9HI_II/IKJIOHEJIII/IIIECKASI CEPI/I51
`
`BHIJI/IKJIOHEJII/I591
`HPIBKOTEMHEPATYPHOH
`
`IIJIA3MI>I
`
`BB0,uHLIi’a TOM
`III
`
`H01: peJ:[aK11I/IeI71
`aKaJ‘_[CMI/IKa
`B. E. CDOPTOBA
`
`«HAYKA»
`
`«HAYKA / I/IHTEPHEPI/IOHI/IKA»
`2000
`
`GILLETTE 1010
`
`GILLETTE 1010
`
`

`
`CO,EI,EP>KAHl/IE
`
`Pa3p,en VI
`
`|'1J'|A3Mb|
`B3A|/|MO,E|,E|7ICTB|/IE HI/|3KOTEM|'|EPATVPHO|7I
`C KOHJJ,EHCV|POBAHHbIM BE|J.LECTBOM,
`|'A3OM
`I/I 3J'|EKTPOMAl"H|/|THb|M |'|OJ1EM
`
`BBEIEEHI/IE
`
`V1.1. B3AI/IMOJlEI;ICTBI/IE HJIABMLI C KOHIIEHCI/IPOBAHHI:-IM BEIIIECTBOM
`
`VI.1.1. OcHo3H3Ie IIOHSITI/ISI H 3cpq)eKTL1 33a11Mo—
`,11efic'1'311;1 ru1a3M31 c KoH11eHc11po3a113:31M
`BCILICCTBOM .................................................. ..
`
`1. BBCJICHHC (7). 2. OCHOBHLIC c3o1?1c'r3a
`TT H EX 11o3epxHocTe_1?1 11p1/1 33a1»1MoJ1efic'r-
`31111 c HHMI/I HTH (7). 3. IIapaMe'1'pL1 11o'ro-
`KOB qacrnu H 1a3J1ytIeH1aJ?1, nonanaromnx H3
`IUIa3MLI Ha 11o3epx11ocT3 KOHJ1eHCPIpOBaH-
`Horo 3e1uec'r3a (8). 4. KJ1accm1mKa1J;w1
`Z-JMHCCHOI-IHLIX srsnermfi Ha rpanmte pa3JJ;e-
`na 3aKyyM—TT (9). 5. OCHOBHBIC 11po11ec-
`cm,
`o11peJ1e11;11o11.111e Maccoo6MeH r1J1a3—
`Ma——11o3epxHoc'r3 (10). 6. HPOHCCCLI, or1pe—
`JICJI5IfOII.II/I6 aHepro6a.11aHc 33anMone131c'r3y-
`Iomero c 11J1a3Mo171 TI‘ (11). 7. 3MJz1cc11s1 c
`nonepxnocm cbo1'o11o3 (11). 8. 3po31a1s1 11
`'rpaHc<1)opMaIms1 11o3epx11ocT1v1 3 pe3yJ1Hra—
`Te II.TIa3MeHHO1‘O 3o3)1efic'r31r151 (12). 9. He-
`yc'ro1"1<11r1331e 1103:-:px11ocT11o—11J1a3Me11H31e
`33am/1oJ1e1”1c'1*31a51. BJIHHHHC Mal"HI/IT]-IOI‘0
`1101151 (12).
`VI.1.2. C'1'poeHne E'3epnL1x Ten ............................
`1. Me)KaTo1v1H31e CB$I3I/I (13). 2. C'.rpyK'rypa
`KpHCT3.J'IJIOB (18). 3. 3J1eKTpo1111oe c1poe-
`H116 TT (21). 4. K0J1e6a1ms1 3 TI‘ 11 K3a3n-
`qac'r1a1131 (29). -5. J"_[etpeK'r1>1 Kpr1c'raJ1J11111e-
`cK0fi c'1'pyK'1*ypLI. AMop(bHI>Ie Tena (36).
`VI.1.3. C3o171c'r3a '1'3ep;1L1x TCII
`......................... ..
`1. MexaH1»1'1e'c1<1ae
`11
`'re1111ocp1z131»1*1ecK1»Ie
`c3o1‘7’1c'r3a TT (42). 2. 3J1eK'1'p1111ecK11e, Mar-
`11I«1TH31e 14 onT1mecKHe c3oI7IcT3a 'IT (45).
`
`VI-1-4- CB0I7IC'I‘Ba l'PaHK11I=I TBePJ1I=IX T€J1- K011-
`Ta1<T1131e 513116111151 ....................................... ..
`
`57
`
`1. B3eJ1eH1«1e. IIo11s1'r11e 11o3epxHocT1a (57).
`2. CTpyK'rypa 11 11oTeH1ma.113Hb1171 penheqa
`rpaHm131 TT (57). 3. Pa6oTa 331xo;1a I/I
`SJICKTPOHHOC cpop;c'r3o (61). 4. KOHTaKT-
`Hue SIBJICHHH. KOHTHKTHEUI pa3HOCTI: no-
`TeH111aaJ1o3 (64). 5. TepMo)mHaM11Ka 110-
`BCPXHOCTH (66).
`VI.1.5. 3J1eK1'poH1131e 3MJ1cc1m c 11o3epxHocT11
`TBepJ101"O Tena ............................................ ..
`
`1. Knaccncpuxanna 3111103 3M11cc11H (66).
