(12) Ulllted States Patent
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`Singh et al.
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`(10) Patent No.:
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`(45) Date of Patent:
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`US 8,065,882 B2
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`*NoV. 29, 2011
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`US008065882B2
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`(75)
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`(54) COMPOSITIONS CONTAINING FLUORINE
`SUBSTITUTED OLEFINS
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`IHVGIHOFSI RaJ1V R-S1I1gh,GetZV111e,NY (US);
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`(73) Assignee: Honeywell International Inc.,
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`Subject to any d1scla1mer, the term ofth1s
`patent is extended or adjusted under 35
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`1549
`This patent is subject to a terminal dis-
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`Claimer.
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`(21) APPLNO" 12/412342
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`Filedi
`(22)
`Man 26, 2009
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`(65)
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`Prior Publication Data
`US 2009/0278076 A1
`Nov. 12, 2009
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`Related U_s_ Application Data
`(60) Division of application No. 11/847,192, filed on Aug.
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`29, 2007, which is a division of application No.
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`10/837,525, filed on Apr. 29, 2004, now Pat. No.
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`7,279,451, which is
`continuation-in-part of
`a
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`application No. 10/694,273, filed on Oct. 27, 2003,
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`now Pat. No. 7,534,366, and a continuation-in-part of
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`application No. 10/694,272, filed on Oct. 27, 2003,
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`now Pat N0 7’230’146'
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`(60) Provisional application No. 60/421,263, filed on Oct.
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`25, 2002, provisional application No. 60/421,435,
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`filed on Oct, 25, 2002,
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`(51)
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`Int. Cl.
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`C09K 5/04
`(2006.01)
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`(52) U.S. Cl.
`............... .. 62/6, 252/68, 252/71, 252/78.1,
`(58) Field of Classification S/earch ........,....
`252/67,
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`252 68’ 71’ 7&1’ 62.6’ 401’ 498
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`366 aPP11CaU0I1 file for Complete Search h1St01'Y~
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`
`References Cited
`
`
`U.S. PATENT DOCUMENTS
`
`
`
`8/1958 Haluska
`
`
`10/1958 Baileyetal.
`
`6/1959 Ruh etal.
`
`
`
`12/1959 Baileyetal.
`
`4/1960 Maley
`
`
`2/1961 Lo
`
`
`8/1961 Rausch
`
`
`4/1963 Kvalnes
`
`
`4/1963 Sherlikeretal.
`
`
`10/1969 Potts et al.
`
`
`
`9/1971 Murphyet al.
`
`
`4/1972 Regan
`
`
`3/1973 Butler et al.
`
`
`5/1975 Butler
`
`
`
`
`
`
`
`
`
`2,846,458 A
`
`2,834,748 A
`
`2,889,379 A
`
`2,917,480 A
`
`2,931,840 A
`
`2,970,988 A
`
`2,996,555 A
`
`3,085,065 A
`
`3,085,918 A
`
`3,472,826 A
`
`3,607,755 A
`
`3,659,023 A
`
`3,723,318 A
`
`3,884,828 A
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`aizmrfilerdet 81.
`2
`00 BI
`,
`,
`7/1988 Magid et al.
`4,755,316 A
`
`
`
`
`11/1988 Smutny
`4,788,352 A
`
`
`
`
`
`
`1/1989 Baizeretal.
`4,798,818 A
`2/1990 Ihara et al.
`4,900,874 A
`
`
`
`
`7/1990 Deeb et al.
`4,944,890 A
`
`
`
`
`7/1990 Smitsetal.
`4,945,119 A
`
`
`
`
`
`
`
`11/1990 Gorski etal.
`4,971,712 A
`12/1990 Thomas et al.
`4,975,212 A
`
`
`
`4/1991 Jolley et al.
`5,008,028 A
`
`
`
`
`10/1992 Tung et al.
`5,155,082 A
`
`
`
`
`
`
`
`
`1/1993 Bartlett et 31-
`5482940 A
`:3/122:
`
`
`
`
`533703812 A * 12/1994 Brown .......................... .. 252/68
`
`
`
`
`
`
`5,532,419 A
`7/1995 Van Der puy et 31.
`5,545,777 A
`8/1996 Morikawa et al.
`
`
`
`
`
`
`
`
`2,232,124:
`11/1232 ierfuiem
`ea y C 3.
`.
`,
`,
`
`
`
`
`5,611,210 A
`3/1997 Nimitz et al.
`
`
`
`
`5,616,275 A
`4/1997 Chisolm etal.
`
`
`
`5,648,017 A
`7/1997 Bartlett et al.
`
`
`
`
`5,674,451 A
`10/1997 Nimitz et al.
`
`
`
`
`5,679,875 A
`10/1997 Aoyama etal.
`
`
`
`5,710,352 A
`1/1998 T
`
`
`
`5,714,083 A
`2/1998 Tiirnrigeret al.
`
`
`
`
`5,728,904 A
`3/1998 Van Der Puy et al.
`
`
`
`
`
`
`
`
`5,736,062 A
`4/ 1998 Basile
`5,736,063 A
`4/1998 Richard et al.
`
`
`
`
`5,744,052 A
`4/1998 Bivens
`
`
`
`5,763,063 A
`6/1998 Pass et al.
`
`
`
`
`
`
`
`5,788,886 A
`8/1998 Minor et a1.
`(commued)
`
`FOREIGN PATENT DOCUMENTS
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`EP
`
`
`
`0398147
`
`. 11/1990
`
`
`(Contlnued)
`
`
`
`
`OTHER PUBLICATIONS
`
`
`Translation of JP4-1 10385 provided by applicant in U S Appl No
`
`
`
`
`
`
`
`10/694,273 on Nov. 10, 2008.*
`
`
`
`
`U.S.App1. No. 10/694,273,filed Oct. 27, 2003, Singh et al.
`
`
`
`
`
`
`
`
`U.S. Appl. No. 10/695,212, filed Oct. 27, 2003, Thomas et al.
`
`
`
`
`
`
`
`U.S. Appl. No. 10/826,811, filedApr. 16,2004, Singh et al.
`
`
`
`
`
`
`
`U.S. Appl. No. 10/826,592, filed Apr. 16,2004, Singh et al.
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`U.S. Appl. No. 10/826,072, filed Apr. 16,2004, Singh et al.
