeatedly refers to “an
`
`excited atom source such as a metastable atom source,” see, e.g., ‘779 Patent at
`
`2:13-14, 17-18, 22-24 (Ex. 1401), and says that “[i]n some embodiments, the
`
`metastable atom source 204 generates some excited atoms that are in excited states
`
`other than a metastable state.” Id. at 5:63-65 (Ex. 1401)
`
`Admitted prior art FIG. 1 of the ‘779 Patent shows a plasma chamber
`
`consisting of a magnetron sputtering system, without an excited atom source.
`
`Kortshagen Decl. ¶ 29 (Ex. 1402). It generates plasma through a process that the
`
`patent refers to as a direct ionization process. ‘779 Patent at 3:36-47 (“The
`
`ionization process in known plasma sputtering apparatus is generally referred to as
`
`direct ionization…. The collision between the neutral argon atom and the ionizing
`
`electron results in an argon ion (Ar+) and two electrons.”) (Ex. 1401).
`
`As is generally known, this system has an anode, a cathode assembly 114 for
`
`holding a target material to be sputtered, and a magnet 130 that generates a
`
`magnetic field 132 proximate to the target to trap and concentrate electrons. Id. at
`
`2:46-3:18 (Ex. 1401). See also Kortshagen Decl. ¶ 30 (Ex. 1402).
`
`The alleged invention generally relates to coupling an excited or metastable
`
`atom source to some plasma chamber. ‘779 Patent at 5:27-34 (“The metastable
`
`- 6 -
`
`

`

`
`
`
`atom source 204 can be coupled to any type of process chamber, such as the
`
`chamber 104 of FIG. 1. In fact, a plasma generator according to the present
`
`invention can be constructed by coupling a metastable atom source to a
`
`commercially available plasma chamber. Thus, commercially available plasma
`
`generators can be modified to generate a plasma using a multi-step ionization
`
`process according to the present invention.”) (Ex. 1401). See also Kortshagen
`
`Decl. ¶ 31 (Ex. 1402).
`
`FIGS. 2 and 3 of the ‘779 Patent show such plasma generators “according to
`
`the present invention” that are coupled with separate metastable atom sources
`
`(annotated in color below). ‘779 Patent at 2:3-11; FIGS. 2 and 3 (Ex. 1401).
`
`Specifically, FIG. 2 shows metastable atom source 204, and FIG. 3 shows
`
`
`
`
`
`metastable atom source 304 (annotated in color above). Kortshagen Decl. ¶ 33
`
`(Ex. 1402). The metastable atom sources 204 and 304 “generate[] a volume of
`
`metastable atoms 218 from [a] volume of ground state atoms. See, e.g., ‘779
`
`Patent at 4:56-58 (Ex. 1401). Metastable atoms 218 are transported from the
`
`- 7 -
`
`

`

`
`
`
`source where they are generated to the region between the cathode 114/306 and
`
`substrate support 136/352, where plasma 202/302 is formed. Kortshagen Decl. ¶
`
`33 (Ex. 1402).
`
`Power supply 222 (annotated in color above) provides power to the
`
`metastable atom source. See, e.g., ‘779 Patent at 4:60-62 (Ex. 1401). Another
`
`(pulsed) power supply 201 (in FIG. 2) or power supply 316 (in FIG. 3) raises the
`
`energy of the metastable atoms to generate a plasma 202. See, e.g., id. at 11:4-14
`
`(“A power supply 316 is electrically coupled to the volume of metastable atoms
`
`218. The power supply 316 can be any type of power supply, such as a pulsed
`
`power supply, a RF power supply, an AC power supply, or a DC power supply. …
`
`The power supply 316 generates an electric field 322 between the cathode 306 and
`
`the anode 308 that raises the energy of the volume of metastable atoms 218 so that
`
`at least a portion of the volume of metastable atoms 218 are ionized, thereby
`
`generating the plasma 302.”) (Ex. 1401). See also Kortshagen Decl. ¶ 34 (Ex.
`
`1402).
`
`The metastable atom sources shown in FIGS. 2 and 3 can be mounted to the
`
`inside wall of the chamber 230 (FIG. 3), or on the outside wall (FIG. 2). See, e.g.,
`
`‘779 Patent at 4:31-34 and 9:51-62 (Ex. 1401). Kortshagen Decl. ¶ 35 (Ex. 1402).
`
`Consistent with the claim language, FIGS. 2 and 3, and the specification, the
`
`“excited atom source” and “metastable atom source” generate the excited atoms in
`
`- 8 -
`
`

