`
`BEFORE THE PATENT TRIAL AND APPEAL BOARD
`______________________
`THE GILLETTE COMPANY, FUJITSU SEMICONDUCTOR LIMITED, and
`FUJITSU SEMICONDUCTOR AMERICA, INC.
`
`Petitioners
`
`v.
`
`ZOND, LLC
`Patent Owner
`
`______________________
`Case No. IPR2014-006041
`Patent 6,896,775 B2
`______________________
`
`
`
`
`
`
`PATENT OWNER’S NOTICE OF APPEAL
`35 U.S.C. § 142 & 37 C.F.R. § 90.2
`
`
`
`
`
`1 Case IPR 2014-01482 has been joined with the instant proceeding.
`
`
`
`Pursuant to 37 C.F.R. § 90.2(a), Patent Owner, Zond, LLC, hereby provides
`
`notice of its appeal to the United States Court of Appeals for the Federal Circuit for
`
`review of the Final Written Decision of the United States Patent and Trademark
`
`Office (“USPTO”) Patent Trial and Appeals Board (“PTAB”) in Inter Partes
`
`Review 2014-00604, concerning U.S. Patent 6,896,775 (“the ’775 patent”), entered
`
`on September 18, 2015, attached hereto as Appendix A.
`
`ISSUES TO BE ADDRESSED ON APPEAL
`
`A. Whether the PTAB erred in finding claims 30-34 and 37 unpatentable as
`
`being obvious under 35 U.S.C. § 103(a) in view of U.S. Pat. 6,413,382 to
`
`Wang (“Wang”), D.V. Mozgrin, et al., High-Current Low-Pressure
`
`Quasi-Stationary Discharge in a Magnetic Field: Experimental
`
`Research, 21 PLASMA PHYSICS REPORTS 400–409 (1995)
`
`(“Mozgrin”), and and U.S. Pat. 6,190,512 to Lanstman (“Lantsman”)?
`
`B. Whether the PTAB erred in finding claim 35 unpatentable as being
`
`obvious under 35 U.S.C. § 103(a) in view of Wang, Mozgrin, Lantsman,
`
`and A. A. Kudryavtsev and V.N. Skrebov, Ionization Relaxation in a
`
`Plasma Produced by a Pulsed Inert-Gas Discharge, 28(1) SOV. PHYS.
`
`TECH. PHYS. 30–35 (1983) (“Kudryavtsev”)?
`
`C. Whether the PTAB erred in finding claim 36 unpatentable as being
`
`obvious under 35 U.S.C. § 103(a) in view of Wang and Mozgrin?
`
` 2
`
`
`
`Simultaneous with submission of this Notice of Appeal to the Director of the
`
`United States Patent and Trademark Office, this Notice of Appeal is being filed
`
`with the Patent Trial and Appeal Board. In addition, this Notice of Appeal, along
`
`with the required docketing fees, is being filed with the United States Court of
`
`Appeals for the Federal Circuit.
`
`
`
`
`
`
`
`
`Dated: November 19, 2015
`
`
`
`
`
`
`ASCENDA LAW GROUP, PC
`333 W. San Carlos St., Suite 200
`San Jose, CA 95110
`Tel: 866-877-4883
`Email: tarek.fahmi@ascendalaw.com
`
`Respectfully submitted,
`/Tarek N. Fahmi/
`
`
`
`Tarek N. Fahmi, Reg. No. 41,402
`
` 3
`
`
`
`APPENDIX A
`
`APPENDIX A
`
`
`
`
`
`
`
`
`
` Paper 50
`Trials@uspto.gov
`571-272-7822
`
` Entered: September 18, 2015
`
`
`
`UNITED STATES PATENT AND TRADEMARK OFFICE
`____________
`
`BEFORE THE PATENT TRIAL AND APPEAL BOARD
`____________
`
`THE GILLETTE COMPANY, FUJITSU SEMICONDUCTOR
`LIMITED, and FUJITSU SEMICONDUCTOR AMERICA, INC.,
`Petitioner,
`
`v.
`
`
`
`ZOND, LLC,
`Patent Owner.
`____________
`
`Case IPR2014-006041
`Patent 6,896,775 B2
`____________
`
`Before KEVIN F. TURNER, DEBRA K. STEPHENS, JONI Y. CHANG,
`SUSAN L.C. MITCHELL, and JENNIFER MEYER CHAGNON,
`Administrative Patent Judges.
