`571-272-7822
`
`
`
` Paper 9
`
`Entered: October 20, 2014
`
`
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`
`
`UNITED STATES PATENT AND TRADEMARK OFFICE
`____________
`
`BEFORE THE PATENT TRIAL AND APPEAL BOARD
`____________
`
`
`
`TAIWAN SEMICONDUCTOR MANUFACTURING COMPANY, LTD.
`and TSMC NORTH AMERICA CORP.,
`Petitioners,
`
`v.
`
`ZOND, LLC,
`Patent Owner.
`____________
`
`Case IPR2014-00821
`Patent 6,853,142 B2
`____________
`
`
`
`Before KEVIN F. TURNER, DEBRA K. STEPHENS, JONI Y. CHANG,
`SUSAN L. C. MITCHELL, and JENNIFER M. MEYER,
`Administrative Patent Judges.
`
`TURNER, Administrative Patent Judge.
`
`
`DECISION
`Institution of Inter Partes Review
`37 C.F.R. § 42.108
`
`
`
`
`
`
`
`IPR2014-00821
`Patent 6,853,142 B2
`
`
`I. INTRODUCTION
`Taiwan Semiconductor Manufacturing Company, Ltd. and TSMC
`North America Corporation (collectively “TSMC”) filed a Petition
`requesting inter partes review of claims 2, 11, 13, 14, and 16 of U.S. Patent
`No. 6,853,142 B2 (“the ’142 Patent”). Paper 2 (“Pet.”). Zond, LLC
`(“Zond”) filed a Preliminary Response. Paper 8 (“Prelim. Resp.”). We have
`jurisdiction under 35 U.S.C. § 314, which provides that an inter partes
`review may not be instituted “unless . . . there is a reasonable likelihood that
`the petitioner would prevail with respect to at least 1 of the claims
`challenged in the petition.”
`Upon consideration of TSMC’s Petition and Zond’s Preliminary
`Response, we conclude that the information presented in the Petition
`demonstrates that there is a reasonable likelihood that TSMC would prevail
`in challenging claims 2, 11, 13, 14, and 16 as unpatentable under 35 U.S.C.
`§ 103(a). Pursuant to 35 U.S.C. § 314, we hereby authorize an inter partes
`review to be instituted as to claims 2, 11, 13, 14, and 16 of the ’142 Patent.
`
`
`A. Related Matters
`TSMC indicates that the ’142 Patent was asserted in Zond, LLC v.
`
`Fujitsu, No.1:13-cv-11634-WGY (D. Mass.), in which TSMC is a co-
`defendant. Pet. 1. TSMC also identifies other matters where Zond asserted
`the claims of the ’142 Patent against third parties, as well as other Petitions
`for inter partes review that are related to this proceeding. Id.
`
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`
`B. The ’142 Patent
`The ’142 Patent relates to methods and apparatus for generating high-
`density plasma. Ex. 1101, Abs. At the time of the invention, sputtering was
`a well-known technique for depositing films on semiconductor substrates.
`Id. at 1:24–25. The ’142 Patent indicates that prior art magnetron sputtering
`systems deposit films having low uniformity and poor target utilization (the
`target material erodes in a non-uniform manner). Id. at 3:32–36. To address
`these problems, the ’142 Patent discloses that increasing the power applied
`between the target and anode can increase the uniformity and density in the
`plasma. Id. at 3:37–44. However, increasing the power also “can increase
`the probability of generating an electrical breakdown condition leading to an
`undesirable electrical discharge (an electrical arc) in the chamber 104.” Id.
`According to the ’142 Patent, forming a weakly-ionized plasma
`substantially eliminates the probability of establishing a breakdown
`condition in the chamber when high-power pulses are applied between the
`cathode and anode. Id. at 6:21–30. Once the weakly-ionized plasma is
`formed, high-power pulses are applied between the cathode and anode to
`generate a strongly-ionized plasma from the weakly-ionized plasma. Id. at
`7:23–36. The ’142 Patent also discloses that the provision of the feed gas to
`the plasma allows for homogeneous diffusion of the feed gas in the weakly-
`ionized plasma and allows for the creation of a highly uniform strongly-
`ionized plasma. Id. at 6:31–35.