`
`
`
`
`
`
`U_~S~ APP1~ N9 10/‘837s525s_fi1ed_APr~ 2932094 §1ngh_<*~ta1~ _
`Oflzef le0tn:11€’,.Heat
`‘icse;-St:m,S,( Pringilgllzsa A;)p1icati0'nS,.,
`
`
`
`
`
`
`Modem Refrigeration and Air Conditioning, Chapter 26, pp. 999,
`
`
`
`
`
`
`
`
`1002-1003. The Goodheart-Wilcox Co., Inc. (1998) US.
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`(COI1tiI111ed)
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`Primary Examiner — Amina Khan
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`(74) Attorney, Agent, or Firm — Colleen D. Szuch
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`ABSTRACT
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`(57)
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`
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`Disclosed are the use of fluorine substituted olefins, including
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`tetra- and penta-fluoropropenes, in a variety of applications,
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`including connection with blowing agents, foams, foamable
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`compositions, foaming methods, heat transfer compositions
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`and methods, propellants, and solvating methods.
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`52 Claims, No Drawings
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`1of15
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`Arkema Exhibit 1009
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`Arkema Exhibit 1009
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`1 of 15
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`US 8,065,882 B2
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`WO
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`WO
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`W0
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`WO
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`WO
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`WO
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`WO
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`WO
`
`WO
`
`WO
`
`WO
`
`WO
`
`WO
`
`
`
`
`04-110388 A
`
`
`4/1992
`
`
`
`
`
`
`
`
`2000169404
`2073058 C1
`
`95704021
`
`96/01797
`
`98/33755
`
`WO 03064508
`
`
`2004/37752 A2
`
`2004/037913
`
`WO2004/037752
`
`2005/012212
`
`2005742451
`
`2005/042663
`
`2005/103187
`
`2005/103188
`
`2005/103190
`
`2005/103191
`
`2005/103192
`
`2005/0105947
`
`2007/002625
`
`
`
`6/2000
`12/1994
`
`2/1995
`
`1/1996
`
`8/1998
`
`8/2003
`
`5/2004
`
`5/2004
`
`5/2004
`
`2/2005
`
`5/2005
`
`5/2005
`
`11/2005
`
`11/2005
`
`“/2005
`
`11/2005
`
`11/2005
`
`11/2005
`
`1/2007
`
`
`U.S. PATENT DOCUMENTS
`
`
`
`8/1998 Reyes-Gavilan et al.
`5,792,383 A
`
`
`
`
`
`
`
`9/1998 BiVens et al.
`5,800,730 A
`9/1998 Elsheikh
`5,811,603 A
`
`
`
`2/1999 Reyes-Gavilan et al.
`5,866,030 A
`
`
`
`
`10/1999 Thenappan et al.
`5,969,198 A
`
`
`
`
`11/1999 Van Der Puy
`5,986,151 A
`
`
`
`
`
`2/2000 Thenappan et al.
`6,023,004 A
`
`
`
`
`2/2000 51135
`5,025,532 A
`
`
`
`
`2/2000 Mallikarjuna et al.
`6,031,141 A
`
`
`
`3/2000 Olszewski et al.
`6,041,621 A
`
`
`
`
`4/2000 Zima et al.
`6,045,444 A
`
`
`
`
`5/2000 Lake et al.
`6,059,027 A
`
`
`
`
`6/2000 A6113-rya et 31,
`6a076a372 A 7
`
`
`
`
`7/2000 Trachtenberg
`6,089,032 A
`
`
`
`8/2000 Sakyu 5131,
`5,111,150 A
`
`
`
`
`9/2000 Elsheikh et al.
`6,124,510 A
`
`
`
`
`1/2001 Bauer et al.
`6,173,902 B1
`
`
`
`
`
`1/2001 Novak et al.
`6,176,102 B1
`
`
`
`
`
`5/2001 Sakyu 51111,
`5,235,951 131
`
`
`
`
`
`7/2001 Turner et al.
`6,258,292 B1
`
`
`
`
`
`8/2001 Merkel et al.
`6,274,779 B1
`
`
`
`
`
`I0/2001 Tapscott
`6,300,378 B1
`
`
`
`
`10/2001 D30
`6,304,803 B1
`
`
`
`
`11/2001 Y051111“1Wa 61 31,
`6,316,681 B1
`
`
`
`
`
`
`
`
`
`12/2001 Novak et al.
`6,327,866 B1
`
`
`
`
`
`4/2662 Nappa 61 31'
`673697264 B1
`
`
`
`
`4/2002 066116
`6’374’629 B1
`
`
`
`
`5/2002 311115
`5,382,305 131
`
`
`
`
`2/2003 T.h6maS et 61'
`6’516’637 B2
`3/2003 1311105 5131*
`5,530,421 131
`
`
`
`
`
`4/2003 Nair et al
`6,548,719 B1
`
`
`
`
`7/2003 Thomas et al.
`6 589 355 B1
`’
`’
`
`
`
`
`
`11/2003 Thomas
`6 640 841 B2
`
`
`
`
`
`
`’
`’
`
`
`2/2004 Musso
`6,695,973 B1
`
`
`
`
`8/2004 Bivens
`6,783,691 B1
`
`
`
`
`
`
`
`10/2004 Pennetreau et 31.
`6,809,226 B1
`1/2005 Cho
`6,843,930 B2
`
`
`
`
`
`
`
`
`2/2005 Pham et 31.
`6,858,571 B2
`10/2005 Nair e1 31.
`5,953,424 131
`
`
`
`
`
`12/2005 Thomas et al.
`6,972,271 B2
`
`
`
`
`1/2006 Goldsmith
`6,991,532 B2
`
`
`
`
`1/2005 Mahler
`5,991,744 B2
`
`
`
`
`9/2006 Schultz
`7,105,152 B1
`
`
`
`
`
`
`
`
`6/2667 1\/1611561 6131'
`7,236,146 B2
`; :I;:1i~hyay et al.
`
`
`
`
`7/2003 Thomas et al.
`2003/0127115 A1
`
`
`
`
`2004/0119047 A1
`6/2004 Sin h et al.
`
`
`
`
`
`
`
`
`
`
`2004/01273 83 A1
`7/2004 Pham et 31.
`2004/0256594 A1
`12/2004 Singh et 31.
