`571-272-7822
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`
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` Paper 11
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`Entered: October 10, 2014
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`
`
`
`UNITED STATES PATENT AND TRADEMARK OFFICE
`____________
`
`BEFORE THE PATENT TRIAL AND APPEAL BOARD
`____________
`
`
`
`THE GILLETTE COMPANY,
`Petitioner,
`
`v.
`
`ZOND, LLC,
`Patent Owner.
`____________
`
`Case IPR2014-00580
`Patent 6,896,773 B2
`____________
`
`
`
`Before KEVIN F. TURNER, DEBRA K. STEPHENS, JONI Y. CHANG,
`SUSAN L. C. MITCHELL, and JENNIFER M. MEYER,
`Administrative Patent Judges.
`
`
`STEPHENS, Administrative Patent Judge.
`
`
`
`DECISION
`Institution of Inter Partes Review
`37 C.F.R. § 42.108
`
`
`
`
`
`
`
`IPR2014-00580
`Patent 6,896,773 B2
`
`I. INTRODUCTION
`
`On April 30, 2014, Gillette Corporation (“Gillette”) filed a Revised
`
`Petition requesting inter partes review of claims 1–20 and 34–39 (“the
`
`challenged claims”) of U.S. Patent No. 6,896,773 B2 (“the ’773 patent”).
`
`Paper 7 (“Pet.”). Zond, LLC (“Zond”) filed a Patent Owner Preliminary
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`Response. Paper 10 (“Prelim. Resp.”). We have jurisdiction under 35
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`U.S.C. § 314.
`
`The standard for instituting an inter partes review is set forth in
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`35 U.S.C. § 314(a), which provides:
`
`THRESHOLD.—The Director may not authorize an inter
`partes review to be instituted unless the Director determines
`that the information presented in the petition filed under section
`311 and any response filed under section 313 shows that there
`is a reasonable likelihood that the petitioner would prevail with
`respect to at least 1 of the claims challenged in the petition.
`
`Taking into account Zond’s Preliminary Response, and based on the
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`information presented in the Petition, we are persuaded a reasonable
`
`likelihood exists that Gillette would prevail in challenging claims 1–20 and
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`34–39 as unpatentable. Pursuant to 35 U.S.C. § 314, we hereby authorize an
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`inter partes review as to claims 1–20 and 34–39 of the ’773 patent.
`
`A. Related Matters
`
`
`
`Gillette indicates the ’773 patent was asserted in Zond, LLC v. The
`
`Gillette Co., No.1:13-CV-11567-DJC (D. Mass.). Pet. 1 and Paper 5.
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`Gillette also identifies other matters where Zond asserted the claims of the
`
`’773 patent against third parties. Id.
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`2
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`IPR2014-00580
`Patent 6,896,773 B2
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`B. The ’773 patent
`
`The ’773 patent relates to a method and an apparatus for high-
`
`deposition sputtering. Ex. 1001, Abs. At the time of the invention,
`
`sputtering was a well-known technique for depositing films on
`
`semiconductor substrates. Id. at 1:5–6. According to the ’773 patent,
`
`conventional magnetron sputtering systems deposit films with relatively low
`
`uniformity. Id. at 1:53–54. Although film uniformity can be increased by
`
`mechanically moving the substrate and/or magnetron, the ’773 patent
`
`indicates such systems are relatively complex and expensive to implement.
`
`Id. at 1:54–57. The’773 patent further states conventional magnetron
`
`sputtering systems also have relatively poor target utilization (how
`
`uniformly the target material erodes during sputtering) and a relatively low
`
`deposition rate (the amount of material deposited on the substrate per unit of
`
`time). Id. at 1:57–66.
`
`To address these issues, the ’773 patent discloses that increasing the
`
`sputtering yield (the number of target atoms ejected from the target per
`
`incident particle) will increase the deposition rate. Id. at 2:1–4. However,
`
`dramatically increasing power applied to plasma, although resulting in more
`
`uniform erosion of target 116 and high sputtering yield, may increase the
`
`probability of an electrical break-down condition leading to an undesirable
`
`electrical discharge between cathode assembly 114 and anode 130,
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`regardless of pulse duration. Id. at 4:29–36. This undesirable electrical
`
`discharge will corrupt the sputtering process, causing contamination in
`
`3
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`IPR2014-00580
`Patent 6,896,773 B2
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`vacuum chamber 104, and will overheat the target, causing target damage.