`
`TURNER, Administrative Patent Judge.
`
`
`FINAL WRITTEN DECISION
`Inter Partes Review
`35 U.S.C. § 318(a) and 37 C.F.R. § 42.73
`
`The Gillette Company (“Gillette”) filed a Petition requesting inter
`
`partes review of claims 30–37 of U.S. Patent No. 6,896,775 B2 (“the ’775
`
`Patent”). Paper 3 (“Pet.”). Patent Owner Zond, LLC (“Zond”) filed a
`
`
`1 IPR2014-01482 has been joined with IPR2014-00604.
`
`
`
`
`
`IPR2014-00604
`Patent 6,896,775 B2
`
`
`
`
`
`
`Preliminary Response. Paper 7 (“Prelim. Resp.”). We instituted the instant
`
`trial on October 15, 2014, pursuant to 35 U.S.C. § 314. Paper 9 (“Dec.”).
`
`Subsequent to institution, we granted a revised Motion for Joinder
`
`filed by Taiwan Semiconductor Manufacturing Company, Ltd., TSMC
`
`North America Corp., (collectively, “TSMC”), Fujitsu Semiconductor
`
`Limited, and Fujitsu Semiconductor America, Inc. (collectively, “Fujitsu”),
`
`joining Case IPR2014-01482 with the instant trial (Paper 12), and also
`
`granted a Joint Motion to Terminate with respect to TSMC (Paper 40).
`
`Zond filed a Response (Paper 34 (“PO Resp.”)), and Gillette2 filed a Reply
`
`(Paper 42 (“Reply”)). Oral hearing3 was held on May 26, 2015, and a
`
`transcript of the hearing was entered into the record. Paper 49 (“Tr.”).
`
`We have jurisdiction under 35 U.S.C. § 6(c). This Final Written
`
`Decision is entered pursuant to 35 U.S.C. § 318(a) and 37 C.F.R. § 42.73.
`
`For the reasons set forth below, we determine that Gillette has shown, by a
`
`preponderance of the evidence, that claims 30–37 of the ’775 Patent are
`
`unpatentable under 35 U.S.C. § 103(a).
`
`
`
`A. Related District Court Proceedings
`
`
`
`The parties indicate that the ’775 Patent was asserted in Zond, LLC v.
`
`Advanced Micro Devices, Inc., No.1:13-cv-11567-DJC (D. Mass.), and
`
`identify other proceedings in which Zond asserted the ’775 patent. Pet. 1;
`
`Paper 6.
`
`
`
`
`2 We refer to Gillette and Fujitsu collectively as “Gillette” herein.
`3 The hearings for this review and IPR2014-00578 were consolidated.
`2
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`IPR2014-00604
`Patent 6,896,775 B2
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`
`
`B. The ’775 Patent
`
`The ’775 Patent relates to methods and apparatus for generating
`
`magnetically enhanced plasma. Ex. 1101, Abs. At the time of the invention,
`
`sputtering was a well-known technique for depositing films on
`
`semiconductor substrates. Id. at 1:14–25. The ’775 Patent indicates that
`
`prior art magnetron sputtering systems deposit films having low uniformity
`
`and poor target utilization (the target material erodes in a non-uniform
`
`manner). Id. at 3:34–44. To address these problems, the ’775 Patent
`
`discloses that increasing the power applied between the target and anode can
`
`increase the uniformity and density in the plasma. Id. at 3:45–56. However,
`
`increasing the power also “can increase the probability of generating an
`
`electrical breakdown condition leading to an undesirable electrical discharge
`
`(an electrical arc) in the chamber 104.” Id.
`
`According to the ’775 Patent, forming a weakly-ionized plasma
`
`substantially eliminates the probability of establishing a breakdown
`
`condition in the chamber when high-power pulses are applied between the
`
`cathode and anode. Id. at 7:4–15. Once the weakly-ionized plasma is
`
`formed, high-power pulses are applied between the cathode and anode to
`
`generate a strongly-ionized plasma from the weakly-ionized plasma. Id. at
`
`7:16–24. The ’775 Patent also discloses that the provision of the feed gas to
`
`the plasma allows for homogeneous diffusion of the feed gas in the weakly-
`
`ionized plasma and allows for the creation of a highly uniform strongly-
`
`ionized plasma. Id. at 5:59–67.