`2. TepMo3J1e1<'rpoH11as1 3M1»1ccns1 (67). 3. (Do-
`TOSIICKTPOI-IHa5I SMKOCKSI (71). 4. HoJ1e3as1
`3M1/ICCI/I51 3JICKTp0HOB (74). 5. B3pL13Has1
`3M.flCCH.5I 3JIeKTpoH03 (78). 6. 3M11cc1«151 “ro-
`p51r11ax’: 3.TIeKTp0HOB (78). 7. 3K3o3MHcc1»1:1
`(81).
`VI.1.6. C-)M11cc1m 3.r1e1<1'poHo3 npn 33amv1o;1eficT-
`3113 t1ac'rn11 c no3epx11oc'rL1o ..................... ..
`
`1. B'ropm1Has1 3JICKTpOHHa5I SMHCCHSI (84).
`2. IIo're111J;naJ11.Has1 HOH-3JI6KTp0HHa5[ 3MHC-
`c1«1;1 (90). 3. K1»111e'mL1ecKas1 HOH-3JI6KTp0H-
`Has: :—>MHcc1«Is1“('91).
`
`VI.1.7. B3a171MoJJ;e171c'r311e c 11o3epxHocT31o Ten-
`11o331x a'roMo3 11 1101103 .............................. ..
`
`1. AK1<oMoJ1a1u1s1 (92). 2. A11cop61ms1 (que-
`I-IOMeH0.TIO1"H$I 11po11ecco3) (93). 3. <I>113171t1e—
`CKHC 513116111151 11pH a;1cop6I.11m (MOJICJILHOC
`OITHCZIHHC) (95). 4. I'Io3epxHocTHa51 171oH1a3a-
`111151. I/Ic11apeH171e co6cTBeHHL1x a'roMo3 (98).
`
`66
`
`84
`
`92
`
`

`
`11 CTHMyJ'.[PI-
`VI.1.8.. BHe11peH1»1e, oTpa>1<eH11e
`poBaHHas1 11ecop61111s1 qacTm_1 ..................... ..
`1. BBCJICHI/Ie (100). 2. I'IoTeH111«1aJ1b1 11apHo—
`ro B3a11MOJ.IeI7ICTBI/I51 '1ac'r1111 c a'roMaM121 cpe-
`11131 (100). 3. TopMo>KeH11e ZITOMHLIX I1ac'r1111
`(101). 4. 1'Ipo6er11 aToM111.1x qacmu B Be-
`111ec'rBe (101). 5. O'rpa>KeH1«Ie t1acT1»111; (103).
`6. £[ecop611I1s1 non 1[e171c'rBI4eM pa3.TII/I‘{H.I>IX
`KOMIIOHCHTOB I'IJIa3MLI (108).
`VI.1.9. 3axBaT ra3o13L1x 11011013 11 11x BLIJICJIBHI/I6
`1. BBez1eH11e (109). 2. 3.KcI1ep1rIMeH'raJ1L—
`HLIC Ha6JIIOI[eHIrI5i
`(109). 3. <I>11311qecKne
`11po11;ecc1.1 npn HOHHOM BHe1[peH1m ra3a
`(112). 4. Monenn 11J1s1 o111«1caH11s1 11oH11oro
`BHCJIPCHPISI ra3a (114). 5. qECJ'I6HHI:I6 upo-
`I‘paMMI>I (116).
`VI.1.10. Pac11b1J1eH11e .......................................... ..
`
`100
`
`109
`
`117
`
`1. BBBJICHPIC (117). 2. OCHOBHBIC 33.BI/ICPI-
`MOCTI/I Ko3q3q)111meHTa paCl'II:IJICHH5I (117).
`3. XapaKTepHCTI/IKH pac11L1J1eHHL1x qac'r1»11.1
`(119). 4. 3KCI'IepI/IMCI-ITaJ'ILHI:Ie MCTOJILI
`1z13yI1e1111;1 pacnblnemm (120). 5. TeopeTn—
`‘ICCKHB MOJICIIPI paClII:IJIeHIzI5[ (121). 6. He-
`Tpa111«11moHH1>1e MCXaHH3MbI pac11L111eH11s1
`(125).
`VI.1.11. MOJ1HqJIrIKaIJ,H5{ IIOBCPXHOCTI/I TBCPJILIX
`TCJI npn HOHHOM 11 11J1a3MeHHoM Bo311efic'r-
`BIZII/I ............................................................... ..
`
`126
`
`1. BBe11eHHe (126).. 2. PEIBBHTHC PIJIH crJ1a—
`>K11Ba1-11»1e penbeqya IIOBCPXI-IOCTH 3a c'1e'r
`Heo11Hop011Hoc'1‘1I pac11L1J1eHns1 pa3J11«1<1H1>1x
`
`ee yqac'rKoB (126). 3. Pa3BHTHC penbetba
`KaK cJ1e11cTB11e paJIHaI.[I/IOHHO-CTI?[MyJII/IpO-
`BaHHLIX r1p011eccoB B O6'b6MC TT (129).