`
`Id. at 4:37–40.
`
`Figure 4 is reproduced below:
`
`
`
`4
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`IPR2014-00580
`Patent 6,896,773 B2
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`Figure 4 illustrates a cross-sectional view of magnetron sputtering apparatus
`
`200. As illustrated by Figure 4, in one embodiment, magnetron sputtering
`
`apparatus 200 includes vacuum chamber 202 electrically coupled to ground
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`and to feed gas source 208 by one or more feed gas lines 207. Id. at 5:60–
`
`6:2. Magnetron sputtering apparatus 200 includes cathode assembly 216,
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`which includes sputtering target 220. Id. at 6:22–28. Pulsed power supply
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`234 is coupled directly or indirectly to both cathode assembly 216 and anode
`
`238. Id. at 6:40–57. Anode 238 is positioned to form gap 244 between
`
`anode 238 and cathode assembly 216 sufficient to allow current to flow
`
`through region 245 between anode 238 and cathode assembly 216. Id. at
`
`7:3–7.
`
`Feed gas is supplied to chamber 202 directly between cathode
`
`assembly 216 and anode 238, allowing increase of flow rate of the gas. Id.
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`at 7:44–49. “Increasing the flow rate of the gas allows longer duration
`
`impulses and thus, can result in the formation [of] higher density plasmas.”
`
`Id. at 7:49–51.
`
`An ionization source includes pulsed power supply 234 that applies a
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`voltage pulse (a pre-ionizing voltage) having an amplitude and shape
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`between cathode assembly 216 and anode 238 across feed gas 256, such that
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`a weakly-ionized plasma is generated. Id. at 7:53–62. Once the weakly-
`
`ionized plasma is formed, power supply 234 applies high-power pulses
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`between cathode assembly 216 and anode 238, across weakly-ionized
`
`plasma 262, generating strongly-ionized plasma 268 from weakly-ionized
`
`plasma 262. Id. at 8:65–9:1, 13:41–45; Figs. 5B–5D. Electric field 266
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`5
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`IPR2014-00580
`Patent 6,896,773 B2
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`causes the feed gas to experience stepwise ionization, increasing formation
`
`of ions that enhance strongly-ionized plasma 268. Id. at 20:34–38. As
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`illustrated in Figure 11B, after the strongly-ionized plasma is formed (step
`
`626), sputtering yield is monitored (step 628) and the power is increased if
`
`sputtering yield is insufficient (step 630). Id. at 20:53–57. In one
`
`embodiment, power delivered (step 632) to the plasma is “sufficient to
`
`vaporize a surface layer of the target,” thus, increasing sputtering yield in a
`
`substantially non-linear fashion. Id. at 20:60–63.
`
`
`
`C. Illustrative Claim
`
`Of the challenged claims, claims 1 and 34 are independent. Claims 2–
`
`20 and 35–39 depend, directly or indirectly, from claims 1 and 34. Claim 1,
`
`reproduced below, is illustrative:
`
`1. A sputtering source comprising:
`
`a cathode assembly that is positioned adjacent to an anode, the
`cathode assembly including a sputtering target;
`
`an ionization source that generates a weakly-ionized plasma
`from a feed gas proximate to the anode and the cathode
`assembly; and
`
`a power supply that generates a voltage pulse between the
`anode and the cathode assembly that creates a strongly-ionized
`plasma from the weakly-ionized plasma, an amplitude and a
`rise time of the voltage pulse being chosen to increase a density
`of ions in the strongly-ionized plasma enough to generate
`sufficient thermal energy in the sputtering target to cause a
`sputtering yield to be non-linearly related to a temperature of
`the sputtering target.
`
`6
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`IPR2014-00580
`Patent 6,896,773 B2
`
`Ex. 1001, 21:8–24.
`
`
`
`D. The Prior Art Relied Upon
`
`Gillette relies upon the following prior art references:
`
`(Ex. 1003)
`(Ex. 1007)
`(Ex. 1008)
`(Ex. 1009)
`(Ex. 1011)
`
`July 2, 2002
`Oct. 23, 2001
`Feb. 20, 2001
`Sep. 28, 1999
`Jun. 4, 2002
`
` US 6,413,382 B1
`Wang
` US 6,306,265 B1
`Fu
`
` US 6,190,512 B1
`Lantsman
`Kawamata US 5,958,155
`
`Chiang
` US 6,398,929 B1
`
`D.V. Mozgrin, et al., High-Current Low-Pressure Quasi-Stationary
`Discharge in a Magnetic Field: Experimental Research, 21 PLASMA
`PHYSICS REPORTS 400–409 (1995) (Ex. 1002) (hereinafter “Mozgrin”).