`
`
`
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`C. Illustrative Claims
`
`Of the challenged claims, claims 30, 36, and 37 are independent
`
`claims. Claims 31–35 depend from claim 30. Claims 30 and 37, reproduced
`
`below, are illustrative:
`
`30. A method of magnetically enhanced plasma processing,
`the method comprising:
`
`ionizing a volume of feed gas to form a weakly-ionized
`plasma proximate to a cathode;
`
`generating a magnetic field proximate to the weakly-ionized
`plasma, the magnetic field substantially trapping electrons in
`the weakly-ionized plasma proximate to the cathode;
`
`applying an electrical pulse across the weakly-ionized
`plasma to generate a strongly-ionized plasma comprising a first
`plurality of ions;
`
`exchanging the strongly-ionized plasma with a second
`volume of feed gas while applying the electrical pulse across
`the second volume of feed gas to generate a strongly-ionized
`plasma comprising a second plurality of ions; and
`
`applying a bias voltage to a substrate that is positioned
`proximate to the cathode, the bias voltage causing ions in the
`first and the second plurality of ions to impact a surface of the
`substrate in a manner that causes etching of the surface of the
`substrate.
`
`37. A magnetically enhanced plasma processing apparatus
`comprising:
`
`means for ionizing a volume of feed gas to form a weakly-
`ionized plasma proximate to a cathode;
`
`means for generating a magnetic field proximate to the
`weakly-ionized plasma,
`the magnetic
`field substantially
`trapping electrons in the weakly-ionized plasma proximate to
`the cathode;
`
`
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`means for applying an electrical pulse across the weakly-
`ionized plasma
`to generate a strongly-ionized plasma
`comprising a first plurality of ions;
`
`means for exchanging the strongly-ionized plasma with a
`second volume of feed gas while applying the electrical pulse
`across the second volume of feed gas to generate a strongly-
`ionized plasma comprising a second plurality of ions; and
`
`means for applying a bias voltage to a substrate that is
`positioned proximate to the cathode, the bias voltage causing
`ions in the first and the second plurality of ions to impact a
`surface of the substrate in a manner that causes etching of the
`surface of the substrate.
`
`Ex. 1101, 23:46–67, 24:45–65.
`
`
`
`D. Prior Art Relied Upon
`
`Based on the instituted grounds, Gillette relies upon the following
`
`prior art references:
`
`Lantsman
`Wang
`
`
`
`
`
`
`US 6,190,512
`US 6,413,382
`
`Feb. 20, 2001
`July 2, 2002
`
`(Ex. 1104)
`(Ex. 1108)
`
`D.V. Mozgrin, et al., High-Current Low-Pressure Quasi-Stationary
`Discharge in a Magnetic Field: Experimental Research, 21 PLASMA
`PHYSICS REPORTS 400–409 (1995) (Ex. 1102) (hereinafter “Mozgrin”).
`
`
`A. A. Kudryavtsev and V.N. Skrebov, Ionization Relaxation in a
`Plasma Produced by a Pulsed Inert-Gas Discharge, 28(1) SOV. PHYS.
`TECH. PHYS. 30–35 (Jan. 1983) (Ex. 1103) (hereinafter “Kudryavtsev”).
`
`
`
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`
`E. Grounds of Unpatentability
`
`We instituted the instant trial based on the following grounds of
`
`unpatentability (Dec. 28):
`
`Claim(s)
`
`Basis
`
`References
`
`30–34 and 37
`
`§ 103(a) Wang, Mozgrin, and Lantsman
`
`35
`
`36
`
`
`
`§ 103(a)
`
`Wang, Mozgrin, Lantsman, and
`Kudryavtsev
`
`§ 103(a) Wang and Mozgrin
`
`II. ANALYSIS
`
`A. Claim Construction
`
`In an inter partes review, claim terms in an unexpired patent are given
`
`their broadest reasonable construction in light of the specification of the
`
`patent in which they appear. 37 C.F.R. § 42.100(b); see also In re Cuozzo
`
`Speed Techs., LLC, 793 F.3d 1268, 1275–79 (Fed. Cir. 2015) (“Congress
`
`implicitly approved the broadest reasonable interpretation standard in
`
`enacting the AIA,”4 and “the standard was properly adopted by PTO
`
`regulation.”). Significantly, claims are not interpreted in a vacuum but are
`
`part of, and read in light of, the specification. United States v. Adams,
`
`383 U.S. 39, 49 (1966) (“[I]t is fundamental that claims are to be construed
`
`in the light of the specifications and both are to be read with a view to
`
`ascertaining the invention.”). Claim terms are given their ordinary and
`
`customary meaning as would be understood by one of ordinary skill in the
`
`
`4 The Leahy-Smith America Invents Act, Pub. L. No. 11229, 125 Stat. 284
`(2011) (“AIA”).
