`
`UNITED STATES PATENT AND TRADEMARK OFFICE
`________________
`
`BEFORE THE PATENT TRIAL AND APPEAL BOARD
`________________
`
`FUJITSU SEMICONDUCTOR LIMITED,
`FUJITSU SEMICONDUCTOR AMERICA, INC.,
`ADVANCED MICRO DEVICES, INC., RENESAS ELECTRONICS
`CORPORATION, RENESAS ELECTRONICS AMERICA, INC.,
`GLOBALFOUNDRIES U.S., INC., GLOBALFOUNDRIES DRESDEN
`MODULE ONE LLC & CO. KG, GLOBALFOUNDRIES DRESDEN
`MODULE TWO LLC & CO. KG, TOSHIBA AMERICA ELECTRONIC
`COMPONENTS, INC., TOSHIBA AMERICA INC., TOSHIBA
`AMERICA INFORMATION SYSTEMS, INC.,
`TOSHIBA CORPORATION, and
`THE GILLETTE COMPANY,
`Petitioners,
`
`v.
`
`ZOND, LLC,
`Patent Owner
`________________
`
`IPR2014-008271
`Patent 6,853,142 B2
`
`________________
`
`PETITIONER’S REPLY TO PATENT OWNER’S RESPONSE
`
`
`
`
`1 Cases IPR 2014-00865, IPR 2014-01015, and IPR 2014-01063 have been joined
`with the instant proceeding.
`
`
`
`
`
`Petitioner’s Reply to Patent Owner’s Response
`
`IPR2014-00827
` Patent No. 6,853,142
`
`TABLE OF CONTENTS
`
`TABLE OF AUTHORITIES ................................................................................... iv
`
`PETITIONER’S EXHIBIT LIST .............................................................................. v
`
`I.
`
`INTRODUCTION ............................................................................................... 1
`
`II. CLAIM CONSTRUCTION ................................................................................ 1
`
`A. “Weakly-Ionized Plasma” and “Strongly-Ionized Plasma” ......................... 1
`
`III. RESPONSE TO ARGUMENTS ......................................................................... 2
`
`A. Zond Improperly Confounds the Embodiments of Wang. ........................... 2
`
`B. A person of ordinary skill in the art would have combined Wang and
`Kudryavtsev. ................................................................................................. 3
`
`C. Wang in view of Kudryavtsev teaches “a cathode that is positioned
`adjacent to the anode and forming a gap there between” recited in claim
`21. ................................................................................................................. 6
`
`D. Wang in view of Kudryavtsev teaches “the power supply generates a
`constant power” recited in claim 22, “applying the electric field at a
`constant power” recited in claim 33, and “the power supply generates a
`constant voltage” recited in claims 23 and 34. ............................................. 9
`
`E. Wang in view of Kudryavtsev teaches “a pulsed electric field” recited
`in claim 25. ................................................................................................. 11
`
`F. Wang in view of Kudryavtsev teaches “the ionization source is chosen
`from the group comprising an electrode coupled to a DC power supply”
`recited in claim 29. ..................................................................................... 12
`
`
`
`ii
`
`
`
`
`Petitioner’s Reply to Patent Owner’s Response
`
`IPR2014-00827
` Patent No. 6,853,142
`
`G. Wang in view of Kudryavtsev teaches “selecting at least one of a pulse
`amplitude and a pulse width of the electrical pulse in order to increase
`an ionization rate of the strongly-ionized plasma” recited in claim 36. ..... 12
`
`IV. CONCLUSION .................................................................................................. 15
`
`Certificate of Service .............................................. Error! Bookmark not defined.
`
`
`
`
`
`
`
`iii
`
`
`
`
`Petitioner’s Reply to Patent Owner’s Response
`
`IPR2014-00827
` Patent No. 6,853,142
`
`TABLE OF AUTHORITIES
`
`Cases
`
`In re Mouttet, 686 F.3d 1322, 1332 (Fed. Cir. 2012) ................................................ 5
`
`Rules
`
`37 C.F.R. § 42.23 ............................................................................................................. 1
`
`
`
`
`
`
`
`
`
`iv
`
`
`
`
`Petitioner’s Reply to Patent Owner’s Response
`
`IPR2014-00827
` Patent No. 6,853,142
`
`PETITIONER’S EXHIBIT LIST
`
`
`
`April 16, 2015
`
`Exhibit
`1301
`
`Description
`U.S. Patent No. 6,853,142 (“’142 Patent”)
`
`1302
`
`1303
`
`1304
`
`1305
`
`1306
`
`1307
`
`1308
`
`1309
`
`1310
`
`1311
`
`1312
`
`Kortshagen Declaration (“Kortshagen Decl.”)
