throbber

`
`UNITED STATES PATENT AND TRADEMARK OFFICE
`________________
`
`BEFORE THE PATENT TRIAL AND APPEAL BOARD
`________________
`
`FUJITSU SEMICONDUCTOR LIMITED,
`FUJITSU SEMICONDUCTOR AMERICA, INC.,
`ADVANCED MICRO DEVICES, INC., RENESAS ELECTRONICS
`CORPORATION, RENESAS ELECTRONICS AMERICA, INC.,
`GLOBALFOUNDRIES U.S., INC., GLOBALFOUNDRIES DRESDEN
`MODULE ONE LLC & CO. KG, GLOBALFOUNDRIES DRESDEN
`MODULE TWO LLC & CO. KG, TOSHIBA AMERICA ELECTRONIC
`COMPONENTS, INC., TOSHIBA AMERICA INC., TOSHIBA
`AMERICA INFORMATION SYSTEMS, INC.,
`TOSHIBA CORPORATION, and
`THE GILLETTE COMPANY,
`Petitioners,
`
`v.
`
`ZOND, LLC,
`Patent Owner
`________________
`
`IPR2014-008181
`Patent 6,853,142 B2
`
`________________
`
`PETITIONER’S REPLY TO PATENT OWNER’S RESPONSE
`
`
`1 Cases IPR 2014-00866, IPR 2014-01012, and IPR 2014-01075 have been joined
`with the instant proceeding.
`
`
`

`

`
`Petitioner’s Reply to Patent Owner’s Response
`
`IPR2014-00818
` Patent No. 6,853,142
`
`TABLE OF CONTENTS
`
`TABLE OF AUTHORITIES ................................................................................... iii
`
`PETITIONER’S EXHIBIT LIST ............................................................................ iv
`
`I.
`
`INTRODUCTION ............................................................................................... 1
`
`II. CLAIM CONSTRUCTION ................................................................................ 1
`
`A. “Weakly-Ionized Plasma” and “Strongly-Ionized Plasma” ......................... 1
`
`III. RESPONSE TO ARGUMENTS ......................................................................... 2
`
`A. Zond Improperly Confounds the Embodiments of Wang. ........................... 2
`
`B. A person of ordinary skill in the art would have combined Wang and
`Lantsman. ...................................................................................................... 3
`
`C. Wang in view of Lantsman teaches “the feed gas diffusing the strongly-
`ionized plasma, thereby allowing additional power from the pulsed
`power supply to be absorbed by the strongly ionized plasma” recited in
`claim 1 and similarly in recited in claim 10. ................................................ 5
`
`D. Wang in view of Lantsman teaches “an electrical pulse having a
`magnitude and a rise time that is sufficient to increase the density of the
`weakly-ionized plasma to generate a strongly-ionized plasma” recited
`in claim 1 and claim 10. ................................................................................ 8
`
`E. Wang in view of Lantsman teaches “selecting at least one of a pulse
`amplitude and a pulse width of the electrical pulse in order to cause the
`strongly-ionized plasma to be substantially uniform” recited in
`dependent claim 15. ...................................................................................... 9
`
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`Petitioner’s Reply to Patent Owner’s Response
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`IPR2014-00818
` Patent No. 6,853,142
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`F. Wang in view of Lantsman teaches “the gas line supplies additional
`feed gas that exchanges the weakly-ionized plasma while applying the
`electrical pulse across” recited in claims 3 and 12. .................................... 11
`
`G. Wang in view of Lantsman teaches “the power supply generates a
`constant power” recited in claim 4 and “the power supply generates a
`constant voltage” recited in claim 5. .......................................................... 13
`
`H. Wang in view of Lantsman teaches “the ionization source is chosen
`from the group comprising an electrode coupled to a DC power supply”
`recited in claim 6. ....................................................................................... 15
`
`IV. CONCLUSION .................................................................................................. 15
`
`Certificate of Service .............................................. Error! Bookmark not defined.
