`
`S..t’«§s_\'i?A}_.i_5.§ F-cr~':.i:1i
`
`{I0
`xaiiszmticsax
`
`.-.-’\ §§i..‘:'}
`4..
`
`‘
`
`fifegg
`
`T*
`
`(§.C
`
`.f*:’>.¢z*%2=.-E '2
`
`Isl.
`
`xix.
`
`‘ML
`
`f§3§i}R.:
`
`Q01
`
`m1~:1s;~_:m:1r;<r i
`by Pm-‘:»~::;:ts
`
`\'\ ‘ N“
`\
`s~4_:>.i
`
`§.1*§§‘C‘§_.A
`
`RA“.§[‘§§;§l\f
`
`\‘#'\*q‘1
`sin
`
`§*i§§.§§_..
`
`)7\~’V.§§
`
`.\E17,
`
`113
`
`\-\2‘}_1:ia":[i'1
`
`mi2';_::s
`
`‘='_yi§ 1:33,
`
`..:.<3s‘\.»‘
`
`:3
`
`33:35.5 s;}s::>i:'s;m::>.i:‘37
`
`‘
`
`ma
`
`£-
`
`.«
`\=x;.2:*::‘=i.t‘§"
`
`n...
`
`.3
`
`\X«.
`
`Y.
`
`Fax
`
`.\n.WmV3mum
`r..
`
`3%».If
`
`000001
`
`AKBM 1052
`
`000001
`
`
`
`
`
`
`
`
`-3.
`
`6.
`
`7:
`
`
`
`
`
`...8.,.ax...N».,.....V31.cf.1.,H.mmHYfir.3G....3.....,..,,32rap3Rh..:.\.11+4...3.EH.no...t\anLHC.......u.5\\...,Au.$30
`
`
`,..3.V.anE....,..,..am......I...3%.RAE8H8..
`...G3......SI,,.x6.........,.<,...,.:33..1......31..H1.........3KwN“c0p0_x59xm0s.0nm.2..mmum....3S.m;E,3.,3.
`
`
`
`
`
`2..."¢.$,.xi...3,..I.3:,I.ax...mm...»C.1..wk.134..am.3!at(L.3.}37\9.\\>.x23.
`
`.,.\.u\..:5;«n401;.W1T..ft13.vb;\.MW.,\!1....AC.0,v\\\...._2n.Dr...9303..9.v.F.......A.4.anE9..,.enG3a.1.n.
`
`.A3...<.9....2wn\£..§..wt.1SM.»«....:31......z.X:0en....|\‘_\.x..3«L,$3..1....Wu...33C,,.xV.33.,.13:w....W.3.2..1..3...,
`
`
`
`.10w.H:1.CV.x...:1fir...T.1......:5O3r33U,\\—3
`..8.,1E,.n,1.PY33..A.
`2m.K-QNPK3.mr.3.3.S.0.0xi.ams.3:\.(.cw5“5.n....,...:.,...5,.3...234..,R6»ti.1{U.,1»,3as.Q.»is.3..2.avH_...n.2...19QS..u6.1..1rR...
`
`
`
`
`.x...f.1.5.2.«L...,..>+..w«A.1...,1w.3..av..1«.1W)3..Lmm.nA0msm0n0an.m.0Lu.0..:nsw.m.:..1\\......1x‘M,.,XI..G\.,I.:....
`\x.,.a.u...nb..1.0.,4,,9.0am30.n.1m.L,,..7..u.,.\\x..32.»u,..K3.w,.1m....nu=83.0aanE2.0M...Eman.0._......_.K..E._...,,.MW:9.PH.Vf..3.1....,V1.1I.»R.m..Junnun9..xiS,ix.3C..no,T3RH...,_9.xx.:9_.34..mm19.V.....3M2«J..38._;,I.,mm.09.,2.13,.....w,W,:0Sn3.1a,}ame,.Q.“.L....1:y9.1:1,..z\fw.$2.~11\..3..\..,_.\iE......,as.3.
`
`
`
`
`
`
`
`_...c,.\v._.Q..4.9,00ha.km....:..3.:Q.flu3N»%..U...<.FLgnu...E(.1.E.,.wl.V.
