`
`Reference
`
`‘569 Patent (IPR2013-00505)
`Basis
`Challenged Claims
`
`Kanebo (Ex. 1006)
`
`§103
`
`1-12, 15, 17-19, 23, 26, 28-30, and 32
`
`Reference
`
`‘300 Patent (IPR2013-00509)
`Basis
`Challenged Claims
`
`Kanebo (Ex. 1006)
`
`§102(b)
`
`1, 2, 4, 5, 11, 13, 16, 17, and 20
`
`Kanebo (Ex. 1006)
`
`Evans (Ex. 1010)
`
`§103
`
`§103
`
`3, 18 and 25
`
`1, 12, 16, 19, and 24
`
`Page 1 of 11
`
`UNILEVER EXHIBIT 1064
`UNILEVER VS. PROCTOR & GAMBLE
`IPR2013-00509
`
`
`
`‘569 Patent – Claim 1
`
`1. A shampoo composition comprising:
`a) from about 5% to about 50%, by weight, of an anionic surfactant;
`b) from about 0.01% to about 10%, by weight, of a non-volatile conditioning
`agent;
`c) from about 0.1% to about 4%, by weight, of an anti-dandruff particulate;
`d) from about 0.02% to about 5%, by weight, of a cationic polymer;
`e) water;
`f) from about 0.1% to about 10%, by weight of the composition, of a suspending
`agent;
`wherein said composition:
`has a bioavailability/coverage index value, of at least about 1.25;
`has a first conditioning index value, of less than or equal to about 1.0;
`has a second conditioning index value, of at least about 1.5; and
`has a minimal inhibitory concentration index value, of at least about 0.125.
`
`Page 2 of 11
`
`
`
`‘569 Patent – Claims 10, 18, 19
`
`10. A shampoo composition according to claim 1, wherein said
`suspending agent is ethylene glycol distearate.
`
`18. A shampoo composition according to claim 1, wherein said
`cationic polymer is selected from the coup consisting of
`guar derivatives, cellulose derivatives, and mixtures thereof.
`
`19. A shampoo composition according to claim 18, wherein at
`least one of said guar derivatives is guar
`hydroxypropyltrimonium chloride.
`
`Page 3 of 11
`
`
`
`Kanebo (Ex. 1006) (filed January 9, 1996)
`
`[0037] Example 10 (Anti-dandruff shampoo)
`• Ammonium lauryl sulphate
`• POE (3) lauryl ether sodium sulphate
`• Triethanolamine N-lauroyl-L-glutamate
`• Coconut oil fatty acid isopropanolamide
`• Dimethyl polysiloxane (1,000 cSt; 25°C)
`
`• Cationized cellulose derivative (Trade name: Catinal HC-200 manufactured by Toho Kagaku
`Kogyo)
`• Ethylene glycol dimyristate
`• Dipropylene glycol
`• Zinc pyrithione
`
`• Highly polymerized polyethylene glycol (Trade name: Polyox WSR-301; manufactured by UCC)
`• Citric acid
`• Antiseptic agent
`• Pigment and perfume
`• Water
`
`(in %)
`
`10.0
`
`5.0
`
`3.0
`
`2.0
`
`5.0
`
`1.0
`
`2.0
`
`1.0
`
`0.5
`
`0.1
`
`0.1
`
`0.1
`
`q.s.
`
`balance
`
`[0038] The anti-dandruff shampoo of the above composition was prepared according to the conventional
`method and evaluation was conducted for its spreadability and running of the fingers through the hair upon
`application, usability upon rinsing, feeling of the finish and dispersing stability whereupon any of those
`characteristic properties was excellent showing good results.
`Page 4 of 11
`
`
`
`Kanebo (Ex. 1006)
`
`
`
`Kanebo (Ex. 1006)
`
`[0014] The high molecular compound (excluding dimethyl pclysilcxane} used in the present
`
`inventicn has the visccsity cf 1,000 tc 100,000 cps when measured by a B—type visccmeter at
`
`25°C in a farm cf a 1% aquecus scluticn er a 1% aquecus dispersicn- 1When the ccmpcund
`
`where the visccsity is less than 1,000 cps is used, gccd dispersing stability is net available-
`
`When the ccmpcund where the visccsity is mere than 1,000,000 cps is used, gccd dispersing
`
`stability and usability are net available. The high molecular compound as such may be any cf
`
`anicnic, caticnic, amphcteric and ncnicnic cnes and_, far achieving the best ccnditicning effect
`
` , guaternized pclyyinylpyrrclidcne derivative, dimethyldiallylammcnium chlcride
`
`derivative, pgjyglycwcl pclyamine ccndensate, caticnized starch and caticnized pclypeptide-
`
`mg cellulcse derivative such as Catinal HC—200 [trade name; manufactured by Tchc
`
`Kagaku chfcl is particularly preferred-
`
`[0015] Each cf these high mcIecuIar ccmpcunds may be used—
`—_ Fer achieving gccd dispersing stability and usability, it is preferred tc be
`ccmpcunded in the ccmpcsiticn cf the present inventicn—
`Page 5 of 11
`
`
`
`‘300 Patent – Claim 1
`
`1. A shampoo composition comprising:
`a) from about 5% to about 50%, by weight of the composition, of an anionic surfactant;
`b) from about 0.01% to about 10%, by weight of the composition, of a non-volatile
`conditioning agent;
`c) from about 0.1% to about 4%, by weight of the composition, of an anti-dandruff particulate;
`d) from about 0.02% to about 5%, by weight of the composition, of at least one cationic
`polymer;
`e) from 0.005% to about 1.5%, by weight of the composition, of a polyalkylene glycol
`corresponding to the formula:
`
`i) wherein R is selected from the group consisting of hydrogen, methyl and mixtures thereof,
`ii) wherein n is an integer having an average value from about 1,500 to about 120,000;
`and
`f) water.