`
`
`
`
`
`2005/0020352 A1
`1/2005 "rung e1 31.
`
`
`
`
`
`2005/0054741 A1
`3/2005 Zjpfel e131,
`
`
`
`
`
`2005/0090593 A1
`4/2005 Merke1e1a1,
`
`
`
`
`
`2005/0107246 A1
`5/2005 Thomas et al.
`
`
`
`
`
`2005/0171391 A1
`8/2005 Janssens et al.
`
`
`
`
`
`
`
`2006/0243944 A1
`11/2006 Minor et al.
`
`
`
`
`
`2007/0069175 A1*
`3/2007 Thomas et al.
`
`
`
`
`2007/0098646 A1
`5/2007 Nappa et al.
`
`
`
`
`
`2007/0100010 A1
`5/2007 Creazzo et al.
`
`
`
`
`2007/0108403 A1
`5/2007 SieVeIT Gt 31.
`
`
`
`
`
`2007/0284555 A1
`12/2007 Leck Gt 511
`
`
`
`
`
`*
`et al.
`
`
`
`
`
`2009/0272134 A1* 11/2009 Hulse et al.
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`............... .. 252/68
`
`
`
`
`
`. . . . . . . . . . . . ..
`
`
`................... .. 62/112
`
`
`
`
`
`
`
`FOREIGN PATENT DOCUMENTS
`
`
`0522539
`1/1993
`
`
`0644173
`5/1993
`
`
`6 661 933 A1
`11/1993
`
`0974571
`1/2000
`1055439
`11/2000
`
`
`1191080
`7/2002
`
`
`0971571
`4/2003
`
`
`950 876
`2/1964
`
`
`
`3.157347 A
`0/1995
`
`
`9/ 1988
`63.211245
`
`
`63-303950
`12/1988
`
`
`4/1992
`4-110385
`
`
`
`*
`
`
`
`EP
`
`EP
`
`EP
`
`EP
`EP
`
`EP
`
`EP
`
`GB
`
`JP
`
`JP
`
`JP
`
`JP
`
`
`20f15
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`Kutz
`Meyer
`Mechanical
`“Refrigerants,”
`(Editor),
`
`
`
`
`
`Engineers’Handbook, 2d Ed. p. 1887, John Wiley & Sons, Inc.
`
`
`
`
`
`
`
`
`
`(pub1.)(1998)US.
`
`
`
`
`
`
`
`Althouse et al., “Automobile Air Conditioning,” Modern Refrigera-
`
`
`
`
`
`
`
`
`
`tion andAir Conditioning, Chapter 27, pp. 949-976. The Goodheart-
`
`
`
`
`
`Wilcox Co., Inc. (1988) US.
`
`
`
`
`
`
`H. Michael Hughes, “Refrigerants,” Refrigeration Systems for
`HVAC Section 6
`6 1 2-6 1 15 McGraw-Hill Co (1997) US
`
`
`
`
`
`
`.
`’
`231"
`' I
`'
`'
`9
`.
`.
`.
`'
`S
`.
`'
`
`
`
`
`
`
`
`
`
`
`oc1ety of Heatrng, A1r-Condit1on1ng and San1tary Engrneers,
`“Cha ter 1. Refr1 erat1on S stem and Heat Pum OVerV1ew” Air
`
`
`
`
`
`
`3
`,
`Y
`P
`P
`
`
`
`
`
`
`
`
`Conditionin and Sanitar En ineerin Handbook 12”’ Ed. (Mar.
`
`
`
`
`
`
`
`
`3
`V
`3
`,
`3
`25, 1995) JP"
`.
`.
`.
`.
`
`
`
`
`
`
`
`
`
`
`
`
`
`Syb1l Parker (Ed.), McGraw—Hill Encyclopedia ofEngineering, 2d
`E91 (1993), P 5,25 (11531 1’“mP)~ US
`_
`_
`7,
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`Spatz et al., HFO-1234yf Low GWP Refrrgerant, Presentat1on
`g1Ven at SAE 2008 Alternate Refrigerant Systems Symposium,
`
`
`
`
`
`
`
`
`Scottsdale (AZ), Jun. 10-12, 2008. US.
`
`
`
`
`
`
`M Spatz et al., “ HFO-1234yf Low GWP Refrigerant,” Presentation
`
`
`
`
`
`
`
`given at International Refrigeration and Air Conditioning Confer-
`
`
`
`
`
`
`
`ence at Purdue, Jul. 14-17, 2008 US.
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`LJM Kuipers, “Impact of the decreasein CFC Emissions on refrig-
`:rjt1(1)r11: It\Ia(r)g:t of$151;)IIIIJ{S1n1t1at1Ve,” Int. J'. Refrigeration, pp. 35-51,
`
`
`
`
`
`
`
`'
`'
`.
`'
`.’
`'
`.
`.
`
`
`
`
`
`
`
`
`D1rect1Ve 2006/40/EC ofthe European Parl1ament and ofthe Counc1l
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`of May 17, 2006 relat1ng to em1ss1ons from a1r-cond1t1on1ng systems
`1n motor Vehrcles and amendrng Counc1l D1rect1Ve 70/156/EC. EU.
`
`
`
`
`
`
`
`
`
`European Parl1ament Sess1on Document. “Report On The Proposal
`
`
`
`
`
`
`
`For A European Parliament And Council Regulation On Certain
`
`
`
`
`
`
`
`
`Fluorinated Greenhouse Gases.”
`(COM(2003)492-C5-0397/03-
`
`
`
`
`2003/0189(COD)), Mar. 18, 2004.
`
`
`
`
`J Jones, CJ Morrissey, Nearly Azeotropic mixtures to replace refrig-
`
`
`
`
`
`
`
`
`erant 12, NASA Tech Brie)’, Vol 16, No. 8, Item #122 from JPL New
`
`
`
`
`
`
`
`
`
`
`
`
`
`Technology Report NPO 18030//528, pp. 1-39, Aug. 1992 US.
`
`
`
`
`
`
`
`
`
`“Compatibility With Refrigeration Oil,” Extract from the Daikin
`
`
`
`
`
`
`
`Handbook, Jun. 2001, pp. 25-28.