`
`
`,.,s.,3Rn«LH.<2,,..E.+aY..0TE.1...1..ct..\..w...15¢.nu:.v......:..1:.«.13.,,.,...)E,...._Y‘....in,Y4,..,3.....,..+l....r.M,3.
`
`
`
`
`
`.....bx...I..\1..3am3..DK1C..38inu”.E,.r,1ad«.2.S...\3an1...cl,
`
`
`
`
`
`3.3..I:.14.3.97...Anne.Ana..1,.Canu.u.._..AVS.
`...i.,...,..,...3...Q.T.T.Kw.3WmM...an.S:3ca.mms:.F.
`
`.3.G3.......EEQ;rsre,3.,3.3.......2...we
`
`.,A2.,V.,.ItC\.~.P».v\.Cmm?
`
`
`/...<2..SEQ”in...mmma.8Q...i,Id.»x..1~44...,.rx.(..1...:3...1;x,_....inL....M.73.1...:1L«:1..,>G8.91..\+9.3Wu3ma.Av,IA...mu
`
`
`
`3nX.us.3mm...+&..<,C.Lmu«Q,..am.«Q............an81,._..Sn:Cvs:C.4“.an3..,B..a..,_.4:ii
`
`
`..i\m...1T.T)3E..,1.i....,...1Let\.X.3.....3.W;>3...t\&.r.V...«.2C0,.R.lmu.x§....my»;
`.1Q.8SmV,1.3KCQS8M....5HHmm.
`
`
`
`
`
`
`.._Jn\\..1.\.ex.....$..3».L.A\\»K),2}2.....6..ex.3.S\1»41....a.Am..,...ixx....5.6:<3.12...1...5...3:$3..AU,QMnukws.
`
`
`..,0.,039.33......R.0...n..2Hua.3c3S,.\....,._.,...,3L..m.
`
`
`,3./.SM.».,2..$3<9kc3.«.,,....,..«hC,.At.1.1..
`.1.3B‘Qnn0.,.3.i.._rCW..4......A...i0...,
`,13....T..<m..2.,3..3:33.9L...6,..s».(,....
`$1»...1...,D.“.3..332..v.....n.S8.1.3:,.Pm....132.13...1.31:..23..11...H.3...S1.inM,.S.,44.1.14...333xx.3.$2fixLo\F.<1...,Av.«A2‘..19ex.3...IS1C0:,H...3.S.1.131...F:1ixT.As....r..,CV:..mi,.51.13..am..k\E...V.0.cc.
`
`
`
`
`
`
`
`,1.1..non.3........3311,‘s.I...“E.u\xx},51..\x3..
`.Pvt.nr...us.2.3..mVE...1../)\.\fax...5,S..3.8H4....:3O.,..wM......3+...$3MA3..\.1}3..w%Va.5..«L:,.T..3VJno.4...Nulxd.C:.1.1mm,u00,10.$33:,,gum...,.,..x..1...1...,Y14.....l0$5.4I31.SECC..9.ILwt«Qc.mu..,.fin3,mmx..5..W.
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`.3Svs»,\).RX9.Rx.hm,.\...~WCV.ptmsuw.rt14rx...u\St..\.«.31..7....\CL«.31.....\...........flums!“,an+3.v.\...finNaEU...H_,.¢~..u_19Q.QM.%ion.43.....,...C....s»....I..._...:_«.4H«mu.5”.M:1HYnCC.u.1,.“.1yaera..£..HMx(32.~.,.w.
`
`
`
`(QX),«......_.w\._x9.3.6...“1}.van;C,«ifinxv..3.V..r\Erxx..\.,.stk.r.,..53.,.....xx..ax...MK3!.5..1at4....xi,.wiE...
`
`
`nrfxA,B.“{L......{5..ix.¢\.19:,.x/W.ix..\\.1at.1am.pt;413,6..§E,..:8.+.....