`

`
`
`
`a source that is distinct from, and coupled to, the components that later raise the
`
`energy of the excited or metastable atoms to generate a plasma with “multi-step
`
`ionization,” a term the ‘779 Patent defines as an ionization process whereby ions
`
`are ionized in at least two distinct steps.”1 ‘779 Patent at 6:60-63 (Ex. 1401).
`
`Prosecution History
`
`B.
`The first substantive office action for the application that led to the ‘779
`
`Patent rejected all independent claims as being anticipated based on prior art that
`
`showed a first chamber for generating excited/metastable atoms, and a second
`
`chamber for increasing the energy of the excited atoms, and for generating a
`
`plasma using multi-step ionization. See 02/11/04 Office Action at 2-3 (Ex. 1408).
`
`The applicant did not dispute the rejection, but amended the independent
`
`claims at issue here to require that the distinct source further includes “a magnet
`
`that generates a magnetic field for substantially trapping electrons proximate to the
`
`ground state atoms.” See 05/06/04 Resp. at 2, 4, 6, 8 and 10 (Ex. 1409). The
`
`claims were then allowed.
`
`
`
`Notwithstanding this difference, the ‘779 Patent does not indicate that an
`
`excited atom source with magnets has any special significance over other ways for
`
`generating excited/metastable atoms. Although the magnet embodiment was
`
`claimed, the specification indicates that there were other ways to generate excited
`
`1 All bold/italics emphasis is added.
`
`- 9 -
`
`

`

`
`
`
`atoms, and shows multiple embodiments – e.g., FIGS. 4, 5, 8, 9, and 11—without
`
`the magnets that were required for the claims to be allowed. The “magnet” recited
`
`in the claims refers particularly to the embodiments of FIGS. 6, 7, and10, and
`
`specifically to magnets 504a, 504b, 506a and 506b in FIG. 6; magnets 566a-d and
`
`570a-d in FIG. 7; and magnets 712 and 714 in FIG. 10. ‘779 Patent at FIGS. 6 and
`
`7; 14:46-15:45; and 16:12-20 (Ex. 1401).
`
`European Counterpart. The applicants had also identified these magnets,
`
`located in the separate excited atom source of FIG. 6, as the claimed magnets in
`
`counterpart claims in Europe, which read in part:
`
`characterised [sic] in that the excited atom source (204) comprises a
`magnet (504, 506) that is arranged to generate a magnetic field (508)
`that traps electrons proximate to the ground state atoms.
`
`24 July 2007 Response in EP 1614136 (Ex. 1410)
`
`However, as explained in detail below, and contrary to the Examiner’s
`
`reasons for allowance, the prior art addressed herein teaches using magnets in this
`
`manner, along with the other limitations of the challenged claims. Kortshagen
`
`Decl. ¶ 41 (Ex. 1402).
`
`VI. OVERVIEW OF THE PRIMARY PRIOR ART REFERENCES
`A.
`Summary of the Prior Art
`As explained in detail below, limitation-by-limitation, there is nothing new
`
`- 10 -
`
`