`
`D.V. Mozgrin, et al, High-Current Low-Pressure Quasi-Stationary
`Discharge in a Magnetic Field: Experimental Research, Plasma Physics
`Reports, Vol. 21, No. 5, pp. 400-409, 1995 (“Mozgrin”)
`
`A. A. Kudryavtsev and V.N. Skerbov, Ionization relaxation in a plasma
`produced by a pulsed inert-gas discharge, Sov. Phys. Tech. Phys. 28(1),
`pp. 30-35, January 1983 (“Kudryavtsev”)
`
`U.S. Pat. No. 6,413,382 (“Wang”)
`
`File History for U.S. Pat. No. 6,853,142, Office Action dated October 7,
`2003 (“10/07/03 Office Action”)
`
`File History for U.S. Pat. No. 6,853,142, Response dated March 8, 2004
`(“03/08/04 Response”)
`
`File History for U.S. Pat. No. 6,853,142, Notice of Allowance dated
`March 29, 2004 (“03/29/04 Allowance”)
`
`04/21/08 Response in EP 1560943
`
`U.S. Patent No. 7,147,759 (“’759 Patent”)
`
`File History for U.S. Pat. No. 7,147,759, Response dated May 2, 2006
`(“05/02/06 Response of ‘759 Patent File History”)
`
`Plasma Etching: An Introduction, by Manos and Flamm, Academic
`Press (1989) (“Manos”)
`
`1313
`
`The Materials Science of Thin Films, by Ohring M., Academic Press
`
`
`
`v
`
`
`
`
`Petitioner’s Reply to Patent Owner’s Response
`
`IPR2014-00827
` Patent No. 6,853,142
`
`(1992) (“Ohring”)
`
`1314
`
`1315
`
`1316
`
`1317
`
`1318
`
`1319
`
`1320
`
`1321
`
`
`Claim Chart Based on Mozgrin and Kudryavtsev as used in 1:13-cv-
`11570-RGS (“Claim Chart based on Mozgrin and Kudryavtsev”)
`
`Claim Chart Based on Wang and Kudryavtsev as used in 1:13-cv-
`11570-RGS (“Claim Chart based on Wang and Kudryavtsev”)
`
`Affidavit of Mr. Fitzpatrick in Support of Motion for Pro Hac Vice
`Admission
`
`Rismiller Declaration ISO Motion for PHV Admission of Brett C
`Rismiller
`
`Declaration of Dr. Lawrence J. Overzet (“Overzet Decl.”)
`
`Dr. Hartsough Deposition Transcript for U.S. Patent No. 6,853,142
`
`Dr. Hartsough Deposition Transcript for U.S. Patent No. 6,896,775
`
`Dr. Hartsough Deposition Transcript for U.S. Patent No. 7,808,184
`
`
`
`
`vi
`
`
`
`
`Petitioner’s Reply to Patent Owner’s Response
`
`IPR2014-00827
` Patent No. 6,853,142
`
`I.
`
`INTRODUCTION
`
`Petitioner submits this reply under 37 C.F.R. § 42.23 in response to Zond’s
`
`Response to Petition filed on January 2, 2015 (“Response,” Paper No. 26). The
`
`evidence and arguments in this reply confirm the Board’s initial determination that
`
`claims 22, 23, 25, 29, 30, 33-36, 39, and 43 of the ’142 Patent are rendered obvious
`
`over the prior art of record and thus should be canceled.
`
`Indeed, the ’142 Patent presents nothing novel; and Zond’s own declarant
`
`Dr. Hartsough concedes that the limitations in the claims were well known before
`
`the effective date of the ’142 Patent. See e.g., Ex. 1319 at 30:3-35:21.
`
`II. CLAIM CONSTRUCTION
`A.