`
`
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`art in the context of the entire disclosure. In re Translogic Tech., Inc., 504
`
`F.3d 1249, 1257 (Fed. Cir. 2007). An inventor may rebut that presumption
`
`by providing a definition of the term in the specification with “reasonable
`
`clarity, deliberateness, and precision.” In re Paulsen, 30 F.3d 1475, 1480
`
`(Fed. Cir. 1994). In the absence of such a definition, limitations are not to
`
`be read from the specification into the claims. In re Van Geuns, 988 F.2d
`
`1181, 1184 (Fed. Cir. 1993).
`
`The parties identify five claim elements recited in the claims as
`
`means-plus-function elements, invoking 35 U.S.C. § 112, ¶ 6.5 Pet. 12–15;
`
`Prelim. Resp. 15–19. We address the claim terms identified by the parties
`
`below.
`
`We agree that those claim elements are written in means-plus-function
`
`form and fall under 35 U.S.C. § 112, ¶ 6, because: (1) each claim element
`
`uses the term “means for”; (2) the term “means for” in each claim element is
`
`modified by functional language; and (3) the term “means for” is not
`
`modified by any structure recited in the claim to perform the claimed
`
`function. Personalized Media Commc’ns, LLC v. Int’l Trade Comm’n,
`
`161 F.3d 696, 703–04 (Fed. Cir. 1998) (using the term “means for” creates a
`
`rebuttable presumption that the drafter intended to invoke § 112, ¶ 6)
`
`(citations omitted); Sage Prods., Inc. v. Devon Indus., Inc., 126 F.3d 1420,
`
`1427–28 (Fed. Cir. 1997) (the presumption is not rebutted if the term
`
`“means for” is modified by functional language and is not modified by any
`
`
`5 Section 4(c) of the AIA re-designated 35 U.S.C. § 112, ¶ 6, as 35 U.S.C.
`§ 112(f). Pub. L. No. 112-29, 125 Stat. 284, 296 (2011). Because the ’775
`Patent has a filing date before September 16, 2012 (effective date), we refer
`to the pre-AIA version of § 112 in this Decision.
`
`
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`7
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`structure recited in the claim to perform the claimed function); see also
`
`Williamson v. Citrix Online, LLC, 792 F.3d 1339, 1349 (Fed. Cir. 2015)
`
`(confirming that “use of the word ‘means’ creates a presumption that § 112,
`
`¶ 6 applies” (citing Personalized Media, 161 F.3d at 703)).
`
`The first step in construing a means-plus-function claim element is to
`
`identify the recited function in the claim element. Med. Instrumentation &
`
`Diagnostics Corp. v. Elekta AB, 344 F.3d 1205, 1210 (Fed. Cir. 2003). The
`
`second step is to look to the specification and identify the corresponding
`
`structure for that recited function. Id. A structure disclosed in the
`
`specification qualifies as “corresponding” structure only if the specification
`
`or prosecution history clearly links or associates that structure to the function
`
`recited in the claim. B. Braun Med., Inc. v. Abbott Labs., 124 F.3d 1419,
`
`1424 (Fed. Cir.1997). “While corresponding structure need not include all
`
`things necessary to enable the claimed invention to work, it must include all
`
`structure that actually performs the recited function.” Default Proof Credit
`
`Card Sys. Inc. v. Home Depot U.S.A., Inc., 412 F.3d 1291, 1298 (Fed. Cir.
`
`2005) (citation omitted).
`
`Upon review of the parties’ contentions and the Specification, we set
`
`forth our claim constructions in the Decision on Institution for the means-
`
`plus-function elements identified by the parties. Dec. 8–14. Petitioner does
`
`not challenge any aspect of our claim constructions as to these claim
`
`elements, and Patent Owner does not challenge these constructions, except
`
`as noted below in our substantive discussion of the grounds of
`
`unpatentability. PO Resp. 10–17; Reply 2. Based on this entire record, we
`
`also discern no reason to modify our claim constructions at this juncture.