`
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`ii
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`Petitioner’s Reply to Patent Owner’s Response
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`IPR2014-00818
` Patent No. 6,853,142
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`TABLE OF AUTHORITIES
`
`Cases
`
`In re Mouttet, 686 F.3d 1322, 1332 (Fed. Cir. 2012) ................................................ 5
`
`Rules
`
`37 C.F.R. § 42.23 ............................................................................................................. 1
`
`
`
`
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`iii
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`Petitioner’s Reply to Patent Owner’s Response
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`IPR2014-00818
` Patent No. 6,853,142
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`PETITIONER’S EXHIBIT LIST
`
`
`
`April 16, 2015
`
`Description
`
`Exhibit
`
`1001 U.S. Patent No. 6,853,142 (“’142 Patent”)
`
`1002 Kortshagen Declaration (“Kortshagen Decl.”)
`
`1003 D.V. Mozgrin, et al, High-Current Low-Pressure Quasi-Stationary
`Discharge in a Magnetic Field: Experimental Research, Plasma Physics
`Reports, Vol. 21, No. 5, 1995 (“Mozgrin”)
`
`1004 U.S. Patent No. 6,190,512 (“Lantsman”)
`
`1005 U.S. Pat. No. 6,413,382 (“Wang”)
`
`1006
`
`1007
`
`1008
`
`1009
`
`Plasma Etching: An Introduction, by Manos and Flamm, Academic
`Press (1989) (“Manos”)
`
`10/07/03 Office Action
`
`03/08/04 Response
`
`03/29/04 Allowance
`
`1010 U.S. Patent No. 7,147,759 (“the ’759 patent”)
`
`05/02/06 Response from the ’759 patent file history
`
`The Materials Science of Thin Films, by Ohring M., Academic Press
`(1992) (“Ohring”)
`
`Thin-Film Deposition: Principles & Practice by Smith, D.L., McGraw
`Hill (1995) (“Smith”)
`
`04/21/08 Response in EP 1560943
`
`Claim Chart Based on Mozgrin and Lantsman used in 1:13-cv-11570-
`
`iv
`
`1011
`
`1012
`
`1013
`
`1014
`
`1015
`
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`

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`Petitioner’s Reply to Patent Owner’s Response
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`IPR2014-00818
` Patent No. 6,853,142
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`Exhibit
`
`Description
`RGS (“Claim Chart based on Mozgrin and Lantsman”)
`
`1016
`
`1017
`
`Claim Chart Based on Wang and Lantsman used in 1:13-cv-11570-
`RGS (“Claim Chart based on Wang and Lantsman”)
`
`Claim Chart Based on Wang, Lantsman and Mozgrin used in 1:13-cv-
`11570-RGS (“Claim Chart based on Wang, Lantsman and Mozgrin”)
`
`1018 Affidavit of Anthony J. Fitzpatrick in support of motion for pro hac
`vice admission.
`
`1019
`
`1020
`
`1021
`
`Stipulations of Dismissals
`
`“Board Only” Settlement Agreement
`
`Rismiller Declaration ISO Motion for PHV Admission of Brett C
`Rismiller
`
`1022 Declaration of Dr. Lawrence J. Overzet (“Overzet Decl.”)
`
`1023 Dr. Hartsough Deposition Transcript for U.S. Patent No. 7,808,184
`
`1024 Dr. Hartsough Deposition Transcript for U.S. Patent No. 6,853,142
`
`1025 Dr. Hartsough Deposition Transcript for U.S. Patent No. 8,125,155
`
`1026 Dr. Hartsough Deposition Transcript for U.S. Patent No. 6,896,775
`
`
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`Petitioner’s Reply to Patent Owner’s Response
`
`IPR2014-00818
` Patent No. 6,853,142
`
`I.
`
`INTRODUCTION
`
`Petitioner submits this reply under 37 C.F.R. § 42.23 in response to Patent
`
`Owner’s Response to Petition filed on January 2, 2015 (“Response,” Paper No. 26).
`
`The evidence and arguments in this reply confirm the Board’s initial determination
`
`that claims 1, 3-10, 12, 15, 17-20, and 42 of the ’142 Patent are rendered obvious
`
`over the prior art of record and thus should be canceled.