`
`V1.2. HJIA3MA c KOHLLEHCI/IPOBAHHOI7I <I>A3OI7I
`
`VI.2.1. IIp11noBepxHocTHa51 J1a3ep11as1 11J1a3Ma
`1. BBeJ1eH11e (138). 2. Harpes MPIIIICHPI 11a-
`3epHLIM I/I3JIy‘IeHIrI€M (139). 3. O6pa3oBa-
`Hne HJIH B LIP B 11apora3oB1.1x cMecs1x
`(143). 4. O6pa3oBaHne IIJIa3MI:I B rm1po111»1—
`HaM11t1ecKoM pe>1<11Me 11p11 Hanuqnu 3po311-
`oHHoro cbaxena (146). 5. 3aKJIIO‘{eHI/Ie
`(149).
`VI.2.2. <I>o'rope3oHaHcHa$1 11J1a3Ma ..................... ..
`1. BBCIICHIIIC (149). 2. MeTo11L1 11oJ1yt1eH11s1
`11 HCCJ'ICI[OBaHE[$I <I>PH (150). 3. 3J1eMeHTap-
`HBIC 11po11ecc1.1 B cboTope3oHa11cHo1?1 r1J1a3Me
`(152). 4. K1a11e'mKa 06pa30BaHJ151 H pa3py-
`111eH11s1 cpo'rope3oHaHcHo1Z1 I'I.TIa3MLI
`(155).
`
`138
`
`149
`
`5. Hpp1MeHeH11s1 (1)oTope3oHaHc11o171 l'I.TIa3MLI
`(157).
`VI.2.3. HLIJICBEISI II.TIa3Ma .................................... ..
`
`160
`
`1. BBeJ1eH1»1e (160). 2. O6pa3oBaHp1e 121 3a-
`p$1;n;1<a IILIJICBLIX I1ac'r1/111 B 11J1a3Me (161).
`3. B3a1»1Mo11e1F1c'rB1z1e
`IILIJICBLIX I1ac'r1z111 c
`BHCIIIHI/IMI/I 11oJ1s1M11 11 Me>K,11y co6o171 (164).
`4. HeHI[eaHLHOCTb 11L1J1eBo171 l'IJ'Ia3MbI 11 (ba-
`3oBL1e IICPCXOJILI (166). 5. BOJIHBI 'B 11L1J1e-
`Bofi 11J1a3Me 6e3 Ma1“I-IPITHOFO 1101151 (169).
`6. ,[Ina1'Hoc'r11Ka HLIJICBLIX t1ac'r1111 B 11.I1a3-
`Me (172). 7. 3Kc11ep1z11v1e11TaJ11.}1me 11ccJ1e-
`J1oBaH1»1s1
`c1«1J11>Ho11e1111eaJ11>Ho1?1
`11L1J1eBo171
`11J1a3ML1 11 IILIJICBOFO KpHCT3..TIJIa (177).
`
`VI.3. SIBJIEHI/I51 HA I‘PAHI/ILIE HJIA3MA—I‘A3
`
`BBCJICHI/I6 ............................................................. ..
`VI.3.1. I/IoH113y1o1ruz1e y11apHL1e 30111151 .............. ..
`1. Bo3H1«1KHoBeH11e 11 c'rpyKTypa yJ1apH1.1x
`BOJIH B ra3ax (183). 2. Yc'raHoBJIeH1v1e
`MaKCBe.TIJIOBCKOI‘0
`pac11pe11e11eH1«1s1
`(184). 3. Bo36y>KJ1eH11e BpaIJ.1a'reI1LHL1x
`c'reI1eHefi cBo6o11L1 (186). 4. KHHeTPIKa
`Kone6aTe.r1bHo171
`penaKca1um (187).
`5. K1»1He1‘1«11<:a 11 MeXaHH3MbI nnccounauun
`
`MoJ1eKyJ1 3a YB (188). 6. Mexa111z131s/11,1
`11oH113a111111 ra3oB 3a ynapH1.1M11 BOJII-IaMH
`(191).
`
`VI.3.2. P0111: 11epeHoca 121311yt1eH121s1 B cpopM1«1po-
`Banpm 11 pacr1pocTpaHeH1111 cm1LHb1x 1101111-
`3y1o111nx yJ1apHb1x BOJIH .............................. ..
`1. P0111, r1epeHoca I/I3JIy‘ICI-II/D‘-I B ¢>opM11po—
`BaH1m- CHJIBHBIX y11apHb1x B011}!
`(194).
`2. Pacnpenenemzle 11apaMeTpoB B 11peKyp—
`c0pHo171 BOHC CH.TILHOI7I y1[apH0171 BOJIHLI
`(196). 3. B1111s1H11e r1epeHoca I/I3.TIy‘{€HI/I5! Ha
`
`182
`183
`
`194
`
`pac11poc'rpaHeH1«Ie CHJIBHLIX nonnsyronmx
`y11apHL1x BOJIH B Kananax (197).
`VI.3.3. 1'IJ1a3MeHHas1 O6'0.IIO‘IKa, B031-II/IKaIOII.Ia5I
`11p11 JIBIDKCHHH KOCMI/I‘IeCKI/IX a1111apaToB B
`a'rMocq3epe ............................................. ..
`1. IIapaMeTpb1 l'IJ'Ia3MI>I B ynapno-Harpe-
`TOM cnoe Boxpyr o6TeKaeMoro Tena (199).
`2. O11epe>Ka1o111as1 q)o'1*o1«1oHJa3a1J;r1s1 Bo311y-
`xa 11epeJ1 cbpoHToM roJ1oBHo1‘»’1 YB (202).