`
`
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`8
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`For convenience, our claim constructions are reproduced in the table
`
`below:
`
`Means-Plus-Function
`Claim Element
`“means for ionizing a
`[volume of] feed gas”
`
`“means for generating a
`magnetic field”
`
`“means for applying an
`electrical field [or pulse]”
`
`“means for exchanging”
`
`“means for applying a
`bias voltage”
`
`
`Identified Corresponding Structure
`
`a power supply electrically connected to a
`cathode, an anode, and/or an electrode
`a magnet assembly having either a
`permanent magnet or a current source
`coupled to one or more electro-magnets
`a pulsed power supply electrically
`connected to a cathode, an anode, and/or an
`electrode
`a gas flow control system and structures for
`supplying the gas to the strongly-ionized
`plasma
`a bias voltage source electrically coupled to
`substrate
`
`B. Principles of Law
`
`A patent claim is unpatentable under 35 U.S.C. § 103(a) if the
`
`differences between the claimed subject matter and the prior art are such that
`
`the subject matter, as a whole, would have been obvious at the time the
`
`invention was made to a person having ordinary skill in the art to which said
`
`subject matter pertains. KSR Int’l Co. v. Teleflex Inc., 550 U.S. 398, 406
`
`(2007). The question of obviousness is resolved on the basis of underlying
`
`factual determinations including: (1) the scope and content of the prior art;
`
`(2) any differences between the claimed subject matter and the prior art;
`
`(3) the level of ordinary skill in the art; and (4) objective evidence of
`
`nonobviousness. Graham v. John Deere Co., 383 U.S. 1, 17–18 (1966). In
`
`that regard, an obviousness analysis “need not seek out precise teachings
`
`
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`directed to the specific subject matter of the challenged claim, for a court
`
`can take account of the inferences and creative steps that a person of
`
`ordinary skill in the art would employ.” KSR, 550 U.S. at 418; Translogic,
`
`504 F.3d at 1259. We analyze the asserted grounds of unpatentability in
`
`accordance with the above-stated principles.
`
`
`C. Claims 30–37—Obviousness over Wang, Mozgrin, and Lantsman;
`Wang, Mozgrin, Lantsman, and Kudryavtsev; or Wang and Mozgrin
`
`Gillette asserts that claims 30–34 and 37 are unpatentable under
`
`35 U.S.C. § 103(a) as obvious over the combination of Wang, Mozgrin, and
`
`Lantsman. Pet. 38–51. Gillette also asserts that claims 35 and 36 are
`
`unpatentable under 35 U.S.C. § 103(a) as obvious over the combination of
`
`Wang, Mozgrin, Lantsman, and Kudryavtsev, or Wang and Mozgrin,
`
`respectively. Pet. 51–58. As support, Gillette provides detailed
`
`explanations as to how each claim limitation is met by the references and
`
`rationales for combining the references, as well as a declaration of
`
`Mr. Richard DeVito (Ex. 1111). Gillette also submitted a Declaration of
`
`Dr. John Bravman (Ex. 1120) to support its Reply to Zond’s Patent Owner
`
`Response.
`
`Zond responds that the combinations of prior art do not disclose every
`
`claim element. PO Resp. 34–46. Zond also argues that insufficient reason
`
`exists to combine the technical disclosures of Wang, Mozgrin, Lantsman,
`
`and Kudryavtsev. Id. at 18–34. To support its contentions, Zond proffers a
`
`Declaration of Dr. Larry D. Hartsough (Ex. 2006).
`
`We have reviewed the entire record before us, including the parties’
`
`explanations and supporting evidence presented during this trial. We begin
`
`
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`our discussion with a brief summary of Wang, Lantsman, and Kudryavtsev,
`
`address their combination with Mozgrin, and then we address the parties’
`
`contentions in turn.
`
`Wang
`
`
`
`Wang discloses a power pulsed magnetron sputtering apparatus for
`
`generating a very high plasma density. Ex. 1108, Abs. Wang also discloses
`
`a sputtering method for depositing metal layers onto advanced
`
`semiconductor integrated circuit structures. Id. at 1:4–15.
`
`Figure 1 of Wang, reproduced below, illustrates a cross-sectional view
`
`of a power pulsed magnetron sputtering reactor:
`
`
`
`Fig. 1 of Wang illustrates its magnetron sputtering apparatus.