`
`Indeed, the ’142 Patent presents nothing novel; and Zond’s own declarant
`
`Dr. Hartsough concedes that the limitations in the claims were well known before
`
`the effective date of the ’142 Patent. See e.g., Ex. 1024 at 30:3-35:21.
`
`II. CLAIM CONSTRUCTION
`A.
`“Weakly-Ionized Plasma” and “Strongly-Ionized Plasma”
`The Board construed the term strongly-ionized plasma to mean a plasma with a
`
`relatively high peak density of ions and the term weakly-ionized plasma to mean a
`
`plasma with a relatively low peak density of ions. Petitioners and their experts agree
`
`with this construction. Ex. 2010 at 25:25-26:23; Ex. 1022, ¶¶ 22-30. This construction
`
`is consistent with the ’142 Patent in that it does not require any specific or quantified
`
`difference in magnitude between the peak ion densities of the weakly-ionized plasma
`
`and the strongly-ionized plasma. Ex. 1022, ¶ 28-29. Also, Zond’s declarant, Dr.
`
`Hartsough, agrees with the Board’s construction and concedes that there is “not a
`
`magic number that one can arbitrarily say across all conditions as to what’s a weakly
`
`
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`1
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`Petitioner’s Reply to Patent Owner’s Response
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`IPR2014-00818
` Patent No. 6,853,142
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`ionized plasma or a strongly ionized plasma.” Ex. 1023 at 60:5-8; 63:7-10.
`
`III. RESPONSE TO ARGUMENTS
`A. Zond Improperly Confounds the Embodiments of Wang.
`Zond’s arguments directed to Wang are flawed, for among other reasons,
`
`because throughout they indiscriminately transition between two different
`
`embodiments of Wang – applying statements directed from one embodiment (Fig.
`
`4) to another embodiment (Fig. 6). Ex. 1022, ¶ 53.
`
`
`
`Ex. 1005, Figs 4 and 6 (annotated); Ex 1022, ¶ 53.
`
`Wang shows and discusses a system diagram of a magnetron sputter reactor
`
`in Fig. 1, and then in connection with Figs. 4 and 6, shows and discusses two
`
`different embodiments, respectively, of pulsing a target in the reactor of Fig. 1. See
`
`Ex. 1005 at 3:37-50. These two separate and distinct embodiments are illustrated in
`
`the figures reproduced above. Further, Dr. Overzet provides a chart summarizing
`
`
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`2
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`Petitioner’s Reply to Patent Owner’s Response
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`IPR2014-00818
` Patent No. 6,853,142
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`the difference between these two embodiments, including the portion cited below.
`
`Ex. 1022, ¶¶ 54-58.
`
`
`
`Wang embodiment of Fig. 4
`
`Wang embodiment of Fig. 6
`
`Internal
`impedance
`
`“[C]hamber impedance
`dramatically changes.” Wang
`at 5:29-30, 52-53.
`
`“[C]hamber impedance changes
`relatively little ….” Wang at 7:49-
`51.
`
`Power
`Pulse or
`Voltage
`Pulse
`
`Arcing
`
`“Where chamber impedance
`is changing, the power pulse
`width is preferably specified
`rather than the current or
`voltage pulse widths.” Wang
`at 5:52-54.
`
`Where chamber impedance changes
`“relatively little,” there is no
`preference to specify power pulse
`over current or voltage pulse. See
`Wang at 7:49-51.
`
`Tendency to arc during
`ignition/generation of strongly
`ionized plasma: See Wang at
`7:1-12.
`
`Arcing is avoided during ignition
`and during generation of strongly
`ionized plasma. See Wang at 7:26-
`28, 47-48.
`
`B. A person of ordinary skill in the art would have combined Wang
`and Lantsman.
`
`Zond argues that a person of ordinary skill in the art would not combine
`
`Wang and Lantsman because each reference allegedly discloses very different
`
`structures and processes. Response at 28-33. These arguments are based on
`
`physically incorporating Lantsman into Wang. This is not the proper standard for
`
`determining obviousness. In re Mouttet, 686 F.3d 1322, 1332 (Fed. Cir. 2012) (“It
`
`is well-established that a determination of obviousness based on teachings from
`
`multiple references does not require an actual, physical substitution of elements.”).
