`Petition for Inter Partes Review
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`DOCKET NO.: 0107131-00275 US1
`Filed on behalf of Intel Corporation
`By: Richard Goldenberg, Reg. No. 38,895
`David L. Cavanaugh, Reg. No. 36,476
`Wilmer Cutler Pickering Hale and Dorr LLP
`1875 Pennsylvania Ave., NW
`Washington, DC 20006
`Tel: (202) 663-6000
`Email: Richard.Goldenberg@wilmerhale.com
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` David.Cavanaugh@wilmerhale.com
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`UNITED STATES PATENT AND TRADEMARK OFFICE
`____________________________________________
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`
`BEFORE THE PATENT TRIAL AND APPEAL BOARD
`____________________________________________
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`INTEL CORPORATION
`Petitioner
`
`v.
`
`Patent Owner of
`U.S. Patent No. 7,808,184 to Roman Chistyakov
`
`IPR Trial No. TBD
`
`
`PETITION FOR INTER PARTES REVIEW OF
`U.S. PATENT NO. 7,808,184
`CHALLENGING CLAIMS 1-5 AND 11-15
`UNDER 35 U.S.C. § 312 AND 37 C.F.R. § 42.104
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`U.S. PATENT 7,808,184
`Petition for Inter Partes Review
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`TABLE OF CONTENTS
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`I. Mandatory Notices ............................................................................................. 1
`A. Real Party-in-Interest .................................................................................... 1
`B. Related Matters .............................................................................................. 1
`C. Counsel .......................................................................................................... 1
`D. Service Information ....................................................................................... 1
`II. Certification of Grounds for Standing ............................................................... 2
`III. Overview of Challenge and Relief Requested ................................................. 2
`A. Prior Art Patents and Printed Publications .................................................... 2
`B. Grounds for Challenge .................................................................................. 3
`IV. Brief Description of Technology ...................................................................... 4
`A. Plasma ............................................................................................................ 4
`B.
`Ions and Excited Atoms ................................................................................ 5
`V. Overview of the ‘184 Patent .............................................................................. 6
`A. Summary of Alleged Invention of the ‘184 Patent ....................................... 6
`B. Prosecution History ....................................................................................... 7
`VI. Overview of the Primary Prior Art References ................................................ 8
`A. Summary of the Prior Art .............................................................................. 8
`B. Overview of Mozgrin .................................................................................... 8
`C. Overview of Kudryavtsev ...........................................................................10
`D. Overview of Wang ......................................................................................11
`VII. Claim Construction ......................................................................................12
`A.
`“Strongly-ionized plasma” and “weakly-ionized plasma” ..........................13
`VIII. Specific Ground for Petition .......................................................................15
`A. Ground I: Claims 1, 2, 4, 5 and 11, 12, 14 and 15 are obvious in view of
`the combination of Mozgrin and Kudryavtsev ....................................................15
`1.
`Independent claim 1 .................................................................................15
`2.
`Independent claim 11 ...............................................................................27
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`U.S. PATENT 7,808,184
`Petition for Inter Partes Review
`3. Dependent claims 2, 4, 5 and 12, 14 and 15 are obvious in view of the
`combination of Mozgrin and Kudryavtsev ......................................................30
`B. Ground II: Claims 1, 2, 4, 5 and 11, 12, 14 and 15 are obvious in view of
`the combination of Mozgrin and the Mozgrin Thesis .........................................34
`1.
`Independent claim 1 .................................................................................35
`2.
`Independent claim 11 ...............................................................................38
`3. Dependent claims 2, 4, 5, 12, 14 and 15 ..................................................39
`C. Ground III: Claim 3 and 13 are obvious in view of the combination of
`Mozgrin, Kudryavtsev and Wang ........................................................................39
`D. Ground IV: Claim 3 and 13 are obvious in view of the combination of
`Mozgrin, Mozgrin Thesis and Wang ...................................................................41
`E. Ground V: Claims 1-5 and 11-15 are obvious in view of the combination
`of Wang and Kudryavtsev ...................................................................................43
`1.
`Independent claim 1 .................................................................................43
`2.
`Independent claim 11 ...............................................................................52
`3. Dependent claims 2-5 and 12-15 are obvious in view of the combination
`of Wang and Kudryavtsev ...............................................................................53
`IX. Conclusion ......................................................................................................60
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`ii
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`U.S. PATENT 7,808,184
`Petition for Inter Partes Review
`TABLE OF AUTHORITIES
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`
`In re ICON Health & Fitness, Inc., 496 F.3d 1374, 1379 (Fed. Cir. 2007).