`
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`
`C. Illustrative Claims
`Of the challenged claims, all are dependent and all depend from one
`of claims 1 or 10. Claims 10 and 11, reproduced below, are illustrative:
`10. A method for generating a strongly-ionized plasma in a
`chamber, the method comprising:
`ionizing a feed gas to form a weakly-ionized plasma that
`reduces the probability of developing an electrical breakdown
`condition in the chamber;
`supplying power to the weakly-ionized plasma by applying
`an electrical pulse across the weakly-ionized plasma, the
`electrical pulse having a magnitude and a rise-time that is
`sufficient to increase the density of the weakly-ionized plasma
`to generate a strongly-ionized plasma; and
`diffusing the strongly-ionized plasma with additional feed
`gas thereby allowing the strongly-ionized plasma to absorb
`additional energy from the power supply.
`
`11. The method of claim 10 wherein the applying the
`electrical pulse across the weakly-ionized plasma excites atoms
`the weakly-ionized plasma and generates secondary
`in
`electrons, the secondary electrons ionizing the excited atoms,
`thereby creating a strongly-ionized plasma.
`Ex. 1101, 21:13–31 (emphases added).
`
`
`D. Prior Art Relied Upon
`TSMC relies upon the following prior art references:
`Lantsman
`
`US 6,190,512 B1 Feb. 20, 2001
`Wang
`
`
`US 6,413,382 B1 July 2, 2002
`
`
`(Ex. 1104)
`(Ex. 1105)
`
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`Patent 6,853,142 B2
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`
`D.V. Mozgrin, et al., High-Current Low-Pressure Quasi-Stationary
`Discharge in a Magnetic Field: Experimental Research, 21 PLASMA
`PHYSICS REPORTS, NO. 5, 400–409 (1995) (Ex. 1103) (hereinafter
`“Mozgrin”).
`A. A. Kudryavtsev and V.N. Skrebov, Ionization Relaxation in a
`Plasma Produced by a Pulsed Inert-Gas Discharge, 28(1) SOV. PHYS.
`TECH. PHYS. 30–35 (Jan. 1983) (Ex. 1106) (hereinafter “Kudryavtsev”).
`
`D.V. Mozgrin, High-Current Low-Pressure Quasi-Stationary
`Discharge in a Magnetic Field: Experimental Research, Thesis at
`Moscow Engineering Physics Institute (1994) (Ex. 1119) (hereinafter
`“Mozgrin Thesis”).1
`
`
`E. Asserted Grounds of Unpatentability
`TSMC asserts the following grounds of unpatentability:
`
`Claim(s)
`
`Basis
`
`References
`
`14
`13 and 14
`2 and 11
`2 and 11
`13 and 16
`16
`
`
`
`§ 103(a)
`§ 103(a)
`§ 103(a)
`§ 103(a)
`§ 103(a)
`§ 103(a)
`
`Mozgrin and Lantsman
`Wang and Lantsman
`Mozgrin, Lantsman, and Kudryavtsev
`Wang, Lantsman, and Kudryavtsev
`Mozgrin, Lantsman, and Mozgrin Thesis
`Wang, Lantsman, and Mozgrin Thesis
`
`
`1 The Mozgrin Thesis is a Russian-language reference. The citations to the
`Mozgrin Thesis are to the certified English-language translation submitted
`by TSMC (Ex. 1118).
`
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`
`II. ANALYSIS
`A. Printed Publication under 35 U.S.C. § 102
`As an initial matter, we address the issue of whether the Mozgrin
`Thesis is available as prior art under 35 U.S.C. § 102 for the purposes of this
`decision. In its Petition, TSMC asserts that the Mozgrin Thesis is a doctoral
`thesis at Moscow Engineering Physics Institute, published in 1994, and it is
`prior art under 35 U.S.C. § 102(b). Pet. 4. As support, TSMC proffers a
`copy of the catalogue entry for the Mozgrin Thesis at the Russian State
`Library. Ex. 1120.