`
`
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`IPR2014-00818
` Patent No. 6,853,142
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`Further, Zond’s argument is incorrect and shows a clear misunderstanding of
`
`the ordinary level of skill in the art. Ex. 1022, ¶ 66. Whether Wang and Lantsman
`
`teach different processing conditions is beside the point; these conditions are
`
`determined by external factors such as process flow and recipes, which a person of
`
`ordinary skill in the art would have been accustomed to working with on a regular
`
`basis. A skilled artisan would consider it routine to make any necessary changes to
`
`accommodate any and all such factors. Ex. 1022, ¶¶ 67-68. And Zond’s declarant,
`
`Dr. Hartsough, concedes that notwithstanding physical differences, Lantsman’s
`
`teachings are applicable to any plasma process, including Wang’s magnetron
`
`sputtering process. Ex. 1024 at 65:2-15; Ex. 1004 at 6:14-17.
`
`Further still, and contrary to Zond’s arguments, Wang and Lantsman are
`
`strikingly similar, and a person of ordinary skill in the art would be encouraged to
`
`combine the teachings of the two references. Ex. 1022, ¶ 69. For instance, both
`
`Wang and Lantsman teach two stage plasma sputtering systems. See Ex. 1005 at
`
`7:28-30 (“the application of the high peak power PP instead quickly causes the
`
`already existing plasma to spread and increases the density of the plasma.”); Ex.
`
`1004 at 2:48-51; 4:58-61; 5:5-8 (discussing first “limited” plasma stage, and a
`
`second “substantial” plasma stage). Also, Lantsman uses a continuous flow of feed
`
`gas, and Wang uses a mass flow controller (34), which would be understood to
`
`control continuous flow of feed gas. Ex. 1022, ¶ 69; see also Ex. 1005 at 4:53.
`4
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`Petitioner’s Reply to Patent Owner’s Response
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`IPR2014-00818
` Patent No. 6,853,142
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`C. Wang in view of Lantsman teaches “the feed gas diffusing the
`strongly-ionized plasma, thereby allowing additional power from the
`pulsed power supply to be absorbed by the strongly ionized plasma”
`recited in claim 1 and similarly in recited in claim 10.
`
`Zond argues that Wang “does not teach feed gas diffusing the strongly-ionized
`
`plasma to thereby allow additional power from the pulsed power supply to be
`
`absorbed by the strongly ionized plasma.” See Response at 1-2; 35-36. Zond attempts
`
`to support this by arguing that the feed gas in Wang enters “far from the area where
`
`plasma is generated at the top of the chamber near the cathode.” Id. at 2; see also Ex.
`
`2005, ¶ 96. As discussed below, this argument is contrary to basic physics.
`
`As a threshold matter, it is noted that Dr. Hartsough concedes that Lantsman
`
`“indicates that the feed gas is provided throughout the sputtering process.” Ex. 1024 at
`
`66:3-5; see also Ex. 1004 at 3:9-13; 4:8-10, 36-38; 5:30-61; Ex. 1022, ¶ 80; see also
`
`Ex. 2011 at 81:14-19. Dr. Hartsough also concedes that Lantsman teaches providing
`
`the continuous feed gas to the strongly ionized plasma. Ex. 1024 at 71:1-25.
`
`Moreover, Dr. Hartsough concedes that “the gas will tend to diffuse
`
`throughout the whole volume.” Ex. 1024 at 88:22-89:2. Dr. Hartsough also
`
`concedes that the continuous feed gas will diffuse (or mingle/intermingle (Ex. 1024 at
`
`87:22-88:9)) into the high-density plasma:
`
`Q. Well, if the high -- the area of the high-density plasma is small
`relative to the total volume, then there will be a tendency for -- as you
`put it, there will be tendency to lower the pressure of the gas atoms in
`
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`IPR2014-00818
` Patent No. 6,853,142
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`that high-density plasma; correct?
`A. It would try to expand.
`Q. And if gas is being fed into that volume, then it will, in turn, try
`to diffuse into that area of high-density plasma; correct?
`…
`THE WITNESS: It will mingle.
`Ex. 1024 at 92:18-93:7.