`
`
`«.1.5»,.IC.1I2<...,c...A....3)viWA1.,3mm.V.3:,
`
`
`
`xmw»vs.1E...gm.3.u.,....«.30:u.3.3.imiab,5:3.(8as...«Li
`ru.23..5..3....3.i\.V...11in.«£vs.‘st,..xi
`
`,...,\5...._...,.n9..,....aTI..II,1..:......,.,..L....W»:.3.V.wmM.134«r,GHasm....anU.)3.M...4,.2..,.>.
`
`
`
`
`
`
`
`..CH»;mm.«XA.£02x.0ma‘.»{,\...x:..,x..r..3.5.,..§3.....A...Bana....2.,.LK.2.......,t..a..0.33ES.0..0......CC.3.3...M...en.,.i\...<wflErAL.5»x...,...x.3‘.5.1,..3»W‘...xx»..¢\
`
`
`
`
`V...‘\\x,wu.1awLam.flux.M,.bx.«Lx{V.»
`
`.1.«J.)1.1.,1,3g..5:.nu.9:«.1......,,,...,.flu.{A.N._..73V.s..A..nu”.CV«I,.2.L.E5U3
`
`P.»..w3.0)Mm»xx.an.inn.V4?;,.~.119.3.:nxH..
`av,..1n0W...1..1...sFInt.(x\M...nz>{£.xh...\:.st,3.....
`.......1aw..,H2.3.5....03...0.,M.Eu..0.3,332«hm.3.Vxu.am.in-..,....\._.....’.V.\\.1..3133.C9.,_.2..5._.6amD8K4..E3an,
`
`
`
`
`
`
`
`.C..8..mun.ru...x1!..15vs.7..Ya..3.,...x,1!:[A
`..\.u«x1:.3..x:W?.\..1....1......T.£2....<.(....I....w.a.,r3\5..1..We.R.nu.
`
`
`
`
`rmY“Lu,Qmtex......3mu3.?L7\:00..
`
`«Sn...s.....x..3.
`1\2xx.»1.5$3.,?..x....1_‘.1«cam,9.»+\\.1:IV17.V),(xL?,ex.3:1,4.2..xx.mm...
`
`
`
`000002
`
`000002
`
`
`
`
`
`
`
`
`
`
`..«.1..3.y....i9....una..,033.1mm3E..3ru5C.x.1....z3.I...,E....if\.V;.\..\x..in
`X....1RIN;«E13.,V:WM1“K.”«L\.I\.tms..2L36.1i;C...,.st».«.i.3._.....
`
`
`:2..R.<2..Y.1...V»A.,:.3.11..1.....E...,2.V0...\...YM...tE.1,,.m1TBEX.e.23.nm3:8S.10...0V.3iinu:I.....,
`
`+3EVK0xi,....:_.._.._.,,ns.
`
`
`..\v..2.3vi..({on.$84.2.1+8«UV..\..8.‘3».B..\,.EV.3Au.3.0.3...,QV.\HCK.3.cl.0..G.3.mmx:1...HW...SH...E.:_Htmm.
`s.m.e._:0e0”n00.0,0--.00nm....C.S...«Jxxm3r.....,v.,.1w.“M....1.“........1.......K...K3H.9mmB:3,Hma.,\0...0.3...
`.1CF,C“I_.3.5.A..L11.,1.1...nu.ma«.0>11..
`.1».ii...\isr1......3.5.._..ax\.»..1.uV.3.,SW1...Ia\)+1..5...N03.
`.1Ef..:2.1......3Lbrd.3m.“«Aan.0LLmu.QQ1!axWW.3Fs0d.imflLi09.n..8QS.51H...C.5IE...z},3;
`\.,..NP.
`
`
`
`
`..x...2....SC,..\.VA3:U.0).Zoo.“Hwm.$4.4!<_:w~AEl..4...an.._3.
`.(,T”F.ti.T..n.,5«L.:1Cana.....\4..YZ1...£9...6;
`1..,Q..2re.:2...IE\S.4.....2}._LmAanRV.43.S..3.C..\L.
`
`1.1.1n:«O..31Cw....V»n_1)!(R1...1.....Ix.8...3,
`
`2.1X3..cu.:1vi...-lV.S3..,1,\i3.5..