`“Weakly-Ionized Plasma” and “Strongly-Ionized Plasma”
`The Board construed the term strongly-ionized plasma to mean a plasma with a
`
`relatively high peak density of ions and the term weakly-ionized plasma to mean a
`
`plasma with a relatively low peak density of ions. Petitioners and their experts agree
`
`with this construction. Ex. 2010 at 25:25-26:23; Ex. 1318, ¶¶ 23-30. This construction
`
`is consistent with the ’142 Patent in that it does not require any specific or quantified
`
`difference in magnitude between the peak ion densities of the weakly-ionized plasma
`
`and the strongly-ionized plasma. Ex. 1318, ¶¶ 28-29. Also, Zond’s declarant, Dr.
`
`Hartsough, agrees with the Board’s construction and concedes that there is “not a
`
`magic number that one can arbitrarily say across all conditions as to what’s a weakly
`
`
`
`1
`
`
`
`
`Petitioner’s Reply to Patent Owner’s Response
`
`IPR2014-00827
` Patent No. 6,853,142
`
`ionized plasma or a strongly ionized plasma.” Ex. 1321 at 60:5-8; 63:7-10.
`
`III. RESPONSE TO ARGUMENTS
`A. Zond Improperly Confounds the Embodiments of Wang.
`Zond’s arguments directed to Wang are flawed, for among other reasons,
`
`because throughout they indiscriminately transition between two different
`
`embodiments of Wang – applying statements directed from one embodiment (Fig.
`
`4) to another embodiment (Fig. 6). Ex. 1318, ¶ 53.
`
`
`
`Ex. 1305, Figs 4 and 6 (annotated); Ex. 1318, ¶ 53.
`
`Wang shows and discusses a system diagram of a magnetron sputter reactor
`
`in Fig. 1, and then in connection with Figs. 4 and 6, shows and discusses two
`
`different embodiments, respectively, of pulsing a target in the reactor of Fig. 1. See
`
`Ex. 1305 at 3:37-50. These two separate and distinct embodiments are illustrated in
`
`the figures reproduced above. Further, Dr. Overzet provides a chart summarizing
`
`
`
`2
`
`
`
`
`Petitioner’s Reply to Patent Owner’s Response
`
`IPR2014-00827
` Patent No. 6,853,142
`
`the difference between these two embodiments, including the portion cited below.
`
`Ex. 1318, ¶¶ 54-58.
`
`
`
`Wang embodiment of Fig. 4
`
`Wang embodiment of Fig. 6
`
`Internal
`impedance
`
`“[C]hamber impedance
`dramatically changes.” Wang
`at 5:29-30, 52-53.
`
`“[C]hamber impedance changes
`relatively little ….” Wang at 7:49-
`51.
`
`Power
`Pulse or
`Voltage
`Pulse
`
`Arcing
`
`“Where chamber impedance
`is changing, the power pulse
`width is preferably specified
`rather than the current or
`voltage pulse widths.” Wang
`at 5:52-54.
`
`Where chamber impedance changes
`“relatively little,” there is no
`preference to specify power pulse
`over current or voltage pulse. See
`Wang at 7:49-51.
`
`Tendency to arc during
`ignition/generation of strongly
`ionized plasma: See Wang at
`7:1-12.
`
`Arcing is avoided during ignition
`and during generation of strongly
`ionized plasma. See Wang at 7:26-
`28, 47-48.
`
`B. A person of ordinary skill in the art would have combined Wang
`and Kudryavtsev.
`
`Zond makes numerous arguments as to why a person of ordinary skill in the
`
`art would not combine Wang and Kudryavtsev. Response at 25-34. All of these
`
`arguments are based on nothing more than the alleged differences between the
`
`physical systems of Wang and Kudryavtsev and focus on bodily incorporating their
`
`systems. This is not the proper standard for determining obviousness. In re
`
`Mouttet, 686 F.3d 1322, 1332 (Fed. Cir. 2012) (“It is well-established that a
`
`determination of obviousness based on teachings from multiple references does not
`
`
`
`3
`
`
`
`
`Petitioner’s Reply to Patent Owner’s Response
`
`IPR2014-00827
` Patent No. 6,853,142
`
`require an actual, physical substitution of elements.”). And Zond’s declarant, Dr.