`
`D.V. Mozgrin, High-Current Low-Pressure Quasi-Stationary Discharge in a
`Magnetic Field: Experimental Research, Thesis at Moscow Engineering
`Physics Institute (1994) (Ex. 1015) (hereinafter “Mozgrin Thesis”).1
`
`Interaction of Low-Temperature Plasma With Condensed Matter, Gas, and
`Electromagnetic Field in (III) ENCYCLOPEDIA OF LOW-TEMPERATURE
`PLASMA, (V.E. Fortov ed., 2000)(Ex. 1004)(hereinafter “Fortov”).2
`
`A.A. Kudryavtsev and V.N. Skrebov, Ionization Relaxation in a Plasma
`Produced by a Pulsed Inert-Gas Discharge, 28(1) SOV. PHYS. TECH. PHYS.,
`pp. 30-35, January 1983 (Ex. 1006) (hereinafter “Kudryavtsev”).
`
`
`
`1 Mozgrin Thesis is a Russian-language reference (Ex. 1016). The citations
`to Mozgrin Thesis are to the certified English-language translation submitted
`by Gillette (Ex. 1015).
`2 Fortov is a Russian-language reference (Ex. 1010). The citations to Fortov
`are to the certified English-language translation submitted by Gillette (Ex.
`1004).
`
`7
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`IPR2014-00580
`Patent 6,896,773 B2
`
`E. The Asserted Grounds of Unpatentability
`
`Gillette asserts the following grounds of unpatentability:
`
`Claim(s)
`
`Basis
`
`References
`
`1, 6, and 8–20 3
`
`§ 103 Mozgrin and Fortov
`
`5
`
`§ 103 Mozgrin, Fortov, and Kawamata
`
`1, 6, and 8–20
`
`§ 103 Wang and Fortov
`
`5
`
`§ 103 Wang, Fortov, and Kawamata
`
`3, 4, and 34–39
`
`§ 103 Mozgrin, Fortov, and Lantsman
`
`3, 4, and 34–39
`
`§ 103 Wang, Fortov, and Lantsman
`
`7
`
`7
`
`2
`
`2
`
`
`
`§ 103 Mozgrin, Kudryavtsev, and Fortov
`
`§ 103
`
`§ 103
`
`Wang, Mozgrin, Kudryavtsev, and
`Fortov
`Mozgrin, Mozgrin Thesis, Fortov,
`and Raizer
`
`§ 103 Wang, Fortov, Fu, and Raizer
`
`II. DISCUSSION
`
`A.
`
`Printed Publication under 35 U.S.C. § 102
`
`As an initial matter, we address the issue of whether Mozgrin Thesis
`
`is available as prior art under 35 U.S.C. § 102 for the purposes of this
`
`
`
`3 We note under this Ground, Gillette includes claims 36–39 which depend
`from independent claim 34, in the headings. Pet. i, 13. These claims are not
`argued in the ground nor is independent claim 34 addressed under this
`ground. Accordingly, we determine this was an inadvertent typographical
`error and do not address these claims in the discussion of this ground.
`8
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`IPR2014-00580
`Patent 6,896,773 B2
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`decision. In its Petition, Gillette asserts that Mozgrin Thesis is a doctoral
`
`thesis at Moscow Engineering Physics Institute, published in 1994, and thus,
`
`is prior art under 35 U.S.C. § 102(b). Pet. 8, 55–57. As support, Gillette
`
`proffers a copy of the catalog entry for Mozgrin Thesis at the Russian State
`
`Library. Ex. 1014.
`
`Zond responds that Gillette fails to demonstrate the Morgrin Thesis is
`
`prior art under 35 U.S.C. § 102. Prelim. Resp. 55–57. Specifically, Zond
`
`contends the evidence is insufficient to demonstrate that the document was
`
`disseminated or otherwise made available to the extent ordinarily skilled
`
`artisans, exercising reasonable diligence, would have been able to locate it.
`
`Id. at 55–56.
