`571-272-7822
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` Paper 11
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`Entered: September 2, 2014
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`UNITED STATES PATENT AND TRADEMARK OFFICE
`____________
`
`BEFORE THE PATENT TRIAL AND APPEAL BOARD
`____________
`
`
`
`
`INTEL CORPORATION
`Petitioner
`
`v.
`
`ZOND, LLC
`Patent Owner
`____________
`
`Case IPR2014-00470
`Patent 7,811,421 B2
`____________
`
`
`
`
`
`Before KEVIN F. TURNER, DEBRA K. STEPHENS, JONI Y. CHANG,
`SUSAN L. C. MITCHELL, and JENNIFER M. MEYER,
`Administrative Patent Judges.
`
`
`STEPHENS, Administrative Patent Judge.
`
`
`
`
`
`
`
`DECISION
`Institution of Inter Partes Review
`37 C.F.R. § 42.108
`
`
`
`
`
`
`IPR2014-00470
`Patent 7,811,421 B2
`
`
`I. INTRODUCTION
`
`On March 7, 2014, Intel Corporation (“Intel”) filed a Petition
`
`requesting inter partes review of claims 9, 14, 21, 26, 35, and 37 of U.S.
`
`Patent No. 7,811,421 B2 (“the ’421 patent”). Paper 1 (“Pet.”). Zond, LLC
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`(“Zond”) filed a Patent Owner Preliminary Response. Paper 10 (“Prelim.
`
`Resp.”). We have jurisdiction under 35 U.S.C. § 314.
`
`The standard for instituting an inter partes review is set forth in
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`35 U.S.C. § 314(a), which provides:
`
`THRESHOLD.—The Director may not authorize an inter
`partes review to be instituted unless the Director determines
`that the information presented in the petition filed under section
`311 and any response filed under section 313 shows that there
`is a reasonable likelihood that the petitioner would prevail with
`respect to at least 1 of the claims challenged in the petition.
`
`Taking into account Zond’s Patent Owner Preliminary Response, we
`
`conclude that the information presented in the Petition demonstrates there is
`
`a reasonable likelihood that Intel would prevail in challenging claims 9, 14,
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`21, 26, 35, and 37 as unpatentable under 35 U.S.C. § 103(a). Pursuant to 35
`
`U.S.C. § 314, we hereby authorize an inter partes review to be instituted as
`
`to claims 9, 14, 21, 26, 35, and 37 of the ’421 patent.
`
`A. Related Matters
`
`
`
`Intel indicates the ’421 patent was asserted in Zond, LLC v. Intel
`
`Corp., No.1:13-cv-11570-RGS (D. Mass.). Pet. 1 and Paper 5. Intel also
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`identifies other matters where Zond asserted the claims of the ’421 patent
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`against third parties. Id.
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`2
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`IPR2014-00470
`Patent 7,811,421 B2
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`
`B. The ’421 patent
`
`The ’421 patent relates to a high-deposition sputtering apparatus.
`
`Ex. 1201, Abstract At the time of the invention, sputtering was a well-
`
`known technique for depositing films on semiconductor substrates. Id. at
`
`1:15–16. The ’421 patent indicates prior art magnetron sputtering systems
`
`deposit films having low uniformity, poor target utilization (the target
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`material erodes in a non-uniform manner), and relatively low deposition rate
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`(low amount of material deposited on the substrate per unit time). Id. at
`
`1:63–2:14. To address these problems, the ’421 patent discloses that
`
`increasing the power applied between the target and anode can increase the
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`amount of ionized gas, therefore, increasing the target utilization and
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`sputtering yield. Id. at 3:20–22. However, increasing the power also
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`“increases the probability of establishing an undesirable electrical discharge
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`(an electrical arc) in the process chamber.” Id. at 3:23–29.
`
`According to the ’421 patent, magnetron sputtering apparatus 200
`
`includes cathode assembly 216, which includes cathode 218 and sputtering
`
`target 220. Id. at 6:46–49. Pulsed power supply 234 is directly coupled to
`
`cathode assembly 216. Id. at 7:7–9. Pulsed power supply 234 generates
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`peak voltage levels of between about 5 kV and about 30 kV, and operating
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`voltages are generally between about 50 V and 1 kV. Id. at 7:17–20.