`3. CTpyKTypa c'rpy11 11poJ1yKToB c1"opaH1»1s1
`)KP,[I (203). 4. HepaBHoBecHas1 peKOM5PI-
`11a111«1s1 cBo6o;11H1.1x 3JIeKTp0I-[OB B cBepx-
`3ByKoBofi c'rpye 11po11yK'roB c1"opaH1151
`(204).
`VI.3.4. PeKOM5I/IHaIII/IOHHLIC 11po11eccb1 Ha I'pa—
`HI/IIJ;C pa311eJ1a 11J1a31v1a—ra3 .................... ..
`
`1. BBe11eHne (206). 2. YpaBHeHus1 MoJ1e1111
`05pa3OBaHH$I II.TIa3MeHHOI‘0 KaHaJ1a (206).
`3. OcHoBHb1e :—>J1eMeH'rap111.1e 11po11eccL1
`(207). 4. Xapa1<'rep1«1c'r1«11<1»1 m1a3MeHHoro
`1<a11a11a (211).
`
`

`
`V1.1. B3APIMO,[IE171CTBIr1E 1'I.l'IA3MbI C KOHJIEHCI/IPOBAHHLIM BELLIECTBOM
`
`117
`
`S = 47r7'D[u(w - y) -— N§y exp (—Eb/kT)].
`3,£[6Cb u — KoHueHTpauHs1 )1Htpq)yH11Hpyio111ero raaa, y — KOH-
`Hex-rrpaimsi B neqaeicrax, w — KoHueHTpaI1HH caMHx netpexros,
`np — npoqmm» 'ropMo>KeHHH HoHoB, S — crox B Jietpexrm, 7* -—
`acp¢>e1<-rH13HLn71 pazmyc necpexra, N — a'roMHaa HJIOTHOCTL TT,
`5 ——- qncno B03M0)K1-IBIX Mecr B Mex<,uoy3nH:1x BOKpyl" jiecpeicra.
`B cnyviae J1IrICIJ¢Jy3HH B MHorocnoHHoH c'rpyK'rype pacema-
`TpHBae'rcsi 11Hcpcpy3Hs1 13 Ka>i<)1oM once, a KoHueHTpa.uHH Ha [pa-
`HHuax paanena CB}I3bIBa.10TCi1 qepe3 paCTBOpHMOC'1‘H. BHeLuHHH
`Hc'roqHHx O6bI‘iH0 6€pCTC51 H3 He3aBHcHML1x pacqeros. BHy-
`Tpel-IHI/I171 CTOK B necpexrbi COCTOHT H3 mayx '-UICHOBZ 11Hc13cpy-
`3HoHHoro npHToKa B J1e¢)eK'rL1 H TepMPI‘ieCKIrI HIIH pa,1IPIaIIH-
`oHHo aK'rHBHpyeMoro Bmxona H3 HHx. Error xe q.neH B ypaB-
`HeHHH J1Hq)q)y3HH O1'II/ICb[Ba€T H cxopocrb Haxormenmi '-1acTHI.1
`3 necpexrax-nosyinxax. O6Lr=iHo paccMa"rpHBaeTc;~1 HCCKOJILKO
`TI/Il'1OB necpercron c pa3IIP1‘lHbIMI/I 3HeprHHMH cBH3H H KOHI.IC1-I-
`TpaI1Hs1MH, Ho Bmme crox 3aHHcaH 111151 OJIHOFO THna necpeicron.
`B Fpal-IH‘1HI:IX ycnoimsix 3anHcLtBaeTcsi 6a.naHc IIOTOKB. J1Hcb¢>y—
`3HH H noroxa ;1ecop6uHH. Hpennonaraercx, qro Mexny KOH-
`ueHTpauHHMH Ha noBepxHocTH T51" H H011 Heir‘: 6L1c1'po ycTa—
`HaB.IIHBaCTCSI JIoKa.rtLHoe paBHoBecHe, T.‘-I.
`IIpH npa3HnbHoM
`Bmfiope 1co3cpc1)HuHeHTa IIpO1'10pI.IPIOHaJ'1bHOCTH Mexqzy :->THMH
`1<oHueH"rpauH51MH cxopocrb L1ecop6I.1HH IIp0l'10pI.[PIOHaJ'II>Ha Kna-
`)1paTy O6'bCMH0I7I KoHueH'rpauHH B6HH3H 11o3epxHocrH. K03111-
`cpHuHeHT nponopuHoHaHbHocTH, Ha3LIBaeML1171 3c13c13eKTHBHbIM
`Ko3(1JcpHI.tHeHToM peKoM6HHauHH, JIH6o B121‘-II/ICJISICTCSI aHaJ1HTH-
`Hecim, nH6o PI3MCp5ICTC$I 3Kc1'1epHMeHTa.nLHo. KpoMe J1CCOp6-
`HHH Broporo nopsmxa, B rpaHHqHL1e ycJ1oBHs1 MO)K€T
`BBO-
`J1HTbC$1 TC1'l.TIOBa.51 H paJ1Ha.uHoHHo-c"rHMynHponaHHaa 11ecop6—
`HHH, a "raxoxe zLecop61.1Ha nepsoro nopsmxa.