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`37 C.F.R. §42.22(a)(1)
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`37 C.F.R. § 42.100(b)
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`37 C.F.R. §42.104(a)
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`37 C.F.R. §42.104(b)(1)-(5)
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`77 Fed. Reg. 48764 (Aug. 14, 2012).
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`U.S. PATENT 7,808,184
`Petition for Inter Partes Review
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`I. MANDATORY NOTICES
`A. Real Party-in-Interest
`Intel Corporation (“Petitioner”) is the real party-in-interest.
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`B. Related Matters
`There are currently several litigation matters that would affect or be affected
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`by a decision in the proceeding. Additionally, Petitioner is also filing Petitions for
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`Inter Partes review for several patents related1 to U.S. Patent No. 7,808,184. A
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`complete list of the related litigations is submitted herewith as Exhibit 1024.
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`C. Counsel
`Lead Counsel: Richard Goldenberg (Registration No. 38,895)
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`Backup Counsel: David L. Cavanaugh (Registration No. 36,476)
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`Service Information
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`D.
`E-mail:
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`David.Cavanaugh@wilmerhale.com;
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`Richard.Goldenberg@wilmerhale.com
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`Post and hand delivery: Wilmer, Cutler, Pickering, Hale and Dorr, LLP
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`1875 Pennsylvania Ave., NW
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`Washington, DC 20006
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`Telephone: 202-663-6000
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`Fax: 202-663-6363
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`1 The related patents, e.g., name the same alleged inventor.
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`1
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`U.S. PATENT 7,808,184
`Petition for Inter Partes Review
`II. CERTIFICATION OF GROUNDS FOR STANDING
`Petitioner certifies pursuant to Rule 42.104(a) that the patent for which
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`review is sought is available for inter partes review and that Petitioner is not
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`barred or estopped from requesting an inter partes review challenging the patent
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`claims 1-5 and 11-15 on the grounds identified in this Petition.
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`III. OVERVIEW OF CHALLENGE AND RELIEF REQUESTED
`Pursuant to Rules 42.22(a)(1) and 42.104(b)(1)-(2), Petitioner challenges
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`claims 1-5 and 11-15 of the ’184 Patent.
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`Prior Art Patents and Printed Publications
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`A.
`The following references are pertinent to the grounds of unpatentability
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`explained below:2
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`1.
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`D.V. Mozgrin, et al, High-Current Low-Pressure Quasi-Stationary
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`Discharge in a Magnetic Field: Experimental Research, Plasma Physics Reports,
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`Vol. 21, No. 5, pp. 400-409, 1995 (“Mozgrin” (Ex. 1003)), which is prior art under
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`102(b).
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`2
`The ’184 Patent issued prior to the America Invents Act (the “AIA”).
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`Accordingly, Petitioner has chosen to use the pre-AIA statutory framework to refer
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`to the prior art.
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`2
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`U.S. PATENT 7,808,184
`Petition for Inter Partes Review
`A. A. Kudryavtsev and V.N. Skerbov, Ionization relaxation in a plasma
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`2.
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`produced by a pulsed inert-gas discharge, Sov. Phys. Tech. Phys. 28(1), pp. 30-35,
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`January 1983 (“Kudryavtsev” (Ex. 1004)), which is prior art under 102(b).
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`3.
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`U.S. Pat. No. 6,413,382 (“Wang” (Ex. 1005)), which is prior art under
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`102(a) and (e).
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`4.
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`D.V. Mozgrin, High-Current Low-Pressure Quasi-Stationary Discharge in a
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`Magnetic Field: Experimental Research, Thesis at Moscow Engineering Physics
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`Institute, 1994 (“Mozgrin Thesis” (Ex. 1006), which is prior art under 102(b).
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`Exhibit 1006 is a certified English translation of the original Mozgrin Thesis,
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`attached as Exhibit 1007. A copy of the catalogue entry for the Mozgrin Thesis at
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`the Russian State Library is attached as Exhibit 1008.