`
`
`..._.....4;mmrs
`
`....".V.G,”2.3.1....a\.\_\\.WL
`
`
`
`
`,_6mg9+..clVi1._....,.t1...1.......:...,..,._.xx.._1:.onc,nxnfim.m.32;.,6“.4.0...ma.1..SA1:H..12%..}w..I3.F.:i....1...K.{Nii.~...\C3..Rx..EEa,Q.r.._H..1...1....€.83Y33..13u.1.4{vaw.1..\.{LV1.
`
`
`.S3.L-\S.1x;\.3..5:_.v».A..n...11.in.3...
`_u<(.6\\wtIv_..Q.E.1:3HIVINnu..xS.0.15..Li......63is.\.2.3i2.a...1.S._2...5,,.L..1...u.35,..93..:5_+.n.1<..;.M:D.16..L...J3m\EW,.anE.um:9E:3K...JC...CP.YL...Ru(_1axx.1..es.3.3.3RisRV3..
`
`.i90.as‘;.3.....,<51youxx.U...in0:B...7.3.C\.1!,ofT»1;
`
`
`
`
`
`
`.5“..3qt.51as.x)..,PSw}fiuV».‘flu,»us...mo“\.c..3..RDi.nu.Q;.1.2.33.an9..V»
`«on...X...C.k.cPmB.m3+1sw....iW..2G.\.,as.A»:ri.3{.:3..xx;13.9.3...:&v3M.«Hmmvxx0.0a.
`21.W......lA|\M3.xi.«..J..avX.“.........H4.?c«tn«xx5.5‘E.1:vs;sa........oi.:.\..ac.1...5\)J.Cin1Lu...:1on......m.1..\.Jor.it.Vx....\.3.£\\..
`
`
`
`.ir:.5..3an...«.9..8,W:XR5.:39.mm.3A31:.w1..4!.5+xx.ax.T.s.3..
`
`,.3E...w..P.6....si1Va.mu....v,w.mmmay6_vi0..,..u....E._..n+...1..\........r:9.3«,0D3..0rMn.5.0anaxq._nT.5....zzm.{3..«QGmuYi.(.hG...4.,8flQ.2:I4?...T3f\\\...CL,....s.10Y.a.....?\.
`
`...u..l:\..:1r»as.»M...1...so....3Ex..1T5\3...1.......7»2...2AV...tutufink.{.54«:11».$1xx».«in(V-..lkQym..CSvsvr.S2.+..1.3.R,V.GH...0.3cmwuBMRmi6....16ms...«nu...Q.2.»..\«IL..1;axur1.....cv.€\\..:.E..J.".xx3it...4%....:N1.1.S3m4.......:1.Q6ETS.12....aa4
`
`
`
`
`
`9.»0Wxi.0+0nuwk.3:1.
`\\v4.\A...nv»2.ma...
`
`1.»3..Et0..3._mm.Q3EC.3S.w...A1..\......1.\.
`.uS..\.s...
`2...33N.>.,.weFiBX0.3u8g...Sfxfir.vsEQ.J}‘58T2ix.ifu.Cin“......,r..N...»,\T...1..wJ.\u~<§c.«in.s....3‘!C...R..\vAnn.“
`
`
`
`
`.0axLam11;:0.w._.3.8.1.....r..CL.s....k3...r\.\dsx.8.HanMr...Ti._m1M..
`
`.m0ma.
`...1.3..._1.\\\—U.2x.0.00.xam3..03Tkm.08L..9ca.
`
`
`
`..~5..v.an.3xx...:1.:.F.3...».>nu.U.....c........+1(3,.3mmex:WVF.xvuh§8ma0....3:3._..rs..,cI.,.1.M3CW...,..wpawkn,m‘uwk,TW3.?nen.xv§..04..
`....SC...
`.2M...
`
`
`
`1.1..\\.m.3.13an..03SL1..
`
`.1...:..,,.3..\\..qa..K2.33.5F<0.18...K0xs&Hcu:m.132Si.3P...6.....P1..:2th....anS,,mmW«W,..mHMS3.am4..
`
`...J.«Ics.C+1Sr_ai5no8....as.34<3
`
`......,wef1.;cm2;x,.1.i1.“L»(..M.E.