`
`Hartsough, concedes that a person of ordinary skill in the art would have
`
`understood how physical differences (such as pressure, chamber geometry, gap
`
`dimensions, magnetic field) would affect a system and understood how to adjust
`
`for such differences. Ex. 1319 at 75:24-80:2. As further discussed below, a person
`
`of ordinary skill in the art would be encouraged to combine the teachings of the
`
`Wang and Kudryavtsev. See also Ex. 2011 at 171:14-21.
`
`Kudryavtsev is a study of the behavior of plasma, and modeling such
`
`behavior, which is general in its application. Ex. 1318, ¶ 61. Kudryavtsev applies
`
`its theory to an experimental embodiment. Id.; see also Ex. 1304, Abstract.
`
`Kudryavtsev’s theoretical framework is not intended to be limited in application to
`
`any specific type of apparatus (flash tube or otherwise) within which plasma is
`
`discharged. Ex. 1318, ¶ 61. In fact, while Kudryavtsev may have utilized a
`
`particular experiment to verify the disclosed model and “show[] that the electron
`
`density increases explosively in time,” Kudryavtsev provides general teachings
`
`that are applicable “whenever a field is suddenly applied to a weakly ionized
`
`gas.” Id.; see also Ex. 1304 at Abstract; p. 34, right col., ¶ 4 (emphasis added).
`
`Wang is directed to a specific application of a plasma reactor—a pulsed
`
`sputtering reactor with a small rotating magnetron. Ex. 1305, Abstract. Like
`
`Kudryavtsev, Wang teaches a pulsed power supply. Ex. 1318, ¶ 62. During peak
`4
`
`
`
`
`
`
`Petitioner’s Reply to Patent Owner’s Response
`
`IPR2014-00827
` Patent No. 6,853,142
`
`power PP, Wang suddenly applies an electric field by way of a “negative voltage
`
`pulse” to “quickly cause[] the already existing [weakly ionized] plasma to
`
`spread and increase[] the density of the plasma.” Id.; see also Ex. 1305 at 7:29-
`
`30; 7:62 (emphasis added). In view of Wang’s application, a person of ordinary
`
`skill in the art would have looked to Kudryavtsev to understand how plasma would
`
`react to a quickly applied voltage pulse, and how to achieve an explosive increase
`
`in electron density (if not already experienced) while generating strongly ionized
`
`plasma. Ex. 1318, ¶ 62. In short, Kudryavtsev is useful for describing how a
`
`voltage pulse, such as Wang’s voltage pulse, operates and how to adjust voltage
`
`amplitude and duration in order to increase the ionization rate so that a rapid
`
`increase in electron density and the formation of a strongly ionized plasma occurs,
`
`for the benefit of improved sputtering and manufacturing processing capabilities.
`
`Id.
`
`Whether there are differences in the systems of Wang and Kudryavtsev is
`
`inconsequential. Ex. 1318, ¶ 63. A person of ordinary skill in the art still would
`
`have known how to apply the teachings of Kudryavtsev to systems such as Wang’s
`
`(i.e., for performing sputtering, irrespective of different pressures, different
`
`dimensions, different sizes, magnets, and/or other feature differences). Id.
`
`Differences in such systems are routine and a person of ordinary skill in the art
`
`would work with such differences on a regular basis, and would consider it routine
`5
`
`
`
`
`
`
`Petitioner’s Reply to Patent Owner’s Response
`
`IPR2014-00827
` Patent No. 6,853,142
`
`to make any necessary changes to accommodate for any and all such variables. Id.;
`
`see also Ex. 1319 at 75:24-80:2. In fact, Mozgrin is evidence that those of
`
`ordinary skill in the art not only would, but actually did look to and apply the
`
`teachings of Kudryavtsev to systems similar to Wang’s. Ex. 1318, ¶ 64; Ex. 1303
`
`at p. 401 ¶ spanning left and right cols.
`
`Finally, it is not necessary to conduct actual experiments in order to
`
`conclude that Wang and Kudryavtsev are combinable. See Response at 33-34; Ex.