`
`The ’421 patent forms a weakly-ionized or pre-ionized plasma that
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`substantially eliminates the probability of establishing a breakdown
`
`condition in the chamber when high-power pulses are applied between the
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`cathode and anode. Id. at 9:16–19. Once the weakly-ionized plasma is
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`3
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`IPR2014-00470
`Patent 7,811,421 B2
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`formed, high-power pulses are applied between the cathode and anode to
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`generate a strongly-ionized plasma from the weakly-ionized plasma. Id. at
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`9:29–31, 10:8–9.
`
`C. Illustrative Claims
`
`Of the challenged claims, none are independent. Claims 9, 14, 21, 26,
`
`35, and 37 depend, directly or indirectly, from claims 1, 17, and 34. Claims
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`1 and 9, reproduced below, are illustrative:
`
`1. A sputtering source comprising:
`
`a) a cathode assembly comprising a sputtering target that is
`positioned adjacent to an anode; and
`
`
`b) a power supply that generates a voltage pulse between the anode
`and the cathode assembly that creates a weakly-ionized plasma and
`then a strongly-ionized plasma from the weakly-ionized plasma
`without an occurrence of arcing between the anode and the cathode
`assembly, an amplitude, a duration and a rise time of the voltage pulse
`being chosen to increase a density of ions in the strongly-ionized
`plasma.
`
`
`
`9. The sputtering source of claim 1 wherein the voltage pulse
`generated between the anode and the cathode assembly excites atoms
`in the weakly-ionized plasma and generates secondary electrons from
`the cathode assembly, the secondary electrons ionizing a portion of
`the excited atoms, thereby creating the strongly-ionized plasma.
`
`
`
`Ex. 1201, 22:14–24, 22:52–57 (emphases added).
`
`
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`4
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`IPR2014-00470
`Patent 7,811,421 B2
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`D. The Prior Art Relied Upon
`
`Intel relies upon the following prior art references:
`
`July 2, 2002
`Feb. 20, 2001
`
`(Ex. 1204)
`(Ex. 1205)
`
` US 6,413,382 B1
` US 6,190,512 B1
`
`Wang
`Lantsman
`
`D.V. Mozgrin, et al., High-Current Low-Pressure Quasi-Stationary
`Discharge in a Magnetic Field: Experimental Research, 21 PLASMA
`PHYSICS REPORTS 400–409 (1995) (Ex. 1203) (hereinafter “Mozgrin”).
`
`A.A. Kudryavtsev and V.N. Skrebov, Ionization Relaxation in a Plasma
`Produced by a Pulsed Inert-Gas Discharge, 28(1) SOV. PHYS. TECH. PHYS.,
`30-35 (January 1983)(Ex. 1206) (hereinafter “Kudryavtsev”).
`
`D.V. Mozgrin, High-Current Low-Pressure Quasi-Stationary Discharge in a
`Magnetic Field: Experimental Research, Thesis at Moscow Engineering
`Physics Institute (1994) (Ex. 1207) (hereinafter “Mozgrin Thesis”).1
`
`
`
`
`
`
`1 The Mozgrin Thesis is a Russian-language reference (Ex. 1208). The
`citations to the Mozgrin Thesis are to a certified English-language
`translation by Intel (Ex. 1207).
`
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`5
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`IPR2014-00470
`Patent 7,811,421 B2
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`E. The Asserted Grounds of Unpatentability
`
`Intel asserts the following grounds of unpatentability:
`
`Claim
`
`Basis
`
`References
`
`9 and 35
`
`§ 103
`
`Mozgrin and Kudryavtsev
`
`14 and 37
`
`§ 103
`
`Mozgrin and Mozgrin Thesis
`
`21
`
`26
`
`§ 103
`
`Mozgrin, Lantsman, and Kudryavtsev
`
`§ 103
`
`Mozgrin, Lantsman, and Mozgrin Thesis
`
`9, 21, and 35
`
`§ 103
`
`Wang and Kudryavtsev
`
`14, 26, and 37
`
`§ 103
`
`Wang and Mozgrin Thesis
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`
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`II. DISCUSSION
`
`A.
`
`Printed Publication under 35 U.S.C. § 102
`
`As an initial matter, we address the issue of whether the Mozgrin
`
`Thesis is available as prior art under 35 U.S.C. § 102 for the purposes of this
`
`decision. In its Petition, Intel asserts that the Mozgrin Thesis is a doctoral
`
`thesis at Moscow Engineering Physics Institute, published in 1994, and thus,
`
`is prior art under 35 U.S.C. § 102(b). Pet. 3. As support, Intel proffers a
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`copy of the catalog entry for the Mozgrin Thesis at the Russian State
`
`Library. Ex. 1209.