`
`
`
`
`
`Sj oholm et al, “Twin-Screw Compressor Performance And Suitable
`
`
`
`
`
`
`
`Lubricants With HFC-134a,” International Compressor Engineering
`
`
`
`
`
`Conference at Purdue
`17.20,
`Proceedings Vol. II,
`
`
`
`
`
`
`
`
`733-740, Us,
`
`HoneyWell’s submission to EPO dated May 2, 2009 together with
`
`
`
`
`
`
`
`
`documents cited and referred to therein. EP(documents submitted
`
`
`
`
`
`
`
`herein are below (16a-16k).
`
`
`
`
`Althouse et al., “Basic Air Conditioning Systems,” Modern Refrig-
`
`
`
`
`
`
`
`
`eration and Air Conditioning, Chapter 19, pp. 679-705. The
`
`
`
`
`
`
`
`
`
`Goodheart-Wilcox Co., Inc. (pub.) (1988) US.
`
`
`
`
`
`
`d
`I.
`,,R f.
`“A t
`t. A. C dit.
`B“ C L
`1
`.
`
`
`
`
`
`
`
`
`
`
`erigera ion an
`u omo1Ve_ 1r on
`1on1ng,
`y . ang ey,
`
`
`
`
`
`
`
`
`
`Air Conditioning, 3d Ed. Prent1ce-Hall, (1986) Chapter 21, pp. 525-
`
`
`
`
`
`
`
`
`
`553 US
`_
`
`
`European Parl1ament, “Report on the proposal for a European Par-
`
`
`
`
`
`
`
`
`liament and Council regulation on certain fluorinated greenhouse
`
`
`
`
`
`
`
`
`gases,” (COM(2003)492-C5-0397/03-2003/0189(COD)) Mar. 18,
`
`
`
`
`2004 (EP).
`
`
`
`
`
`
`
`
`
`2 of 15
`
`

`
`
`
`
`
`
`
`
`
`
`
`
`
`
`US 8,065,882 B2
`Page 3
`
`
`Pollution Prevention Fact Sheet No. 10, Pollution Prevention Pro-
`
`
`
`
`
`
`
`
`
`gram. Federal Programs Division, Managing Controlled Refriger-
`
`
`
`
`
`
`
`ants, Jan. 1997, pp. 1-8 CA.
`
`
`
`
`
`
`Graham, “Global Market for Heating, Ventillation and Air-Condi-
`
`
`
`
`
`
`
`
`tioning Systems,” ABOUT Automotive —Research Report, 2006
`
`
`
`
`
`
`
`Edition. GB.
`
`
`Ignatio De Alvaro et al., “Market Report, Minisplits,” BSRIA Report
`
`
`
`
`
`
`
`
`No. 18588/5, May 2004.
`
`
`
`
`Emil Milker et al., “Worldwide Air Conditioning,” BSRIA Report
`
`
`
`
`
`
`
`
`No. 19947B, BSRIA Limited, Mar. 2008, GB.
`
`
`
`
`
`
`
`National Technical Inforn1ation Service, U.S. Dept. of Commerce,
`
`
`
`
`
`
`
`Support: Letter from DuPont Haskell Lab to USEPA Regarding
`
`
`
`
`
`
`
`
`Results of Bacterial Reverse Mutation Assay Conducted With
`
`
`
`
`
`
`
`
`1-Propene, 1,3,3,3-Pentafluoro-. Apr. 17, 2000.
`
`
`
`
`
`Morrissey, C.J., “Nearly Azeotropic Mixtures to Replace Refrigerant
`
`
`
`
`
`
`
`12,” From National Aeronautics and Space Administration Contract
`
`
`
`
`
`
`
`
`No. NAS 7-918, Aug. 1992, NASA Tech Brief, vol. 16, No. 8,
`
`
`
`
`
`
`
`
`
`
`
`Item #122. US.
`
`
`
`1234yf OEM Group, “Update: 1234yf as a replacement for R134a,”
`
`
`
`
`
`
`
`
`publighed following MAC (Mobile Air-Conditioning) Summit in
`
`
`
`
`
`
`2008, see pp. 14, 15 and 18.
`
`
`
`
`
`
`PRNewswire, Honeywell’s Low-Global-Warming-Potential Refrig-
`
`
`
`
`erant Endorsed by SAE International Cooperative Research Project,
`
`
`
`
`
`
`
`Internet
`article,
`www.prnewswire .co .uk/cgi/news/
`
`
`
`
`release?id:244472 (Dec. 8, 2008) GB.
`
`
`
`
`Takahashi, “Alternative Technologies for Refrigeration And Air-
`
`
`
`
`
`
`
`Conditioning Applications,”
`Environmental
`Chemistry
`of
`
`
`
`
`
`Chlorofluorocarbon and Control Engineering, (Quarterly Issue of
`
`
`
`
`
`
`
`General Review of Chemistry, 1991, No. 11) JP.
`
`
`
`
`
`
`
`Kenji Tojo, “Insulations Systems and Materials for Hermetic Motor,”
`
`
`
`
`
`
`
`
`
`Latest new refrigerant and insulation system technology, Chapter 7,
`
`
`
`
`
`
`
`
`First Edition, (1996) JP.
`
`
`
`Honeywell International Inc. Response to Notice of Opposition of
`
`
`
`
`
`
`Arkema France and exhibits cited therein.
`
`
`
`
`
`
`Althouse et al., “Basic Air Conditioning Systems, ” Modern Refrig-
`
`
`
`
`
`
`
`
`eration and Air Conditioning, Chapter 19, pp. 679-705. The
`
`
`
`
`
`
`
`
`
`Goodheart-Wilcox Co., Inc. (pub.) (1988) US (previously cited).
`
`
`
`
`
`
`
`Graham, “Global Market for Heating, Ventillation and Air-Condi-
`
`
`
`
`
`
`
`
`tioning Systems,” ABOUT Automotive—Research Report, 2006
`
`
`
`
`
`
`Edition. GB (previously cited).
`
`
`
`Ignatio De Alvaro et al., “Market Report, Minisplits,” BSRIA Report
`
`
`
`
`
`
`
`
`No. 18588/5, May 2004. (previously cited).
`
`
`
`
`
`
`Milker, et al., “Report, Worldwide Air Conditioning,” BSRIA, Report
`
`
`
`
`
`
`
`
`No. 19947B, Mar. 2008. GB.