`
`As shown in Figure 1 of Wang, magnetron sputtering apparatus 10 has
`
`pedestal electrode 18 for supporting semiconductor substrate 20, anode 24,
`
`cathode 14, magnet assembly 40, pulsed DC power supply 80, and bias
`
`power supply 44, the latter used to apply a bias voltage to the substrate. Id.
`
`at 3:57–4:55. According to Wang, the apparatus is capable of creating high
`
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`density plasma in region 42, from argon gas feed 32 through mass flow
`
`controller 34, which ionizes a substantial fraction of the sputtered particles
`
`into positively charged metal ions and also increases the sputtering rate. Id.
`
`at 4:5–34. Wang further recognizes that, if a large portion of the sputtered
`
`particles are ionized, the films are deposited more uniformly and
`
`effectively—the sputtered ions can be accelerated towards a negatively
`
`charged substrate, coating the bottom and sides of holes that are narrow and
`
`deep. Id. at 1:24–29.
`
`Figure 6 of Wang, reproduced below, illustrates how the apparatus
`
`applies a pulsed power to the plasma:
`
`
`
`Fig. 6 of Wang illustrates a representation of applied pulses.
`
`As shown in Figure 6 of Wang, the target is maintained at background
`
`power level PB between high power pulses 96 with peak power level PP. Id.
`
`at 7:13–39. Background power level PB exceeds the minimum power
`
`necessary to support a plasma in the chamber at the operational pressure
`
`(e.g., 1kW). Id. Peak power PP is at least 10 times (preferably 100 or 1000
`
`times) background power level PB. Id. The application of high peak power
`
`PP causes the existing plasma to spread quickly, and increases the density of
`
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`the plasma. Id. According to Mr. DeVito, Wang’s apparatus generates a
`
`low-density (weakly-ionized) plasma during the application of background
`
`power PB, and a high-density plasma during the application of peak power
`
`PP. Ex. 1111 ¶¶ 137–140; see also Pet. 43–45.
`
`Lantsman
`
`Lantsman discloses a plasma ignition system for plasma processing
`
`chambers having primary and secondary power supplies, used to generate a
`
`plasma current and a process initiation voltage, respectively. Ex. 1104, Abs.
`
`The primary power supply provides the primary power to electrically drive
`
`the cathode during the plasma process, and the secondary power supply
`
`supplies an initial plasma ignition voltage to “pre-ignite” the plasma so that
`
`when the primary power supply is applied, the system smoothly transitions
`
`to final plasma development and deposition. Id. at 2:48–51.
`
`The system is applicable to magnetron and non-magnetron sputtering
`
`and RF sputtering systems. Id. at 1:6–8. Lantsman also provides that
`
`“arcing which can be produced by overvoltages can cause local overheating
`
`of the target, leading to evaporation or flaking of target material into the
`
`processing chamber and causing substrate particle contamination and device
`
`damage,” and “[t]hus, it is advantageous to avoid voltage spikes during
`
`processing wherever possible.” Id. at 1:51–59.
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`Lantsman also discloses that “at the beginning of processing . . . gas is
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`introduced into the chamber” and “[w]hen the plasma process is completed,
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`the gas flow is stopped.” Id. at 3:10–13. This is illustrated in Figure 6 of
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`Lantsman reproduced below:
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`Fig. 6 of Lantsman illustrates the timing of its processes
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`Figure 6 illustrates that the gas flow is initiated, and the gas flow and
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`pressure begin to ramp upwards toward normal processing levels for the
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`processing stage. Id. at 5:39–42.
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`Kudryavtsev
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`Kudryavtsev discloses a multi-step ionization plasma process,
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`comprising the steps of exciting the ground state atoms to generate excited
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`atoms, and then ionizing the excited atoms. Ex. 1103, Abs., Figs. 1, 6.
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`Figure 1 of Kudryavtsev (annotations added) illustrates the atomic
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`energy levels during the slow and fast stages of ionization. Annotated
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`Figure 1 is reproduced below:
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`Annotated Fig. 1 of Kudryavtsev illustrates stages of ionization.