`
`Zond responds that Intel fails to demonstrate the Morgrin Thesis is
`
`prior art under 35 U.S.C. § 102. Prelim. Resp. 51-54. Specifically, Zond
`
`contends the evidence of publication – 1) a copy of the thesis, 2) an entry
`
`from a catalog of “Dissertation’s in Russian since 1995,” and 3) English
`
`translations of these documents – is insufficient to evidence publication. Id.
`6
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`IPR2014-00470
`Patent 7,811,421 B2
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`at 52-53. Zond asserts the document does not indicate “1) when the
`
`university received its copy of the thesis, 2) whether or when the public had
`
`unrestricted access to the university’s copy, and 3) whether or when the
`
`university had a system such as a catalog by which interested persons could
`
`search for and locate the thesis” or even from where the thesis came. Id. at
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`53.
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`Given the evidence on this record thus far, we are persuaded Intel has
`
`demonstrated a reasonable likelihood that the Mozgrin Thesis is a “printed
`
`publication” within the meaning of 35 U.S.C. § 102(b). Consequently, at
`
`this juncture, the Mozgrin Thesis is available as prior art for the purposes of
`
`this decision to demonstrate that the challenged claims are unpatentable
`
`under 35 U.S.C. § 103(a).
`
`B. Claim Interpretation
`
`In an inter partes review, claim terms in an unexpired patent are given
`
`their broadest reasonable construction in light of the specification of the
`
`patent in which they appear. 37 C.F.R. § 42.100(b). Claim terms are given
`
`their ordinary and customary meaning as would be understood by one of
`
`ordinary skill in the art in the context of the entire disclosure. In re
`
`Translogic Tech. Inc., 504 F.3d 1249, 1257 (Fed. Cir. 2007). An inventor
`
`may rebut that presumption by providing a definition of the term in the
`
`specification with reasonable clarity, deliberateness, and precision. In re
`
`Paulsen, 30 F.3d 1475, 1480 (Fed. Cir. 1994). In the absence of such a
`
`definition, limitations are not to be read from the specification into the
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`claims. In re Van Geuns, 988 F.2d 1181, 1184 (Fed. Cir. 1993).
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`IPR2014-00470
`Patent 7,811,421 B2
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`Here, both parties agree the broadest reasonable construction standard
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`applies to the claims involved in the instant proceeding, and propose
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`constructions for the claim terms “weakly-ionized plasma” and “strongly-
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`ionized plasma.” Pet. 10–13; Prelim. Resp. 12–14.
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`“weakly-ionized plasma” and “strongly-ionized plasma”
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`Claim 1 recites “a voltage pulse . . . that creates a weakly-ionized
`
`plasma and then a strongly-ionized plasma from the weakly-ionized
`
`plasma.” Intel proposes the claim term “weakly-ionized plasma” should be
`
`interpreted as “a lower density plasma,” and the claim term “strongly-
`
`ionized plasma” should be interpreted as “a higher density plasma.” Pet.
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`12–14. Intel’s Declarant, Dr. Uwe Kortshagen, defines the term “density” in
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`the context of plasma as “the number of ions or electrons that are present in
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`a unit volume.” Ex. 1202 ¶ 22.
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`In its Preliminary Response, Zond proposes the claim term “weakly-
`
`ionized plasma” should be interpreted as “a plasma with a relatively low
`
`peak density of ions,” and the claim term “strongly-ionized plasma” as “a
`
`plasma with a relatively high peak density of ions.” Prelim. Resp. 14-15
`
`(citing Ex. 1212, 10:4-5, 12:11–12 (“The strongly-ionized plasma 268 is also
`
`referred to as a high-density plasma.”), 9:24–25 (“the weakly-ionized plasma
`
`has a low-level of ionization”)).
`
`Zond directs our attention to the Specification of U.S. Patent No.