`Zond responds that TSMC fails to demonstrate the Mozgrin Thesis is
`prior art under 35 U.S.C. § 102. Prelim. Resp. 56–58. Specifically, Zond
`contends that the 2002 date printed below the catalog entry does not
`establish that the Mozgrin Thesis was available publicly prior to the critical
`date (i.e., November 4, 2002—the filing date of the application that issued as
`the ’142 Patent). Id. at 57–58. Zond also alleges that TSMC “did not
`provide any explanation of the meaning of that date, such as whether or not
`it is the date on which the Mozgrin Thesis became accessible to interested
`persons.” Id.
`We are not persuaded by Zond’s arguments, as they are predicated on
`the incorrect assumption that the 2002 date is the publication date of the
`Mozgrin Thesis. As shown in the catalog entry, the 2002 date appears to be
`a claim of copyright in the Ex Libris database from which the catalogue
`entry was retrieved. Ex. 1120, 2. More importantly, the catalog entry
`clearly shows a publication date of 1994 (“Imprint Moscow 1994”). Id. The
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`certified English-language translation of the catalog entry is reproduced
`below (Ex. 1120, 1 (annotation added)):
`
`
`Zond does not address why the 1994 imprint date on the catalog entry
`at the Russian State Library is insufficient to establish that the Mozgrin
`Thesis was accessible publicly before the critical date. See In re Hall,
`781 F.2d 897, 899–900 (Fed. Cir. 1986) (holding a dissertation shelved in
`the stacks and indexed in the catalog at a university library is a printed
`publication under § 102). To the contrary, the catalog entry demonstrates
`that the Mozgrin Thesis was made available to interested persons by virtue
`of its title and “Subject” characterization.
`Given the evidence on this record, we determine that TSMC has
`shown sufficiently that the Mozgrin Thesis is a “printed publication” within
`the meaning of 35 U.S.C. § 102(b). Consequently, the Mozgrin Thesis is
`available as prior art for the purposes of this decision to demonstrate that the
`challenged claims are unpatentable under 35 U.S.C. § 103(a).
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`
`B. Claim Construction
`In an inter partes review, claim terms in an unexpired patent are given
`their broadest reasonable construction in light of the specification of the
`patent in which they appear. 37 C.F.R. § 42.100(b). Claim terms are given
`their ordinary and customary meaning as would be understood by one of
`ordinary skill in the art in the context of the entire disclosure. In re
`Translogic Tech. Inc., 504 F.3d 1249, 1257 (Fed. Cir. 2007). An inventor
`may rebut that presumption by providing a definition of the term in the
`specification with reasonable clarity, deliberateness, and precision. In re
`Paulsen, 30 F.3d 1475, 1480 (Fed. Cir. 1994). In the absence of such a
`definition, limitations are not to be read from the specification into the
`claims. In re Van Geuns, 988 F.2d 1181, 1184 (Fed. Cir. 1993).
`In the instant proceeding, the parties propose claim constructions for
`two claim terms. Pet. 13–15; Prelim. Resp. 19-22. We address the claim
`terms identified by the parties below.
`
`“weakly-ionized plasma” and “strongly-ionized plasma”
`Independent claim 1 recites “the electrical pulse having a magnitude
`and a rise-time that is sufficient to increase the density of the weakly-ionized
`plasma to generate a strongly-ionized plasma,” with independent claim 10
`reciting a similar limitation. All of the challenged claims depend from
`claims 1 or 10.
`TSMC proposes that the claim term “weakly-ionized plasma” should
`be interpreted as “a lower density plasma,” and that the claim term
`“strongly-ionized plasma” should be interpreted as “a higher density
`plasma.” Pet. 15 (emphasis omitted). Dr. Uwe Kortshagen, supporting
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`declarant for TSMC, defines the term “density” in the context of plasma as
`“the number of ions or electrons that are present in a unit volume.” Ex. 1102
`¶ 21.