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`B. Grounds for Challenge
`Petitioner requests cancellation of claims 1-5 and 11-15 of the ’184 Patent as
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`unpatentable under 35 U.S.C. §103. This Petition, supported by the declaration of
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`Dr. Richard DeVito (“DeVito Decl.” (Ex. 1002)) filed herewith, demonstrates that
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`there is a reasonable likelihood that Petitioner will prevail with respect to at least
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`3
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`U.S. PATENT 7,808,184
`Petition for Inter Partes Review
`one challenged claim and that each challenged claim is not patentable.3 See 35
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`U.S.C. § 314(a).
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`IV. BRIEF DESCRIPTION OF TECHNOLOGY
`Plasma
`A.
`A plasma is a collection of ions, free electrons, and neutral atoms. DeVito
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`Decl. ¶ 20 (Ex. 1002). The negatively charged free electrons and positively
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`charged ions are present in roughly equal numbers such that the plasma as a whole
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`has no overall electrical charge. The “density” of a plasma refers to the number of
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`ions or electrons that are present in a unit volume.4 DeVito Decl. ¶ 20 (Ex. 1002).
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`Plasma had been used in research and industrial applications for decades
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`before the ‘184 Patent was filed. DeVito Decl. ¶ 21 (Ex. 1002). For example,
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`sputtering is an industrial process that uses plasmas to deposit a thin film of a
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`target material onto a surface called a substrate (e.g., silicon wafer during a
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`3 The term “challenged claims” as used herein refers to claims 1-5 and 11-15 of the
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`’184 Patent. Petitioner seeks to invalidate the remaining claims of the ‘184 Patent
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`in a separate petition.
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`4 The term “plasma density” and “electron density” are often used interchangeably
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`because the negatively charged free electrons and positively charged ions are
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`present in roughly equal numbers in plasmas that do not contain negatively
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`charged ions or clusters. DeVito Decl. ¶ 20, n.1 (Ex. 1002).
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`4
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`U.S. PATENT 7,808,184
`Petition for Inter Partes Review
`semiconductor manufacturing operation). DeVito Decl. ¶ 21 (Ex. 1002). Ions in
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`the plasma strike a target surface causing ejection of a small amount of target
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`material. DeVito Decl. ¶ 21 (Ex. 1002). The ejected target material then forms a
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`film on the substrate. DeVito Decl. ¶ 21 (Ex. 1002).
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`Under certain conditions, electrical arcing can occur during sputtering.
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`DeVito Decl. ¶ 22 (Ex. 1002). Arcing is undesirable because it causes explosive
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`release of droplets from the target that can splatter on the substrate. DeVito Decl. ¶
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`22 (Ex. 1002). The need to avoid arcing while sputtering was known long before
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`the ‘184 patent was filed. DeVito Decl. ¶ 22 (Ex. 1002).
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`Ions and Excited Atoms
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`B.
`Atoms have equal numbers of protons and electrons. DeVito Decl. ¶ 23 (Ex.
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`1002). Each electron has an associated energy state. DeVito Decl. ¶ 23 (Ex.
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`1002). If all of an atom’s electrons are at their lowest possible energy state, the
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`atom is said to be in the “ground state.” DeVito Decl. ¶ 23 (Ex. 1002).
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`On the other hand, if one or more of an atom’s electrons is in a state that is
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`higher than its lowest possible state, then the atom is said to be an “excited atom.”
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`DeVito Decl. ¶ 24 (Ex. 1002). Excited atoms are electrically neutral– they have
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`equal numbers of electrons and protons. DeVito Decl. ¶ 24 (Ex. 1002).
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`A collision with a free electron (e-) can convert a ground state atom to an
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`excited atom. DeVito Decl. ¶ 25 (Ex. 1002). For example, the ‘184 Patent uses
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`5
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`U.S. PATENT 7,808,184
`Petition for Inter Partes Review
`the following equation to describe production of an excited argon atom, Ar*, from
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`a ground state argon atom, Ar. See ‘184 Patent at 10:40 (Ex. 1001).
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`Ar + e- Ar* + e-
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`An ion is an atom that has become disassociated from one or more of its
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`electrons. DeVito Decl. ¶ 26 (Ex. 1002). A collision between a free, high energy,
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`electron and a ground state or excited atom can create an ion. DeVito Decl. ¶ 26
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`(Ex. 1002). For example, the ‘184 Patent uses the following equation to describe
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`production of an argon ion, Ar+, from an excited argon atom, Ar*. See ‘184 Patent
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`at 10:42 (Ex. 1001).