`
`Indeed, Dr. Hartsough had no option but to concede this point because Zond’s
`
`argument is contrary to basic principles of gas motion. Ex. 1022, ¶ 74 and ¶¶ 77-78;
`
`see also Ex. 2011 at 74:6-14. Wang’s Fig. 1 has been reproduced and annotated below
`
`to illustrate the plasma region 42 inside the chamber, and the location where the feed
`
`gas 32, i.e., Argon (Ar), a noble gas, enters the chamber. Ex. 1022, ¶ 75.
`
`Plasma
`
`Feed gas enters here, and
`then fills the volume by
`diffusive motion
`
`Ex.1005, Fig. 1 (annotated); see also Ex. 1022, ¶ 75.
`
`
`
`
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`6
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`Petitioner’s Reply to Patent Owner’s Response
`
`IPR2014-00818
` Patent No. 6,853,142
`
`As can be seen from Figure 1, the feed gas enters and is directed toward the
`
`curved shape of the anode 24. The gas moves throughout the region 22, including
`
`plasma region 42. See Ex. 1005 at 4:5-12. A “plasma of the argon working gas” is
`
`then formed at the plasma region 42, and the argon gas is eventually removed by a
`
`vacuum system 38. Id. at 4:5-15. Thus in the system of Wang, the Argon feed gas will
`
`diffuse into the high density plasma, thereby allowing additional power from the
`
`pulsed power supply to be absorbed by the plasma. Ex. 1022, ¶ 76.
`
`Further, Dr. Hartsough testified that to deposit TiN on a substrate, the feed gas
`
`including Nitrogen will need to be supplied continuously to the plasma chamber. Ex.
`
`1023 at 184:22-185:3. This is consistent with Dr. Overzet’s conclusion that Wang
`
`teaches a continuous supply of Argon feed gas including Nitrogen for use with a
`
`Titanium target, “to form TiN on the surface of the wafer.” Ex. 1022, ¶ 79; Ex. 1005
`
`at 4:19-23. Further still, Dr. Hartsough concedes that “providing continuous flow of
`
`gas into a chamber was well known by a person of ordinary skill.” Ex. 1024 at 32:18-
`
`33:5; see also Ex. 2011 at 81:14-19. Thus, even if Wang did not teach a continuous
`
`feed of gas during the plasma process – which it does – this was well known by a
`
`person of ordinary skill and consistent with the teachings of Lantsman. Ex. 1022, ¶
`
`80; see also Ex. 2011 at 81:14-19.
`
`Zond finally argues that Petitioners have provided no evidence “indicating that
`
`a skilled artisan would have had a reasonable expectation of success of achieving a
`7
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`Petitioner’s Reply to Patent Owner’s Response
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`IPR2014-00818
` Patent No. 6,853,142
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`system that supplies feed gas to diffuse strongly ionized plasma to allow it to absorb
`
`additional power as claimed in the ‘142 Patent by modifying Wang.” Response at 29.
`
`This argument is flawed for several reasons. First, as discussed above, it is clear that
`
`Wang’s strongly-ionized plasma is diffused with the feed gas. Second, as also
`
`discussed above, Lantsman teaches two stages of plasma: a first “limited” plasma and
`
`a second “substantial” plasma. Ex. 1004 at 2:48-51; 4:58-61; 5:6. Since the second,
`
`substantial plasma is denser than the initial plasma, it reads on the claimed “strongly-
`
`ionized plasma” per the agreed-upon construction of that term. Ex. 1022, ¶¶ 69, 82;
`
`see also Ex. 1024 at 71:1-21. Third, experiments are not necessary to prove the basic
`
`principle which skilled artisans knew; namely, that a feed gas is commonly used to
`
`diffuse a strongly-ionized plasma. Ex. 1022, ¶ 83. As stated above, both Wang and
`
`Lantsman teach such things, and as admitted by Dr. Hartsough this was a basic,
`
`common, and normal practice in the art. Id.; Ex. 1024 at 32:18-33:5.
`
`D. Wang in view of Lantsman teaches “an electrical pulse having a
`magnitude and a rise time that is sufficient to increase the density of the
`weakly-ionized plasma to generate a strongly-ionized plasma” recited in
`claim 1 and claim 10.