`
`7,147,759 B2 (“the ’759 patent”), being challenged in Intel Corp. v. Zond,
`
`Inc., IPR2014-00443, which refers to “strongly-ionized plasma [as] having a
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`large ion density” (Prelim. Resp. 15; Ex. 1211, 10:3–5) and of U.S. Patent
`
`8
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`IPR2014-00470
`Patent 7,811,421 B2
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`No. 6,806,652 B1 (“the ’652 patent”), which is being challenged in Intel
`
`Corp. v. Zond, Inc., IPR2014-00843 (PTAB), which states:
`
`The high-power pulses generate a high-density plasma from the
`initial plasma. The term “high-density plasma” is also referred
`to as a “strongly-ionized plasma.” The terms “high-density
`plasma” and “strongly-ionized plasma” are defined herein to
`mean a plasma with a relatively high peak plasma density. For
`example, the peak plasma density of the high-density plasma is
`greater than about 1012 cm-3. The discharge current that is
`formed from the high-density plasma can be on the order of
`about 5 kA with a discharge voltage that is in the range of about
`50V to 500V for a pressure that is in the range of about 5 mTorr
`to 10 Torr.
`
`IPR2014-00843, Ex. 1101, 10:57–67.
`
`We recognize when construing claims in patents that derive from the
`
`same parent application and share common terms, “we must interpret the
`
`claims consistently across all asserted patents.” NTP, Inc. v. Research In
`
`Motion, Ltd., 418 F.3d 1282, 1293 (Fed. Cir. 2005). Here, although Zond
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`characterizes the ’652 patent as “a related patent” and refers to the ’759
`
`patent (Prelim. Resp. 14), Zond does not explain how either the ’652 patent
`
`or the ’759 patent is related to the involved patent in the instant proceeding
`
`(i.e., the ’421 patent). The ’652 and ’759 patents do not share the same
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`written disclosure, nor do they derive from the same parent application as
`
`the ’421 patent.
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`Nevertheless, we observe no significant difference exists between the
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`parties’ constructions. Pet. 10–13; Ex. 1202 ¶ 22; Prelim. Resp. 12–14.
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`More importantly, the claim terms “weakly-ionized plasma” and “strongly-
`
`9
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`IPR2014-00470
`Patent 7,811,421 B2
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`ionized plasma” appear to be used consistently across all three patents. See,
`
`e.g., Ex. 1201, 8:22–28. On this record, therefore, we construe the claim
`
`term “weakly-ionized plasma” as “plasma with a relatively low peak density
`
`of ions,” and the claim term “strongly-ionized plasma” as “plasma with a
`
`relatively high peak density of ions.”
`
`C. Principles of Law
`
`A patent claim is unpatentable under 35 U.S.C. § 103(a) if the
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`differences between the claimed subject matter and the prior art are such that
`
`the subject matter, as a whole, would have been obvious at the time the
`
`invention was made to a person having ordinary skill in the art to which said
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`subject matter pertains. KSR Int’l Co. v. Teleflex Inc., 550 U.S. 398, 406
`
`(2007). The question of obviousness is resolved on the basis of underlying
`
`factual determinations including: (1) the scope and content of the prior art;
`
`(2) any differences between the claimed subject matter and the prior art;
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`(3) the level of ordinary skill in the art; and (4) objective evidence of
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`nonobviousness. Graham v. John Deere Co., 383 U.S. 1, 17–18 (1966).
`
`In that regard, an obviousness analysis “need not seek out precise
`
`teachings directed to the specific subject matter of the challenged claim, for
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`a court can take account of the inferences and creative steps that a person of
`
`ordinary skill in the art would employ.” KSR, 550 U.S. at 418; see
`
`Translogic, 504 F.3d at 1259. A prima facie case of obviousness is
`
`established when the prior art itself would appear to have suggested the
`
`claimed subject matter to a person of ordinary skill in the art. In re Rinehart,
`
`531 F.2d 1048, 1051 (CCPA 1976). The level of ordinary skill in the art is
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`10
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`IPR2014-00470
`Patent 7,811,421 B2
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`reflected by the prior art of record. See Okajima v. Bourdeau,
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`261 F.3d 1350, 1355 (Fed. Cir. 2001); In re GPAC Inc., 57 F.3d 1573, 1579
`
`(Fed. Cir. 1995); In re Oelrich, 579 F.2d 86, 91 (CCPA 1978).
`
`We analyze the asserted grounds of unpatentability under 35 U.S.C.
`
`§ 103(a) in accordance with the above-stated principles.