`In its Preliminary Response, Zond proposes that the claim term
`“weakly-ionized plasma” should be construed as “a plasma with a relatively
`low peak density of ions,” and that the claim term “strongly-ionized plasma”
`should be construed as “a plasma with a relatively high peak density of
`ions.” Prelim. Resp. 21–22 (citing Ex. 1101, 9:43–45 (“The rapid ionization
`results in a strongly-ionized plasma 238 having a large ion density being
`formed in the area 234 proximate to the cathode 204.”)). Zond also directs
`our attention to the Specification of U.S. Patent No. 6,806,652 B1 (“the ’652
`Patent”), which is being challenged in Taiwan Semiconductor
`Manufacturing Company, Ltd. v. Zond, LLC, Case IPR2014-00861. Id.
`The Specification of the ’652 patent provides:
`The high-power pulses generate a high-density plasma from the
`initial plasma. The term “high-density plasma” is also referred
`to as a “strongly-ionized plasma.” The terms “high-density
`plasma” and “strongly-ionized plasma” are defined herein to
`mean a plasma with a relatively high peak plasma density. For
`example, the peak plasma density of the high-density plasma is
`greater than about 1012 cm-3. The discharge current that is
`formed from the high-density plasma can be on the order of
`about 5 kA with a discharge voltage that is in the range of about
`50V to 500V for a pressure that is in the range of about 5 mTorr
`to 10 Torr.
`IPR2014-00861, Ex. 1101, 8:55–59.
`We recognize when construing claims in patents that derive from the
`same parent application and share common terms, “we must interpret the
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`Patent 6,853,142 B2
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`claims consistently across all asserted patents.” NTP, Inc. v. Research In
`Motion, Ltd., 418 F.3d 1282, 1293 (Fed. Cir. 2005) (citation omitted). Here,
`although Zond characterizes the ’652 Patent as “a related patent” (Prelim.
`Resp. 21), Zond does not explain how the ’652 Patent is related to the
`involved patent in the instant proceeding (i.e., the ’142 Patent). In fact,
`those patents do not share the same written disclosure, nor do they derive
`from the same parent application.
`Nevertheless, we observe no significant difference between the
`parties’ constructions. Pet. 15; Ex. 1102 ¶ 21; Prelim. Resp. 21–22. More
`importantly, the claim terms “weakly-ionized plasma” and “strongly-ionized
`plasma” appear to be used consistently across both the ’652 Patent and the
`’142 Patent. See, e.g., Ex. 1101, 6:31–35. For this decision, we construe the
`claim term “weakly-ionized plasma” as “a plasma with a relatively low peak
`density of ions,” and the claim term “strongly-ionized plasma” as “a plasma
`with a relatively high peak density of ions.”
`
`
`C. Principles of Law
`A patent claim is unpatentable under 35 U.S.C. § 103(a) if the
`differences between the claimed subject matter and the prior art are such that
`the subject matter, as a whole, would have been obvious at the time the
`invention was made to a person having ordinary skill in the art to which said
`subject matter pertains. KSR Int’l Co. v. Teleflex Inc., 550 U.S. 398, 406
`(2007). The question of obviousness is resolved on the basis of underlying
`factual determinations including: (1) the scope and content of the prior art;
`(2) any differences between the claimed subject matter and the prior art;
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`Patent 6,853,142 B2
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`(3) the level of ordinary skill in the art; and (4) objective evidence of
`nonobviousness. Graham v. John Deere Co., 383 U.S. 1, 17–18 (1966).
`In that regard, an obviousness analysis “need not seek out precise
`teachings directed to the specific subject matter of the challenged claim, for
`a court can take account of the inferences and creative steps that a person of
`ordinary skill in the art would employ.” KSR, 550 U.S. at 418; see
`Translogic, 504 F.3d at 1259. A prima facie case of obviousness is
`established when the prior art itself would appear to have suggested the
`claimed subject matter to a person of ordinary skill in the art. In re Rinehart,
`531 F.2d 1048, 1051 (CCPA 1976). The level of ordinary skill in the art is
`reflected by the prior art of record. See Okajima v. Bourdeau,
`261 F.3d 1350, 1355 (Fed. Cir. 2001); In re GPAC Inc., 57 F.3d 1573, 1579
`(Fed. Cir. 1995); In re Oelrich, 579 F.2d 86, 91 (CCPA 1978).