`

`
`
`
`or non-obvious in the challenged claims of the ‘779 Patent. Id. at ¶ 42 (Ex. 1402).
`
`B. Overview of Mozgrin
`Fig. 7 of Mozgrin shows the current-voltage characteristic (“CVC”) of a
`
`plasma discharge generated by Mozgrin. As shown, Mozgrin divides this CVC
`
`into four distinct regions. Id. at ¶ 43 (Ex. 1402).
`
`Mozgrin calls region 1 “pre-ionization.” Mozgrin at 402, right col, ¶ 2 (Ex.
`
`1403). See also Kortshagen Decl. ¶ 44 (Ex. 1402).
`
`Mozgrin calls region 2 “high current magnetron discharge.” Mozgrin at 409,
`
`left col, ¶ 4 (Ex. 1403). See also Kortshagen Decl. ¶ 45 (Ex. 1402). Application of
`
`a high voltage to the pre-ionized plasma causes the transition from region 1 to 2.
`
`Id. (Ex. 1402). Mozgrin teaches that region 2 is useful for sputtering. Mozgrin at
`
`403, right col, ¶ 4 (“Regime 2 was characterized by an intense cathode
`
`sputtering…”) (Ex. 1403). See also Kortshagen Decl. ¶ 45 (Ex. 1402).
`
`Mozgrin calls region 3 “high current diffuse discharge.” Mozgrin at 409, left
`
`col, ¶ 5, (Ex. 1403). Increasing the current applied to the “high-current magnetron
`
`discharge” (region 2) causes the plasma to transition to region 3. Kortshagen
`
`Decl. ¶ 46 (Ex. 1402). Mozgrin also teaches that region 3 is useful for etching, i.e.,
`
`removing material from a surface. Mozgrin at 409, left col, ¶ 5 (“The high-current
`
`diffuse discharge (regime 3) is useful … Hence, it can enhance the efficiency of
`
`ionic etching…”) (Ex. 1403). See also Kortshagen Decl. ¶ 46 (Ex. 1402).
`
`- 11 -
`
`

`

`
`
`
`Mozgrin calls region 4 “arc discharge.” Mozgrin at 402, right col, ¶ 3(Ex.
`
`1403). Further increasing the applied current causes the plasma to transition from
`
`region 3 to the “arc discharge” region 4. Kortshagen Decl. ¶ 47 (Ex. 1402).
`
`C. Overview of Kudryavtsev
`Kudryavtsev is a technical paper that studies the ionization of a plasma with
`
`voltage pulses. See, e.g., Kudryavtsev at 30, left col. ¶ 1 (Ex. 1404). In particular,
`
`Kudryavtsev describes how ionization of a plasma can occur via different
`
`processes. The first process is direct ionization, in which ground state atoms are
`
`converted directly to ions. See, e.g., id. at Fig. 6 caption (Ex. 1404). The second
`
`process is multi-step ionization, which Kudryavtsev calls stepwise ionization. See,
`
`e.g., id. (Ex. 1404). Kudryavtsev notes that under certain conditions multi-step
`
`ionization can be the dominant ionization process. See, e.g., id. (Ex. 1404).
`
`Mozgrin took into account the teachings of Kudryavtsev when designing his
`
`experiments. Mozgrin at 401, ¶ spanning left and right cols. (“Designing the unit,
`
`we took into account the dependences which had been obtained in
`
`[Kudryavtsev]…”) (Ex. 1403). See also Kortshagen Decl. ¶ 48 (Ex. 1402).
`
`D. Overview of Iwamura
`Iwamura discloses “a plasma treatment apparatus for treating a surface of an
`
`object….” Iwamura at 2:51-52 (Ex. 1407). “A first plasma generation unit for
`
`preactivating the gas to generate a plasma is positioned upstream along the flow
`
`- 12 -
`
`