`
`Zond argues that “Wang does not teach that the magnitude and rise time are
`
`sufficient to increase the density of weakly ionized plasma to generate strongly
`
`ionized plasma . . .” Response at 42. This argument fails as discussed below.
`
`
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`8
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`Petitioner’s Reply to Patent Owner’s Response
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`IPR2014-00818
` Patent No. 6,853,142
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`All of the experts agree that Wang teaches a weakly and a strongly ionized
`
`plasma. Ex. 1025 at 140:7-25; Ex. 1022, ¶¶ 70-72; Ex. 2011 at 151:25-152:6.
`
`Further, Wang specifically teaches that a magnitude (amplitude) is selected and
`
`delivered during the peak power pulse PP to generate a strongly ionized plasma. See,
`
`e.g., Ex. 1005, 7:28-30; Fig. 7; Ex. 1022, ¶ 85. This voltage amplitude is relative to
`
`the voltage during background power PB such that “the peak power PP is at least 10
`
`times the background power PB … and most preferably 1000 times to achieve the
`
`greatest effect of the invention.” Ex. 1005 at 7:19-22. Wang also teaches using a high-
`
`pass filter allowing a specific peak pulse width and rise time. Ex. 1005 at 7:65-8:1;
`
`Fig. 7 (see HPF 104). Dr. Hartsough concedes that a high-pass filter “could enable
`
`fast rise times.” Ex. 1023 at 181:9-17. Also, and like the ’142 Patent, Wang notes
`
`that the particular shape of the pulse depends on the design of the power supply.
`
`Ex. 1005 at 5:25-27 (The “exact shape depends on the design of the pulsed DC
`
`power supply 80, and significant rise times . . . are expected.”); Ex. 1001 at 13:66-
`
`14:5 (“The particular … shape …of the high-power pulses depend[s] on various
`
`factors including …the design of the pulsed power supply.”).
`
`E. Wang in view of Lantsman teaches “selecting at least one of a
`pulse amplitude and a pulse width of the electrical pulse in order to
`cause the strongly-ionized plasma to be substantially uniform” recited
`in dependent claim 15.
`
`Zond admits that Wang has uniform plasma, but argues that the substantially
`
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`IPR2014-00818
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`uniform plasma that is not the result of selecting either the amplitude or width of an
`
`electrical pulse. Response at 42-43. It appears that Zond is arguing that Wang’s
`
`substantially uniform plasma is solely due to the rotating magnetron. Id. citing Ex.
`
`2005, ¶ 105 (“Wang [] teaches that the uniformity of its plasma is limited to the area
`
`beneath the rotating magnet.”). The claim, however, only requires that plasma be
`
`uniform, not that it be uniform across the entire cathode at a single point in time. Ex.
`
`1022, ¶ 104. And, while a rotating magnetron does help to spread and make a uniform
`
`plasma (Ex. 1026 at 130:11-20) Wang is clear that selecting the amplitude and the
`
`width of the power pulse PP also contributes to the uniformity. Ex. 1022, ¶¶ 104-107.
`
`This is further represented in Fig. 2 of Dr. Overzet’s declaration, reproduced below.
`
`Ex. 1022, Fig. 2.
`
`
`
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`IPR2014-00818
` Patent No. 6,853,142
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`Dr. Overzet’s Fig. 2 shows how the plasma is uniform in the localized area
`
`under the cathode/target aligned with the magnet. It is also noted that there is an
`
`area between the cathode/target and the plasma called a “sheath,” and the electric
`
`field is substantially uniform in the sheath on the plane between the plasma and the
`
`cathode/target. Ex. 1022, ¶¶ 104-105.
`
`Wang also describes that the rotation of the magnet moves the uniform
`
`strongly-ionized plasma to provide a resulting electric field and plasma that are
`
`uniform over the entire surface of the cathode/target. Dr. Hartsough concedes that
`
`this is carried out in order to cause a more uniform erosion of the target over time.