`
`1318, ¶ 65. While the application of Kudryavtsev’s teachings to Wang is
`
`straightforward and easily combinable for a person of ordinary skill in the art,
`
`conducting actual experiments may inevitably take more time, such as to carry out
`
`routine characterization of this system in order to ready it for manufacturing (e.g.,
`
`performing design of experiments (DOE)) and the like. Ex. 1318, ¶ 65; Ex. 1321 at
`
`132:5-135:23. To characterize the system of the ’142 Patent for manufacturing
`
`would take a similar amount of time (e.g., including time for performing a DOE).
`
`Ex. 1318, ¶ 65. Therefore, and contrary to Zond’s argument, a person of ordinary
`
`skill in the art would have combined the teachings of Wang and Kudryavtsev.
`
`C. Wang in view of Kudryavtsev teaches “a cathode that is
`positioned adjacent to the anode and forming a gap there between”
`recited in claim 21.
`
`With regard to claim 21, Zond argues that Wang does not teach a gap.
`
`Response at 35-37. However, with regard to claim 28 (which depends from claim
`6
`
`
`
`
`
`
`Petitioner’s Reply to Patent Owner’s Response
`
`IPR2014-00827
` Patent No. 6,853,142
`
`21), Zond concedes that “Wang’s device has a gap of 14-29 cm and that longer
`
`gaps give the best distribution.” Response at 53 (IPR2014-00819). Zond then cites
`
`its own declarant for support that Wang has a gap. Id. (citing Ex. 2005, ¶ 138).
`
`Therefore, Zond agrees that Wang teaches a gap.
`
`As to a particular gap size, Zond’s declarant, Dr. Hartsough, concedes that
`
`the claims are not “limited to a gap size of .3 to 10 centimeters.” Ex. 1320 at
`
`64:17-65:15. Dr. Hartsough also indicated that “there are other distances of the …
`
`gap” and that the gap can be measured diagonally from the edge of the anode to the
`
`cathode. Ex. 1320 at 21:5-6 (and Deposition Exhibit 1028); see also Ex. 2011 at
`
`130:1-15. As such, Wang’s gap, when measured from the wall of the anode 24 to
`
`the cathode/target 14, results in a dimension less than 10cm.
`
`Zond also argues that Wang does not teach a gap because it does not teach
`
`that any plasma is positioned between its cathode and the anode. Response at 36.
`
`However, in Wang the cathode is part of the target 14 and it is separated from the
`
`anode 24 by a gap. Ex. 1318, ¶ 124. For example, Fig. 1 of Wang clearly shows
`
`that target 14 is directly connected to the pulsed DC supply 80. Ex. 1305, Fig. 1;
`
`see also Ex. 1318, ¶ 124. The DC supply 80 “biases the target 14 to between about
`
`-300 to -700VDC to support a plasma of the argon working gas.” Ex. 1305 at 4:13-
`
`15. The other electrode of Wang’s power supply 80 is connected to the anode 24,
`
`illustrated as a common ground connection in Figure 1. Ex. 1305, Fig. 1; see also
`7
`
`
`
`
`
`
`Petitioner’s Reply to Patent Owner’s Response
`
`IPR2014-00827
` Patent No. 6,853,142
`
`Ex. 1318, ¶ 125. An electric field is formed between the two electrodes. Ex. 1305
`
`at 3:64–4:5; see also Ex. 1318, ¶ 125. And, the electric field forms plasma 42
`
`between the cathode and the anode.
`
`Zond additionally argues that Wang’s floating shield 26 makes the anode 24
`
`and cathode 14 not adjacent. Response at 36. However, and contrary to Zond’s
`
`argument, the vast majority of Wang’s gap between the anode 24 and cathode 14 is
`
`not blocked by the floating shield 26. And, Zond’s declarant Dr. Hartsough
`
`concedes that although an electrode may partially block an anode and cathode, the
`
`other portions of the anode and cathode are considered adjacent nonetheless. Ex.
`
`1320 at 75:23-76:8.
`
`Furthermore, while the target/cathode in Wang may be structurally different
`
`than the cathode in the ’142 Patent, it was commonly known to have the cathode
`
`separated from the target, as shown in the ’142 Patent. Ex. 1318, ¶ 126. Dr.