`We analyze the asserted grounds of unpatentability in accordance with
`the above-stated principles.
`
`
`D. Claims 13 and 14 – Obviousness over Wang and Lantsman
`TSMC asserts that claims 13 and 14 are unpatentable under 35 U.S.C.
`§ 103(a) as obvious over the combination of Wang and Lantsman. Pet. 31–
`44. As support, TSMC provides detailed explanations as to how each claim
`limitation, including those of independent claim 10 from which claims 13
`and 14 depend, is met by the references and rationales for combining the
`references, as well as a Declaration of Dr. Kortshagen (Ex. 1102). Id.
`Zond responds that the combination of Wang and Lantsman does not
`disclose every claim limitation. Prelim. Resp. 45–52. Zond also argues that
`11
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`IPR2014-00821
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`there is insufficient reason to combine the technical disclosures of Wang and
`Lantsman. Id. at 24–44.
`We have reviewed the parties’ contentions and supporting evidence.
`Given the evidence on this record, we determine that TSMC has
`demonstrated a reasonable likelihood of prevailing on its assertion that
`claims 13 and 14 are unpatentable as obvious over the combination of Wang
`and Lantsman. Our discussion focuses on the deficiencies alleged by Zond
`as to the claims.
`
`Wang
`
`Wang discloses a power pulsed magnetron sputtering apparatus for
`generating a very high plasma density. Ex. 1105, Abs. Wang also discloses
`a sputtering method for depositing metal layers onto advanced
`semiconductor integrated circuit structures. Id. at 1:4–15.
`
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`
`Figure 1 of Wang, reproduced below, illustrates a cross-sectional view
`of a power pulsed magnetron sputtering reactor:
`
`
`As shown in Figure 1 of Wang, magnetron sputtering apparatus 10 has
`pedestal 18 for supporting semiconductor substrate 20, anode 24,
`cathode 14, magnet assembly 40, and pulsed DC power supply 80. Id. at
`3:57–4:55. According to Wang, the apparatus is capable of creating high
`density plasma in region 42, from argon gas feed 32 through mass flow
`controller 34, which ionizes a substantial fraction of the sputtered particles
`into positively charged metal ions and also increases the sputtering rate. Id.
`at 4:5–34. Wang further recognizes that, if a large portion of the sputtered
`particles are ionized, the films are deposited more uniformly and
`effectively—the sputtered ions can be accelerated towards a negatively
`
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`IPR2014-00821
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`charged substrate, coating the bottom and sides of holes that are narrow and
`deep. Id. at 1:24–29.
`Figure 6 of Wang, reproduced below, illustrates how the apparatus
`applies a pulsed power to the plasma.
`
`
`As shown in Figure 6 of Wang, the target is maintained at background
`power level PB between high power pulses 96 with peak power level PP. Id.
`at 7:13–39. Background power level PB exceeds the minimum power
`necessary to support a plasma in the chamber at the operational pressure
`(e.g., 1kW). Id. Peak power PP is at least 10 times (preferably 100 or 1000
`times) background power level PB. Id. The application of high peak power
`PP causes the existing plasma to spread quickly, and increases the density of
`the plasma. Id. According to Dr. Kortshagen, Wang’s apparatus generates a
`low-density (weakly-ionized) plasma during the application of background
`power PB, and a high-density plasma during the application of peak power
`PP. Ex. 1102 ¶¶ 123–127, 129; see Pet. 31–32.
`
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`Lantsman
`Lantsman discloses a plasma ignition system for plasma processing
`chambers having primary and secondary power supplies, used to generate a
`plasma current and a process initiation voltage, respectively. Ex. 1104, Abs.
`The primary power supply provides the primary power to electrically drive
`the cathode during the plasma process, and the secondary power supply
`supplies an initial plasma ignition voltage to “pre-ignite” the plasma so that
`when the primary power supply is applied, the system smoothly transitions
`to final plasma development and deposition. Id. at 2:48–51.