`
`Ex. 1026 at 128:14-22. Further, Dr. Hartsough concedes that Wang teaches the
`
`formation of a uniform plasma over time. Ex. 1026 at 130:11-16. This means that
`
`the uniformity of the plasma is a direct result of two things: (1) the amplitude and
`
`pulse width of the electric field spreading out the plasma under the magnet; and (2)
`
`the magnet rotation causing the plasma to cover the entire surface of the
`
`cathode/target over time. Ex. 1022, ¶ 107.
`
`F. Wang in view of Lantsman teaches “the gas line supplies
`additional feed gas that exchanges the weakly-ionized plasma while
`applying the electrical pulse across” recited in claims 3 and 12.
`
`Zond first argues that Wang does not disclose this limitation because Wang
`
`does not teach “adding feed gas while applying an electrical pulse . . . .” Response at
`
`44. Contrary to Zond’s argument, and as discussed above, Wang teaches adding
`
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`IPR2014-00818
` Patent No. 6,853,142
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`Nitrogen to the feed gas for use with a Titanium target, thereby depositing Titanium
`
`Nitride (TiN). Ex. 1005 at 4:19-23. The feed gas, including the Nitrogen, is supplied
`
`continuously into the plasma so as to maintain the TiN deposition. Ex. 1022, ¶ 86; Ex.
`
`1023 at 184:22-185:3.
`
`Zond second argues that Lantsman does not disclose this limitation because it
`
`“does not disclose a pulsed power supply; it instead discloses only two DC power
`
`supplies.” Response at 43-44. In other words, Zond is arguing that since Lantsman
`
`does not teach a pulse, it cannot suggest supplying additional feed gas “while applying
`
`the electrical pulse.” Contrary to Zond’s argument, Lantsman clearly suggests
`
`providing a continual gas feed during the plasma processing. See ,e.g., Ex. 1004 at
`
`4:8-10; 5:30-61. Further, Lantsman discloses a pulse because it teaches a first
`
`“limited” plasma stage, and a second “substantial” plasma stage, (see id. at 2:48-51;
`
`4:61; 5:6), and consistent with Zond’s assertions, the different voltage/current/power
`
`levels that occur would be a pulse. Ex. 1022, ¶ 88. Indeed, Zond’s declarant, Dr.
`
`Hartsough, has the same understanding; noting that “a pulse is-- as you might say, is
`
`something that increases and has duration and decreases.” Ex. 1023 at 91:1-7.
`
`This is exactly what Lantsman shows in its figures. See e.g., Ex. 1004 Figs. 2, 3, 6, 7,
`
`and 8; Ex. 1022, ¶ 88.
`
`
`
`12
`
`

`

`
`Petitioner’s Reply to Patent Owner’s Response
`
`IPR2014-00818
` Patent No. 6,853,142
`
`G. Wang in view of Lantsman teaches “the power supply generates a
`constant power” recited in claim 4 and “the power supply generates a
`constant voltage” recited in claim 5.
`
`Zond argues that Wang does not teach a constant power or a constant voltage.
`
`Response at 46, 49. However, Zond’s argument is contradicted by its own
`
`declarant, Dr. Hartsough, who concedes that Wang’s power supply generates a
`
`constant power: “Wang’s power supply 80 emits a series of [voltage] pulses as
`
`shown [in Fig. 7], wherein the power supply tries to maintain a constant power
`
`level [as shown in Fig. 6].” Ex. 2005, ¶ 57. Dr. Hartsough also concedes that in
`
`systems like Wang’s where “the chamber impedance changes relatively little
`
`between,” “voltage would approach a constant value.” Ex. 1023 at 152:4-6; Ex.
`
`1025 at 176:20-25; Ex. 1005 at 7:49-51.
`
`Dr. Hartsough further concedes that the typical power supply described by
`
`Wang operates exactly as how Fig. 5 of the ’775 Patent operates. Ex. 1026 at
`
`149:17-150:20 (“…Q: So we can agree that Wang is explaining how a typical
`
`pulsed power supply operates; right? A: Yes … Q: And that’s exactly what
`
`Figure 5 of the ‘775 patent is showing; right? … A: Yes.”). Notably, Fig. 5 of
`
`the ’775 Patent is the same as Fig. 4 of the ’142 Patent, which Dr. Hartsough
`
`concedes operates in “power mode.” Ex. 1024 at 45:10-12.