`KOMHLIOTCPHBIC nporpaMML1 no3BonHnH oHHcaTb 6om.u1oe
`Konuqecmo pa3H006pa3HbIX 3KCIICpPIMeI-ITOB no HoHHoMy BHC-
`;tpeHH1o ra3a (pHc.VI.1.308, VI.l.309).
`HeH36e)KHa5i
`ripo-
`6J1eMa — 60JIbI.IIOC KOJII/I‘-ICCTBO riapamerpois, KOTOPBIC '-IaCTO
`1
`1
`
`j, 1013 cM'2 - c‘
`
`j, 1013 civrz ~ c‘
`
`I/IX ‘-IaCTO y}1ae'rc51 XOPOIIIO OHPICZTI: MaT€MaTI/I"1CCKI/I. OH-
`1/1
`HaK0 qll/I31/1'-IeCKa5I_KapTIrIHi:1 SIBIICHI/I51 ‘-IaCTO 0Ka3I:IBa€TC5I Cy-
`IJICCTBCHHO CIIOXHCC,
`‘IBM TC l'lp€I[CTaBJ'ICHI/I51, KOTOPI-:16 PIM6-
`iorca 3 Hacrosimee Bpewi.
`I/Imeerca MHOFO tpaxron, KOTOPLIC
`He Haxonsrr 06'I>SICHCHPI$I, H MI-IOI‘0 Cba.KTOpOB, KOTOpbI6 rpynno
`Hpe)1BH,ue'rL.
`1'1o3'roMy HpaK'rHqecKHe npe11cKa3aHH51 l'[0BB,]IC-
`HPI51 I/IOHHO-BHBIIPCHHOFO ra3a )IJ'15I KOHKPCTHBIX TBXHI/PICCKI/IX
`npHMeHeHH171 TpC6yIOT OCTOpO)KHOCTH.
`1. McCracken G.M. The Behaviour of Surfaces under Ion Bombardment.
`
`2. Ozawa K.,
`P.241—327.
`1975. V.38.
`Reports on Progress in Physics.
`Fukushima K., Ebisawa K. Data Compilation for Radiation Effects on Hydrogen
`Recycle in Fusion Reactor Materials. Preprint JAERI-M 84-089, 138 p. 3. Ya-
`maguchi S., Ozawa K., Nakai Y., Sugizaki Y. Data on Trapping and Reemission
`of Energetic Hydrogen Isotopes and Helium in Materials. Preprint JAERI-M
`84-093, 59 p. 4.
`Pa.l1PIa.I.[lvlOHHa5I CTOHKOCTL Marepnanon. I'1po6neMu rerma H
`aonopona B peairropnbix Marepuanax. Pecpepar. c6. / Hon pen. A.B.I.I.Ia.nsHoBa
`H B.A.KanHHa. H M.: MLIHTI/I, 1986.
`114 c. 5. Hucapee A.A., ‘lepuuxoa
`B.H. B3aHMoneHc1'aHe nonopona c panHauHoHHb1MH 11etpe1c'raMH 3 Meramiax / B
`K1-1. B3aHMo11eHc'r3He BO1l0p01.'1a c Me'ra.ru1aMn. — M.: Hayxa, 1987. C.233—264.
`
`6. Wilson K.L.. Hydrogen and Helium Trapping. Nuclear Fusion, 1984. Special
`.Issue, p.28-42.
`
`© A.A. Hucapee
`
`VI.1.10. Pac1II.n1eHHe
`
`1. Beebeuue. Kamobnoe pacnbuzeuue, cefiqac Hame Ha3I:I-
`Baemoe npocro pacnbmeyuem, —— aro pa3pyuIeHHe MaTepHa-
`non yCKOpeHHbIMPI HoHaMH HHH aTOMaMPI, KOTOPOC I'1pOI/ICXOJII/IT
`B BI/U16 aTOMOB HJIH pexe aTOMHbIX Knacrepon HJIH Monexyn.
`OcHoBH0I7I xapa1<TepHcTHKoH pacHLLrIeHHs1 sIBJI51e'rcsI Ko:ecp¢)H-
`uHeHT pacm>meHHs1 Y, onpeJ1eJ1s1eML1H Kax OTHOIIICHHC ‘-IPICJ'1a
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`8"”, me u 2: 2. BL1coKoaHepre'mqHL1I71 Xsocr cneKTpa, a
`Taxoxe cpenmm anepma (S) paCI'IbIJ'IeHHbIX aTOMOB pacrer npu
`y13enm1eHnH :-znepnrm H0!-IOB 8. Cpemma anepmn (8) B03-
`pac'rae'r Taroxe npn ynenmxennu yrna nanenns PIOHOB 9 PI yrna
`31.me1'a pacnsmennmx aTOMOB 12 (0 H 1/ o'rcqHTL13a1o'rc>1 OT Hop-
`Mann K HOBCPXHOCTPI). B Hn3KoaHepre*rHHecKo171 qacm cneK*rpa
`(S < U) npn xopo1ueM paspemennn 06!-Iapy}KHBalOTCfl aTOM'bI c
`MaKcBeJmoBcK11M pacnpe11eJ1eHueM H 'reMr1epa1'ypo17I 0,1—1 3B,
`no o6mH17i BKJ'Ia,l1 Taxnx qacmn B pacnbmenue COC'I‘aBJIi1CT 0K.