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`As shown in annotated Figure 1 of Kudryavtsev, ionization occurs
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`with a “slow stage” (Fig. 1a) followed by a “fast stage” (Fig. 1b). During
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`the initial slow stage, direct ionization provides a significant contribution to
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`the generation of plasma ions (arrow Γ1e showing ionization (top line labeled
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`“e”) from the ground state (bottom line labeled “1”)). Mr. DeVito explains
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`that Kudryavtsev notes that under certain conditions multi-step ionization
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`can be the dominant ionization process. Ex. 1111 ¶¶ 121–124; Pet. 53.
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`Specifically, Kudryavtsev discloses:
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`For nearly stationary n2 [excited atom density] values . . . there
`is an explosive increase in ne [plasma density]. The subsequent
`increase in ne then reaches its maximum value, equal to the rate
`of excitation . . . which is several orders of magnitude greater
`than the ionization rate during the initial stage.
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`Ex. 1103, 31 (emphasis added). Kudryavtsev also recognizes that “in a
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`pulsed inert-gas discharge plasma at moderate pressures . . . [i]t is shown
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`that the electron density increases explosively in time due to accumulation of
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`atoms in the lowest excited states.” Id. at Abs., Fig. 6.
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`Rationale to Combine References
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`Gillette notes Mozgrin provides for a similar system to that described
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`in Wang (Pet. 40), and Gillette also argues the similarities between the
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`systems of Wang and Mozgrin would have made it obvious to have used the
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`system of Wang for etching, as taught by Mozgrin. Pet. 47–48 (citing
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`Ex. 1102, 403). With respect to Wang and Lantsman, Gillette argues that:
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`[I]f one of ordinary skill took Lantsman’s teaching of
`continually introducing new feed gas during processing, then
`the electrical pulse of Wang would be applied across a second
`volume of feed gas, i.e., the additional volume of feed gas being
`supplied, and Mozgrin’s pulse would thus generate a second
`plurality of ions.
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`Pet. 45–46. Gillette further argues that it would have been obvious to
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`continue to add feed gas during etching, as confirmed by Lantsman.
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`Id. at 46.
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`In addition, Gillette argues that it would have been obvious to
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`combine Wang, Mozgrin, and Lantsman with Kudryavtsev because
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`Kudryavtsev generally discloses the characteristic of ionization
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`whenever a field is applied suddenly to a weakly-ionized gas.
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`Pet. 30–33, 53 (citing Ex. 1103, 34). The applied pulses of Wang,
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`discussed above, would act to generate suddenly an electric field, and
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`one of ordinary skill reading Wang would have been motivated to
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`consider Kudryavtsev to further appreciate the effects of applying
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`Wang’s pulse. Id. Mr. DeVito provides similar conclusions,
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`testifying that “Kudryavtsev . . . explains the contribution of excited
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`atoms to the overall ionization process,” and that this would have been
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`obvious to have been applied to the system in Wang. Ex. 1111
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`¶¶ 120, 156.
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`The parties’ dispute mainly centers on whether Gillette has articulated
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`a reason with rational underpinning why one with ordinary skill in the art
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`would have combined the prior art teachings. Zond argues that Gillette fails
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`to demonstrate that one with ordinary skill in the art would have combined
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`the systems of Wang, Mozgrin, Kudryavtsev, and Lantsman to achieve the
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`claimed invention with reasonable expectation of success or predictable
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`results. PO Resp. 18–34.
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`In particular, Zond contends that Gillette does not take into
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`consideration the substantial, fundamental structural differences between the
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`systems of Wang, Mozgrin, Kudryavtsev, and Lantsman—e.g., pressure,
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`chamber geometry, gap dimensions, and magnetic fields. Id. at 29–34
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`(citing, e.g., Ex. 1102, Abstract, 400–401; Ex. 1104, Abstract, 2:49–51,
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`4:11–37, 5:42–52, Fig. 6; Ex. 1108, 3:60–61, 5: 18–22, 26–27, 43–48, 52–
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`54, 8:41–42; Ex. 2006 ¶¶ 12, 15, 57–60, 66, 70–71, 78). Additionally, even
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`if a combination was somehow made, Zond argues that it would differ
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`significantly from the system disclosed in the ’775 Patent. Id.
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`In its Reply, Gillette responds that Zond’s arguments focus on bodily
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`incorporating one system into the other. Reply 8–11. Gillette also responds
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`that Mozgrin demonstrates that the teachings of Kudryavtsev can be
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`successfully applied in different systems with different geometries and
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`conditions. Id. at 10–11. Upon consideration of the evidence before us, we
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`are persuaded by Gillette’s contentions.