`
`Figs. 6 and 7 of Wang, below, show similar wave forms as Fig. 4 of the ’142
`
`Patent. In fact, Wang’s wave forms, like the ’142 Patent, include portions that are
`
`
`
`13
`
`

`

`
`Petitioner’s Reply to Patent Owner’s Response
`
`IPR2014-00818
` Patent No. 6,853,142
`
`of “constant power” and “constant voltage.” Ex. 1022, ¶¶ 115-117. For example,
`
`during the PB phase, shown in Figure 6, Wang states that the DC power supply
`
`“supplies an essentially constant negative voltage” and during the PP phase Wang
`
`at Fig. 7 illustrates that the voltage pulses have a constant amplitude. Ex. 1005 at
`
`7:57-61; Fig. 7 (emphasis added); Ex. 1022, ¶ 117; see also Ex. 2011 at 179:12-
`
`180:2.
`
`Ex. 1001, Fig. 4 (annotated); Ex. 1005, Figs. 6 and 7 (annotated).
`
`
`
`Moreover, Zond’s assertion that Wang’s pulse is a full width at half
`
`maximum does not mean that the power is always changing. Ex. 1022, ¶ 118. In
`
`fact, for a majority of time (except for transitions between background power PB
`
`and peak power PP, where the state of the plasma changes), Wang’s power and
`
`voltage will be constant. Ex. 1022, ¶ 119.
`
`14
`
`
`
`

`

`
`Petitioner’s Reply to Patent Owner’s Response
`
`IPR2014-00818
` Patent No. 6,853,142
`
`H. Wang in view of Lantsman teaches “the ionization source is
`chosen from the group comprising an electrode coupled to a DC power
`supply” recited in claim 6.
`
`Zond argues that an anode and cathode are not electrodes and that the
`
`claimed electrode is a “filament.” Response at 53-54. Zond’s argument is
`
`contradicted by its declarant, Dr. Hartsough, who concedes that under the
`
`“broadest possible interpretation, ‘electrode’ would include . . . other electrodes
`
`in the system” including “the anode and the cathode.” Ex. 1024 at 98:17-99:15.
`
`Dr. Overzet confirms this understanding. Ex. 1022, ¶ 128.
`
`IV. CONCLUSION
`For the reasons set forth in the Petition and above, claims 1, 3-10, 12, 15, 17-
`
`20, and 42 of the ’142 Patent are unpatentable and should be canceled.
`
`
`
`
`
`
`
`
`
`Dated: April 16, 2015
`
`
`
`
`
`
`
`Respectfully submitted,
`
`
`
` /s/ David M. Tennant
`David M. Tennant
`Registration No. 48,362
`Lead Counsel for Petitioner
`GlobalFoundries
`
`
`
`15
`
`

`

`
`Petitioner’s Reply to Patent Owner’s Response
`
`IPR2014-00818
` Patent No. 6,853,142
`
`CERTIFICATE OF SERVICE
`
`The undersigned certifies, in accordance with 37 C.F.R. § 42.105, that
`
`service was made on the Patent Owner as detailed below.
`
`Date of service April 16, 2015
`
`Manner of service Electronic Mail
`
`Documents served Petitioner’s Reply to Patent Owner’s Response;
`
`Exhibits 1022 - 1026; and
`
`Petitioner’s Exhibit List of April 16, 2015
`
`Persons served
`
`
`
`
`
`Dr. Gregory Gonsalves
`2216 Beacon Lane
`Falls Church, Virginia 22043
`
`Bruce Barker
`Chao Hadidi Stark & Barker LLP
`176 East Mail Street, Suite 6
`Westborough, MA 01581
`
`
`/s/ Anna Goodall
`
`
`
`
`
`Anna Goodall
`White & Case LLP
`3000 El Camino Real
`Five Palo Alto Square, 9th Floor
`Palo Alto, CA 94306
`Tel: (650) 213-0367
`Email: agoodall@whitecase.com
`
`16
`
`
`
`
`
`

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