`
`
`
`
`
`Pollution Prevention Fact Sheet No. 10, Pollution Prevention Pro-
`
`
`
`
`
`
`
`
`
`gram. Federal Programs Division, Managing Controlled Refriger-
`
`
`
`
`
`
`
`ants, Jan. 1997, pp. 1-8 CA (previously cited).
`
`
`
`
`
`
`
`About MACS Worldwide, “Welcome to the Mobile Aire Condition-
`
`
`
`
`
`
`
`
`ing Society (MACS) Worlwide,” webpage printout http://www.
`
`
`
`
`
`
`
`macsw.org//AlVUTemplate.cfm?Section:Home.
`
`Billy C. Langley, “Automotive Air Conditioning,” Refrigerationand
`
`
`
`
`
`
`Air Conditioning, 3d Ed. Prentice-Hall, (1986) Chapter 21, pp. 525-
`
`
`
`
`
`
`
`
`
`553 US (previously cited).
`
`
`
`H. Kruse, “CFC Research Programmes In Western Europe,” Int. J.
`
`
`
`
`
`
`
`
`
`Refrig. 1990, vol. 13 (Presented at the 1989 ASHRAE CFC Tecnol-
`
`
`
`
`
`
`
`
`
`
`ogy Conference, Gaithersburg, MD (Sep. 27-28, 1989). US.
`
`
`
`
`
`
`Bivens et al., “Fluoroethers and Other Next-Generation Fluids,”
`
`
`
`
`
`
`ASHRAE/NIST Refregerants Conference—Oct. 1997.
`
`
`
`
`Smith, New Chemical Alternatives for CFCs And HCFCs, U.S. Envi-
`
`
`
`
`
`
`
`
`
`
`ronmental Protection Agency, EPA-600/F-92-012 (Mar. 24, 1002)
`
`
`
`
`
`
`
`US.
`
`J. Calm and D. Didion et al., “Trade-Offs in Refrigerant Selections:
`
`
`
`
`
`
`
`
`Past, Present, and Future,” ASHRAE/NIST Refrigerant Confer-
`
`
`
`
`
`
`
`ence—Oct. 1977.
`
`
`Denis Clodic, “Automobile Air Conditioning: Environmental Issues
`
`
`
`
`
`
`
`and Future Technical Alternatives,” The globalization of automobile
`
`
`
`
`
`
`
`air conditioning. General review of refrigeration and air condition-
`
`
`
`
`
`
`
`ing, May 2008 (translation).
`
`
`
`
`R. Gicquel, “Thermodynamic Diagrams—Mixtures Used in Refrig-
`
`
`
`
`
`
`eration” FR.
`
`
`Weiss et al., “Current and Projected use of Refrigerants in Europe,”
`
`
`
`
`
`
`
`
`ASHRAE/NIST Refrigerants Conference—Oct. 1997.
`
`
`
`
`
`
`
`30f15
`
`2006 Standard for Sepcifications for Fluorocarbon Refrigerants,
`
`
`
`
`
`
`Standard 700—ARI (Air-Conditioning & Refrigerant Institute),
`
`
`
`
`copyright 2006.
`
`
`J Jones, CJ Morrissey, Nearly Azeotropic mixtures to replace refrig-
`
`
`
`
`
`
`
`
`erant 12, NASA Tech Brie)’, vol. 16, No. 8, Item #122 from JPL New
`
`
`
`
`
`
`
`
`
`
`
`
`
`Technology Report NPO 18033//528, pp. 1-39, Aug. 1992 US (pre-
`
`
`
`
`
`
`
`
`
`viously cited).
`
`
`Kopko, “Beyond CFCs: Extending the Search for New Refrigerants,”
`
`
`
`
`
`
`
`
`Supplied by The British Library.
`
`
`
`
`1234yf OEM Group, “Update: 1234yf as a replacement for R134a,”
`
`
`
`
`
`
`
`
`published following MAC (Mobile Air-Conditioning) Summit in
`
`
`
`
`
`
`2008, see pp. 14, 15 and 18. (previously cited).
`
`
`
`
`
`
`
`
`PRNewswire, Honeywell’s Low-Global-Warming-Potential Refrig-
`
`
`
`
`erant Endorsed by SAE International Cooperative Research Project,
`
`
`
`
`
`
`
`internet
`article,
`www.prnewswire .co .uk/cgi/news/
`
`
`
`
`
`release?id:244472 (Dec. 8, 2008) GB (previously cited).
`
`
`
`
`
`Clodic, Automobile Air Conditioning: Environmental Issues and
`
`
`
`
`
`
`
`Future Technical Alternatives, the New Refrigerant Fluids. (transla-
`
`
`
`
`
`
`
`
`tion) (May 2008) FR.
`
`
`
`
`“Arkema Beefs Up Chemicals; Eyes Acquisition ofAcrylics Assets,”
`
`
`
`
`
`
`Business & Finance News, Chemical Week, Nov. 17, 2008, p. 19.
`
`
`
`
`
`
`
`
`
`Executed Assignment of
`Inventorship for U.S. Application,
`
`
`
`
`
`
`Honeywell Reference US.
`
`
`
`Exeduted Declaration of Inventorship for U.S. Appl. No. 10/837,525,
`
`
`
`
`
`
`
`
`Honeywell Reference. US.
`
`
`
`National Technical Information Service, U.S. Dept. of Commerce,
`
`
`
`
`
`
`
`Support: Letter from DuPont Haskell Lab to USEPA Regarding
`
`
`
`
`
`
`
`
`Results of Bacterial Reverse Mutation Assay Conducted With
`
`
`
`
`
`
`
`
`1-Propene, 1,1,3,3,3-Pentfluoro—. Apr. 17, 2000 (previously cited).
`
`
`
`
`
`
`
`al.,
`et
`“Automobile Air Conditioning,” Modern
`Althouse
`
`
`
`
`
`
`
`Refrigerationand Air Conditioning, Chapter 27, pp. 949-976. The
`
`
`
`
`
`
`
`
`Goodheart-Wilcox Co., Inc. (1988) US (previously cited).
`
`
`
`
`
`
`Honeywell webpage printout, re: Honeywell Genetron Refrigerants,
`
`
`
`
`
`
`“Commercial AC Products,” (Jul. 14, 2010) US.