`
`D. Asserted Ground: Claims 9, 21, and 35 – Obvious over Wang and
`Kudryavtsev
`
`Intel asserts claims 9, 21, and 35 are unpatentable under § 103 as
`
`unpatentable over Wang and Kudryavtsev. Pet. 42–55. As support, Intel
`
`provides detailed explanations as to how each claim limitation is met by the
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`combination of Wang and Kudryavtsev. Id. Intel proffers a declaration of
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`Dr. Kortshagen. Ex. 1202.
`
`Zond responds that the combination of Wang and Kudryavtsev does
`
`not disclose every claim element. Prelim. Resp. 39–49. Specifically, Zond
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`argues Wang does not disclose the elements recited in independent claims 1,
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`17, and 34, from which claims 9, 21, and 35 depend.
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`We have reviewed the parties’ contentions and supporting evidence.
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`Given the evidence on this record, we determine Intel has demonstrated a
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`reasonable likelihood of prevailing on its assertion that claims 9, 21, and 35
`
`are unpatentable over Wang and Kudryavtsev. Our discussion focuses on
`
`the deficiencies alleged by Zond as to the claims.
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`1. Wang (Ex. 1204)
`
`
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`Wang discloses a power pulsed magnetron sputtering apparatus for
`
`generating a very high plasma density. Ex. 1204, Abs. Wang also discloses
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`11
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`IPR2014-00470
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`a sputtering method for depositing metal layers onto advanced
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`semiconductor integrated circuit structures. Id. at 1:4–15. Figure 1 of Wang
`
`illustrates a cross-sectional view of a power pulsed magnetron sputtering
`
`reactor. Figure 1 is reproduced below:
`
`
`
`
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`As shown in Figure 1 of Wang, magnetron sputtering apparatus 10 has
`
`cathode of target 14, magnet assembly 40, and pulsed DC power supply 80.
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`Id. at 3:57–4:55. According to Wang, the apparatus is capable of creating
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`high density plasma in region 42, which ionizes a substantial fraction of the
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`sputtered particles into positively charged metal ions and also increases the
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`sputtering rate. Id. at 4:13–34. Wang further describes target 14 as powered
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`12
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`IPR2014-00470
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`by narrow pulses of negative DC power, the exact shape of which depends
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`on the design of pulsed DC power supply 80, and significant rise times and
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`fall times are expected. Id. at 5:18–27.
`
`Figure 6 of Wang illustrates how the apparatus applies a pulsed power
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`to the plasma. Figure 6 is reproduced below:
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`
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`As shown in Figure 6 of Wang, the target power waveform maintains
`
`the target at background power level PB between high power pulses 96 with
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`peak power level PP. Id. at 7:13–17. Background power level PB exceeds
`
`the minimum power necessary to support a plasma in the chamber at the
`
`operational pressure (e.g., 1kW). Id. at 7:17–19. Peak power PP is at least
`
`10 times (preferably 100 or 1000 times) background power level PB. Id. at
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`7:19–22. The application of high peak power PP causes the existing plasma
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`to spread quickly, and increases the density of the plasma. Id. at 7:28–30.
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`According to Declarant Dr. Kortshagen, Wang’s apparatus generates a
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`low-density (weakly-ionized) plasma during the application of background
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`power PB, and a high-density plasma during the application of peak power
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`PP. Ex. 1202 ¶ 126; see Pet. 45.
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`13
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`2. Kudryavtsev (Ex. 1206)
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`Kudryavtsev discloses a multi-step ionization plasma process,
`
`comprising the steps of exciting the ground state atoms to generate excited
`
`atoms, and then ionizing the excited atoms. Ex. 1206, Abs., Figs. 1, 6.
`
`Figure 1 of Kudryavtsev illustrates the atomic energy levels during the slow
`
`and fast stages of ionization. Figure 1 of Kudryavtsev is reproduced below
`
`with annotations added by Intel (Pet. 28):
`
`
`
`As shown in annotated Figure 1 of Kudryavtsev, ionization occurs
`
`with a “slow stage” (Fig. 1a) followed by a “fast stage” (Fig. 1b). Pet. 27–
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`28 (citing Description of Fig. 1; p. 31, right column, ¶7), 53. During the
`
`initial slow stage, direct ionization provides a significant contribution to the
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`generation of plasma ions (arrow Γ1e showing ionization (top line labeled
`
`“e”) from the ground state (bottom line labeled “1”)). Dr. Kortshagen
`
`explains that Kudryavtsev shows the rapid increase in ionization once multi-
`
`step ionization becomes the dominant process. Ex. 1202 ¶ 81; Pet. 28.