`The system is applicable to magnetron and non-magnetron sputtering
`and radio frequency (RF) sputtering systems. Id. at 1:6–8. Lantsman also
`provides that “arcing which can be produced by overvoltages can cause local
`overheating of the target, leading to evaporation or flaking of target material
`into the processing chamber and causing substrate particle contamination
`and device damage,” and “[t]hus, it is advantageous to avoid voltage spikes
`during processing wherever possible.” Id. at 1:51–59.
`Lantsman also discloses that “at the beginning of processing . . . gas is
`introduced into the chamber” and “[w]hen the plasma process is completed,
`the gas flow is stopped.” Id. at 3:10–13. This is illustrated in Figure 6 of
`Lantsman reproduced below:
`
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`Patennt 6,853,1442 B2
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`Figuure 6 illustrrates that thhe gas floww is initiateed, and thee gas flow aand
`for the
`
`
`
`
`
`presssure begin to ramp uppwards towward normmal process
`ing levels
`
`
`proccessing stagge. Id. at 55:39–42.
`
`
`Claimms 13 and 14
`
`
`
`
`
`
`
`With resspect to claaim 13, recciting that ““applying
`
`the electriccal pulse
`
`
`
`
`compprises appllying a quaasi-static electric fiel
`
`
`d across thhe weakly--ionized
`
`
`
`
`
`plasmma,” TSMC argues thhat the ’1442 Patent ddescribes a
`
`
`“quasi-staatic electricc
`a period o
`
`
`
`
`fieldd” as “an ellectric fieldd that is coonstant for
`
`of time ‘thaat is much
`
`
`greatter than thee collision
`
`
`
`
`time for eelectrons wwith neutrall gas particcles.’” Pet
`
`
`
`
`
`
`42 (cciting Ex. 1101, 7:166–19). Bassed on a texxtbook andd another rreference
`
`
`
`
`
`
`incorrporated innto Wang, TSMC arggues that thhe longest
`
`collision tiime in
`
`
`
`
`
`
`Wanng is 0.188 μs, and thhat the pulsse width off the powerr peak is att least 50
`
`. Id. at 42–
`
`
`
`
`
`
`μs, ssuch that WWang’s elecctric field iis considerred to be quuasi-static
`
`
`
`44 (cciting Ex. 1102 ¶ 1277).
`
`
`
`
`
`
`With resspect to claaim 14, recciting that tthe pulse aamplitude oor width is
`
`
`
`seleccted “in ordder to incr
`
`
`
`
`ease an ionnization ratte of the sttrongly-ionnized
`
`–
`
`.
`
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`plasma,” TSMC argues that Wang’s peak power pulse increases the density
`of the plasma, forming a strongly-ionized plasma. Id. at 44. TSMC also
`argues that while the density is increasing, the ionization rate is increasing
`too. Id.; Ex. 1102 ¶ 129.
`
`
`Reasons to Combine Wang and Lantsman
`TSMC asserts that it would have been obvious to have combined
`Wang and Lantsman to render claims 1 and 10 obvious in order to
`demonstrate the unpatentability of the challenged dependent claims. Pet.
`38–40 (citing Ex. 1002 ¶¶ 113–115). With regard to the claim feature of
`claim 1—a gas line that supplies feed gas to the strongly-ionized plasma—
`and to the claim feature of claim 10—diffusing the strongly-ionized plasma
`with additional feed gas thereby allowing the strongly-ionized plasma to
`absorb additional energy from the power supply—TSMC discusses the
`suggestion of continuing to supply the feed gas in the process of Wang, and
`argues that it is likely to occur during that disclosed process, although not
`expressly recited. Pet. 36–39; Ex. 1102 ¶ 111. TSMC also argues that even
`if Wang does not disclose maintaining the flow of the feed gases, “[i]t would
`have been obvious to one of ordinary skill to continue to exchange the feed
`gas during Wang’s application of background power and high peak power,
`as taught by Lantsman.” Pet. 38–39. TSMC submits an ordinarily skilled
`artisan would have been motivated to combine Wang and Lantsman because
`both are directed to sputtering and both employ two power supplies, one for
`pre-ionization and the other for deposition. Id. In addition, both Wang and
`
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`Lantsman are concerned with generating plasma while avoiding arcing. Id.