`1......3:«A1%..av..:._:\Il.1.!u2;ins.»:.3z.5i..\._3.T11x..
`.I....w..(.3.,......30,.4Xmm.
`
`
`.mu.31ix.t_9..1.3:2.G..3..V..3.9.1is.<......AUnu.:..CH)....2}.mu.5..
`..,3..ifi#4€ma1:r.S\22i..9.‘a..1R:1.5.
`..ox.<1,Hvs13,..S3S«QRixz.32,isL.K.\_.2.r...s:v”.«(Ax.8.28..
`
`,5.i..2zDK.4...:2...zMaS..L3..R.m.0.c..3;E¥.:mmm...rm.....
`./M.2...KP6.3.”mmasM.B3.3..J.3,.....,:..0E«.13.H{36ms..fl..,9+LC_\3carm.1....
`
`
`1.“....._wmdRaw.«0MCPu.Own«G.3.2....nfl<....uH:\.;...w.id_,0.0as.1»i
`
`
`..5L\VA.it\..~«.1..»...t..ALn...a\I...nuh.ii5,.“\3...;
`
`
`
`
`
`...5.C.$..\...K(\+4»\x..,
`um(.is«Gfix.HV”VH5.ms.15wk“.9fix.
`...‘.7:.13..
`<V.5)}..x_\3.1A$3..1».5Y),.x.33K(A.
`
`000003
`
`000003
`
`
`
`
`‘gneiwzaeiz
`
`E%}.=.::}‘:.
`
`<
`5§'§$0s*§§m-* Ba‘: *§g§:§. Nan. .:£EPN~G€Z\1.«’7‘"§Z’US 3 Ii 36§3~I?.{}i
`beriafi
`1373 -C’?};?
`
`39
`
`”
`
`sania. 11i:13.iim’s
`
`the
`
`1.
`:;»‘.‘.e:c.§.(rc1:'{‘i3— C{?Z'f§3£:i' fer the "“m.s—3mm‘3r a?§fi—:c§3,
`‘=
`:
`chemiszai »:‘.£m”},?ova:‘ fmm ‘p:7§m" sampi:3s._ ‘£§i12s.:':e§ f;f}1T:€L
`
`
`
`€11
`
`
`-‘.i}_x~‘.. fizzmi. <'_sf’.._..}“§?-1% aa9:<a’£af31*;i‘?.:‘iEe ‘&-‘Q-“Em
`
`ms:
`
`i‘?:.rI.:::g
`
`«ciay, E34->33-'e::::;: «every sa:m'pie
`
`v{‘wh§ci3 w<m§d was}: :3‘-at C£Z&i"1‘}” over
`
`
`
`' a (£223?
`
`-:.:ni§: v1.13} is 3'.110.i.;§a:i
`
`;3-igggure 2. Maia ihat this signai i,s:ie.nsii'y'
`
`2::
`
`mu’: <>,:-ai<:.:‘ wf‘
`
`sziaggiiiitztia
`
`‘5;ha:«fs in fi';.=.~3
`
`~(i¥3;}:?%::I5{3#
`
`§*’§gtz§‘C ‘E Vii‘-a:‘..S
`
`.:"%2{’§,{3" in
`
`The. 3:239-R
`
`at
`
`:1':.:":1u=L:es
`
`—<:s.3‘:2‘:z:zm.ine:.s‘A'€ in
`
`:_a::si‘<I»:':.s';_i‘ 1*;2}_2:;11:..
`
`.s...'3_st:
`
`§s:we‘z
`
`_émii<:.ai.i‘x='e af
`
`Eow ,§t3’~»"G}_ of $3.3 s::a‘>:’.a*:.a'm:l3‘3.e=a.f:w:. The
`
`31% ‘i13i§’1{3.‘.ft‘3S.iS due is
`
`c0:1c<::?:::2‘223t§<m of aceétszaiztrihs us-ad ":23
`
`c<::s§.m‘m3.
`
`R‘
`
`weii ‘s<;m_‘.-\.§«'t*.a in
`
`:.€is:E<§.
`
`;E1z~.-,1.