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`Ar* + e- Ar+ + 2e-
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`Similarly, U.S. Pat. No. 7,147,759 (the “’759 Patent”) (Ex. 1013), which names the
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`same inventor and is owned by a common assignee, uses the following equation to
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`describe production of an argon ion, Ar+, from a ground state argon atom, Ar. See
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`‘759 Patent at 3:58 (Ex. 1013).
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`Ar + e- Ar+ + 2e-
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`The production of excited atoms and ions was well understood long before
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`the ’184 Patent was filed. DeVito Decl. ¶ 28 (Ex. 1002).
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`V. OVERVIEW OF THE ‘184 PATENT
`Summary of Alleged Invention of the ‘184 Patent
`A.
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`6
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`U.S. PATENT 7,808,184
`Petition for Inter Partes Review
`The ‘184 Patent describes generating a plasma by applying a voltage pulse
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`in a manner that allegedly avoids arcing.
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`More specifically, the claims of the ‘184 Patent are directed to methods that
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`supply a feed gas and apply a voltage pulse between an anode and a cathode
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`assembly. The voltage pulse increases an ionization rate and forms a so-called
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`“strongly-ionized plasma.” The strongly-ionized plasma is generated “without
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`forming an arc.”
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`The dependent claims are directed to further operational details, such as
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`moving a magnet, characteristics of the voltage pulse, processes that occur during
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`the generation of a voltage pulse, and the type of power supply used.
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`Prosecution History
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`B.
`In the first substantive office action, the only rejection was a nonstatutory
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`obviousness-type double patenting over U.S. Patent No. 7,095,179 in view of U.S.
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`Patent No 5,746,693. See 12/08/09 Office Action (Ex. 1009). The Patent Owner
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`traversed the double patenting rejection by filing a terminal disclaimer. See
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`06/03/10 Response and accompanying Terminal Disclaimer (Ex. 1010). The
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`claims were then allowed. See 06/28/10 Notice of Allowance (Ex. 1011).
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`In the Notice of Allowability, the Examiner noted that the prior art of record
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`failed to disclose “the voltage pulse having at least one of a controlled amplitude
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`and a controlled rise time that increase an ionization rate so that a rapid increase in
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`U.S. PATENT 7,808,184
`Petition for Inter Partes Review
`electron density…” and “the voltage pulse having at least one of a controlled
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`amplitude and a controlled rise time that shifts an electron energy distribution in
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`the plasma to higher energies that increase an ionization rate so as to result in a
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`rapid increase in electron density.” 06/28/10 Notice of Allowance at 2 (Ex. 1011).
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`However, as will be explained in detail below, and contrary to the
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`Examiner’s reasons for allowance, the prior art addressed herein teaches those and
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`all other limitations of the challenged claims.
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`VI. OVERVIEW OF THE PRIMARY PRIOR ART REFERENCES
`Summary of the Prior Art
`A.
`As explained in detail below, limitation-by-limitation, there is nothing new
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`or non-obvious in the challenged claims of the ‘184 Patent. DeVito Decl. ¶ 34 (Ex.
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`1002).
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`B. Overview of Mozgrin5
`Mozgrin teaches forming a strongly-ionized plasma “without forming an
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`arc.” Fig. 7 of Mozgrin, copied below, shows the current-voltage characteristic
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`(“CVC”) of a plasma discharge.
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`5 Mozgrin is art of record for the ‘184 Patent. However, Mozgrin was not
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`substantively applied during prosecution of the ‘184 Patent.
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`U.S. PATENT 7,808,184
`Petition for Inter Partes Review
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`As shown, Mozgrin divides this CVC into four distinct regions.
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`Mozgrin calls region 1 “pre-ionization.” Mozgrin at 402, right col, ¶ 2 (“Part
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`1 in the voltage oscillogram represents the voltage of the stationary discharge (pre-
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`ionization stage).” (emphasis added)) (Ex. 1003). DeVito Decl. ¶ 37 (Ex. 1002).
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`Mozgrin calls region 2 “high current magnetron discharge.” Mozgrin at 409,
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`left col, ¶ 4 (“The implementation of the high-current magnetron discharge
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`(regime 2)…” (emphasis added)) (Ex. 1003). DeVito Decl. ¶ 38 (Ex. 1002).