`

`
`
`
`path of the gas in the gas supply; and a second plasma generation unit for
`
`activating the gas to generate a plasma downstream along the flow path of the gas
`
`in the gas supply is also provided. Thus, the first plasma generation unit
`
`preactivates the gas and the second plasma generation unit activates the gas and
`
`forms activated gas species. Then, the activated gas species formed by the second
`
`plasma generation unit treat the object to be treated.” Iwamura at 2:56-65. (Ex.
`
`1407); see also Kortshagen Decl. ¶ 49 (Ex. 1402).
`
`
`
`Iwamura discloses multiple ways for generating excited/metastable atoms,
`
`and discloses the desirability of providing a first excitation step followed by a
`
`further energy providing step, and also claims such a system. Iwamura at 2:1-50,
`
`claim 1 (Ex. 1407); see also Kortshagen Decl. ¶ 50 (Ex. 1402).
`
`E. Overview of Pinsley and Angelbeck
`Pinsley discloses a gas laser having a magnetic field that is oriented
`
`transversely with respect to the flow of the gases. Pinsley at Abstract (“A flowing
`
`gas laser having an electric discharge plasma with the electric field oriented
`
`transversely with respect to the flow of gases therethrough is provided with a
`
`magnetic field which is oriented transversely with respect to both the flow and the
`
`electric field to overcome the forces of flowing gases thereon.”) (Ex. 1405); see
`
`also Kortshagen Decl. ¶ 51 (Ex. 1402). The transverse magnetic field traps
`
`electrons. Pinsley at 2:43-47 (“As is known, the interaction between the current
`
`- 13 -
`
`

`

`
`
`
`and the magnetic field will result in an upstream force as indicated by the force
`
`vector 32. This force is exerted upon the electrons, and tends to maintain the
`
`electrons in an area between the anode and cathode.”) (Ex. 1405); see also
`
`Kortshagen Decl. ¶ 51 (Ex. 1402).
`
`Pinsley does not specifically use the words “excited atoms,” but one of
`
`ordinary skill would understand that increasing the energy and using a magnetic
`
`field to maintain the electrons in place would allow excited atoms to be generated
`
`and pass through. Id. at ¶ 52 (Ex. 1402). The Angelbeck patent (with a lead
`
`inventor who is also a co-inventor on the Pinsley patent) makes clear that gas
`
`lasers of the type disclosed by Pinsley generate excited atoms as part of their
`
`operation. Angelbeck at 1:21-25 (“This invention relates to gas lasers, and
`
`particularly to a method and apparatus for increasing and controlling the light
`
`output of a gas laser by applying a transverse magnetic field to the laser.”); 2:18-20
`
`(“A high gas pressure P is advantageous, however, for creating a high density of
`
`excited atoms in the laser.”) (Ex. 1403); Kortshagen Decl. ¶ 52 (Ex. 1402).
`
`VII. CLAIM CONSTRUCTION
`A claim in inter partes review is given the “broadest reasonable construction
`
`in light of the specification.” 37 C.F.R. § 42.100(b). Any claim term that lacks a
`
`definition in the specification is therefore also given a broad interpretation. In re
`
`ICON Health & Fitness, Inc., 496 F.3d 1374, 1379 (Fed. Cir. 2007). Any claim
`
`- 14 -
`
`

`

`
`
`
`terms not included in the following discussion are to be given their broadest
`
`reasonable interpretation in light of the specification as commonly understood by
`
`those of ordinary skill in the art. 2
`
`“multi-step ionization”
`
`A.
`Each of the independent claims in the ‘779 Patent recites the term “multi-
`
`step ionization.” The ‘779 Patent defines this term “to mean an ionization process
`
`whereby ions are ionized in at least two distinct steps.” ‘779 Patent at 6:60-63 (Ex.
`
`1401). This is consistent with the claim language, FIGS. 2 and 3, and the
`
`specification, which generate the excited atoms in a source that is distinct from,
`
`and coupled to, the components that later raise the energy of the excited or
`
`metastable atoms to generate a plasma. Thus the proposed construction for “multi-
`
`step ionization” is “an ionization process whereby ions are ionized in at least two
`
`distinct steps.” This proposed construction is consistent with the position taken by
`
`the Patent Owner in 1:13-cv-11634-WGY (Zond v. Fujitsu, et al.), where the
`
`Patent Owner construed this term as “an ionization process having two or more
`
`distinct steps.” (Ex. 1415).
`
`VIII. SPECIFIC GROUNDS FOR PETITION
`
`2 Petitioner adopts the “broadest reasonable construction” standard as required by
`
`37 C.F.R. § 42.100(b). Petitioner reserves the right to pursue different
`
`constructions in a district court, where a different standard is applicable.
`
`- 15 -
`
`