`
`Kortshagen provides examples in his earlier-filed declaration, but one simple
`
`example is the “Prior Art” Fig. 1 of the ’142 Patent, showing the gap between the
`
`anode 130 and the cathode 114. Id. It therefore would have been obvious for Wang
`
`to have a separate cathode from the target, if such is deemed to be a requirement of
`
`the claims. Id. Positioning the target (separated from the cathode) and all of the
`
`other components of Wang’s reactor, including the floating shield 26, would be a
`
`routine course of engineering for one of ordinary skill in the art. Id.
`8
`
`
`
`
`
`
`Petitioner’s Reply to Patent Owner’s Response
`
`IPR2014-00827
` Patent No. 6,853,142
`
`D. Wang in view of Kudryavtsev teaches “the power supply
`generates a constant power” recited in claim 22, “applying the electric
`field at a constant power” recited in claim 33, and “the power supply
`generates a constant voltage” recited in claims 23 and 34.
`
`Zond argues that Wang does not teach a constant power or a constant voltage.
`
`Response at 40-46. However, Zond’s argument is contradicted by its own
`
`declarant, Dr. Hartsough, who concedes that Wang’s power supply generates a
`
`constant power: “Wang’s power supply 80 emits a series of [voltage] pulses as
`
`shown [in Fig. 7], wherein the power supplies tries to maintain a constant power
`
`level [as shown in Fig. 6].” Ex. 2005, ¶ 57. Dr. Hartsough also concedes that in
`
`systems like Wang’s where “the chamber impedance changes relatively little
`
`between,” “voltage would approach a constant value.” Ex. 1321 at 152:4-6; Ex.
`
`1305 at 7:49-51.
`
`Dr. Hartsough further concedes that the typical power supply described by
`
`Wang operates exactly as how Fig. 5 of the ’775 Patent operates. Ex. 1320 at
`
`149:17-150:20 (“…Q: So we can agree that Wang is explaining how a typical
`
`pulsed power supply operates; right? A: Yes … Q: And that’s exactly what
`
`Figure 5 of the ‘775 patent is showing; right? … A: Yes.”). Notably, Fig. 5 of
`
`the ’775 Patent is the same as Fig. 4 of the ’142 Patent, which Dr. Hartsough
`
`concedes operates in “power mode.” Ex. 1319 at 45:10-13.
`
`
`
`9
`
`
`
`
`Petitioner’s Reply to Patent Owner’s Response
`
`IPR2014-00827
` Patent No. 6,853,142
`
`And, when discussing constant voltage or constant power, the’142 Patent
`
`refers to a subset of a voltage or power signal, as shown in Fig. 4, reproduced and
`
`annotated below. “At time t1, the current 328 and the power 330 have constant
`
`value.” Ex. 1301 at 12:64-66. Time t1 in the graphs, below, is a single point in
`
`time that is exactly aligned with the vertical axis. Ex. 1318, ¶ 115. The circled
`
`portions of the waveforms, for instance, show them being constant for a period of
`
`time.
`
`Ex. 1301, Fig. 4 (annotated); Ex. 1305, Figs. 6 and 7 (annotated).
`
`
`
`Figs. 6 and 7 of Wang, above, show similar wave forms as Fig. 4 of the ’142
`
`Patent. In fact, Wang’s wave forms, like the ’142 Patent, include portions that are
`
`of “constant power” and “constant voltage.” Ex. 1318, ¶¶ 115-117. For example,
`
`during the PB phase, shown in Figure 6, Wang states that the DC power supply
`10
`
`
`
`
`
`
`Petitioner’s Reply to Patent Owner’s Response
`
`IPR2014-00827
` Patent No. 6,853,142
`
`“supplies an essentially constant negative voltage” and during the PP phase Wang
`
`at Fig. 7 illustrates that the voltage pulses have a constant amplitude. Ex. 1305 at
`
`7:57-61; Fig. 7 (emphasis added); Ex. 1318, ¶ 117; see also Ex. 2011 at 179:12-
`
`180:2.
`
`Moreover, Zond’s assertion that Wang’s pulse is a full width at half
`
`maximum does not mean that the power is always changing. Ex. 1318, ¶ 118. In
`
`fact, for a majority of time (except for transitions between background power PB
`
`and peak power PP, where the state of the plasma changes), Wang’s power and
`
`voltage will be constant. Ex. 1318, ¶ 119.