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`Additionally, Zond asserts the 2002 date printed below the catalog
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`entry does not establish that Mozgrin Thesis was available publicly prior to
`
`the critical date (i.e., November 14, 2002—the filing date of the application
`
`that issued as the ’773 patent). Id. at 56. Zond also alleges Gillette “did not
`
`provide any explanation of the meaning of that date, such as whether or not
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`it is the date on which Mozgrin Thesis became accessible to interested
`
`persons.” Id.
`
`We are not persuaded by Zond’s arguments, as these arguments are
`
`predicated on the incorrect assumption that the 2002 date is the publication
`
`date of Mozgrin Thesis. As shown in the catalog entry, the 2002 date
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`appears to be a claim of copyright in the Ex Libris database from which the
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`catalog entry was retrieved. Ex. 1014, 2. More importantly, the catalog
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`entry clearly shows a publication date of 1994 (“Imprint Moscow 1994”).
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`9
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`IPR2014-00580
`Patent 6,896,773 B2
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`Id. The certified English-language translation of the catalog entry is
`
`reproduced below (Ex. 1014, 1 (annotation added)):
`
`Ex. 1014, 1 is an English translation of the catalog entry of Mozgrin
`
`
`
`Thesis.
`
`Zond does not address why the 1994 imprint date on the catalog entry
`
`at the Russian State Library is insufficient to establish that Mozgrin Thesis
`
`was accessible publicly before the critical date. See In re Hall, 781 F.2d
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`897, 899–900 (Fed. Cir. 1986) (holding a dissertation shelved in the stacks
`
`and indexed in the catalog at a university library is a printed publication
`
`under § 102). To the contrary, the catalog entry demonstrates Mozgrin
`
`Thesis was made available to interested persons by virtue of its title and
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`“Subject” characterization.
`
`Given the evidence on this record, we determine Gillette has shown
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`sufficiently that Mozgrin Thesis is a “printed publication” within the
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`10
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`IPR2014-00580
`Patent 6,896,773 B2
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`meaning of 35 U.S.C. § 102(b). Consequently, Mozgrin Thesis is available
`
`as prior art for the purposes of this decision to demonstrate that the
`
`challenged claims are unpatentable under 35 U.S.C. § 103(a).
`
`B.
`
`Claim Interpretation
`
`In an inter partes review, claim terms in an unexpired patent are given
`
`their broadest reasonable construction in light of the specification of the
`
`patent in which they appear. 37 C.F.R. § 42.100(b). Claim terms are given
`
`their ordinary and customary meaning as would be understood by one of
`
`ordinary skill in the art in the context of the entire disclosure. In re
`
`Translogic Tech. Inc., 504 F.3d 1249, 1257 (Fed. Cir. 2007). An inventor
`
`may rebut that presumption by providing a definition of the term in the
`
`specification with reasonable clarity, deliberateness, and precision. In re
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`Paulsen, 30 F.3d 1475, 1480 (Fed. Cir. 1994). In the absence of such a
`
`definition, limitations are not to be read from the specification into the
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`claims. In re Van Geuns, 988 F.2d 1181, 1184 (Fed. Cir. 1993).
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`Here, both parties agree the broadest reasonable construction standard
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`applies to the claims involved in the instant proceeding, and propose
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`constructions for the claim terms “weakly-ionized plasma” and
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`“strongly-ionized plasma.” Pet. 4–5; Prelim. Resp. 19–20.
`
`“weakly-ionized plasma” and “strongly-ionized plasma”
`
`Claim 1 recites “a voltage pulse . . . that creates a weakly-ionized
`
`plasma and then a strongly-ionized plasma from the weakly-ionized
`
`plasma.” Gillette proposes the claim term “weakly-ionized plasma” should
`
`be interpreted as “a lower density plasma,” and the claim term “strongly-
`
`11
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`IPR2014-00580
`Patent 6,896,773 B2
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`ionized plasma” should be interpreted as “a higher density plasma.” Pet. 4–
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`5.
`
`In its Preliminary Response, Zond proposes the claim term “weakly-
`
`ionized plasma” should be interpreted as “a plasma with a relatively low
`
`peak density of ions,” and the claim term “strongly-ionized plasma” as “a
`
`plasma with a relatively high peak density of ions.” Prelim. Resp. 19 (citing
`
`Ex. 1001, 13:31–33 (“strongly-ionized plasma 268 having a large ion
`
`density being formed”)).
`
`Zond directs our attention to the Specification of U.S. Patent No.
`
`6,806,652 B1 (“the ’652 patent”), which is being challenged in Gillette
`
`Corp. v. Zond, Inc., Case IPR2014-01000 (PTAB), for claim construction.