`

`
`
`
`Pursuant to Rule 42.104(b)(4)-(5), the below sections, and as confirmed in
`
`the Kortshagen Declaration (Ex. 1402), demonstrate in detail how the prior art
`
`discloses each and every limitation of Claims 7, 9, 20, 21, 38, and 44 of the ‘779
`
`Patent, and how those claims are rendered obvious by the prior art.3
`
`A. Ground I: Claims 9, 21 and 44 would have been obvious in view
`of Mozgrin, Kudryavtsev, Pinsley and Gruber
`1. Independent claim 1
`
`The preamble: “[a] plasma generator that generates a plasma
`with a multi-step ionization process, the plasma generator
`comprising”
`
`Mozgrin teaches a plasma generator that generates plasma using the power
`
`supply shown in Fig 2. Kortshagen Decl. ¶ 57 (Ex. 1402). The power supply
`
`includes a stationary discharge supply unit, to generate a pre-ionized plasma.
`
`Mozgrin at 401, right col, ¶ 2 (“For pre-ionization… the initial plasma density in
`
`the 109 – 1011 cm-3 range.”) Kortshagen Decl. ¶ 57 (Ex. 1402).
`
`The power supply further includes a high-voltage supply unit, to deliver
`
`voltage pulses to the pre-ionized plasma. See Mozgrin at 401, left col, ¶ 4
`
`(“…applying a square voltage pulse to the discharge gap which was filled up with
`
`3 Petitioner addresses the invalidity of independent claims 1, 18 and 30 in a
`
`separate petition IPR2014-00598. Claims 1, 18 and 30 are addressed herein to
`
`demonstrate the invalidity of claims that depend from claims 1, 18 and 30.
`
`
`
`- 16 -
`
`

`

`
`
`
`either neutral or pre-ionized gas.”) (Ex. 1403). See also Kortshagen Decl. ¶ 58
`
`(Ex. 1402). Mozgrin explains that in “[d]esigning the [pulsed power supply] unit,
`
`we took into account the dependences which had been obtained in [8] of ionization
`
`relaxation on pre-ionization parameters, pressure, and pulse voltage amplitude.”
`
`Mozgrin at 401, ¶ spanning left and right columns (Ex. 1403). The reference [8] is
`
`Kudryavtsev.
`
`Kudryavtsev discloses “multi-step ionization.” It would have been obvious
`
`for one of ordinary skill to combine Mozgrin with Kudryavtsev. See also
`
`Kortshagen Decl. ¶ 59 (Ex. 1402). In addition to the fact that Mozgrin itself cites
`
`Kudryavtsev and Mozgrin explicitly notes that its power supply unit was designed
`
`in accordance with Kudryavtsev, Kudryavtsev also states, “[s]ince the effects
`
`studied in this work are characteristic of ionization whenever a field is suddenly
`
`applied to a weakly ionized gas, they must be allowed for when studying emission
`
`mechanisms in pulsed gas lasers, gas breakdown, laser sparks, etc.” Kudryavtsev
`
`at 34, right col, ¶ 4 (Ex. 1404). Because Mozgrin applies voltage pulses that
`
`“suddenly generate an electric field,” one of ordinary skill reading Mozgrin would
`
`have been motivated to consider Kudryavtsev to further appreciate the effects of
`
`applying Mozgrin’s pulses. Kortshagen Decl. ¶ 59 (Ex. 1402).
`
`Kudryavtsev explains the contribution of multi-step ionization to the overall
`
`ionization process. Id. at ¶ 60 (Ex. 1402). Referring to the annotated copy of
`
`- 17 -
`
`