`
`E. Wang in view of Kudryavtsev teaches “a pulsed electric field”
`recited in claim 25.
`
`Zond argues that “absent from the Petition is any explanation as to how
`
`Wang’s disclosure of a voltage pulse could possibly teach or suggest a claim
`
`limitation requiring a pulsed electric field.” Response at 46. It appears that Zond
`
`admits that Wang produces voltage pulses, but argues that voltage pulses do not
`
`result in a pulsed electric field. Ex. 1318, ¶ 113. Notably, Zond’s declarant, Dr.
`
`Hartsough, does not support this position and concedes that “if the voltage is
`
`pulsed, then the electric field will be pulsed.” Ex. 1319 at 101:3-6. Thus, it is a
`
`basic principle of physics, and a person of ordinary skill in the art would have
`
`
`
`11
`
`
`
`
`Petitioner’s Reply to Patent Owner’s Response
`
`IPR2014-00827
` Patent No. 6,853,142
`
`understood, that voltage pulses (like Wang’s “train of negative voltage pulses,” see
`
`Ex. 1305 at 7:61-63) generate a pulsed electric field. Ex. 1318, ¶ 113.
`
`F. Wang in view of Kudryavtsev teaches “the ionization source is
`chosen from the group comprising an electrode coupled to a DC power
`supply” recited in claim 29.
`
`Zond argues that an anode and cathode are not electrodes and that the
`
`claimed electrode is a “filament.” Response at 47-49. Zond’s argument is
`
`contradicted by its declarant, Dr. Hartsough, who concedes that under the
`
`“broadest possible interpretation, ‘electrode’ would include . . . other electrodes
`
`in the system” including “the anode and the cathode.” Ex. 1319 at 98:17-99:15.
`
`Dr. Overzet confirms this understanding. Ex. 1318, ¶ 128.
`
`G. Wang in view of Kudryavtsev teaches “selecting at least one of a
`pulse amplitude and a pulse width of the electrical pulse in order to
`increase an ionization rate of the strongly-ionized plasma” recited in
`claim 36.
`
`Zond argues that Wang in view of Kudryavtsev does not teach this claimed
`
`feature. See Response at 50-51; Ex. 2005, ¶ 150. Zond is incorrect because Wang
`
`is specifically directed to obtaining a target power of its pulses to increase the
`
`ionization rate of its strongly-ionized plasma. A power pulse, which is an electrical
`
`pulse, will have a corresponding voltage pulse with an amplitude and a width. Ex.
`
`1318, ¶ 90.
`
`
`
`12
`
`
`
`
`Petitioner’s Reply to Patent Owner’s Response
`
`IPR2014-00827
` Patent No. 6,853,142
`
`Wang teaches selecting and delivering a voltage pulse corresponding to a
`
`power pulse PP that is to be provided by a power supply 80. Ex. 1318, ¶ 91. The
`
`shape of the power pulse PP is controlled in two ways. First, Wang teaches using a
`
`voltage with a magnitude (amplitude) that is selected and delivered during the
`
`peak power pulse PP, as compared to the background pulse PB. See e.g., id.; Ex.
`
`1305 at 9:38-40 and Fig. 7. This voltage amplitude PP “is at least 10 times the
`
`background power PB, … and most preferably 1000 times . . . .” Ex. 1305 at 7:19-
`
`22; see also Ex. 1318, ¶ 91. Second, Wang teaches that “[t]he choice of pulse
`
`widths τw is dictated by considerations of both power supply design, radio
`
`interference, and sputtering process conditions. Typically, it should be at least 50
`
`µs . . . but it is anticipated that for most applications it will be less than 1 ms.” Ex.
`
`1305 at 5:43-48. A representation of the pulse width τw is represented in Figures 6
`
`and 7 of Wang:
`
`Id. at Figs. 6 and 7; Ex. 1318, ¶ 92.
`
`
`
`
`
`13
`
`
`
`
`Petitioner’s Reply to Patent Owner’s Response
`
`IPR2014-00827
` Patent No. 6,853,142
`
`Wang selects the voltage amplitude and chooses the pulse width for the
`
`specific purpose of increasing an ionization rate of the strongly-ionized plasma.