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`Application of a high voltage to the pre-ionized plasma causes the transition from
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`region 1 to 2. DeVito Decl. ¶ 38 (Ex. 1002). Mozgrin teaches that region 2 is
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`useful for sputtering. Mozgrin at 403, right col, ¶ 4 (“Regime 2 was characterized
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`by an intense cathode sputtering…”) (Ex. 1003).
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`Mozgrin calls region 3 “high current diffuse discharge.” Mozgrin at 409, left
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`col, ¶ 5, (“The high-current diffuse discharge (regime 3)…” (emphasis added))
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`(Ex. 1003). DeVito Decl. ¶ 39 (Ex. 1002). Increasing the current applied to the
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`“high-current magnetron discharge” (region 2) causes the plasma to transition to
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`U.S. PATENT 7,808,184
`Petition for Inter Partes Review
`region 3. DeVito Decl. ¶ 39 (Ex. 1002). Mozgrin also teaches that region 3 is
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`useful for etching, i.e., removing material from a surface. Mozgrin at 409, left col,
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`¶ 5 (“The high-current diffuse discharge (regime 3) is useful … Hence, it can
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`enhance the efficiency of ionic etching…”) (Ex. 1003). See also DeVito Decl. ¶ 39
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`(Ex. 1002).
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`Mozgrin calls region 4 “arc discharge.” Mozgrin at 402, right col, ¶ 3
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`(“…part 4 corresponds to the high-current low-voltage arc discharge…”
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`(emphasis added)) (Ex. 1003). DeVito Decl. ¶ 40 (Ex. 1002). Further increasing
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`the applied current causes the plasma to transition from region 3 to the “arc
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`discharge” region 4. DeVito Decl. ¶ 40 (Ex. 1002).
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`Within its broad disclosure of a range of issues related to sputtering and
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`etching, Mozgrin describes arcing and how to avoid it. DeVito Decl. ¶ 41 (Ex.
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`1002).
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`C. Overview of Kudryavtsev6
`Kudryavtsev is a technical paper that studies the ionization of a plasma with
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`voltage pulses. See, e.g., Kudryavtsev at 30, left col. ¶ 1 (Ex. 1004). In particular,
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`Kudryavtsev describes how ionization of a plasma can occur via different
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`processes. DeVito Decl. ¶ 42 (Ex. 1002). The first process is direct ionization, in
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`6 Kudryavtsev is art of record for the ‘184 Patent. However, Kudryavtsev was not
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`substantively applied during prosecution of the ‘184 Patent.
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`U.S. PATENT 7,808,184
`Petition for Inter Partes Review
`which ground state atoms are converted directly to ions. See, e.g., Kudryavtsev at
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`Fig. 6 caption (Ex. 1004). See also DeVito Decl. ¶ 42 (Ex. 1002). The second
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`process is multi-step ionization, which Kudryavtsev calls stepwise ionization. See,
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`e.g., Kudryavtsev at Fig. 6 caption (Ex. 1004). See also DeVito Decl. ¶ 42 (Ex.
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`1002). Kudryavtsev notes that under certain conditions multi-step ionization can
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`be the dominant ionization process. See, e.g., Kudryavtsev at Fig. 6 caption (Ex.
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`1004). See also DeVito Decl. ¶ 42 (Ex. 1002). Mozgrin took into account the
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`teachings of Kudryavtsev when designing his experiments. Mozgrin at 401, ¶
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`spanning left and right cols. (“Designing the unit, we took into account the
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`dependences which had been obtained in [Kudryavtsev]…”) (Ex. 1003). See also
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`DeVito Decl. ¶ 42 (Ex. 1002).
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`D. Overview of Wang7
`Wang discloses a pulsed magnetron sputtering device having an anode (24),
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`a cathode (14), a magnet assembly (40), a DC power supply (100) (shown in Fig.
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`7), and a pulsed DC power supply (80). See Wang at Figs. 1, 7, 3:57-4:55; 7:56-
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`8:12 (Ex. 1005). Fig. 6 (annotated and reproduced below) shows a graph of the
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`power Wang applies to the plasma. The lower power level, PB, is generated by the
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`DC power supply 100 (shown in Fig. 7) and the higher power level, PP, is
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`7 Wang is art of record for the ‘184 Patent. However, Wang was not substantively
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`applied during prosecution of the ‘184 Patent.