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`Specifically, we are not persuaded by Zond’s argument that Mozgrin’s
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`and Wang’s sputtering apparatuses would have been viewed as significantly
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`different, or that one with ordinary skill in the art would not have had a
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`reasonable expectation of success in combining the teachings. Obviousness
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`does not require absolute predictability, only a reasonable expectation that
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`the beneficial result will be achieved. In re Merck & Co., 800 F.2d 1091,
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`1097 (Fed. Cir. 1986).
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`As Dr. Bravman testifies, it was known that increasing the sputter
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`etching rate was desirable and that all of the references are directed to that
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`same common goal. Ex. 1120 ¶¶ 68, 71, 79. Additionally, Kudryavtsev’s
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`model on plasma behavior is not intended to be limited to a particular type
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`of plasma apparatus. Id. ¶ 72. Indeed, Kudryavtsev discloses a study of the
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`ionization relaxation in plasma when the external electric field suddenly
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`increases. Id. Specifically, Kudryavtsev discloses that “the electron density
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`increases explosively in time due to accumulation of atoms in the lowest
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`excited states.” Ex. 1103, Abs. (emphasis added). Kudryavtsev also
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`describes the experimental results that confirm the model. Id. at 32–34.
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`Moreover, Kudryavtsev expressly explains that “the effects studied in this
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`work are characteristic of ionization whenever a field is suddenly applied to
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`a weakly ionized gas.” Id. at 34 (emphasis added).
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`Dr. Bravman also testifies that a person having ordinary skill in the art
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`“would have looked to Kudryavtsev to understand how plasma would react
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`to a quickly applied voltage pulse, and how to achieve an explosive increase
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`in electron density” when generating a strongly-ionized plasma for
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`improving sputtering and manufacturing processing. Ex. 1120 ¶ 73.
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`Dr. Bravman further explains that such an artisan would have known how to
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`apply Kudryavtsev’s model to Wang’s system by making any necessary
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`changes to accommodate the differences through routine experimentation.
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`Id. ¶¶ 73–74. Mozgrin cites to Kudryavtsev and discloses that in
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`“[d]esigning the unit, we took into account the dependences which had been
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`obtained in [Kudryavtsev] of ionization relaxation on pre-ionization
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`parameters, pressure, and pulse voltage amplitude.” Ex. 1102, 401.
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`Dr. Bravman also explains that this illustrates that one with ordinary skill in
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`the art at the time of the invention was capable of applying the teachings of
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`Kudryavtsev to magnetron sputtering systems, such as Wang’s. Ex. 1120 ¶
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`75. On this record, we credit Dr. Bravman’s testimony (id. ¶¶ 68–77)
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`because his explanations are consistent with the prior art of record.
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`For the foregoing reasons, we are persuaded that Gillette has
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`articulated a reason with rational underpinning why one with ordinary skill
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`in the art would have combined Wang, Mozgrin, Lantsman, and
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`Kudryavtsev as indicated in the Petition.
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`The Steps of Claim 30 Do Not Require a Specific Order
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`Claim 30 recites steps of “ionizing a . . . feed gas to form a weakly-
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`ionized plasma,” and “generating a magnetic field proximate to the weakly-
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`ionized plasma.” Zond argues that the Petition is deficient because it fails to
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`demonstrate the method steps of claim 30 in their required, recited order,
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`because the magnetic field in Wang is always on and not generated later,
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`after the formation of the weakly-ionized plasma. PO Resp. 34–37.
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`Gillette responds that Zond’s expert, Dr. Hartsough, acknowledges
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`that claim 15, which recites similar steps in the same order, covers
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`embodiments where the magnetic field is applied prior to feed gas being
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`ionized to form the weakly-ionized plasma. Reply 2–3 (citing Ex. 1101,
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`Figs. 12A, 13A; Ex. 1119, 87:6–18). Gillette also cites to its own expert,
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`Dr. Bravman, to support its interpretation of claim 30. Reply 3 (citing
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`Ex. 1120 ¶¶ 97–100). We agree with Gillette’s arguments.
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`During Oral Hearing, counsel for Zond acknowledged
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`Dr. Hartsough’s testimony and did not dispute that the steps of claim 15, and
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`thus, claim 30, do not require a specific order, but continued to emphasize
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`that if Gillette believed a specific order was required, and did not make th