`10%, 3a 1»1cK.mol1eHHeM TSDKCIIBIX PIOHOB c anepmefi nopsmxa
`1 K3B H BLICOKPIX 're'MnepaTyp Mnmenn.
`B Mace-cnexrpax pacr1w1eHHL1x qacmu Ha6mo11a1o'rcs1 Kna-
`c'repL1 I/I3 zuzyx H 6onee (BIUIOTI: no 10) aTOMOB. Ozmaxo 01'-
`I-IOCPITCJILHOC '-IPICIIO aTOMOB, pacm.mzeM1.1x KJIac'repaM1«I, He-
`1_3em»1Ko (< 1%) H 6I>ICTpO y6bIBaCT c p0CTOM tmcna aToMoB
`
`
`
`
`
`

`
`120 P. VI. B3AI/IMOI[EI7ICTBI/IE l'I.TIA3MI:I C KOHJIEHCI/IPOBAHHHM BELLIECTBOM, l"A3OM I/I C9J'IEKTPOMAI"I-II/ITHBIM HOIIEM
`
`B Knacrepe. ‘incno aromos, pacnsmaemux K.nacTepaMn, pa-
`crer c p0CTOM Maccm nona.
`l'Ipn pacnsmennn JICFKHMPI no-
`Hazvm (H, D, He) pacnunenne K.1'[aCTCpaMH npaxmqecxn OT-
`cyTc*r1aye'r'. ‘incno pacnunennblx Knacrepoa y6L1Bae'r c pocrom
`aneprnn Knacrepa "rem 6I:ICTp€C,
`‘ICM 6o.nLu1e aTOMOB B Kna-
`crepe (pnc. VI.1.319).
`
`150 K3B
`V He
`Ne
`Ar
`Cu
`K:
`Xe
`
`10
`
`1000
`
`%’, 3B
`
`Pnc. VI.1.319. Bnepremuecxcnir cnexcrp pflCl'[I>1J'IeHHI>IX aromas H aapsuxex-n-Isxx
`xnacrepos
`
`EOJIBLLIHSI qacn. pacnbmaemrx aromas ne17rrpa.In.na, nona
`qacmn, pacnnnuembrx B BHJIC nonos, 06bI'{H0 Menee 1 %. I/Ic-
`1ono_qe1-n»1e COCTaBJI5IIOT menoqnme MBTEIIUIBI, KOTOPBIC pacnm-
`n51Io'1‘ca B Bnne nonoxmenbnmx nonos.
`
`10°
`
`0°
`
`10°
`
`Pnc. VI.1.320. Yrnosoe pacnpenenenne DBCHBUTCHHHX aromoa Bonsqnpama, 60M-
`Gapnnpyemoro Honamn Kr+ (10 143B), nanaxonmmn Ha IIOBCPXHOCTL non yrnoM
`6 = 60°; cnnonrnasi xpnaaa —— axcnepnmem, mcworpaumbx — xomnuorepnsxix
`pacIIeT
`
`Yrnosoe pacnpencnex-me pacnsmenx-tux aTOMOB npn nop-
`MBJILHOM nanennn nonon Ha nomncpncrann cnmmerpnqno or-
`Hocmensno nopMa.nn, npnnxem nml 6onLumx anepmfi 8 >
`1 QB, d2Y/d1/2 ~ cos 1/, B TO spew; Ka.K npn 8 < 1 K3B
`npeo6nana1o'r aTOMbI, pacnbmsxemrne 6nn>Ke K nosepxnocrn
`(npn 6onLn1nx 1/). Ilpn HaKJ10I-II-[OM nanennn nonos (0 sé 0)
`Ha pacnpenenenne, cnMMe-
`Tpnqnoe ornocmenu-Io Hop-
`Mamx, Haxnanmsaerca max
`3. Hanpannennn,
`B KOT0-
`p0M CMCILIBIOTCSI
`nep3nq-
`1-nae
`cmemem-me
`KTOMBI
`
`(pnc. VI.1.320).
`Mnn1e1-In
`Hpn 5OJ'IbI.LIHX yrnax nane-
`Hnsx
`I-JTOT nnx cranonmcx
`
`Onx-Iaxo
`npeofinanaxonmm.
`npn OQCI-lb fionsmnx 91-1ep-
`msxx yrnosoe pacnpenane-
`1-nae pacnsmemmx aTOMOB
`ocraercx cnMMeTpnnHLIM or-
`nocnrensx-Io Hopmann n npn
`naxnonnom nanex-Inn
`no-
`
`Pnc. VI.1.321. l'Ism-ta Bénepa. no.nyqeH-
`Hue npn pacnbmex-Inn Monoxpncrama
`Menu (rpm-n: (001)), nonawm Ar+, nua-
`IOIIIPLMPI non yrnom nanennn 30° c 3HCp-
`rwmn: 130 3B (:1), 1 KBB (6), 10 K3B
`(3). 40 K33 (2) n uoHaMn H+ c 3Hep-
`men 10 m3 (0)
`
`HOB. B cnyqae MoHoKpn-
`cranna yrnonoe pacnpene—
`nex-me
`pacnbmennmx
`‘<13.-
`cmn CPUIBHO annaorponnoz
`pacnsmennue aTOMbI BbUIe-
`Ta1oT, B OCHOBHOM, B na.npa-
`BIICHPISIX
`nnoTnoynaKoBaH-
`nmx 3.TOMI-[LIX psznos KPH-
`cranna (pnc. VI.1.321), o6pa3ys1 Ha Kapmne ocanxa pacnL1.nen-
`noro Bemecraa xapamepnble nsnna (nsrrna Bénepa).