`

`Kudryavtsev’s Fig. 1 copied below, ionization occurs with an initial “slow stage”
`
`
`
`
`(Fig 1a) followed by a
`
`“fast stage” (Fig. 1b).
`
`Kudryavtsev at 31,
`
`right col, ¶ 7 (Ex.
`
`1404) (“The behavior of the increase in ne with time thus enables us to arbitrarily
`
`divide the ionization process into two stages, which we will call the slow and fast
`
`growth stages. Fig. 1 illustrates the relationships between the main electron
`
`currents in terms of the atomic energy levels during the slow and fast stages.”).
`
`See also Kortshagen Decl. ¶ 60 (Ex. 1402).
`
`During the initial slow stage, direct ionization provides a significant
`
`contribution to the generation of plasma ions (see arrow Γ1e colored in green
`
`showing ionization (top line labeled “e”) from the ground state (bottom line
`
`labeled “1”)). Id. at ¶ 61 (Ex. 1402). In addition, during the slow stage, excited
`
`atoms are also created within the plasma chamber (see arrow Γ12 colored in blue
`
`showing excitation into lowest excited state (middle line labeled “2”) from the
`
`ground state (bottom line labeled “1”)). Id. (Ex. 1402). Once the population of
`
`excited atoms becomes large enough, fast stage occurs, as shown in Fig. 1b. As
`
`shown, multi-step (or “stepwise”) ionization, which occurs through the generation
`
`of excited atoms (see arrow Γ12 colored in blue), becomes the dominant ionization
`
`- 18 -
`
`

`

`
`
`
`process as shown by the thick arrow labeled Γ2e ((colored in red) showing
`
`ionization (top line labeled “e”) from the lowest excited state (middle line labeled
`
`“2”)). See also Kudryavtsev at Fig. 6 (Ex. 1404); see also Kortshagen Decl. ¶ 61
`
`(Ex. 1402). The thin arrows labeled Γ1e show that direct ionization produces ions
`
`at a roughly constant rate in both the slow and fast stages. Id. (Ex. 1402). The
`
`thick arrow labeled Γ2e in Fig. 1b shows that multi-step ionization can produce ions
`
`at a much greater rate than direct ionization. Id. (Ex. 1402).
`
`Kudryavtsev explains the rapid increase in ionization once multi-step
`
`ionization becomes the dominant process as follows: “For nearly stationary n2
`
`[excited atom density] values … there is an explosive increase in ne [plasma
`
`density]. The subsequent

This document is available on Docket Alarm but you must sign up to view it.


Or .

Accessing this document will incur an additional charge of $.

After purchase, you can access this document again without charge.

Accept $ Charge
throbber

Still Working On It

This document is taking longer than usual to download. This can happen if we need to contact the court directly to obtain the document and their servers are running slowly.

Give it another minute or two to complete, and then try the refresh button.

throbber

A few More Minutes ... Still Working

It can take up to 5 minutes for us to download a document if the court servers are running slowly.

Thank you for your continued patience.

This document could not be displayed.

We could not find this document within its docket. Please go back to the docket page and check the link. If that does not work, go back to the docket and refresh it to pull the newest information.

Your account does not support viewing this document.

You need a Paid Account to view this document. Click here to change your account type.

Your account does not support viewing this document.

Set your membership status to view this document.

With a Docket Alarm membership, you'll get a whole lot more, including:

  • Up-to-date information for this case.
  • Email alerts whenever there is an update.
  • Full text search for other cases.
  • Get email alerts whenever a new case matches your search.

Become a Member

One Moment Please

The filing “” is large (MB) and is being downloaded.

Please refresh this page in a few minutes to see if the filing has been downloaded. The filing will also be emailed to you when the download completes.

Your document is on its way!

If you do not receive the document in five minutes, contact support at support@docketalarm.com.

Sealed Document

We are unable to display this document, it may be under a court ordered seal.

If you have proper credentials to access the file, you may proceed directly to the court's system using your government issued username and password.


Access Government Site

We are redirecting you
to a mobile optimized page.





Document Unreadable or Corrupt

Refresh this Document
Go to the Docket

We are unable to display this document.

Refresh this Document
Go to the Docket