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`U.S. PATENT 7,808,184
`Petition for Inter Partes Review
`generated by the pulsed power supply 80. See Wang 7:56-64 (Ex. 1005); see also
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`DeVito Decl. ¶ 43 (Ex. 1002). Wang’s lower power level, PB, maintains the
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`plasma after ignition and application of the higher power level, PP, raises the
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`density of the plasma. Wang at 7:17-31 (“The background power level, PB, is
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`chosen to exceed the minimum power necessary to support a plasma.... [T]he
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`application of the high peak power, PP, quickly causes the already existing plasma
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`to spread and increases the density of the plasma.”) (Ex. 1005). DeVito Decl. ¶ 43
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`(Ex. 1002). Wang applies the teachings of Mozgrin and Kudryavtsev in a
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`commercial, industrial plasma sputtering device. DeVito Decl. ¶ 43 (Ex. 1002).
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`VII. CLAIM CONSTRUCTION
`A claim in Inter Partes Review is given the “broadest reasonable
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`construction in light of the specification in which it appears.” 37 C.F.R. §
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`42.100(b). Any claim term which lacks a definition in the specification is therefore
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`U.S. PATENT 7,808,184
`Petition for Inter Partes Review
`also given a broad interpretation.8 In re ICON Health & Fitness, Inc., 496 F.3d
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`1374, 1379 (Fed. Cir. 2007). The following discussion proposes constructions of
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`and support therefore of those terms. Any claim terms not included in the
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`following discussion are to be given their broadest reasonable interpretation in
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`light of the specification as commonly understood by those of ordinary skill in the
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`art. Moreover, should the Patent Owner, in order to avoid the prior art, contend
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`that the claim has a construction different from its broadest reasonable
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`interpretation, the appropriate course is for the Patent Owner to seek to amend the
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`claims to expressly correspond to its contentions in this proceeding. See 77 Fed.
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`Reg. 48764 (Aug. 14, 2012).
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`“Strongly-ionized plasma” and “weakly-ionized plasma”
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`A.
`All challenged claims require generation of a “strongly-ionized plasma.”
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`Additionally, some of the dependent claims further require the creation of a
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`“weakly-ionized plasma” before generating the “strongly-ionized plasma.” See
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`Claims 4 and 14.
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`8 Petitioner adopts the “broadest reasonable construction” standard as required by
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`the governing regulations. 37 C.F.R. § 42.100(b). Petitioner reserves the right to
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`pursue different constructions in a district court, where a different standard is
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`applicable.
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`13
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`U.S. PATENT 7,808,184
`Petition for Inter Partes Review
`These terms relate to the density of the plasma, i.e., a weakly-ionized plasma
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`has a lower density than a strongly-ionized plasma. DeVito Decl. ¶ 46 (Ex. 1002).
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`With reference to Fig. 4, the ‘184 Patent describes forming a weakly-ionized
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`plasma by application of the low power stage 258 and then forming a strongly-
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`ionized plasma by application of higher voltage and power. ‘184 Patent at 7:29-
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`46; 8:41-60 (Ex. 1001). The ‘184 Patent also provides exemplary densities for the
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`weakly-ionized and strongly-ionized plasmas. See ‘184 Patent at 7:14-17
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`(“Weakly-ionized plasmas are generally plasmas having plasma densities that are
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`less than about 1012 – 1013 cm-3 and strongly-ionized plasmas are generally plasmas
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`having plasma densities that are greater than about 1012-1013 cm-3.”) (Ex. 1001).
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`Thus, the proposed construction for “weakly-ionized plasma” is “a lower
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`density plasma.” Likewise, the proposed construction for “strongly-ionized
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`plasma” is “a higher density plasma.”
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`Petitioner’s proposed construction is consistent with the position the Patent
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`Owner has taken in other jurisdictions. For example, the Patent Owner, when
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`faced with a clarity objection during prosecution of a related European patent
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`application, argued that “it is [sic] would be entirely clear to the skilled man, not
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`just in view of the description, that a reference to a ‘weakly-ionised plasma’ in the
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`claims indicates a plasma having an ionisation level lower than that of a ‘strongly-
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`U.S. PATENT 7,808,184
`Petition for Inter Partes Review
`ionized plasma’ and there can be no lack of clarity.” 04/21/08 Response in EP
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`1560943 (Ex. 1017).