`
`
`
`
`
`
`Honeywell webpage printout, re: Honeywell Genetron Refrigerants,
`
`
`
`
`
`
`“Mobile A.C,” (Jul. 14, 2010) US.
`
`
`
`
`
`
`Honeywell webpage printout, re: Honeywell Genetron Refrigerants,
`
`
`
`
`
`
`“Genetron 134a,” (Jul. 14, 2010) US.
`
`
`
`
`
`
`OJ Nielsen et al., “Atmospheric chemistry of CF3CF:CH2. Kinetics
`
`
`
`
`
`
`and mechanisms of gas-phase reactions withCI atoms, OH radicals,
`
`
`
`
`
`
`and O3” Science Direct, Chemical Physics Letters 439 (2007) pp.
`
`
`
`
`
`
`
`
`
`18-22 (www.sciencedirect.com) US.
`
`
`
`ANSI/ASHRAE Standard 34-2007 Designation and Safety Classifi-
`
`
`
`
`
`
`
`cation ofRefrigerants, 2007.
`
`
`
`BSR/ASHRAE Addendum 2 zu ANSI—ASHRAE Standard 34-2007,
`
`
`
`
`Public Review Draft, Sep. 2008.
`
`
`
`
`
`M Spatz et al., “HFO-1234yf Low GWP Refrigerant,” Presentation
`
`
`
`
`
`
`given at SAE 2008 Alternate Refrigerant Systems Symposium,
`
`
`
`
`
`
`Scottsdale (AZ), (Jun. 10-12, 2008) U.S.
`
`
`
`
`
`
`V. I. Orkin et al., Rate Constants for the Reactions of OH with
`
`
`
`
`
`
`
`
`
`HFC-245cb (CH3 CL Fluoroalkenes (CH2 CHCF3, CH2 CFCF3, CF2
`
`
`
`
`
`
`
`CFCF3 andCF2 CF2, J'. Phys Chem. A, vol. 101 . pp. 91 18-9 124 (1997)
`
`
`
`
`
`
`
`
`
`
`US.
`
`Wikipedia (the free encyclopedia) entry of Jul. 14, 2010, “HVAC,
`
`
`
`
`
`
`
`
`
`Background, heating, Ventilating, Air conditioning, Energy Effi-
`
`
`
`
`
`
`
`ciency, HVAC Industry and Standards,” http://en.wikipedia.org/wiki/
`
`
`
`
`
`
`HVAC; and of collection of patent applications disclosing HVAC
`
`
`
`
`
`
`
`
`systems in automobiles.
`
`
`Proposal for the Regulation of the European Parliament and of the
`
`
`
`
`
`
`
`
`Council on certain fluorinated greenhouse gases—Aug. 11, 2003.
`
`
`
`
`
`
`Orkin et al., “Photochemistry of Bromine—containing Fluorinated
`
`
`
`
`
`Akenes; Reactivity toward OH and UV Spectra,” J. Phys. Chem. A
`
`
`
`
`
`
`2002, vol. 106, pp. 10195-10199 US.
`
`
`
`
`
`
`Calorix Heat Pumps Ltd., “Energy Efficient Hot Water Heating,”
`
`
`
`
`
`
`
`
`booklet, 4 pages. US.
`
`
`
`Mitsubishi Electric, “Water Heating Units,” (leaflet), (4 pages) GB.
`
`
`
`
`
`
`
`Ivt Heat Pumps, “Greenline,” (leaflet), (2 pages) SE.
`
`
`
`
`
`
`
`Conergy, “Conergy Heat Pump: the Clever Choice for Hot Water,”
`
`
`
`
`
`
`
`
`
`(leaflet), (2 pages) AU.
`
`
`
`
`Dimplex, “Hot watr heat pump with sheet steel casing, air duct
`
`
`
`
`
`
`
`
`
`
`
`connection and additional heat exchanger,” Data Sheet (1 page) DE.
`
`
`
`
`
`
`
`
`
`Honeywell International Inc. “Guide to Alternative Refrigerants,”
`
`
`
`
`
`
`(leaflet), (2 pages) US.
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`3 of 15
`
`

`
`
`
`US 8,065,882 B2
`Page 4
`
`
`Additional Non-Patent Literature Documents Cited in U.S. Appl. No.
`
`
`
`
`
`
`
`10/694,273.
`
`
`Saunders and Frisch, “Polyurethanes Chemistry & Technology,” vol.
`
`
`
`
`
`
`XVI, Part I and Part II Technology, John Wiley and Sons, NewYork,
`
`
`
`
`
`
`
`
`
`NY (1962), pp. 193-201 and 219-223. US.
`
`
`
`
`
`
`
`Downing, Ralph C., “Fluorocarbon Refrigerants Handbook,”
`
`
`
`
`
`Prentice Hall, Excepts from Chapter 3 and Chapter 16. US.
`
`
`
`
`
`
`
`
`
`Additional Non-Patent Literature Documents Cited in U.S. Appl. No.
`
`
`
`
`
`
`
`10/837,525 or 11/847,192.
`
`
`Haszeldine, R. N. et al., “Free-radical Additions to Unsaturated Sys-
`
`
`
`
`
`
`tems. Part XVII. Reaction of Trifluoroiodomethane with Mixtures of
`
`
`
`
`
`
`
`Ethylene andVinyl Fluoride and of Ethylene and Propene,” J. Chem.
`
`
`
`
`
`
`
`
`Soc., Section C, Organic (3), pp. 414-421 (1970).
`
`
`
`
`
`
`
`Henne et al., “Fluorinated Derivatives of Propane and Propylene VI,”
`
`
`
`
`
`
`
`J. Am. Chem. Soc., 68, pp. 496-497 (1946).
`
`
`
`
`
`
`
`
`Kimura, et al., “Poly(ethylene glycols) and poly(ethylene glycol)-
`
`
`
`
`
`
`
`grafted copolymers are extraordinary catalysts for dehydrohalogena-
`
`
`
`
`
`
`
`tion under two-phase and three-phase conditions,” J. Org. Chern.,
`
`
`
`
`
`
`
`
`48,195-0198 (1983).
`
`
`Knunyants I. L. et al., “Reactions of Fluoro Olefins Communication
`
`
`
`
`
`
`
`13, Catalytic DJ Hydrogenation of Perfluoro Oletins,” Bulletin ofthe
`
`
`
`
`
`
`Academy of Sciences ofthe USSR, pp. 1312-1317.