`
`Specifically, Kudryavtsev discloses:
`
`For nearly stationary n2 [excited atom density] values . . . there
`is an explosive increase in ne [plasma density]. The subsequent
`increase in ne then reaches its maximum value, equal to the rate
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`of excitation . . . which is several orders of magnitude greater
`than the ionization rate during the initial stage.
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`Ex. 1206, 31, right col, ¶ 6 (emphasis added). Kudryavtsev also recognizes
`
`that “in a pulsed inert-gas discharge plasma at moderate pressures . . . [i]t is
`
`shown that the electron density increases explosively in time due to
`
`accumulation of atoms in the lowest excited states.” Id. at 30, Abs.; Fig. 6.
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`
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`3. Analysis
`
`Intel argues Wang discloses “a voltage pulse . . . that creates a
`
`weakly-ionized plasma and then a strongly-ionized plasma from the weakly-
`
`ionized plasma without an occurrence of arcing,” as recited in claim 1 and
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`commensurately recited in claims 17 and 34. Pet. 43–52. According to
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`Intel, a low density plasma is generated with the background power, PB, and
`
`a high density plasma is created with the peak power, PP . Id. at 45. Intel
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`further asserts Wang discloses arcing can occur when a plasma is ignited,
`
`i.e., before a first pulse is applied. Id. at 46. Furthermore, Intel contends,
`
`since plasma need not be reignited thereafter, arcing will not occur during
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`subsequent applications of the background and peak power levels, PB and PP.
`
`Id. Intel, thus, asserts Wang describes forming the strongly-ionized plasma
`
`(and subsequently weakly-ionized plasma, strongly-ionized plasma, etc.)
`
`without arcing. Id. at 47.
`
`In the Preliminary Response, Zond argues the portion of Wang’s
`
`disclosure on which Intel relies — “the initial plasma ignition needs to be
`
`performed only once and at much lower power levels so that particulates
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`15
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`IPR2014-00470
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`produced by arcing are much reduced” (emphasis added) — does not
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`disclose the recited “creates a weakly ionized plasma . . . without an
`
`occurrence of an arc” as recited in claim 1. Prelim. Resp. 43–44 (emphases
`
`added).
`
`The discussion in Wang upon which Intel relies discusses initial
`
`plasma ignition that occurs before the waveform illustrated in Figure 6 of
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`Wang is applied. Ex, 1204, 7:3–6. That initial ignition is described by
`
`Wang as being performed only once so particulates produced by arcing are
`
`much reduced. Id. at 7:47–49. Therefore, when the voltage pulse is applied,
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`particulates produced by arcing are much reduced. It follows, as a result of
`
`that initial ignition, the voltage pulse creates a weakly-ionized plasma and
`
`then a strongly ionized plasma without arcing, as recited in claim 1 and,
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`commensurately, recited in claims 17 and 34. Accordingly, based on the
`
`record, we are persuaded Wang discloses the invention as recited in claims
`
`1, 17, and 34.
`
`Claims 9 and 21 recite: “wherein the voltage pulse generated between
`
`the anode and the cathode assembly excites atoms in the weakly-ionized
`
`plasma and generates secondary electrons from the cathode assembly, the
`
`secondary electrons ionizing a portion of the excited atoms, thereby creating
`
`the strongly-ionized plasma.” Ex. 1201, 22:52–57, 23:38–43. Claim 35 is
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`recited commensurately. Id. at 24:25–30.
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`Intel relies on Wang as teaching “the voltage pulse generated between
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`the anode and the cathode assembly” and Kudryavtsev for teaching excited
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`atoms are produced in both a slow and a fast stage of ionization (“the
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`voltage pulse . . . excites atoms in the weakly-ionized plasma and generates
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`secondary electrons from the cathode assembly, the secondary electrons
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`ionizing a portion of the excited atoms” recited in claim 1). Pet. 53.
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`Relying on its Declarant, Dr. Kortshagen, Intel contends Kudryavtsev
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`teaches ionization proceeds in a slow stage followed by a fast stage, each
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`stage producing excited atoms in response to the voltage pulse. Pet. 53; Ex.