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`VIII. SPECIFIC GROUND FOR PETITION
`Pursuant to Rule 42.104(b)(4)-(5), the below sections, and as confirmed in
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`the DeVito Decl. ¶¶ 49- 154 (Ex. 1002), demonstrate in detail how the prior art
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`discloses each and every limitation of claims 1-5 and 11-15 of the 184 Patent, and
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`how those claims are rendered obvious by the prior art.
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`A. Ground I: Claims 1, 2, 4, 5 and 11, 12, 14 and 15 are obvious in
`view of the combination of Mozgrin and Kudryavtsev
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`The claim chart that Petitioner served on Feb. 11, 2014 in its ongoing
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`litigation involving the Petitioner and the Patent Owner, showing that claims 1, 2,
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`4, 5 and 11, 12, 14 and 15 are obvious in view of the combination of Mozgrin and
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`Kudryavtsev, are being submitted hereto as Exhibit 1019 (Ex. 1019). Mr. DeVito
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`has reviewed the claim chart and agrees with it. See DeVito Decl. ¶ 51 (Ex. 1002).
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`1.
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`Independent claim 1
`The preamble
`a)
`Claim 1 begins, “[a] method of generating a strongly-ionized plasma.” The
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`densities in Mozgrin’s regions 1-3 are summarized below.
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`• Region 1: 109 – 1011 cm-3.9
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`9 Mozgrin at 401, right col, ¶2 (“For pre-ionization … the initial plasma density in
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`the 109 – 1011 cm-3 range.”) (Ex. 1003).
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`U.S. PATENT 7,808,184
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`• Region 2: exceeding 2x1013 cm-3.10
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`• Region 3: 1.5x1015cm-3.11
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`Mozgrin generates a strongly-ionized plasma in both regions 2 and 3.
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`DeVito Decl. ¶ 53 (Ex. 1002). The density in those regions matches the exemplary
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`density given for a strongly-ionized plasma in the ‘184 Patent. ‘184 Patent at 7:14-
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`17 (“[S]trongly-ionized plasmas are generally plasmas having plasma densities that
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`are greater than about 1012-1013 cm-3.”) (Ex. 1001). See also DeVito Decl. ¶ 53
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`(Ex. 1002). Accordingly, Mozgrin teaches the preamble. DeVito Decl. ¶ 53 (Ex.
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`1002).
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`Limitation (a)
`b)
`Limitation (a) of claim 1 reads, “supplying feed gas proximate to an anode
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`and a cathode assembly.”
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`In the commonly owned, and previously filed, ‘759 Patent, the Patent Owner
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`admitted that this limitation was known. ‘759 Patent at 3:19-21 [describing prior
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`10 Mozgrin at 409, left col, ¶ 4 (“The implementation of the high-current
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`magnetron discharge (regime 2) in sputtering … plasma density (exceeding
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`2x1013 cm-3).”) (Ex. 1003).
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`11 Mozgrin at 409, left col, ¶5 (“The high-current diffuse discharge (regime 3) is
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`useful for producing large-volume uniform dense plasmas ni ≅ 1.5x1015cm-3…”).
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`(Ex. 1003).
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`U.S. PATENT 7,808,184
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`art Fig. 1] (“A feed gas source 109…is introduced into the vacuum chamber…”);
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`3:23-24 (“The magnetron sputtering apparatus 100 also includes a cathode
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`assembly 114…”); 3:40-41 (“An anode 130 is positioned in the vacuum chamber
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`104 proximate to the cathode assembly 114.”) (Ex. 1013). See also DeVito Decl. ¶
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`54 (Ex. 1002).
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`Mozgrin’s Fig. 1 also shows anode “2” and cathode “1.” DeVito Decl. ¶ 55
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`(Ex. 1002). Mozgrin discloses filling the space between the anode and cathode
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`with a feed gas such as Argon. Mozgrin at 401, left col, ¶ 4 (“…the discharge gap
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`which was filled up with either neutral or pre-ionized gas.”); 400, right col, ¶ 3
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`(“We investigated the discharge regimes in various gas mixtures at 10-3 – 10
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`torr…”); 402, ¶ spanning left and right cols (“We studied the high-current
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`discharge in wide ranges of discharge current…and operating pressure…using
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`various gases (Ar, N2, SF6, and H2) or their mixtures of various composition…”);
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`401, left col, ¶ 1 (“The [plasma] discharge…was adjacent to the cathode.”) (Ex.