`
`
`
`
`
`EPO Communication in EP Application No. 08011766.6, Filed: Oct.
`
`
`
`
`
`
`
`25, 2004, Applicant: Honeywell International Inc., Re: Third Party
`
`
`
`
`
`
`
`
`
`Observations filed Feb. 18, 2011 by Potter Clarkson LLP on behalfof
`
`
`
`
`
`
`
`
`
`anonymous third party. (EP).
`
`
`
`
`Patent Owner’s Response to the First Office Action Mailed Dec. 22,
`
`
`
`
`
`
`
`
`
`2010, filed Mar. 21, 2011. (in In re Reexamination Control No.
`
`
`
`
`
`
`
`
`
`95/000,576, Filed Oct. 5, 2010 for U.S. Patent No. 7,279,451).
`
`
`
`
`
`
`
`
`Declaration of Rajiv R. Singh filed Mar. 21, 2011. (in In re Reexami-
`
`
`
`
`
`
`
`
`
`nation Control No. 95/000,576, Filed Oct. 5, 2010 forU.S. Patent No.
`
`
`
`
`
`
`
`
`
`
`7,279,451).
`
`(as attached to
`Exhibit A—Raj iv Ratna Singh-U.S. Patents,
`
`
`
`
`
`
`
`
`Declarationof Rajiv Ratna Sing, filed Mar. 21, 2011 in Patent Own-
`
`
`
`
`
`
`
`
`
`
`er’s Response to the First Office Action dated Dec. 22, 2010 in In re
`
`
`
`
`
`
`
`
`
`
`Reexamination Control No. 95/000,576, Filed Oct. 5, 2010 for U.S.
`
`
`
`
`
`
`
`
`
`Patent No. 7,279,451.)
`
`
`
`Exhibit B—Rule 132 Declaration of George Rusch, dated Oct. 15,
`
`
`
`
`
`
`
`
`
`2007 and Rule 132 Declaration of George Rusch dated Apr. 25, 2007
`
`
`
`
`
`
`
`
`
`
`
`(as attached to Declaration of Rajiv Ratna Singh, filed Mar. 21, 2011
`
`
`
`
`
`
`
`
`
`
`in Patent Owner’s Response to the First Office Action dated Dec. 22,
`
`
`
`
`
`
`
`
`
`
`
`2010 in In re Reexamination Control No. 95/000,576, Filed Oct. 5,
`
`
`
`
`
`
`
`2010 for U.S. Patent No. 7,279,451.)
`
`
`
`
`
`
`Exhibit C—European Centre fro Ecotoxicology and Toxicology of
`
`
`
`
`
`
`
`Chemical (ECETOC), “Toxcity of Possible Impurities and By-prod-
`
`
`
`
`
`
`
`ucts in Fluorocarbon Products,” Technical Report No. 103, (pp. 1 to
`
`
`
`
`
`
`
`
`
`186), ISSN-0733-8072-103, Dec. 2008, Brussels, BE.
`
`
`
`
`
`
`Exhibit D—Translationof JP Patent Application H4-110388, pub-
`
`
`
`
`
`
`lished Apr. 10, 1992 (“Inagaki”).
`
`
`
`
`
`Exhibit E—Denis Clodic, “Automobiel Air-Conditioning: Environ-
`
`
`
`
`
`
`mental Stakes and Future Technical Options,” Journal of Cold and
`
`
`
`
`
`
`
`
`
`Air-conditioning, May 2008, original and certified translation, pp.
`
`
`
`
`
`
`
`
`47-52. FR.
`
`
`Exhibit F—Natasha Alperowicz, “Arkema Beefs UpChemicals; Eyes
`
`
`
`
`
`
`
`Acquisition of Acrylics Assets,” Chemical Week, Nov. 17, 2008, p.
`
`
`
`
`
`
`
`
`19.
`
`Exhibit G—Industry Presentation, MAC Summit 2008, 1234yfOEM
`
`
`
`
`
`
`Group, “Update: 1234yf as a replacement for R134a,” pp. 1-20).
`
`
`
`
`
`
`
`
`Exhibit H—Paul Weissler, Ed., “EPA presses for fast switch to NC
`
`
`
`
`
`
`
`
`
`refrigerant R-1234yf,” Automotive Engineering International
`
`
`
`
`
`Online, Apr. 7, 2009, http://www.sae.org/mags/aei/6137.
`
`
`
`
`Exhibit I—“GM First to Market Greenhouse Gas-Friendly Air Con-
`
`
`
`
`
`
`
`
`ditioning Refrigerant in US,” Jul. 23, 2010, online article at www.
`
`
`
`
`
`
`
`
`gm. com/corporate/responsibility/environment/news/20 10/air_con-
`
`
`
`
`
`
`
`ditioning_refrigerant. US.
`
`
`“First-Calss Air
`J—Réne Muller,
`Exhibit
`
`
`
`
`AutomobilKONSTRUKTION, Feb. 2009.
`
`
`
`Exhibit K—“SAE Endorses Honeywell Refrigerant,” Refrigeration
`
`
`
`
`
`and Air Conditioning Magazine (RAC), Jan. 2009.
`
`
`
`
`
`
`
`Exhibit L—“EPA Approves New Coolant for Car Air Conditioning
`
`
`
`
`
`
`
`
`
`Systems/Better climate protection without harming the ozone layer,”
`
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`
`
`
`
`
`
`EPA: United States Environmental Protection Agency, Release date:
`
`
`
`
`
`
`
`
`Feb. 28, 2011.
`
`
`
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`Conditioning,”
`
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`
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`
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`* cited by examiner
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`
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`
`
`
`
`
`
`
`
`M Tekeuchi et al., “An Environmentally Friendly, Highly Efficient,
`
`
`
`
`
`
`
`
`Lightweight Scroll Compressor (QS90) For Car Air Conditioners”
`
`
`
`
`
`
`
`
`Mitsubishi Heavy Industries, Ltd. Technical Review, vol. 45, No. 3,
`
`
`
`
`
`
`
`
`
`pp. 24-26 (Sep. 2008) US.
`
`
`
`
`
`New Refrigerant Insulating System Technology, pp. 75-78 (Apr. 15,
`
`
`
`
`
`
`
`
`1996).