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`1202 ¶ 147. Thus, Intel asserts, because Wang applies a pulse that suddenly
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`generates an electric field, an ordinarily skilled artisan would have found it
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`obvious to utilize Kudryavtsev’s teaching to better understand the effects of
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`applying Wang’s pulse. Pet. 53; Ex. 1202 ¶ 148. According to Intel,
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`Wang’s power levels fall within the range disclosed by the ’421 patent;
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`therefore, an ordinarily skilled artisan would expect the excited atoms
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`produced in the ’421 patent would also be produced in Wang. Pet. 53–54;
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`Ex. 1202 ¶¶ 149–151.
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`With respect to the recited generation of secondary electrons, Intel
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`argues the ’421 patent admits in the Background section, that secondary
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`electrons are produced by collisions with the cathode. Pet. 55. Therefore, as
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`Wang teaches collisions between ions in a high-density plasma (HDP)
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`region in a sputtering process, Intel asserts Wang’s cathode will also
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`produce secondary electrons. Id. Moreover, Intel contends Kudryavtsev
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`teaches collisions between secondary electrons and excited atoms produce
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`ions, and such collisions also occur in Wang. Pet. 53–54.
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`Zond disagrees, contending Intel has failed to show claims 9, 21, and
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`35 are obvious over Wang and Kudryavtsev. Prelim. Resp. 47–49. Zond
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`specifically argues Kudryavtsev withheld teaching of the designed electric
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`circuit; does not discuss choosing or adjusting a rise time or arcing and its
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`avoidance; and does not cite mathematically modeled conditions that trigger
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`arcing or the effects of pulse rise time. Id. at 47. Zond additionally argues
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`the electrode structure and geometry in Kudryavtsev and Wang are
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`“radically different” and specifically asserts Wang’s closely spaced
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`electrodes surrounded by a magnetic field for trapping ions is incompatible
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`with Kudryavtsev’s two foot long electrode arrangement. Id. at 48-49.
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`Thus, Zond contends, Petitioner does not proffer a persuasive argument or
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`evidence to justify combining Kudryavtsev’s teaching with Wang given their
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`structural incompatibility. Id. at 49.
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`Based upon the record before us, Zond’s arguments are not
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`persuasive. “It is well-established that a determination of obviousness based
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`on teachings from multiple references does not require an actual, physical
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`substitution of elements.” In re Mouttet, 686 F.3d 1322, 1332 (Fed. Cir.
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`2012) (citing In re Etter, 756 F.2d 852, 859 (Fed. Cir. 1985) (en banc)
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`(noting that the criterion for obviousness is not whether the references can
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`be combined physically, but whether the claimed invention is rendered
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`obvious by the teachings of the prior art as a whole)). Additionally, one
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`cannot show nonobviousness by attacking references individually where the
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`rejections are based on combinations of references. See In re Merck & Co.,
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`Inc., 800 F.2d 1091, 1097 (Fed. Cir. 1986).
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`Here, Intel is relying on Kudryavtsev for teaching excited atoms are
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`produced in both a slow and a fast stage of ionization. Specifically,
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`Kudryavtsev states “the effects studied in this work are characteristic of
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`ionization whenever a field is suddenly applied to a weakly ionized gas, they
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`must be allowed for when studying emission mechanisms in pulsed gas
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`lasers, gas breakdown, laser sparks, etc.” Ex. 1206, 34, right col. (emphasis
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`added). Kudryavtsev discloses a multi-step ionization plasma process,
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`comprising the steps of exciting the ground state atoms to generate excited
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`atoms, and then ionizing the excited atoms. Ex. 1206, Abs., Figs. 1, 6.
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`Therefore, on this record, we determine Kudryavtsev teaches collisions
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`between secondary electrons and excited atoms produce ions.
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`Wang applies voltage pulses that suddenly generate an electric field
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`between the anode and the cathode assembly. Ex. 1204, 7:61–63; see
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`Ex. 1202 ¶ 148. More importantly, Wang discloses background power PB of
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`1 kW (falling within the ’421 patent’s range of 0.01–100 kW, for generating
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`a weakly-ionized plasma), and pulse peak power PP of at least 10 to 1000
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`times the PB, e.g. 1 MW (falling within the ’421 patent’s range of 1kW–1
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`MW, for generating a strongly ionized plasma). Ex. 1204, 7:19–25; Ex.