`TSMC also cites to the testimony of Dr. Kortshagen that the continuous flow
`of gas would allow for diffusion of the strongly-ionized plasma and
`additional power to be absorbed by the plasma. Id. at 39–40; Ex. 1102 ¶
`114.
`
`In its Preliminary Response, Zond disagrees that it would have been
`obvious to combine the technical disclosures of Wang and Lantsman,
`arguing that Wang’s power pulsed magnetron sputtering apparatus differs
`significantly from Lantsman’s plasma apparatus, where the latter uses two
`power supplies and does not generate strongly-ionized plasma. Prelim.
`Resp. 34–37, 38–39. In particular, Zond argues that “Lantsman does not
`disclose a pulsed power supply, or an electrical pulse,” and would operate
`very differently than the system in Wang. Id. at 36. In addition, Zond
`argues that Lantsman does not disclose generating strongly-ionized plasma,
`or the density of the plasma formed, such that skilled artisans would have no
`reasonable expectation of success in combining Lantsman with Wang, where
`Wang “makes no mention of diffusing strongly-ionized plasma with feed
`gas.” Id. at 38–39.
`Those arguments are not persuasive on the present record. “It is well-
`established that a determination of obviousness based on teachings from
`multiple references does not require an actual, physical substitution of
`elements.” In re Mouttet, 686 F.3d 1322, 1332 (Fed. Cir. 2012) (citing In re
`Etter, 756 F.2d 852, 859 (Fed. Cir. 1985) (en banc) (noting that the criterion
`for obviousness is not whether the references can be combined physically,
`but whether the claimed invention is rendered obvious by the teachings of
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`the prior art as a whole)). In that regard, one with ordinary skill in the art is
`not compelled to follow blindly the teaching of one prior art reference over
`the other without the exercise of independent judgment. Lear Siegler, Inc. v.
`Aeroquip Corp.,733 F.2d 881, 889 (Fed. Cir. 1984); see also KSR, 550 U.S.
`at 420-21 (A person with ordinary skill in the art is “a person of ordinary
`creativity, not an automaton,” and “in many cases . . . will be able to fit the
`teachings of multiple patents together like pieces of a puzzle.”).
`Zond has not shown, based on the present record, that the sputtering
`apparatuses differ significantly from each other. Both apparatuses are used
`in sputtering and both employ two-stage plasma formation processes, as
`discussed above. Additionally, Wang and Lantsman are concerned with
`generating plasma while avoiding arcing; with such a common problem
`being solved in each, the common solutions to avoiding arcing would act as
`a tie to ordinarily skilled artisans to motivate consideration of their
`combination. On this record, Zond has not adequately demonstrated that
`Wang’s apparatus or Lantsman’s apparatus would have been beyond the
`level of ordinary skill, or why one with ordinary skill in the art would not
`have had a reasonable expectation of success in combining the teachings.
`Also, Dr. Kortshagen testifies that “Lantsman’s pre-ionization
`corresponds to Wang’s application of background power, PB, and
`Lantsman’s deposition corresponds to Wang’s application of high peak
`power, PP.” Ex. 1102 ¶ 113 (internal citations omitted). Given these
`similarities, we are persuaded that TSMC has demonstrated on the present
`record that one of ordinary skill in the art would have combined Wang and
`Lantsman as identified in the Petition.
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`On this record, we also credit Dr. Kortshagen’s testimony, as it is
`consistent with the prior art disclosures. We also agree with Dr. Kortshagen
`that “such exchange of the feed gas into and out of Wang’s chamber would
`have both diffused the strongly-ionized plasma and allowed additional
`power from Wang’s repeating voltage pulses to be absorbed by the strongly-
`ionized plasma.” Ex. 1102 ¶ 111. The plasma physics involved with
`continuing to supply the feed gas, i.e., causing lower gas temperature and
`higher neutral gas density, resulting in higher rates of plasma generation, id.,
`are uncontroverted by Zond, inherently “allowing additional power from the
`pulsed power supply to be absorbed by the strongly-ionized plasma,” and
`“allowing the strongly-ionized plasma to absorb additional energy from the
`power supply,” per claims 1 and 10, respectively.