`
`We recognize when construing claims in patents that derive from the
`
`same parent application and share common terms, “we must interpret the
`
`claims consistently across all asserted patents.” NTP, Inc. v. Research In
`
`Motion, Ltd., 418 F.3d 1282, 1293 (Fed. Cir. 2005). Here, although Zond
`
`characterizes the ’652 patent as “a related patent” (Prelim. Resp. 19–20),
`
`Zond does not explain how the ’652 patent is related to the involved patent
`
`(the ’773 patent) in the instant proceeding.
`
`Nevertheless, we observe no significant difference exists between the
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`parties’ constructions. Pet. 4–5; Prelim. Resp. 19–20. On this record,
`
`therefore, we construe the claim term “weakly-ionized plasma” as “plasma
`
`with a relatively low peak density of ions,” and the claim term “strongly-
`
`ionized plasma” as “plasma with a relatively high peak density of ions.”
`
`
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`12
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`IPR2014-00580
`Patent 6,896,773 B2
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`C.
`
`Principles of Law
`
`Obviousness
`
`A patent claim is unpatentable under 35 U.S.C. § 103(a) if the
`
`differences between the claimed subject matter and the prior art are such that
`
`the subject matter, as a whole, would have been obvious at the time the
`
`invention was made to a person having ordinary skill in the art to which said
`
`subject matter pertains. KSR Int’l Co. v. Teleflex Inc., 550 U.S. 398, 406
`
`(2007). The question of obviousness is resolved on the basis of underlying
`
`factual determinations including: (1) the scope and content of the prior art;
`
`(2) any differences between the claimed subject matter and the prior art;
`
`(3) the level of ordinary skill in the art; and (4) objective evidence of
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`nonobviousness. Graham v. John Deere Co., 383 U.S. 1, 17–18 (1966).
`
`In that regard, an obviousness analysis “need not seek out precise
`
`teachings directed to the specific subject matter of the challenged claim, for
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`a court can take account of the inferences and creative steps that a person of
`
`ordinary skill in the art would employ.” KSR, 550 U.S. at 418; see
`
`Translogic, 504 F.3d at 1259. A prima facie case of obviousness is
`
`established when the prior art itself would appear to have suggested the
`
`claimed subject matter to a person of ordinary skill in the art. In re Rinehart,
`
`531 F.2d 1048, 1051 (CCPA 1976). The level of ordinary skill in the art is
`
`reflected by the prior art of record. See Okajima v. Bourdeau,
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`261 F.3d 1350, 1355 (Fed. Cir. 2001); In re GPAC Inc., 57 F.3d 1573, 1579
`
`(Fed. Cir. 1995); In re Oelrich, 579 F.2d 86, 91 (CCPA 1978).
`
`13
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`IPR2014-00580
`Patent 6,896,773 B2
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`We analyze the grounds asserted under 35 U.S.C. § 103(a) in
`
`accordance with the above-stated principles.
`
`D.
`
`Asserted Ground: Claims 1, 6, and 8–20 – Obviousness over Mozgrin
`and Fortov
`
`
`
`Gillette asserts claims 1, 6, and 8–20 are unpatentable under § 103 for
`
`obviousness over the combination of Mozgrin and Fortov. Pet. 13–25. As
`
`support, Gillette provides detailed explanations as to how each claim
`
`limitation is met by the combination of Mozgrin and Fortov. Id. Gillette
`
`proffers a declaration of Mr. DeVito as support. Ex. 1005.
`
`Zond responds Fortov describes the relationship between sputtering
`
`yield and target temperature, but does not describe how to achieve the non-
`
`linear relationship recited. Pet. 26–27. Moreover, Zond contends neither
`
`Fortov nor Mozgrin teaches the recited limitations. Pet. 26–29. Zond
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`further responds that Gillette has failed to demonstrate the recited claims
`
`would have been obvious because Gillette did not show why an ordinarily
`
`skilled artisan would have been motivated to combine the teachings of
`
`Mozgrin and Fortov, and did not follow the legal framework for an
`
`obviousness analysis. Prelim. Resp. 20–23, 43–47, 53–55.
`
`We have reviewed the parties’ contentions and supporting evidence.