`4. Bxcnepuuenmanbnue Memodu uayuemul pacnwze-
`nun. I/Iayqenne pacnmnenmz nponanonnrca pa3nn=1Hx,1Mn eno-
`co6aMn: Bo-nepamx, no canton Mnmenn, Koropasx nccnenyerca
`no 14 nocne pacnmnennn, BO-BTOpbIX, no ocanxy pacnx.u1eH-
`Hmx aTOMOB na KaKOM-J'[PI5O axcpax-Ie n, B—'rperI.nx, c nomonnno
`Henocpencrnennon perncrpannn caMnx pacnbmzemmx qacmu.
`I/Iccnenonanne Mnmenn ocynxecrnnsxerca cnenymnmmn Me-
`Tonamn:
`
`1) MeTonoM Baaenmsanna;
`pacnpocrpanennmil Meron;
`2) MCTOIIOM namepenna anexrpoconpormanenna nnenox n
`nposonoqex, KOT0pLIC y'ronmna1o*rc>1 B npouecce pacnmnenna;
`
`:-rro a6con1oTnLn71 n Han6onee
`
`3) c IIOMOILIBIO npoqannomerpa, Koropmiil namepaer smcory
`crynenbm Me>Kny pacnbmennofl n nepacnbmennofi (npnKpL1—
`T0171) qacnno nosepxnocrn;
`4) MCTOJIOM penepa n3 Tnxenmx nonon, Koropme BHenps1-
`Iorca Ha nocraro-myio rny6nny; c l'IOMOII.I]>IO o6pa'moro paces-
`annn 6L1c'rpL1x 1401-103 (8 > 1 M3B) M0)KHO namepsrrb rny6nHy
`penepa; npn pacnsmennn am rnyénna ymennmae-rca.
`«*
`I/Iccnenonanne Konnqecma ocanxa pacnuneunoro neme-
`c'rBa 1'pe6yeT Kannfipomcn, nocxonbxy ono aanncm or npn.nn-
`naeMocTn pacnmnennoro sernecnsa, reomerpnn n npyrnx yc.r1o-
`
`B14171 axcnepnmemas Ogagox pacnnmennoro Bemecrna nccneny-
`ere:-1 cnenymnmmn Memnamn:
`
`1) tporomerpnqeclcn, no onrnqecxofi nnomoc-rn;
`2) MeTonoM pa.nnoa.KTnBHL1x nsoronos;
`3) Me-ronoM n3MepeHns1 pesonancnofi rxacrorm Ksapnesoro
`Kpncranna, Ha 1<o'ropLn“1 ocaxnaerca pacnbmennoe Bernecrso;
`
`

`
`V1.1. B3Al/IMO)1El7ICTB1/IE IIIIABMBI C KOHIIEHCI/IPOBAHHLIM BELLIECTBOM
`
`12]
`
`IUICHKPI c 11011101111110
`
`4) Mer0110M 1»13MepeH1»1s1 T0111111r1111.1
`06paT110r0 paccesnmsx 5I:lCTpbIX 1401103;
`5) c 11011101111110 Hcr1ape1111s1 0ca,u1<a 11 11cc11e1103aH1«151 11cr1a-
`pe11H1.1x a'1'0M03 c11e1(1'p0c1c0111»1=1ec1<1«1M1«1 MeT011aM11;
`6) MCTOIIOM 1»111'repq)epeH1.11»11»1 Ha 1111eH1<e.
`PIcc11eI103a11He
`pacr1_311151eM31x qacmu ocyL11ecT3.r1s1e'rcs1
`cHe1(1~p0c1(0111»1l1ec1c1»1M11 Me1011aM11
`H
`c
`IIOMOILILIO Macc-
`c11e1c1p0Me1pa. B nep30M c11yt1ae pe1*11c1"p1»1py1oTc>1 3036y)1<11e11-
`Hue aT0ML1, 30 BTOpOM — pacr11;111e1-1111»1e 3 311110 110H03. 111151 pe-
`rHcTpa11H11 He1?1Tpa11L1-131x HeB035y)KJ1CI-IHBIX a'r0M03 11x 3036y—
`)1<11a10T H1111 110H113y10'r SIICKTPOHHBIM Hy’-IKOM 111111 11a3ep0M. Bce -
`MCTOJILI Hcc11e1103a1111s1 HeI10CpC)1CTBeHI-10 pacr1Lm51e1v1L1x 11acT1»111
`1pe6y1o1 Ka.I1I/I5p0BKI/I.
`Pac11pe11e11eHHe ocazuca pac113u1e11H0r0 3e111ec"r3a naer H11-
`q10pMa1.1H10 06 yr1103oM pacnpe11e11eH1111 pacn31.1u1eM31x Ha-
`crnu.