`
`Ex. 1318, ¶ 93. In fact, Wang specifically teaches that “a very high plasma density
`
`is produced during the pulse,” (Ex. 1305 at Abstract), and that “the application of
`
`the high peak power PP instead quickly causes the already existing plasma to
`
`spread and increases the density of the plasma.” Ex. 1305 at 7:28-30; see also
`
`5:78. Dr. Hartsough concedes that “if you have a quick increase in the plasma
`
`density, … that indicate[s] a quick increase in the rate of ionization.” Ex. 1321
`
`at 88:22-90:3. Thus, a person of ordinary skill in the art would have recognized
`
`that Wang is choosing the voltage pulse amplitude and width to increase the
`
`ionization rate of its strongly-ionized plasma. Ex. 1318, ¶ 93.
`
`This operation of providing a voltage pulse (as shown in Wang Fig. 7) is
`
`also discussed in Kudryavtsev. The shape of the voltage pulse will directly impact
`
`the shape of the resulting current. Specifically, Kudryavtsev teaches to choose a
`
`voltage pulse with an amplitude and a width such that at a time tS after the
`
`voltage pulse, current increases along with the ionization rate of the strongly
`
`ionized plasma. See, e.g., Ex. 1304 at p. 31, Fig. 2 (reproduced and discussed
`
`above); see also Fig. 1; Abstract (“the electron density increases explosively in
`
`time.”); Ex. 1318, ¶ 94.
`
`
`
`14
`
`
`
`
`Petitioner’s Reply to Patent Owner’s Response
`
`IPR2014-00827
` Patent No. 6,853,142
`
`The ionization rate for the strongly-ionized plasma is higher than the
`
`ionization rate for the weakly-ionized plasma. As Kudryavtsev explains, the ion
`
`density (dne/dt) is a function of ionization production minus ionization loss. See,
`
`e.g., Ex. 1304 at p. 30, equation (1); Ex. 1318, ¶ 95. For high-density plasma, the
`
`rate of ion production (ionization rate) will be greater than the rate of ion
`
`production for low-density plasma. Ex. 1318, ¶ 95. Combining the teachings of
`
`Wang and Kudryavtsev is discussed in the original declaration of Dr. Kortshagen
`
`as well as the declaration of Dr. Overzet. Ex. 1318, ¶ 94.
`
`It is noted that Zond made an analogy comparing ionization rate to flowing
`
`water through a hose into a bucket. IPR2014-00821, Response at p. 52 (Paper No.
`
`26). This is a bad analogy because it does not account for ionization loss. See Ex.
`
`1318, ¶ 95 (footnote 2).
`
`IV. CONCLUSION
`For the reasons set forth in the Petition and above, claims 22, 23, 25, 29, 30,
`
`33-36, 39, and 43, of the ’142 Patent are unpatentable and should be canceled.
`
`
`
`
`
`Dated: April 16, 2015
`
`
`
`
`
`
`
`
`
`
`
`Respectfully submitted,
`
`
`
` /s/ David M. Tennant
`David M. Tennant
`Registration No. 48,362
`Lead Counsel for Petitioner
`GlobalFoundries
`
`15
`
`
`
`
`
`CERTIFICATE OF SERVICE
`
`The undersigned certifies, in accordance with 37 C.F.R. § 42.105, that
`
`service was made on the Patent Owner as detailed below.
`
`Date of service April 16, 2015
`
`Manner of service Electronic Mail
`
`Documents served Petitioner’s Reply to Patent Owner’s Response;
`
`Exhibits 1318 - 1321; and
`
`Petitioner’s Exhibit List of April 16, 2015
`
`Persons served
`
`
`
`
`
`Dr. Gregory Gonsalves
`2216 Beacon Lane
`Falls Church, Virginia 22043
`
`Bruce Barker
`Chao Hadidi Stark & Barker LLP
`176 East Mail Street, Suite 6
`Westborough, MA 01581
`
`
`/s/ Anna Goodall
`
`
`
`
`
`Anna Goodall
`White & Case LLP
`3000 El Camino Real
`Five Palo Alto Square, 9th Floor
`Palo Alto, CA 94306
`Tel: (650) 213-0367
`Email: agoodall@whitecase.com
`
`
`
`
`
`
`