`
`Given the evidence on this record, we determine Gillette has demonstrated a
`
`reasonable likelihood of prevailing on its assertion that claims 1, 6, and 8–20
`
`would have been rendered obvious by the combination of Mozgrin and
`
`Fortov. Our discussion focuses on the deficiencies alleged by Zond as to the
`
`alleged unpatentability of the claims.
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`14
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`IPR2014-00580
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`1. Mozgrin (Ex. 1002)
`
`Mozgrin discloses experimental research conducted on high-current
`
`low-pressure quasi-stationary discharge in a magnetic field. Ex. 1002, 400,
`
`Title; right column. In Mozgrin, pulse or quasi-stationary regimes are
`
`discussed in light of the need for greater discharge power and plasma
`
`density. Id. In Mozgrin, experiments are conducted using a discharge
`
`device configuration having a cathode (1), anode (2) adjacent and parallel to
`
`cathode (1), and magnetic system (3), as shown in Figure 1(a). Id. at 401.
`
`The cathode, which includes a sputtering target, is placed on a cooled
`
`surface. Id. at 401, left col.; 403, right col.
`
`Figure 2 of Mozgrin illustrates a discharge (power) supply unit. The
`
`supply unit includes a pulsed discharge supply unit and a system for pre-
`
`ionization. Id. at 401, left col. For pre-ionization, a stationary magnetron
`
`discharge was used. Id. In this pre-ionization regime, the initial plasma
`
`density was in the 109 and 1011 cm-3. Id. Various gasses are used in the
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`Mozgrin system in the discharge regimes. Id. at 400, right col.; 401, left col.
`
`Figure 3(b) is reproduced below:
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`
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`15
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`IPR2014-00580
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`Figure 3(b) of Mozgrin illustrates an oscillogram of voltage of the quasi-
`
`stationary discharge. Id. at 402. In Figure 3(b), Part 1 represents the voltage
`
`of the stationary discharge (pre-ionization stage); Part 2 displays the square
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`voltage pulse application to the gap (Part 2a), where the plasma density
`
`grows and reaches its quasi-stationary value (Part 2b); and Part 3 displays
`
`the discharge current growing and attaining its quasi-stationary value. Id. at
`
`402, right col. More specifically, the power supply generates a square
`
`voltage with [rise] times (leading edge) of 5–60µs and durations of as much
`
`as 1.5 ms. Id. at 401, right col.
`
`In regime 2, the plasma density exceeds 2 x 1013 cm-3 and in regime 3
`
`the plasma density produces large-volume uniform dense plasmas η1 ≈ 1.5 x
`1015 cm-3. Id. at 409, right col.
`
`2. Fortov (Ex. 1004)
`
`Gillette’s cited portions of Fortov are directed to interaction of plasma
`
`with condensed matter and, more particularly, to sputtering. Ex. 1004, 3–4.
`
`In Fortov, Y is the coefficient of sputtering, “defined as the relation of the
`
`number of sputtered atoms of a target to the number of bombarding ions
`
`(atoms),” which “depends on the type of ions (its atomic number Zi and
`
`mass Mi).” Id. at 6.
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`16
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`Picture VI.1.315 describes the sputtering coefficient of copper
`
`(cuprum) being bombarded by ions of Ar+ with the energy of 400 eV, from
`
`the temperature: 1 –– electrolytic copper, 2 –– rolled copper, 3–– single
`
`crystal copper (cuprum monocrystal), facet (101). Picture VI.1.315 is
`
`reproduced below.
`
`
`
`
`
`Picture VI.1.315 describes the sputtering coefficient of copper (cuprum)
`
`being bombarded by ions of Ar+ with the energy of 400 eV, from the
`
`temperature: 1 –– electrolytic copper, 2 –– rolled copper, 3–– single crystal
`
`copper (cuprum monocrystal), facet (101). According to Fortov, at a
`
`temperature less than T1, coefficient Y is not actually dependent on the
`
`temperature, and at T ≈ T1, Y starts to grow rapidly, concurrently with
`
`growth of temperature. Id. at 9. Fortov further explains temperature T1 is
`
`sometimes defined according to the empirical relation T1 = 0.7 Tm where Tm
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`is the melting temperature, though in some cases, e.g., for tin (stannum) T1 >
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`Tm and T1 = U/40k (k is Boltzmann constant; U is the energy of sublimation
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`correlated to one atom). Id. at 6–7, 9. Temperature T1 depends on the type,
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`energy, and density of ion flow. Id. at 9.