`
`magc;as“zTz.~‘s:>. £;§mi‘mis musfi‘. be mm
`
`‘-3‘L‘<')?.‘{‘)f.*;?}“"C‘) L ilaxiing s3“~«°€:‘ 25 yfiars in 1.16 19it:1:33 :‘;3:§j‘= a-=c3q'uai§:
`
`fi
`
`A;:c‘<>:‘di:§g3j*,
`
`it’
`2&2;-1 &~:§.‘;«iii'_:‘§_g the aizsisi ::‘e§em‘iie:_i in i';h;°. Eseciaiaiixsxa sf
`‘.uI
`rm}. 3~§ii£§i.3§1’{s’:‘- c0n=L3%0_..s {si.«a;. 3;_>_<3s£=;*h«':%
`
`coma: 13313:‘-3.
`
`...-1
`
`0'
`
`i , 2.891, 3.
`
`§.tz‘:sa‘—;’2‘.
`
`w%1§:‘;2
`
`M»;
`
`»;::_>m§m:.£e;e<E; imt
`
`‘(E2-«:.=..7.
`
`m_§:2s;>:"é:‘3€§ in the .§}eciE3':‘£2‘i*ém1 ca?
`
`3 3., §.‘:_€I}}‘.E,
`
`{_z‘c_5=. -:35? in$e:r:a-3—;3;13i3}.: hf! §;,E;3x;,E,<_}
`
`1..st
`000004
`
`000004
`
`
`
`
`
`y..;.
`
`E fL:rti:e':'<:§es::imfefi1a.f 9,13 sia£§;?1m>:"3i:§.m2:(15_he::T<:i2': {3‘§""£?11j,;"C>W3’},§’?3G~W§8{§gf: are i's:=;zs§. and tizai
`
`s€.;«;éf»:?;11s:::1ts
`
`aim *§m“0:‘1’::a.i'im1 and.
`
`are §.>e§.~§-;wc:é: i0
`
`iime, and f~.11“£E§:€::‘,
`
`ihzai’
`
`Si8.’{s3:iTn£:§§j3i‘S- *4-53:31‘:-:5 313.6%: ‘s-3-"ir:Z3 the §<r0x-"»‘3.z?:<Sge E133; wi§§i’;z.§ fifisst s’€3.te:"z1:—'::§.i‘.<; atmi
`
`>44
`
`iv
`
`£40
`
`3
`
`'gu:1isi“32={§3E;r3 .33},-*
`
`0;.“ im;,7:“£r:;<mm»s::§%:, 0:‘ ‘t><>-‘i;§.‘=_._
`
`Ei€.aJ;<::<:
`
`{_‘i0c§e,.
`
`suci; W-~§§.‘L.f'uE
`
`.{‘E3i5::
`
`st:-3331330323
`
`Eiaciiosi i{?{>_£ Q3“ 3
`Q
`;§'e0pz:ro3i2~:s_ ms: as'=a1idii;«' 0%‘
`
`*.>.3"i.i'_:<:':U:1“iis;3§
`
`‘
`
`_
`
`_
`
`a:;>p:§’i£eiti£>’§3 :3‘: any iisziten? §::=.s:§:iE1g fl3€‘.:"3§;m,
`
`__
`
`ilfizated: Mémriiis
`
`050005
`
`000005
`
`
`
`Phosphoiiuid std
`Hlvlaw.
`L
`.
`.
`‘
`I
`
`Figure 1. Tetai i011 ChmmatQg1"ams fer phasphoiipici staiiciarci s0iuti011. This standard was
`analyzed with 'i’u}i~.9ca.t1 eiecti‘0spray ionization during the anaiysis of 0‘i}'ier pi'1OSpi’lOi,i}5iCi,
`samples.
`
`000906
`
`000006
`
`
`
`§'v'§g§li'€5 2. Totai inn chm1'nat0gram far 2: 26)‘?/is aceton
`so1Vent—pmgrammed at 21 faster 1':»1te fur the Sofie purpuse of
`
`im
`We
`
`:E-320 blank. Snivent biaiiks are ofierz
`‘
`is the case hare“
`sziving ‘itucne as
`
`93791 V1/EN
`
`OOODO7
`
`000007