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`1003). See also DeVito Decl. ¶ 55 (Ex. 1002). Mozgrin also discloses that its
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`cathode includes a sputtering target. DeVito Decl. ¶ 55 (Ex. 1002). Specifically,
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`Mozgrin discusses sputtering that occurs in Region 2. Mozgrin at 403, right col.,
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`¶4 (“Regime 2 was characterized by an intense cathode sputtering….”) (Ex. 1003).
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`See also DeVito Decl. ¶ 55 (Ex. 1002).
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`Mozgrin therefore teaches limitation (a). DeVito Decl. ¶ 56 (Ex. 1002).
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`c)
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`Limitation (b)
`“generating a voltage pulse between the anode and
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`the cathode assembly”
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`Mozgrin generates the voltage pulse shown in Fig. 3(b). Mozgrin at 402,
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`Fig. 3 caption (“Fig. 3. Oscillograms of (a) current and (b) voltage…”) (Ex. 1003).
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`See also DeVito Decl. ¶ 57 (Ex. 1002). Mozgrin applies that voltage pulse
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`between Mozgrin’s anode and cathode. Mozgrin at 401, left col, ¶ 4 (“It was
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`possible to form the high-current quasi-stationary regime by applying a square
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`voltage pulse to the discharge gap which was filled up with either neutral or pre-
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`ionized gas.”) (emphasis added) (Ex. 1003). See also DeVito Decl. ¶ 57 (Ex.
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`1002). Mozgrin therefore teaches “generating a voltage pulse between the anode
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`and the cathode assembly” as required by limitation (b) of claim 1. DeVito Decl. ¶
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`57 (Ex. 1002).
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`“the voltage pulse having at least one of a
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`controlled amplitude and a controlled rise time”
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`Fig 3(b) of Mozgrin, which shows Mozgrin’s voltage pulse, is copied below.
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`U.S. PATENT 7,808,184
`Petition for Inter Partes Review
`The voltage pulse in Mozgrin’s region 2a has a rise time that is controlled to
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`be within 5 – 60 µs. Mozgrin at 401, right col, ¶ 1 (“[t]he power supply was able
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`to deliver square voltage and current pulses with [rise] times (leading edge) of 5 –
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`60 µs ….”) (Ex. 1003). See also DeVito Decl. ¶ 59 (Ex. 1002).
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`The voltage pulse in Mozgrin’s region 2a also has a controlled amplitude.
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`DeVito Decl. ¶ 60 (Ex. 1002). Table 1 of Mozgrin shows the parameters,
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`including voltage, used in Mozgrin’s region 2. Mozgrin at 406, right col, ¶ 2
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`(“Table 1 presents parameter ranges corresponding to regime 2.”) (Ex. 1003). As
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`shown in Mozgrin’s Table 1, the voltage in region 2 was controlled in a series of
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`experiments to be in sub-ranges of 260-1100 Volts (e.g., in one experiment being
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`controlled to 260-990 Volts). Mozgrin at 406, Table 1 (Ex. 1003). See also
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`DeVito Decl. ¶ 60 (Ex. 1002).
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`Therefore, Mozgrin teaches controlling both the rise time and the amplitude
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`of its voltage pulse as required by this portion of limitation (b) of claim 1. DeVito
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`Decl. ¶ 61 (Ex. 1002).
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`“that increases an ionization rate so that a rapid
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`increase in electron density and formation of a strongly-
`ionized plasma occurs”
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`In the Section above regarding the preamble of claim 1, the plasma densities
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`in Mozgrin’s regions 1-3 are provided and it was explained that the plasmas in
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`Mozgrin’s regions 2 and 3 are “strongly-ionized plasmas,” because their densities
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`U.S. PATENT 7,808,184
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`are greater than the density obtained in region 1 and because they match the
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`exemplary density for a strongly-ionized plasma given in the ‘184 Patent. DeVito
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`Decl. ¶ 62 (Ex. 1002). Also, Mozgrin’s density increase from 1011 in region 1 to
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`1013 in region 2 in response to Mozgrin’s pulse shows that Mozgrin generated a
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`strongly-ionized plasma by “increasing ionization rate” and “rapid increase in
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`electron density” as required by limitation (b) of claim 1. DeVito Decl. ¶ 62 (Ex.
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`1002). Such increase in ionization rate and rapid increase in electron density upon
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`application of a voltage pulse were