`Given the evidence before us, we determine that the Petition and
`supporting evidence demonstrate sufficiently that combining the technical
`disclosures of Wang and Lantsman is merely a predicable use of prior art
`elements according to their established functions—an obvious improvement.
`See KSR, 550 U.S. at 417 (“[I]f a technique has been used to improve one
`device, and a person of ordinary skill in the art would recognize that it would
`improve similar devices in the same way, using the technique is obvious
`unless its actual application is beyond his or her skill.”).
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`Alleged Missing Claim Elements from the Combination of Wang and
`Lantsman
`Zond also argues the claim element “diffusing the strongly-ionized
`plasma with additional feed gas thereby allowing the strongly-ionized
`plasma to absorb additional energy from the power supply,” from claim 10
`and a similar element from claim 1, are not taught or suggested by the
`combination of Wang and Lantsman. Prelim. Resp. 45–48. Zond argues
`that TSMC has attempted to demonstrate that the feed gas is supplied during
`processing, but that does not teach supplying the feed gas to the strongly-
`ionized plasma. Id. at 46. Zond also argues that TSMC’s arguments about
`the obviousness of allowing the plasma to absorb more power is based on
`“classic hindsight” that utilizes the same reason provided in the ’142 Patent
`for including the claim limitation. Id. at 46–47. Since Wang discloses the
`formation of a strongly-ionized plasma during its process, supplying the feed
`gas for the entire process, as would have occurred in the combined processes
`of Wang and Lantsman, necessarily would involve supplying the feed gas to
`the strongly-ionized plasma. Also, as discussed above, we are persuaded
`that the ability of plasma to absorb more power based on the supply of the
`feed gas is a matter of plasma physics. See Ex. 1102 ¶ 111. We are not
`persuaded that TSMC used the ’142 Patent “as a blueprint for modifying”
`the references (Prelim. Resp. 47 (emphasis omitted)) because TSMC’s
`analysis is based on common, understood scientific principles. TSMC’s
`reliance on underlying plasma physics principles would not need to be
`guided by hindsight using the ’142 Patent.
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`With respect to claim 13, Zond counters that TSMC argues Wang’s
`electric field is quasi-static because the pulse width is greater than the
`collision time for electrons with neutral gas particles, but that TSMC fails to
`make any comparison between the characteristic time of electric field
`variation and collision time. Prelim. Resp. 49–50. Rather, Zond contends,
`TSMC compares a different quantity, i.e., the pulse width of the power
`pulse, with a collision time, and thus, has not demonstrated that claim 13 is
`taught or suggested by the combination of Wang and Lantsman. Id. We do
`not agree.
`It is clear from the analysis above that an electric field is applied to
`the weakly-ionized plasma in the form of a pulse in Wang. Claim 13
`requires that the electric field applied be “quasi-static,” and the ’142 Patent
`describes a “quasi-static electric field” as an electric field that has “a
`characteristic time of electric field variation,” i.e., while it is constant for a
`period of time, that is much greater than the collision time for electrons with
`neutral gas particles. Ex. 1101, 7:16–19. It is logical to look at the width of
`a pulse to determine the duration over which the field of the pulse is applied.
`Where no pulse is applied, there would be a variation in the applied field as
`compared to when the field is applied. As such, we agree with TSMC that
`looking to a pulse width would allow ordinarily skilled artisans to determine
`if the field applied through the pulse is quasi-static. Given the collision time
`referred to in the Petition (Pet. 42), which has not yet been controverted by
`Zond, we agree that Wang provides for the application of an electric field,
`through its power pulse, that would be quasi-static compared to the collision
`time.
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`With respect to claim 14, Zond argues that TSMC’s analysis is faulty.
`Prelim. Resp. 50–52. Specifically, Zond argues that it does not follow
`necessarily that the ionization rate increases when the plasma density
`increases because the rate at which ions are created does not have to increase
`with increasing density. Id. at 51. However, the ’142 Patent admits, in the
`Background of Invention section, that “the plasma is replenished by
`electron-ion pairs formed by the collision of neutral molecules with
`secondary electrons generated at the target s