`
`The Properties of Gases and Liquids, Poling et al, 2001, excerpts
`
`
`
`
`
`
`
`
`
`from chapters 2, 3, 4, 6 and 7.
`
`
`
`Discussion on Modelling of Properties.
`
`
`
`Fundamental Equation of State for 2,3,3,3-Tetrafluoropropene
`
`
`
`
`
`(HFO-1234yf) Ryo Akasaka et al. (HFO-1234yf Property Sheet).
`
`
`
`
`
`
`
`Opposition 1—Arkema France (translation).
`
`
`
`
`Opposition 1—Arkema further opposition documents (translation).
`
`
`
`
`
`
`Opposition 2—Daikin Industris Ltd (translation).
`
`
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`
`
`Opposition 3—Asahi Glass Company Ltd.
`
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`
`
`Opposition 4—Daimler AG.
`
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`
`Opposition 5—ACEA European Automobile Manufactures Associa-
`
`
`
`
`
`
`tion.
`
`Opposition 6—Anonymous.
`
`
`Opposition 7—Bayerische Motoren Werke AG (translation).
`
`
`
`
`Opposition 8—Mexichem Amanco Holdings SA.
`
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`Opposition 9—Solvay Fluor GmbH.
`
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`
`
`Observation 10—Potter Clarkson LLP, Third Party Observations to
`
`
`
`
`
`
`
`EP Patent Appl. No. 05744161.0, filed by lnneos Fluor Limited, Feb.
`
`
`
`
`
`
`
`
`
`
`26, 2009. EP.
`
`
`
`Observation 11—Anonymous—Filed by Arnason/Faktor, Intellec-
`
`
`
`
`tual Property Consulting, Reykjavik, Iceland, Dec. 9, 2008. IE.
`
`
`
`
`
`
`
`
`Observation 12—Anonymous—Filed by Dr. Modiano & Associates,
`
`
`
`
`Milano, Feb. 26, 2009. IT.
`
`
`
`
`
`Tarrant, et al., “Free Radical Additions Involving Fluorine Com-
`
`
`
`
`
`
`
`
`
`pounds.
`IV. The Addition of Dibromodifluoromethane to Some
`
`
`
`
`
`
`
`Fluoro06letins,” J. Am. Chem Soc., 77,2783-2786 (1955).
`
`
`
`
`
`
`Kunshenko, B. V. et al., “Reaction of Organic Compounds with
`
`
`
`
`
`
`
`
`
`SF4-HF-Halogenating System VII. Reactions of Oletins with the
`
`
`
`
`
`
`
`
`SF4-HF-CI2(Br2) System,” Odessa DM Polytechnicallnstitute,
`
`
`
`
`
`Institute of Organic Chemistry, Academy of Sciences c the Ukraine,
`
`
`
`
`
`
`
`Kiev., Translated from Zhuranl Organicheskoi Khimii, 28(4), 672-80
`
`
`
`
`
`
`
`
`(1982), Original article submitted Aug. 24,1989.
`
`
`
`
`
`
`Additional Non-Patent Literature Documents Cited in U. S. Appl. No.
`
`
`
`
`
`
`11/475,605 and Divisionals Thereof.
`
`
`
`
`Database WPI Section Ch, Week 199221 Derwent Publications Ltd.,
`
`
`
`
`
`
`
`
`London, GB; Class E16, AN 1992-172539.
`
`
`
`
`
`Additional Non-Patent Literature Documents Cited in U.S. Appl.
`
`
`
`
`
`
`Nos. 10/837,526; 11/119,053; 12/198,411.
`
`
`
`
`Written Opinion of International Search Authority for PCT/US2005/
`
`
`
`
`
`
`14874.
`Albert W. Noyes, Editor, the Journal of the American Chemical
`
`
`
`
`
`
`
`
`
`Society, vol. LXXVII; Apr.-Jun. 1955 pp. 3149-3151. US.
`
`
`
`
`
`
`
`
`Additional Non-Patent Literature Documents Cited in U. S. Appl. No.
`
`
`
`
`
`
`11/474,887 and Divisionals and Continuation Thereof.
`
`
`
`
`
`
`Jan H. Schutt, Polyurethane Foam Industry Prepares for ‘Zero ODP’,
`
`
`
`
`
`
`
`
`
`Plastics Technology—Internet article (http://www.plasticstechnol-
`
`
`
`
`ogy.com/articles/199911 fa3.html).
`
`
`Perry Romanowski, “Polyurethane, How Plastics Are Made,” Gale
`
`
`
`
`
`
`
`Edit, Volumes-Polyurethane. US.
`
`
`
`Additional Non-Patent Literature Documents Cited in Parent U.S.
`
`
`
`
`
`
`Appl. Nos. 10/695,121 and 11/,385,259.
`
`
`
`
`
`International Search Report for PCT/US04/35132 (corresponding
`
`
`
`
`
`U.S. Appl. No. 11/385,259).
`
`
`
`
`Observation
`13—Anonymous—Anonymous—Filed
`
`
`Modiano & Associates, Milano, Apr. 2, 2009. IT.
`
`
`
`
`
`
`English Translation of Official Action in Connection With Corre-
`
`
`
`
`
`
`
`
`sponding Japanese Patent Application No. 2004-547148.
`
`
`
`
`
`
`Response to Japanese office action (not translated) and English lan-
`
`
`
`
`
`
`
`
`
`guage translation of claims as amended.
`
`
`
`
`English Translation of JP Anonymous Submission of Prior Art Ref-
`
`
`
`
`
`
`
`erences to Opposition to JP Application No. 2004-547148, dated Jun.
`
`
`
`
`
`
`
`8, 2010.
`
`
`Notice of Allowance in JP Application No. 2004-547148 (not trans-
`
`
`
`
`
`
`
`lated) and allowed claims.
`
`
`
`
`Reexamination Request—451 Patent.
`
`
`
`Reexamination Request—805 Patent.
`
`
`
`
`by
`
`
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`Dr.
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`40f15
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`4 of 15
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`US 8,065,882 B2
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`1
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`COMPOSITIONS CONTAINING FLUORINE
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`SUBSTITUTED OLEFINS
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`RELATED APPLICATIONS
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`The present application is related to and claims the priority
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`benefit of each of the following U.S. Patent Applications:
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