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`1201, 15:56–61, Fig. 6. Furthermore, as testified by Dr. Kortshagen, the
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`’421 admits in the Background section, that secondary electrons are
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`produced by ion bombardment of the target surface. Ex. 1202 ¶ 86 (citing
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`Ex. 1201, 1:44–46). Moreover, Wang teaches combining highly ionized
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`sputtering during the pulses with significant neutral sputtering during the
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`background period. Ex. 1204, 7:36–39. Therefore, we are persuaded Wang
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`teaches secondary electrons will be produced during the sputtering process
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`and the collisions between ions in the HDP region and the cathode. Pet. 58.
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`Zond has not explained adequately why triggering a fast stage of
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`ionization in Wang’s apparatus would have been beyond the level of
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`ordinary skill, or why one of ordinary skill in the art would not have had a
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`reasonable expectation of success in combining the teachings. Moreover,
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`based on the record before us, Zond has not persuaded us of the
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`incompatibility of Kudravtsev’s teaching of the voltage pulse exciting atoms
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`in the weakly-ionized plasma and generating secondary electrons from the
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`cathode assembly with Wang’s teaching of the secondary electrons ionizing
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`a portion of the excited atoms.
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`Accordingly, given the evidence before us, we determine that the
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`Petition and supporting evidence demonstrate sufficiently that combining the
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`technical disclosures of Wang and Kudryavtsev would have been obvious.
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`Therefore, on this record, Intel has demonstrated a reasonable likelihood of
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`prevailing on its assertion that claims 9, 21, and 35 are unpatentable over the
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`combination of Wang and Kudryavtsev under 35 U.S.C. § 103.
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`E. Asserted Ground: Claims 14, 26, and 37 – Obvious over Wang and
`Mozgrin Thesis
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`Intel asserts that claims 14, 26, and 37 are unpatentable under § 103 as
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`unpatentable over Wang and Mozgrin Thesis. Pet. 32–49. As support, Intel
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`provides explanations as to how each claim limitation is met by Wang and
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`Mozgrin Thesis. Id. Intel proffers a declaration of Dr. Kortshagen as
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`support. Ex. 1202.
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`Zond responds that the combination of Wang and the Mozgrin Thesis
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`does not disclose every claim element. Prelim. Resp. 25–28.
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`We have reviewed the parties’ contentions and supporting evidence.
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`Given the evidence on this record, we determine that Intel has demonstrated
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`a reasonable likelihood of prevailing on its assertion that claims 14, 26, and
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`37 are unpatentable over Wang and Mozgrin Thesis. Our discussion focuses
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`on the deficiencies alleged by Zond as to the claims.
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`1. Mozgrin Thesis (Ex. 1207)
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`Mozgrin Thesis is directed to research undertaken to “study the
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`current-voltage characteristics and the regimes of existence of the high-
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`current quasi-stationary low-pressure discharge in magnetic fields of
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`different configurations” and “using a high-current discharge plasma to
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`generate dense plasma formations and intense flows of charged particles.”
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`Ex. 1207, 4. Mozgrin Thesis discusses the possibility of intensive cathode
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`sputtering and the creation of high density flows of sputtered material
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`particles. Id. at 5. Mozgrin Thesis teaches generating high-power, low-
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`power discharges with homogeneous plasma structure. Id. at 25. Mozgrin
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`Thesis further teaches this ability to generate these high-power discharges is
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`limited by the presence of different types of instabilities leading to the
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`contraction of the discharge and the transition to the arc regime. Id.
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`Mozgrin Thesis further discusses an experimental setup of a quasi-
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`stationary discharge power supply system using a power supply that
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`produces square current and voltage pulses with a rise time (leading edge of
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`the pulse) of 5-60 µs with a flat top duration of up to 1.5 ms and a current
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`amplitude of 3 kA at line charging voltage of up to 2.4 kV. Id. at 42.
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`Furthermore, according to Mozgrin Thesis, although pre-ionization of the
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`discharge gap (the path between the anode and the cathode) is not
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`mandatory; the probability of transition to the arc regime increases without
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`pre-ionization. Id. at 102.
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`2. Analysis
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`Intel argues Mozgrin Thesis discloses “wherein the rise time of the
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`voltage pulse is in the range of approximately 0.01V/μsec to 1000V/μsec” as
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`recited in claim 14. Pet. 56. According to Intel, an ordinarily skilled artisan
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`would have looked to Mozgrin Thesis for additional details, such as voltages
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`and rise times, teaching conditions that allow for the