`
`Page 6 of 11
`
`
`
`‘300 Patent – Claims 2, 3, 18, 25
`
`2. A shampoo composition according to claim 1, wherein said at least one cationic polymer
`component is selected from the group consisting of guar derivatives, cellulose derivatives,
`and mixtures thereof.
`3. A shampoo composition according to claim 2, wherein at least one of said guar derivatives is
`guar hydroxypropyltrimonium chloride.
`
`18. A shampoo composition according to claim 17, wherein said suspending agent is ethylene
`glycol distearate.
`
`25. A shampoo composition according to claim 18, comprising from about 0.025% to about
`1.5%, by weight of the composition, of said polyalkylene glycol.
`
`Page 7 of 11
`
`
`
`‘300 Patent – Claims 12 and 19
`
`12. A shampoo composition according to claim 1, wherein said polyalkylene glycol has an
`average value of n from about 1,500 to about 50,000.
`
`19. A shampoo composition comprising:
`a) from about 10% to about 25%, by weight of the composition, of an anionic surfactant;
`b) from about 0.01% to about 10%, by weight of the composition, of an insoluble, non-volatile
`silicone conditioning agent;
`c) from about 0.3% to about 2%, by weight of the composition, of a zinc salt of 1-hydroxy-2-
`pyridinethione;
`d) from about 0.1% to about 2%, by weight of the composition, of at least one cationic polymer
`selected from the group consisting of guar derivatives, cellulose derivatives, and mixtures
`thereof;
`e) from 0.025% to about 1.5%, by weight of the composition, of a polyalkylene glycol
`corresponding to the formula:
`
`i) wherein R is selected from the group consisting of hydrogen, methyl and mixtures thereof,
`ii) wherein n is an integer having an average value from about 3,500 to about 15,000; and
`f) water.
`
`Page 8 of 11
`
`
`
`‘300 Patent – Claims 16 and 24
`
`16. A shampoo composition according to claim 1, comprising from about
`0.3% to about 2%, by weight of the composition, of said anti-dandruff
`particulate.
`
`24. A shampoo composition according to claim 16, wherein said polyalkylene
`glycol has an average value of n from about 3,500 to about 15,000.
`
`Page 9 of 11
`
`
`
`Evans (Ex. 1010) (filed October 15, 1996)
`
`Evans (EX. 1010) (filed October 15,1996)
`
`1. A hair canditiuning shamp-uu cnmpnsjtiun comprising:
`
`fmm 5% 1:0 5fl% by wright {if a. detersiu: gurfaclant selmted Earn 11-";
`
`gmup tansisting crl'
`
`alumni:
`
`surfactant.
`
`nuni-cmir:
`
`surfactant.
`
`mphnleric surfaclam. zwitlen'anic surfaclanL and mjxmrcs thereuf.
`
`preferably Earn 5% 1.4:! 30% by weight affiniunin: surfactant;
`
`f'mm flirt-1% In 111% by weight of a dispemcd silimne canditiuning
`
`agent
`
`I'mrn 11mph: ID‘H: by “tight cfa SuSp-cnding. agent.-
`
`from 0.025% to 1.5%.. prcferabl}: me flit-13.. m 13.5%.. by weight 111'
`
`pulyalkj-‘Lm: glyml
`
`canespunding tn- the funnula;
`
`E-IEUCHzflll-nn‘GH
`R
`
`
`
`wherein R is. hydmgem methyl nr mmhinatiflns weren‘t: prcfirmbly
`
`mcthyl. and n is an integer blaming an avcragn: valm: of ham Liflfl tn
`
`25,0011, preferably frum 15091:. 15.Dflfl: and
`
`from 2% In 94.3% by w-i'igh: Dffi'fl-Ifl.
`
`4. The Eflmpusitiun uf Claims 1, l err 3. wherein said mn‘Ipnsiticrn fimhw Em‘npristfi
`
`Page 10 of 11
`
`a. mafia-nit: mndillnning 33am.
`
`
`
`Evans – Ex. 1010
`
`Evans,
`page 29
`
`Evans,
`page 27
`
`‘418 Patent (Ex. 1011)
`col. 3, ll. 5-10
`
`Page 11 of 11
`
`