`I/IM11yJ1Lc11as1 6oM6ap11I»1p031(a 3 c011e'raHI«11»I c0 c'1'p060-
`cxonmecxnmu yc1'p0171cT3aMH 110330115161‘ c 1101/101111110 0ca111<a
`pac11b111e11110r0 3e111ec'r3a 1«13Mep511L 3Hepre'r11=1ecK11e CI'I6KTpbI
`r10 11p011eT110My BPCMCHPI. 31-lCpl‘CTPI‘-IBCKPIC CHCKTPLI M0)KHO
`1431/1ep11T1: 311exTp0MarH11T1131M11 MeT011aM11 110 0T1<110HeH1110 3a-
`ps1)1<eHH31x 11acT1»111, a 'ra1o1<e cr1e1c1p0c1c0111»1r1ec1<11M1»1 Me1'011aM11
`110 )10l'l.TICp0BCKOMy cMe1.11eHH1o.
`5. Teopemuuecxue Juadezzu pacnbutemuz. HPPII-DITO C‘-[PI-
`TaTL, 1110 pac113111'eH1»1e TT 110HaM11 np011cx011HT 3c11e11cT31«1e
`TpCX_OCI-IOBHLIX 111exa11113M03: 1) 111«111e1711131x Kac1<a1103 aT0MHL1x
`CTOIIKHOBCHI/I171, 2) 11ps1M0r0 B1:161»13aH1»1s1 aTOMOB M11111eH1«1 PIO-
`HaMPI 11 3) 11e.1m11e171Hb1x Kac1<a1103 111111 TCpMPl‘{eCKI/IX 1111x013.
`5.1. Kactcabmuz .M0l)€J1b pacnwzeuuu. Kac1(a11 3.'1‘0MI-ILIX
`cro111<11o3eH11171 — 310 IIOCJ'IC)10BaTCIIbHOCTb c1'0111<1103e111r11?1 11311-
`)1<yu11»1xc51 aTOMOB, 3 K0T0p0I7I c0311a10'rcs1 CMCIIICHHLIC aT01/11,1
`c11e11y101.1.111x 1101c011eH11171 11 TJ1. 110 Tex 110p, 1101ca 3Hep11111 11311-
`>1<y1111»1xc51 qacmu He yMeH1.111H'rc51 110 3Hepm11 fd, He06x0111«1—
`M0171 111151 cMe111eH11s1 aT0Ma 143 ero pa3H03ecH0r0 110110>1<e1-11151 3
`PCIIICTKC. 111151 60111.1111»1HcT3a 1101103 cpe111111x 3Hepr11fi H Mace
`1<ac1(2u1111.1171 MexaH113M s1311s1e1cs1 OCHOBI-I}.»l'M.
`Kac1ca11Has1 Te0p11s1 pacnb111eH1»1a 0c1103a.Ha Ha 1<1«1He*r11=1e-
`CKHX ypanHe1111s1x 111151 q)yH1<111»1171 pacr1pe11e11eH1151 113H>1<y11111xcs1
`1101103 11 111151 JIBPDKYIIIHXCSI c1v1e111e11H31x aTOMOB. Bce c'r0111<110-
`3eH1»1s1 1101103 c aT0MaM11 1<p1»1c'ra1111a 11 CMCIIICHHBIX a'roM03 c
`11pymM1»1 a'r0MaM11 paccMa1p1113a101cs1 KZIK 11apH31e 11 paCC‘-IIrITbI-
`132101051 no 3a.K011aM 1<11acc1»1r1ec1<01”1 MexaH11KH npn 110TeH1111—
`ane 33a1»1Mo)1e171c"r1m11, 1101106paHH0M co0T3e1c13y1011111M 06pa-
`30M. Te0p11s1 11111161711-1as1, T.C. y1111"rL13ae'r cT0111cH03e111151 11311>Ky-
`umxca 1{acT1«111 TOIIBKO c I-ICl'I0)1BIrI)KHblMIrI a'r0MaM11 M11n1e1114.
`
`O63111H0 c11c'reMa 1<1z111e'r1/111ec1c1»1x ypa13HeH1«1I?1 pe1L1aeTcs1 M€T0-
`110M MOMCHTOB. Bra 're0p1«1s1 11aeT c11e11y10111ee 31.1pa)1<eH11e 111151
`1<03qJq11»1111«1eHTa pac111.I11e111151:
`
`3 FD(O,£',0)
`‘ 4712 NOQU ’
`
`(10.4)
`
`:~>Hepr11H, 31=1,11e11eH1-10171 npu ynpyrnx
`F5 (0, 8, 6) — 111101110011.
`CTOJ'IKHOBCHPI$1X 361111311 1103epxH0c'r1»1 (r1p11 z = 0) 3 Kacxane,
`HHH1.11111p03a11H0M 110H01v1, 11az1a1011111M Ha 1103epxH0c1'3 c a11ep—
`r11e171 8 11 yr110M r1a,ueH11s1 0 (q1y111<1111s1 FD(0, 8,0) Hax0111»1Tcs1
`113 PCLLICHKZ 1<11HeT1z1t1ec1<0r0 ypa311e1111>1); N — 11110110 aT01v103
`3 e111«1H1»111e 061.eMa MHHICHPI, 1<010pas1 r1pe1111011arae11:s1 aMopq3—
`H0171; Co — 1<0HcTaHTa B 111»1c11cpepe11I111a111.H01v1 C6961-IP11/I Hepe-
`11a=11«1
`:a11ep11111 T, 1<0T0p