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`17
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`3. Analysis
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`Gillette argues the combination of Mozgrin and Fortov discloses “an
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`amplitude and a rise time of the voltage pulse being chosen to increase a
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`density of ions in the strongly-ionized plasma enough to generate sufficient
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`thermal energy in the sputtering target to cause a sputtering yield to be non-
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`linearly related to a temperature of the sputtering target,” as recited in
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`independent claim 1. Pet. 15–19.
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`In the Preliminary Response, Zond initially argues Gillette has not
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`shown an ordinarily skilled artisan would have been motivated to combine
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`the teachings of Mozgrin and Fortov. Prelim. Resp. 21– 24, 26 –29.
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`Furthermore, Zond contends Gillette has failed to address the Graham
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`factors related to the “scope and content of the prior art” and the “level of
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`ordinary skill in the pertinent art.” Id. at. 23–24, 53–55.
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`Zond additionally contends the claim requires more than separately
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`having a voltage pulse with a rise time and amplitude and achieving greater
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`sputtering yield; it requires achieving greater sputtering yield by choosing
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`the amplitude and rise time of the applied voltage pulse. Id. at 44–46.
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`According to Zond, Mozgrin does not teach achieving a sputtering yield that
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`is non-linearly related to a temperature of the sputtering target, by choosing
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`an amplitude and rise time of the applied voltage pulse, or even discuss
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`temperature of the target. Id. at 45. Moreover, Zond contends Fortov only
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`mentions a non-linear relation of a sputtering yield to a temperature of the
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`sputtering target, but does not teach how that non-linear relation would be
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`achieved. Id. at 46.
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`Based upon the record before us, Zond’s arguments are not
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`persuasive.
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`Mozgrin teaches the power supply generates a square voltage with
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`[rise] times (leading edge) of 5–60 µs and durations of as much as 1.5 ms.
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`Ex. 1002, 401, right col. As illustrated in Figure 3(b) of Mozgrin, as the
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`voltage pulse is applied, the plasma density increases. Id. at 409, right col.
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`Therefore, we are persuaded Mozgrin teaches an amplitude and rise time of
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`a voltage pulse being chosen to increase a density of ions in the strongly-
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`ionized plasma. We are also persuaded by Mr. DeVito’s testimony that
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`sputtering will occur once the chosen voltage pulse is applied. Ex. 1005 ¶¶
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`30, 38–39.
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`We also are persuaded Fortov teaches a non-linear relationship
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`between the sputtering yield and the temperature of the target (Cu (copper)
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`in argon plasma). Ex. 1004, 9. Specifically, we are persuaded Fortov
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`illustrates that the sputtering coefficient of Cu being bombarded by Ar+ ions,
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`relative to temperature is non-linear. Id. at 9, Picture VI.1.315. Fortov
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`further teaches “[t]he dependence of sputtering coefficient on the target
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`material is demonstrated, firstly, in the dependence of mass and atomic
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`number of target atoms, and secondly, in the dependence of binding energy
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`U which is usually considered to be equal to the energy of sublimation
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`correlated to one atom.” Id. at 7. We credit Mr. DeVito’s testimony that it
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`was known “that sputtering causes the temperature of the target surface to
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`increase” and that “sputtering yield is a function of a number of parameters,
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`including target temperature, angle of sputtering ions relative to the target,
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`and the energy of the sputtering ions.” Ex. 1005 ¶ 65.
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`Thus, we are persuaded, based on the record before us, Fortov teaches
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`“generat[ing] sufficient thermal energy in the sputtering target to cause a
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`sputtering yield to be non-linearly related to a temperature of the sputtering
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`target” and further persuaded that the combination of Mozgrin and Fortov
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`teaches “an amplitude and a rise time of the voltage pulse being chosen to
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`increase a density of ions in the strongly-ionized plasma enough to generate
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`sufficient thermal energy in the sputtering target to cause a sputtering yield
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`to be non-linearly related to a temperature of the sputtering target,” as
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`recited in claim 1.
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`Zond argues an ordinarily skilled artisan would not have combined the
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`teachings of Mozgrin and Fortov unless that person had used the ’773 patent
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`as a blueprint for modifying Mozgrin by choosing the amplitude and rise
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`time of the voltage pulse to achieve the non-linear relation in Fortov.
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`Prelim. Resp. 44–47. According to Zond, Mozgrin does not mention the
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`temperature of the target material during the pulse and Fortov does not teach
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`how to achieve a non-linear relation between sputtering yield and
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`temperature. Id. at 45–46. Thus, Zond argues Gillette used hindsight to
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`achieve the recited invention and, further, failed to set forth a proper
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`obviousness analysis. Id. at 46, 54.
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`We are not persuaded by Zond’s arguments. We are persuaded
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`Gillette has articulated reasoning as to why an ordinarily skilled artisan
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`would have been motivated and would have found it obvious to combine the
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`teachings of Mozgrin and Fortov. Zond’s arguments appear to be
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`predicated on an actual, physical substitution of Fortov’s teaching into the
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`system of Mozgrin. “It is well-established that a determination of
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`obviousness based on teachings from multiple references does not require an
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`actual, physical substitution of elements.” In re Mouttet, 686 F.3d 1322,
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`1332 (Fed. Cir. 2012) (citing In re Etter, 756 F.2d 852, 859 (Fed. Cir. 1985)
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`(en banc) (noting that the criterion for obviousness is not whether the
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`references can be combined physically, but whether the claimed invention is
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`rendered obvious by the teachings of the prior art as a whole)).
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`Additionally, one cannot show nonobviousness by attacking references
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`individually where the rejections are based on combinations of references.
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`See In re Merck & Co., Inc., 800 F.2d 1091, 1097 (Fed. Cir. 1986). In that
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`regard, one with ordinary skill in the art is not compelled to follow blindly
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`the teaching of one prior art reference over the other without the exercise of
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`independent judgment. Lear Siegler, Inc. v. Aeroquip Corp., 733 F.2d 881,
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`889 (Fed. Cir. 1984); see also KSR, 550 U.S. at 420–21 (A person with
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`ordinary skill in the art is “a person of ordinary creativity, not an
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`automaton,” and “in many cases . . . will be able to fit the teachings of
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`multiple patents together like pieces of a puzzle.”).
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`We credit Mr. DeVito’s testimony that increasing sputtering yield is
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`beneficial for manufacturing applications. Ex. 1005 ¶ 120. We further
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`credit Mr. DeVito’s testimony that an ordinarily skilled artisan would have
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`found it obvious to pulse the weakly-ionized plasma in Mozgrin with
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`sufficient power to generate strongly-ionized plasma, thereby increasing the
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`strongly-ionized plasma ion density and generating sufficient thermal energy
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`in the sputtering target so as to increase the sputtering yield to a point where
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`“‘it starts to grow rapidly in a non-linear way with the growth of
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`temperature,’ as taught by Fortov.” Id. Additionally, we are persuaded,
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`based on the record before us, that because both Fortov and Mozgrin
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`describe the use of a copper cathode in argon plasma as a suitable system for
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`sputtering, it would have been obvious to an ordinarily skilled artisan to
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`combine the teachings to achieve Fortov’s predictable result of greater
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`sputtering yield. Ex. 1004, Pic. VI.1.315; Ex. 1002, 406, Table1; Ex. 1005,
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`¶ 123. In addition, we note that Mozgrin discusses both the gas temperature
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`and the electrode temperature (Ex. 1002, 406–408), contrary to Zond’s
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`assertion that Mozgrin does not mention the temperature of the target
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`material. Prelim. Resp. 45.
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`Gillette further contends applying the teaching of Fortov to Mozgrin
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`would have been the use of known processes to achieve the predictable
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`result of greater sputtering yield (Pet.19), whereas Zond contends such a
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`combination would be the result of hindsight. Prelim. Resp. 45–46. On this
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`record, we credit Mr. DeVito’s testimony, as it is consistent with the prior
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`art disclosures, and agree with Mr. DeVito that combining Fortov’s teaching
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`of a non-linear relationship between sputtering yield and target temperature
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`and Mozgrin’s apparatus would have been a combination of known
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`techniques, yielding the predictable results of increasing the ionization rate
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`and the degree of multi-step ionization. See Ex. 1005 ¶ 122.
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`Given the evidence before us, we determine that the Petition and
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`supporting evidence demonstrate sufficiently that combining the technical
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`disclosures of Mozgrin and Fortov is merely a predicable use of prior art
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`elements according to their established functions—an obvious improvement.
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`See KSR, 550 U.S. at 417 (“[I]f a technique has been used to improve one
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`device, and a person of ordinary skill in the art would recognize that it would
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`improve similar devices in the same way, using the technique is obvious
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`unless its actual application is beyond [his or her] skill.”).
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`Accordingly, on